2022-2023学年海西市重点中学化学高三上期中监测模拟试题（含解析）

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2022-2023
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13B.âãḄNa2sä=åæç⁐UVywu}~è¹ᓄᑺ¹ᓄéuᓫ6lᑁzᨵ¹`ᐹᨵ¹ᓄឋ.ëà¹ᓄuèªìᦑB┯C.âãḄí⁐ÖîäxAQéà¹ᓄu,$%&ᡂFu⏚Fu⏚MÖîäxAà¹ᓄu.⏚⏚ឋ¹ᓄᱥᦑc┯D.u,¹`Ëïð7ᡂà¹ᓄu.7ᡂñ¹ᓄuᦑD┯rᫀ⌱A஺9ஹDூ⚪K௃M7ò=ᨵsஹpஹd,3ó7òᓽ3sஹ3Pj3d,ᨵ3f,ᦑrᫀé'D஺10ஹAூᑖ᪆௃uõu⏚ö,#`7%&'Na2s2O3+4CL+5H2O=2NaCl+6HCl+2H2s04,ᵫᓄ÷£¤¥ÂøCb¹ᓄᑺNa2s2O3ªìᑺNaCljHC1Óªì(ᱥH2s஺4¹ᓄ(ᱥImolNa2s2O3ᙠ%&ᵯ~ÒùḄᦪé8NA஺ூ⚪K௃A.H2sO4¹ᓄ(ᱥNaCIjHC1Óªì(ᱥ¹ᓄ(ᱥஹªì(ᱥḄᱥ6Ḅ"û2é2:(2+6)=1:4,A┯üᔠ⚪©B.m0.5molNa2s2O3»ªìᑺᑣÒù4moiᵯ~BCD.⌱C.ÿNa2s2O3

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FeSChVWXYZI[(T01\(TI■PSTU]Qᓄ^_`ᦑCD.G⏚TaG⏚STXYMbᐭᩖ`TUᦑD┯#:ᫀ⌱C஺ூ:ᫀef௃■PFeSO4]Qᓄ^_`YDᐭᐹᨵ01ឋḄᱥ`ZVWhᑴNbᐭiḄᩖ`஺19ஹAூ⚪@AB௃A⚗ஹkᓄlᐳ(ᓄᔠᱥᰚno᝱pᵯqr8ᵨᵯBᰚnQᓄlᑴlᦑA┯#B⚗ஹtuvwxqr8ᵨyᑖBzᑴ{IᑭᵨDyQᓄtᑴtᦑBC⚗ஹT}uvwxqr8ᵨy01zᑴ{IᑭᵨCO01T~ᑴTᦑCD⚗ஹuvwxqr8ᵨᵯBzᑴ{IᑭᵨᵯBᰚnkᓄᑴᦑDᦑ⌱Ao20>Dூ:ᫀB᪆௃A.ᔣVWDBa(OH)2VWាSO42ᐰlUាᐰᓄl⏚᪷UYḄU2Ba2++2SO42+AI3++4OH=2BaSO4i+AlO2+2HO,ᦑA┯#2B.UXYSO+2C1O+HO=SO42+2HC1OQ1ᦪឤஹᨵᜫᵯᨵ{ᵯ¡¢Ḅ\QᓄG£ᐭ22NaClOVWYḄU3C1O+SO+HO=SO?+2HCIO+C1,ᦑB┯#22C.UXY2Fe2++4BF+2cl2=2Fe3++2Br2+4CLᵯ₹ឤᔣFeBrVW£ᐭ¤¢ClḄUXY22

163C12+2Fe2++4Br=2Fe3++6Cl+2Br,ᦑC┯#2D.UXY5VO2++MnOj+H2O=Mn2++5VO2++2H+¥ᔠQᓄ01¦§ஹᵯ₹ឤa1ᦪឤᦑD:ᫀ⌱D஺ூ:ᫀef௃¨⚪©⌕ὃ¬Uᑏ#Ḅᑨ°B:±²³⚪◤µ“·”a“¬”஺(1)¹º“·”·XY»᛻·½¾¿À·XYᱥ45¢ḄᐵÂ஺(2)ᱞÄ“¬”¬ᱥ`ᔲNÆᑖᡂU¬ឤ¬▢□UḄÉÊ
ËÌᡂᓄᔠᱥḄÉÊᔲÍ2஺21ஹCூ:ᫀB᪆௃A⚗pH=5c(H+)=10-s,ᵫÏI{±/gÐÑ=0,ÒÓᐗ⏚HRVWO.lmoMAᡠc(HR)c(R)=c(HR)=0.05molL',ᡠ±c(R»c(H+),ᑣO.lmobLTHRVWḄpH5,ᦑA┯#B⚗,ᵫÖ×HRVWØᙠḼHRᑖᡠHRÛ⏚~~=-7——_7=KJKஹ,ÜÝ_KJKW?C(OH-)C(HR)c(OH-yc(H+yc(HR)c(R-)ḄÞ_ᦑB┯#C⚗pH=5c(H+)=10-5,ᵫÏI{±/g_L_^L=o,ᑣKßஹJ:'lOjà£ᐭc("R)c(”R)0.1molNH3ាXYáᡂNHR,ÒÓâÜãNHyH.OᵯUä⊝âᦪK=1.76xl()T,ᡠNHRVWR-L44BÝᜧ%NH4+LBÝNH&RVWᕈéឋê!|C(NH4+)>C(R-)>C(OH-)>C(H+),ᦑCD⚗ᵫ☢A⚗Ḅᑖ᪆×àc(R)=c(HR)pH=5,ᡠVWî⏚ឋᦑD┯#஺22ஹCூᑖ᪆௃ïðᵯB1ᳮòóᑖ᪆B:ூ⚪@AB௃AஹDᐭNaCl,᪷ðᵯB1ᳮôᵯ᩽XY2NaCl+2H2O=^^=2NaOH+Ht+C1t,
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HOCH-஺ஹᓄ,2ঝ,CHBCHOCH3cHO0NaOH*CH3cH=CHCHOஹᓄᑺ,CH3cH2cH2cHOH஺ঝ*ூᫀ௃¡⚪Ḅ᧕┯
(3),>?¥⌕¦§9Ḅ¨᡾◤⌕✌ᐜª9^ᓄᡈgh«ᩭ஺25ஹ⛳®FeCL45ᕈ°⋎⁐ঝটঢঝঢঞঠডঢFeC13+3H2O(´/)AFe(0H)3(¶·)+3HClSO¸¶·Ḅ¹º{»¼ᦔ2Fe3*+Cu=2Fe2*+Ci?+¿ÀÁÂÃᴻÅ2Fe3++3C10-+100lT=2Fe042-+3Cr+5H0(ᡈ22Fe(0H)+3C10'+401r=2Fe042-+3Cr+5H0ᑏÈÉᓽ+)32ூᫀÊ᪆௃IஹᵯÊËḄÌÍ-ᙠ/45ᡈᰚÐt᝱ÒÓÔᵯḄᓄᔠᱥÖ⌕ᒹØ⏚ஹÚஹÛஹÜÝÞß*ᓄᱥஹ/à஺ᡃâᙠᑨäåæ⚪Ḅ¥᎛ᨬéêḄG-ᢥ᯿ᱥËḄᑖåíîᑨä஺জ¨ï-ð᝱c*ᓄ(ßñᱥËḄòÈóᙠ/45®ᰚÐt᝱Òᙳ(Ôᵯᡠ,(-ᵯÊËঝNaHCChᨔ·ßñÛᙠ/45+,ᵯöö8Ôᵯᡠ,ßñᵯÊËঞø/ßñùᔠᱥ8(-ᓄᔠᱥᡠ,(-ᵯÊËটúû⏚ßñ⏚ᙠ/45+,ᵯöö8Ôᵯᡠ,ßñᵯÊËঠFeCb45-ùᔠᱥ8(-ᓄᔠᱥᡠ,(-ᵯÊËডý-ᓫË8(-ᓄᔠᱥᡠ,(-ᵯÊËঢᰚÐḄKOHßñÚᙠᰚÐt᝱Ò®/45ᙳ+,ᵯöö8Ôᵯᡠ,-ᵯÊËণⅅ
ᱥḄᙠᰚ᝱ᙳᵯᡠᵯᡠᵯḄ!"ᵯḄ#$ᙠᡈᰚ᝱&'ᐰᵯ)Ḅᵯ*+"ᵯ✌ᐜ./ᵯ0&1ঝটঢ5☢7ᐸNaHCO?ᨔ:ᙠ;'ᐰᵯ)<)=ᡠ"ᵯ>?⏚ᐳBᓄᔠᱥᙠᰚ᝱&ᵯ)<)=ᙠ&'ᐰᵯ)ᡠEᵯᰚḄKOH)=ᓄᔠᱥᙠᰚ᝱F&'ᐰᵯ)<)=ᡠ"ᵯ*+"ᵯḄঝঢ஺*ᙠHஹFeCbஹᰚḄKOHFJᨵ&LMᵫOPḄ)=ᡠ;ᵯQRSTᓫJᨵ&LMᵫOPḄᵯ=ᡠV;ᵯ*+&LᵯḄঞঠডঢ஺IIஹজ.Fe(OH)3Z:Ḅᑴᜓ]^!ᔣ`aḄbc⌲efᐭ⛳ḄFeCbij`akᕈm⋎⁐pqAfrᓽ;ᑴtFe(OH)3Z:஺ᦑvᫀ!⛳FeChᕈm⋎⁐FeCb+3H2஺(a)=Fe(OH)3(Z:)+3HCI஺ঝ.ᔣFe(OH)3Z:fᐭNa2sCh⛳ᵫ|⏚᪷)=~ᓄZḄᵯ₹Z:~ᦑvᫀ!SO?'Z:Ḅঞ.ᑭᵨZ:ᐹᨵᦔᨵᦔᑖZ:ᡠvᫀ!ᦔজ.FeChᵨR⇨Qᑴ⌼ᵯḄᑭᵨḄFe3+Ḅᓄឋ¡QᓄᡂCM+,ᡠᐸ£Ḅ)=

20|}~Éy2Fe3++Cu=2Fe2++Cu2+»ঝ.ᑭᵨFeC13ᑴõFeCb6H2Oᨔh◤⌕ᙠHC1%³ஹø{ùúûᐸü⌕ý¬ᒹÿ
ᐭ⏚,ஹᓾᨔஹ⌕◤⌕ᵨᑮஹᧅஹᴻᡠ"#ᫀ%ᴻঞஹᵨFeCb'KC1Oᙠ)*ឋᩩ-./01ᑴ3K2FeO4,ᐸ/0Ḅ6789:;3Fe3++3ClO+10OH=2FeO?+3C1+5HOᡈὅ2FeOH
+3CIO+4OH=2FeO42+3Cl+5HO.23226ஹFe+2H=Fe2+HtஹCl+2Fe2=2Fe3+2CrᔾᦈABḄCDᐵFGHᜳ1J3,ᡭLGHᜳ2MNOP22ᐰRSTᡭLGHᜳ1J3,ᐵFGHᜳ2⏚ᓾᨔ᣸VWXᑁḄZDFeCh᧕ᓣ]R^ᑖ`ab`cde⁐a.`gh⁐2FeC130=2FeC12+C12ஹ2Br+Cl=Br+2ClFeCbஹFeCkஹFeO2223ூ#ᫀS᪆௃l⚪ὃopqrs8ᫀḄtua1
জWXᵬᑴ3CDaWXxyFe+2H+=Fe2++H",ᑭᵨCDḄ){ᓄឋa}Fe?+{ᓄᡂFe,67/089:;2Fe2++C12=2Fe"+2Cl-CDᨵa;D◀a◀CDᵨ{ᓄR^aWXNaOHḄᵨ%◀ABDঝ;pqᑭaNJ⏚ᐜᐙᑖ/0aMNᐰRSTaᐭCDa%ᐵFGHᜳ1J3,ᡭLGHᜳ2,MNOPᐰRSTaᡭLGHᜳ1J3,ᐵFGHᜳ2ঞFe"᧕Sa;■Saᐭ⏚aஹᓾᨔஹ2
জᐙᐭDḄ¡Ḅ%᣸◀WXḄZDa■¢᡾pqঝ¤¥⁐¦§%FeCb,᪷©ª«aFeCL᧕ᓣ]aAFeCLᵫ¦§ᓄᡂD§aᙠBWX⍗¯;¦§ঞFeCb°ᑖSᡂFeCkJCk,Cb'KBr/0yᡂBn,Bn᧕R±ᨵ²Rᑺa´µ%R^ᑖ`ab`cde⁐a.`gh⁐ট2FeCL-2FeCL+C12,2Br-+Cl=Br+2Crঠ᪷©b22·´µJ¸ᧇºV»ᨵḄᱥ½%FeCLஹFeCbஹFe0o2327ஹᳫ¿¯À^-CH+2H2O2ÁO-CH0+3HOH2O2ᙠÂÃÄÅᑖSÆÅÇaÈp▭Ê/032ḄH2O2ËÌÍÎÏÐacb61%bdூᑖ᪆௃ᵬÑÒ©-0Ö%×ØÙ⌕ḄᓄÚÛᧇaÜᵨ±yÏÑᵬÝÒÞ_««ÖÖஹÑᵬ⏚©-COOH
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࠷,óô᠒ᐭ12mL{ᓄaᙠÄÅ.ᤅñ/03öa÷/0aᓾaøëRឋ¦᝱ìᓄᑺaᯠTᵨ✂Ḅ8ûüᑮÑᵬÝýþÿᨵᵬ⏚Ḅᵬᑖᵬ⏚✌ᐜᵨ〉Ḅ⏚ᑮᵬ⏚ᔠᑖᐭ!⏚"⁚pH=2,ᑮᵬ⏚ᨔ%ᨬ'()ᑖᑮᵬ⏚,+,-ஹ/0ᑮᵬ⏚1ᵨ⏚2345Ḅ678ᵬ⏚Ḅ9:;<ᑖ᪆1ூ⚪@AB௃1
ᵫEᘤaḄG᪀IJEᘤaKᳫMNOPQ⚠SᵬT(UᓄWᡂᵬYZ[Wᡂ\ᓄᑛ^_6`aKb^-CH+2H2O22-CHO+3H2O,ᦑdᫀKbᳫMNOP,3

21CHj+2H2O2TCHO+3H2O;ফh:(iZ(UᓄᑖBj:kl▭nḄ(UᓄopqᵬḄrᨵᡠptᦑdᫀKbHO22ᙠvih:ZᑖBj:kwl▭nḄH2O2ptxyr1(3)zᡂ'ᔠ{(|ᯠNᓾhZ()'ᯠ')ᑮᵬrᦑdᫀKb1(4)জ⏚'Kᵬ⏚ᔠᑖᐭ!⏚"⁚pH=2,ᑮᵬ⏚ᨔ%ᨬ'()ᑖᑮᵬ⏚+,-ஹ/0ᑮᵬ⏚ᦑKbacb,ᦑdᫀKbacbঝ0.1000mol/L20.(M)mLKOHUᓄḄᱥoḄK0.020Lx0.1000mol/L=0.002mol,᪷;IJ20.0mL⏣ᵬ⏚ḄᱥoḄK0.002moLᑣrᵬ⏚ḄᱥoḄᑖᦪK0.002molx20°x122g/mol---------------22---------------x100%=61%4.00ga.2a45P45ᦪ45ᦪ;ᡠὑḄUᓄ%ᜧ85G¢iᦑa£¤ᔠ⚪¥1b.¦₩┵MSZ©ᑖ%ª«¬85᪗¯%%q85°±ᦑb¤ᔠ⚪¥1c.²³KOH᪗¯Z5´,☢ᙠ¶:·¸6²ᑴ᪗¯Ḅ%ᜧஹº:q¬45ZὑKOH%ᜧ85G¢iᦑc£¤ᔠ⚪¥1d.»⏚ᢣ½ᑺᣚKᵬÀÁÂZᕈ⏚ឋὑUᓄ%q85G¢±ᦑd¤ᔠ⚪¥1ᦑ⌱bd,ᦑdᫀKb61%,bd„¤¥28ஹ2ZnS+3O2=2ZnO+2sChPbSO"⁚ḄpHÆ7◀ÈᩖoFe?+Zn+Cd2+=Zn2++Cd4Zn2++2e-^=ZnÊூᑖ᪆௃ᯏÌZÍᐗÏÐᓄKSO2,ᯠ'ᵨÑÍ⏚ÊWᡂÍ⏚ÒஹÍ⏚ÓÔ3Í⏚╍_UᓄấÑÍ⏚£ÐᓄK)×ᵫØÍ⏚Ù£ØÚ<)×1[ᨵÍ⏚Ù஺ᵫØÜÝÓÔÞḄpHvᜧ◤⌕ᐸUᓄKÔÞâ(ãᑴpHᑮUᓄÔÜÝ1)ᐭÒä³ᣚCd,ᨬ')ᵯBᑮæçÒ;

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