河北省各地2022-2023学年化学高三上期中联考模拟试题（含解析）

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2022-2023
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a-ᵬ̹Í5nὊÏÐABS᪛ᾦḄT]ᓫÔÕJᵫ·¸¹ÖᓄῃØÙᑮᑏÛᵫ·¸¹ᑴÜÝᓫḄÞT]`2஺ßᔠᡂàáâᵨḄ⊤`NybAKᑺAB……TUVᑺAµ᪗nᱥ³ᩩÂ2022-2023MæçèéKᔁëὃíᫀß²îï³᪆ñTஹ⌱ò⚪ßᐳᒹö22÷⚪஺ø⚪ᙳúᨵT÷ûᔠ⚪üḄ⌱⚗ñ1ஹAூ⚪µî³௃A⚗ஹ⏚Ḅᜧ⏚ᔣ⛳⏚ᐭḄᓄ᪆⏚ᨔ!"#ZNa+fCCh'+CCh+UzOuZNaHCCh],ᦑA&'(B⚗ஹ⏚ឋ*+,ᙠᜧḄ᪷ᦑB┯0(C⚗ஹᓄ1ᐹᨵ45ឋ67⏚┛ᐹᨵᓄឋᓄ1967⏚┛:;ᓄ45<=*>:;?ᑖ<=ᦑC┯0(D⚗ஹABCᮞE>ᓄ┛Ḅ⛳ᓄ┛>FGᙠHᐰᵯKᑏ!"M*ᵨᓄO"⊤Q=RᑏᦑD┯0(ᦑ⌱A஺ூVᫀXY௃ABCᮞE>ᓄ┛Ḅ⛳ᓄ┛>FGᙠHᐰᵯKᑏ!"M*ᵨᓄO"⊤Q=RᑏCᮞ[>ᓄ┛\]Kᑏ!"MᵨᓄO"⊤Q*Rᑏ஺2ஹDூVᫀ᪆௃&^_Ḅ⊈aGឋᡠcde>"஺஺3-ḄE!ᜧᵯ!⌱⚗A&'஺_⊈⏚hM+ijNa"C°3k⚪mḄn⊝⌮ᔣqrsὑcu⏚h⌱⚗B&'஺w⊤xᑮ:C|”2C03=C|"CO3-MpH=6.10,#kpH=7,=ᐭd⏚᪷ᡠc⌱⚗C&'஺ᙠpH=7.40Ḅ⊈|aGឋ

11⏚᪷Ḅ>⏚Ḅ20,#⏚᪷⏚ᜧᡠca⏚Ḅឋ|Gឋ”஺3dḄE!஻2஺஺3Ḅᵯ!Ḅᜧ⌱⚗D┯0஺3ஹDூ⚪m௃Aஹᵨ⏚9MnhᔠᑴCL,ᵫ⏚ᐹᨵᢵ:ឋᙠCL¢ᨵᩖHC1¤E¥¦ᐜ¨D©ª◀¬HC1,¨A©ª◀¬E¥¦xᑮ®¯°±Ḅ7¦ᯠ³¨B´µCL>ᔲᐹᨵ·¸ឋ¨C´µ¹ºḄ7¦ᐹᨵ·¸ឋᵫ7¦»¼½ᜧ¦¾¿Àᨬ³¨NaOHÂÃĦᜐᳮᦑkᵨḄ©ªḄᐜ³ÇÈ#DABCE,ᦑA┯0Bஹ᪷ÉA⚗ᑖ᪆+Ê©ªËÌÇÈÍ6##DABCE,ᦑB┯0(Cஹ©ªEḄÎ⌕ᵨ⌶>ᔾᦈÓḄ7¦■Õ¾¿Ö¦ᦑC┯0(Dஹᵫ©ªB×Ø+ᑨÚCL·¸ឋºÛᨵ⁐Ýᩩß⁐>7¦9E<=;ᡂḄHC1OáâḄᦑD&'(Vᫀ⌱D஺4ஹBூVᫀ᪆௃ã⚪ᑖ᪆äAஹ┠Ḅæçèrឋ╅FᦑA┯0(BஹêÊëÖì┠Ḅ5ᳮ᝞îä2RbCl+MgwS4MgeL+2Rb|¦ᩩïî;ᡂᱥRb#¦᝱ò┠¥¦óᑣõö÷;ᡂᱥḄn⊝ᔣ&ᔣqrᡠc<=+c*Úᔣ;ᡂRb|¦ᔣÂÃᦑB&'(CஹMgCLçᨔஹRbçæçᨔRbᰚXùᡠc7ᓄ╅ᰚXúRb,ᦑC┯0(Dஹ┠ḄᓫᓄOឋèüᓫý᝱*᝞ᓄᔠ᝱þe.ᦑD┯ᦑ⌱B஺ὃὃḄஹ⊝ᳮḄᐵ஺5ஹCூᫀ᪆௃Aஹ!"!#$%17gᵬ'()MCHAḄᱥ+Ḅ,-Imol,Imol.ᵬ'/0ᨵ8moi/2%ᡠ0Ḅ/2ᦪ-8NA,ᦑA56B.78ᔠᡂ;<=⌮?@%A78ᔠᡂ;B%CDᡂImolNMEḄᵯ2ᦪG-3NA,ᦑB56C.CO32)

12ᑖ2ᩞᧇ%ᦑB56C.©^ᓄgஹ©^ª⏚ஹª⏣¬®Ḅ+ឋᜫ±Dᳮ²ឋ³ᑮµGḄ%ᦑC┯D.¶·“84”µNW¸ᔓᮣ(⌕ᡂᑖ?ᓄ═ᑴᜓMnCLUMO,ᙠᓄḄB%CD஺Eᫀ⌱C஺10ஹCூEᫀ7᪆௃A⚗PM2.5"ᢣMN;Oᜧ+2.5pmḄQᔾᐭST⚩NᱥB⚗W⁐ᓄY⌕Z[\ᜮ^_◀ᡈabcdefg᛻ḄijC⚗k᯼=ᐭbmᮞQoap⏚r⏚sḄtᡂvwᳮy2CaO+2SO+O=2CaSO
,zᙠ=9{bmᮞ:ᔾᦈCO2,:aḄ᣸~:a!Ḅ᣸~┯224

13D⚗ᜩᯠ(⌕ᡂᑖyCHQᓄm(⌕ᡂᑖyC3H8ஹC4HQ"ᡃᵨḄkᧇEᫀ⌱C஺11ஹDூEᫀ7᪆௃A.᪷“ᐭ,Ḇᓄஹᓄ,”ᑨ“,”⌕ᡂᑖ"⏚ᦑAB.“¡¢᮴,¥ᢚᑖ§¨”"ᢣW©ῃ,ᦑBC.“┡
¬®¯”°±²>✂Ḅ3´ᦑCD.“ᐭ,Ḇᓄ”"ᢣµ+⏚3´cbḄ!⌕"¶Ḅ)ᓄᱥᦑD஺ᦑ⌱D஺12ஹDூ⚪¸7௃A.¹ºQoᵨ»¼⏚⏚½ᑴ᪷¾᝱À☠ÂÃÄwᑣK37C1O+6HC1=37CI-C13+2CLT+3H2O+KCLA┯B.Na2s2஺3=ᐭÆp⏚ÇS2O32-+2H+=S+SO2T+H2O,B┯C.()ᓄpÈᐭᓄÉÊËÌbᡂC┯D.10mLImol-L-1KA1(SO02Í7.5mL2moiL-iBa(OH)2,n[KAl(SO4)2]
n[Ba(OH)]=2
3,ᑣ2Al3++3SO2-4-246OH~+3Ba2+=2Al(OH)3i+3BaSObD4EᫀyD஺ூEᫀÎÏ௃¼⏚⏚½{᪷¾᝱À☠ÂÃÄwᑣᵫC137clÑᡂ஺13ஹCூ⚪¸7௃A.p>Ḅ:ᜧ+ÒÓḄpÔÒÓḄp>pÔᑖÕÖᐰkØὅ~'9ÚᦑA┯B.ÆH+(aq)+OH-(aq)=H2஺পA//=-53.7kJ-moF1,Ü¡Ý1molH2SO4ḄÆÍÝ0.5molBa(OH)2ḄÞᔠᵫ+ᨵp⏚áËÌbᡂ~'Ḅ9ᑣᜧ+57.3kJ,ᦑB┯C.:âãâä¯C(mås)=C(æms)A"=+1.9kJmoir,çèmåéæmä¯ᦑCD.X(g)+Y(g)UZ(g)//>(),ឤឤëᩩ
íᑮï⊝ñ=ᐭX,ï⊝ᔣóe,ô!!öᦑD┯⌱C஺14ஹDூᑖ᪆௃AஹBஹCஹDy&ᕜøᑁw6úOûüýᜧḄᐗÿXஹYஹMஹNᑖᵫᐗᡂḄᐗᓄᔠᱥᵬஹᐸᐗḄᓫ஺ᙳ⁐"#ᑣᓫS,ᓄᔠᱥNazO2,%N&'ᡂᓫᵬᑣᵬ02,()*᥅,-ᙳ32g/moL.ᔠ⚪0஺1X⏚&'ᡂM,M)*&'(N,345MH2S,NH2O,XNazS,ᦑAHᐗஹBOᐗஹCSᐗஹDNa஺ூ⚪89:௃A.ᵫᑖ᪆35NH2O,=>?ᑗ'ABCᦑADEFB.ᵯHIJ᪀LMḄNH,᪶ᵯ₹ᦪSᜧNHUVSWNHᵯHISXNHUVSᜧᦑNHUVS2>O2>Na+>H+,ᓽ

14AN,=ᑖH\]ᙠ_`abcdH2sḄab[M=ᵯNḄᡠÆ~=ᵯNḄ_NHo¿LÈ,e>lO^mol/L,ᦑA┯l;B.ঝpH=12ḄHC1~sᓄ_Ḅo¿O.Olmol/L,¨ঞpH=12ḄÁ=Á=o¿ᜧd0.01mol/L,È#ÉḄ~Ðᔠ,Á=-,Ñ~ÒÓឋ,ᑣp⏚Ḅ#ÉᜧdÁ=ᓽ:ঝᡠÆB┯lC.জpH=2ḄCHCOOH~Ç⏚o¿ᜧd0.01mol/L,¨ঝpH=2ḄHC1~sᓄ_Ḅo3

15¿O.Olmol/L,È#ÉḄ~Ç⏚ḄᱥḄ-ᜧdsᓄ_,Ö&×,Ç⏚'ᡂḄ_*X,ᡠÆCDE;D.º~ḄpH?Øᜧd⏚~ḄpH,ঞஹটḄpHᜧdজஹঝḄ;ঞpH=12ḄÁ=ºË̾ᵯN¾¿Íᜧ~_)᪷NHḄᱥḄ-ᜧdট,Ë̪~ḄPHঞ>ট;¨জpH=2ḄCH,COOH~Ë̪~_NHo¿ᜧdঝ~ḄpHজ<ঝ,ᡠÆᑖᔣÈ#ÉḄ~u=ËÌÜ10(ݪ,~ḄPH:ঞ>@>ঝ>জ,ᦑD┯l;ᫀ[Coூᫀb௃⚪ὃ»~⏚ºឋ~pHḄÞßஹÂᵯ:ḄᵯNà⊝,⚪8¥¿È,â0ã¢~pH~⏚ºឋḄᐵäåEæçÂᵯ:ᵯNà⊝Ḅè;D᧕┯b,â0~pH_NHo¿ᐵä஺18ஹCூ⚪89:௃KNChÐᨵNaClêëKN(h,°ìíe~d=îïðJᨔ.èKNO3Ḅ~:¿òð¿Ḅᓣc¨ᓣcNaClḄ~:¿òð¿Ḅᓣc¨ôåÒõõᓄ.ᑣᨵö÷I>ᙠøùu=~:ö÷II>úyoûüᑮcð¿þḄKNCh⛳
DIᓾᨔᑭᵨ
KNChᨔ᪆KNO.,ᨔᦑ⌱C஺19ஹDூ"ᫀ᪆௃A.%&ᑖ()*ᙠḄ-%%./%&Ḅᵯ(1:N?
N
A⚗┯56B.7ᓄ9:(ᓄᔠᱥNaCl7ᓄ9Ḅᓄ=1>*ᙠ7ᓄ9ᑖ(B⚗┯56C.᪀1)>◤⌕᪗Cᡂ/ᵯ(%&Ḅ᪀1N.N,C⚗┯56D.EF(ᨬ᜜I6Jᵯ(ᐸ)2sL⍝ᨵ2Jᵯ(2pL⍝ᨵ4Jᵯ(EF(Ḅᨬ᜜IL⍝⊤P1QᔣA?0⚗ST"ᫀ⌱D஺20ஹAூ"ᫀ᪆௃AஹO—aUVWḄ:(XYFe2++2OH-+Ba2++SO4*=BaS(M+Fe(OH)2bZFe?+[\]ᐰ_[\`WḄabcdefghᡠjahkYḄ
l(NH஺2so4,ᦑAST6BஹmḼBa(OH)2
ḄpᐭN%+stXYa—bUḄXY2NH4++2OH-+SO4”+Ba2+=BaSO41+2NHbH2O,ᦑB┯56CஹbhkYḄ[\BaSO4Fe(OH)2,uv0.3mol,ᦑC┯56Dஹᑮbhx
)Ḅ:(yzXY{|}x~ὑḄBa(OH)2
Ḅ200mLᦑchᜧ200ml,ᦑD┯5஺"ᫀ⌱A஺21ஹBூ"ᫀ᪆௃A.┱T&Ḅᡂfᓄ=XY)ḄlvឤkefᐭḄẆf

16ḄᳮᦑAST6B.⍝F(=t¡fᑖ(=ᦑB┯56C.¢£ᓄ=¤¥ᣩᑡ¨Vefᐗªᕜ¬®¯ᑴᐗªᕜ¬⊤ᦑCST6D.±²ᱯᑡVefᓄ=´⊝¶·FᳮᦑDST6ᦑ⌱B஺22ஹBூ"ᫀ᪆௃¸ᱥlḄᡂᩭᑖ᪆ᱥlḄᑖº¸XYᱥWᡂᱥ»ºᑖ᪆XYḄº¼¸Fᵯ½Fᳮᩭᑖ᪆¾¿■ῖḄFᳮ஺ூ⚪ÃÄ௃ᵯ:Ḅ▢:(ᐰÆ-ÇE᪷Ḅᓄᔠᱥ¿ÉÊÉ-ËWÌᮞ¿ÉឋEᓄᱥᦑA┯56ÏÐ-ÑÒᑴ⌼Ḅ╨ÕÖᙽ-ᑭᵨFᵯ½ḄFᳮkÙÚÖÛÒÜÝᐜßῖ⇨ᦑBST6Ïá)
ᨵ7ᓄ9¸)âã7ᓄ9-ᱥᳮäᓄᦑC┯56åᣚXY-ᓫlèᓄᔠᱥXYWᡂḄᓫlḄᓄᔠᱥᐝᔠᵨ-êEᓄëáḄXY>-åᣚXYᦑD┯5஺ᦑ⌱B஺êஹì⌱í⚪îᐳ84ᑖð23ஹᵬòCHN0óyôyõFXY77292ூᑖ᪆௃ökᑖ(lv92Ḅ÷ø✏hX-ú»û⌕ḄᨵüᓄýFᧇÿᑖ
ᡂCxH”ᑣ■=7-8,ᵫC
H
ᐵC
ᦪ7,ᦑ✏XḄᑖ
C7H8,᪀!"⏚ஹ%&ᩩ()!*⏚+,-./0,ᡂE,ᔠGḄ᪀EE2ᓄ,ᡂF,ᵫ456᧕8COOHCOOH9ᓄᵫ/0:;Iஹ/0:;IIF5NO2&NH2+,/0,ᡂ<<=>ᑖ
ᓄᔠᱥᦑ<Ḅ᪀H஺

17YCOOHூ⚪\]"௃প`abcᑖ᪆eXIIᵬ)gG(/yNHz)ḄᑖTUᡂY,TUটḄᓄᑡᩩ=জᨵ)gঝ+,nOogঞImolᨵ0ᱥO2moiNaHCChᐰTUAᨵ5ts஺᝞sI-COOHஹ-CHzCOOH,ᨵ¡3,9᪀=᝞sI-CH(COOH)2,ᨵ1,9᪀g᝞sI5-COOHஹ+5-CH3,5-COOHI¢£¤ᨵ2,7ᑖ'᪀;᝞5-COOHI¢£¤ᨵ3,7ᑖ'᪀g᝞5-COOHI¢¡£¤ᨵ1,7ᑖ'᪀gᡠb¦ᔠᩩḄᨵ10,ᦑiᫀI10;fH2clHOCHOHCHCI22(6)b)IᧇᑴᜓrS,Jஹᙠªᓄ«⏣®ஹ¯°ᩩ>±²³TUᡂ„µ±CHpH1ᔠᡂTUº»I:¯ᡂTUᡠ¶·ᱥᙠªᓄ«¸®M±¸"TUᡂCH2CIÀ2Br\^CH2BrHO_CHOH2X.NaOH/⏥NaOH/HzOQ,ᦑiᫀIU¿¿CHCICH622Brx.CH2BrHOyCH20HNaOH/⏥60NaOH/H2O0¿¿ூiᫀÂ௃Ã⚪ὃÅᨵ0ÆÇ஺Ã⚪ḄÈIযMᔠᡂÊËḄÌÍNbÎᵨÐᔣᡈ⌮ᔣBÓÔÌÍᐵÕ*ÖsḄ×ᐭLÖsᦪ\ḄᦋÛB⌕ÜÝᓴßᙠÖs×ᐭMḄàᵨ஺24ஹá⏚árrᓄ()TUCHCHO+2CU(OH)4CUOI+CHCOOH+2HO3I232⏥ᨵẈé⁐ëìᡂC1CHCHC1+KOH^CH=CHC1+KC1+HO66íÕ2222

18Cu,O,îᑴ஺(OH),CH3cH20HfCHCHOfCHCOOH33ூCᫀE᪆௃iH⏣H⏚/0,ᡂᨵK✏ᕡḄᱥMᐸOPH⏚HQ/0RSTQᓄ/0ᡈ-./0;2/0ডTXY8Z9ᓄ[9ᓄ/0Ḅᓄ\]^TCH3cHO+2Cu
OH,3CuC2J+CH3co0H+2H?0,_`abTᨵẈd⁐fg,ᡂh3/0ঞᵨKOHḄH⏣klᜐᳮopHᑴpHrḄ/0sTtu/0]^C1CHCHC1+KOHTCH=CHC1+KC1+HO஺v4x2222y4Hrᡠ{|}ḄOPT~~h54Hrᔠᡂ4Hr+,%/0/0Ḅᓄ\]^T஺(6)H⏣4Hrᧇᔠᡂᨵᱥ✌ᐜᨵH⏚Cu,Oîïu(OH)r2ᐸᔠᡂCH3cH20HTCHCHOT-CH3coOHஹ3¿A⚪ḄTᔠᡂᨵᔠᡂḄᐜ⌕ᧇḄ᪀ᨬᱥḄ᪀|}+,

19ᦋ~
¡ᦪTᔲ+,ᓄ£᪷¥|}ḄឋM§¨஺©ªᱥMḄᔠᡂ«/0¬^◤ᑏ°ᐵḄᱥM±/0ᩩ(ஹ²ᵨḄᱥMᧇᯠ´§¨⌲¶·¸¹º/0ᱥᑮ᪗ᱥ஺25ஹ⛳¾¿ÀZ9ᓄÁklᐵÂᑖlÃᧅÅÆÇÈG%ÀÉ&Aᜐ⏀ËÌÈᨵÍÎ,ÏÐ%&Ñᓾ´ÓÔÕᡂÖ×ÀØAÙÚÛÍ■ÐÝ8ÛÍ9ᓄ,ÞßᡈÞdᡈÞ⋎⁐ḄáAᓰãFe(OH)3MnO+4HCl(!)MnCh+ChT+lHzO2Fe+3cLð2FeCb2ூCᫀE᪆௃(Dᑴ-åæçèḄCL,ATCL+,éêCஹDÍëæᓄéêᐜᵨ⛳¾¿À◀pᓄZ£ᵨ!"⏚çèpÍᨵí■ÐîïÛÍᵨZ9ᓄÁklᔾᦈòÍᡠCḄóᑺT⛳¾¿ÀGḄóᑺTZ9ᓄÁklh(2)জö÷ÍøឋḄ]ùᐵÂᑖlÃᧅÅÆÇÈG%ÀÉ&Aᜐ⏀ËÌÈᨵÍÎ,ÏÐ%&Ñᓾ´ÓÔÕᡂÖ×ÀØhঝûᜐ⏀ËÌ0ᐜãAᜐḄTÙÚÛÍ■ÐÝ8ÛÍ9ᓄhঞEᜐ/0,ᡂüFeCb,FḄab,ÞßᡈÞdᡈÞ⋎⁐ḄáGý°aFe(OH)3fgh(3)A+,/0Ḅᓄ\]^MnO+4HCK!)AMnCl+CLT+2HOE+,/0Ḅᓄ\]^2Fe+2223cLã2FeCb஺26ஹᑭᵨ!"⏚ḄᔾÀឋ²/0ᔣᨵᑭᡂḄᔣNaOHdbஹdNa2cChᑖᜧḄᔠᱥNa2sChᐜ!"⏚$ᨵ%HBr&ᡂ'HBrᢵ)$⌼ᡂHBrḄ+ὑூᑖ᪆௃(1)⏣ᙠ!"⏚23ᓄᑺஹῃ7ᑺḄᩩ9:;<ᓣ>?170C@ᑮ'BCD@⌮BC'!"⏚Fᐹᨵᔾ7ឋJ(2)⏣ᡂḄBCK'!"⏚23ᓄᑺLῃ7ᑺ'!"⏚FᨵMNᓄឋ'O⏣)NᓄFPBC'QRSᱥKᨵ@TUᙠSO2,$VḄWX⌼ᡂY᡾'⌱\]Nᓄ^ᔾᦈSO2O`7)ᡂBCᡂ1,2—bcd'eRᑖ᪆fJ(3)ᵬhijBCjkl'himᵨopqr'sBCtuvwSᱥ'xBCyᐙᑖJ(4)ᑖ{|S}⏚~ஹ⏚L⏣Ḅᔠᱥᐭ⛳LḄ⏚^'ᔾᦈᢵ)Ḅ⏚L⏣'⏚~Ḅ'ᑖ@ᐸᑖ{'ᑮḄ⏚~uvᓽ@J(5)ᢥᫀজLঝW'Sᱥᨵ⁐'ᵫᨵᓫᡂ'7t⁐JᫀঝK¡!"⏚ᐭ¢ᓄ^'$ᨵHBrᡂ'HBrᐹᨵᢵ)ឋ'$xHBr+ᜫ஺ூ⚪¦§௃(1)⏣ᑴwḄFᡂ7'!"⏚ᙠBCK23ᓄᑺLῃ7ᑺ'!"⏚Ḅᵨ©ªª«¬2D3ᓄᑺḄ®ᵨ©'PQ¯!"⏚Fᐹᨵᔾ7ឋ'BCᡂḄ7°!"⏚ᔾᦈ'xBCᔣᨵᑭᡂḄᔣ;

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21(2)NaHSO3K'HSCV{ÐUᙠḄÑ⊝ᨵ¯ᵯ{Ñ⊝HSO3pH++SO3%7Ñ⊝HSO3+lhOWlhSCh+OHஹ⏚ឋ»Ï"⏚]᪷{ÐḄᵯ{Õᜧ7Õ'ᦑfᫀD¯HSO3-{ÐUᙠḄÑ⊝ᨵ¯ᵯ{Ñ⊝HSO3-UH++SO3*,7Ñ⊝HSOj+HzOUH2so3+OH-,QDÏ"⏚]᪷{ÐḄᵯ{Õᜧ7Õ'ᡠ×⏚ឋJ(3)pH=10NaOHK⁐Ùì⁐'XØWᩩ9:]N᪷{ÐV}·⁐ÙSY᡾'ᦑfᫀD¯XØWᩩ9:]N᪷{ÐV}·⁐ÙSY᡾J(4)W¯SO2ᑖöᐭ0.1%}7L0.1%}⏣K஺÷øᑮùὅ·⁐ÁtὅÙ·⁐஺»x}·⁐ḄãäÙSO2i᪷eWbḄabc@û'a.0.1mol/LSO2(pH=2)Ká⌕ÆᨵSO2LH2sCh,⌲ýìþ'ÿ90s
ᐰ⁐b.O.lmol/LNaHSCh(pH=5⌕ᨵHSOGᓽ15s
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