安徽省滁州市2022-2023学年化学高三上期中调研模拟试题（含解析）

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2022-2023
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3A.cdefg^⏚Ḅᵯij-=H+ᦪlm5ᜧB.npH=13ḄNaOH_>op?ᔠr_>ḄpH<7C.dᐭtuCIhCOONavr_>ḄpH5ᜧD.wdNaOH_>Aj$n(CH3co(T)nn(CH3coOH)x=yz3().1mol15ஹ{"V3}~dᦪḄᑡ"#%&Ḅ'()A.Rj®5NHNO=2HNO+4NT+9HO,ᡂ22.4LN2Ḅᵯᦪ33.75NA43322B.n(H2SO3)+n(HSO)=lmolḄNaHS஺3_>$IᨵNaᓱḄᦪlo\NAC.᪗ᵬ=BḄ?ᔠᐳ22.4L,ᐰrᱥḄᑖᦪ3NAD.10gḄD0$IᨵḄRᦪn$ᦪᑖ35NA=4NA216ஹᑡ¡¢£¤ḄE¥%&Ḅ'⌱⚗¢E¥ᔣ©ª⏚«¬᪵$wᐭ®⏚⏚ᓄḄAᡂQ⁐°±¬᪵²BᓄSRBa(ClO)2_>BᔣCoO$wᐭ,®⏚³´⁐BᓄឋµCOO3>C12322¶·_>$IᨵCᔣ¶·>$¸wᐭ¹e=KSCN_>_>S3º⁐Fe2+ᨵQ⁐°±=AIO2nHCO3DᔣNaHCCh_>$wdNaAlCh_>4»e¼½¾A.AB.BC.CD.D¿ஹÀ⌱Á⚪(Ã⚪ᒹÅ5Æ⚪)17ஹ⊟È⏚M'ᑴᜓËᦔ◀ÍᑺஹÎᔠᑺoÏÐÑÒᓄÓḄ⌕Ôᧇ7Öᑡ½¾×Ø£ᑮ(Úᑖ½¾ᩩÜÝᶍ)஺H2CIC4H84Hsebߟ►CHCIᙢ$YH2CN——247ABcDCH3᜛ཾbá¾aCH-(5-CH2COONa2HOOCCCHCOOH-------2OHOHMFݵজR-CH2-CI+NaCN-R-CH2-CN+NaCl

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5ᨵᐵᱥ+ឋ+᝞.⊤:ᵞ2⏚45⏚ᵞ2⏚$6᧕89:;89<⏣᧕89:><⏣᧕89:?89<⏣@ឋᓄᔠᱥC⏚ឋஹCEFឋGHIJKI.ᔠᡂKMNCOPᨵO.lmolFeCCh>200mLi.Omol-L"ᵞ2⏚8Q>〉S45⏚஺GHUᐜᡭXYᘤaḄ\],_MNcO`a᣸cdefghiᤅkglIYᘤbᔣCOeᐭ〉Sopᓄq8Qr⁚pHᑮ6uvwxyᱥᐙᑖxy஺II.ᑖ|Kxy}~dIQeᐭ:<⏣Iஹg஺&.ᑡ⚪K(1)YᘤaḄaYᘤbḄo(2)MNBOPᨵḄᑺGHIJOMNDḄᐭQ☢.Ḅ¡⌕ឋ(3)ᔠᡂIJeᐭ45⏚Ḅ£ᵨ¥FeCO38¦>஺(4)eᐭopᓄq8Qr⁚pH§ᜧ96,ᵞ2⏚$6©S.ª஺F«¬ᵨ|®J¯⊤°±.(5)IJIIOeᐭ:<⏣Ḅ²Ḅ»(6)´H©µOᔲ·ᨵFe3+Ḅᑺ.(7)¸GHᑴº15.3gᵞ2⏚$6(M=204g/mol),ᑣᐸ©᳛%஺20ஹ¿ÀÁÂÃÄÅஹÆÇ⏚pᓄឋḄÈCÉᢥ.ËMNGH(ᜳᢝYᘤÎᶍÐ)஺GH⊤ÑÇ⏚ÒNOpᓄᡂNO2,ÓÆÇ⏚hÒpᓄNO஺ᵫÕºÖḄ}×Ç⏚ḄpᓄឋC9ÆÇ⏚஺¬⌱ÙµKÇ⏚ஹ3mol•!/ÆÇ⏚ஹÚ:ஹÛ⏚ஹopᓄq8QÜÝpᓄÞ஺ßàKopᓄq8QhNOxyÒNO2xyK2NO2+2NaOH====NaNO2+NaNO3+HO2

61ᨵUV᣸ᑮUiঞஹটஹডiḄ)h2jZ⏚rḄhḄU¡ឋjᐭ)ᡭ£¤¥ᜳ¦3জi¨Ḅᓄn234h4ঝḄᵨh________________________________________________¨Ḅᓄn234h5ᡠ½,´¿±n¹h<+,i+ÀÁᡂḄUV஺±n²ᑖXÂÃÁÄ4ÅᩭᑨÈ]PÉÊhᔲÌÍ஺ÎÏ2ᫀiFÑḄhÒ⌱HÓÔIJÕ஺a.j<³⁐+,Ö×Ø⁐lᓄb.jAÙÚ³⁐+,Ö×Ø⁐lᓄc.ᔣ<³⁐+,iÜᐭÝUÖ×Ø⁐lᓄd.ᔣ⛳⏚º+,iÜᐭZ⏚mºßḄUVÖ×Ø⁐lᓄ21ஹàß)Yá⌕ãä@ᓄåoãæq╅ஹvḄè+ᓄᔠᱥêF+ឋᩖìÍᑖ᪆Yiä@ᓄåãqḄ2Êhîïng᪵)jᐭñq_____ÒHᑏ`ᑺÕஹ+ÀஹñòஹóÜᐭôq_______ÒHᑏ`ᑺÕõöஹ÷ᓾஹîq«ùúûVmg஺Ãü᪵)iä@ᓄåḄqᑖᦪÒᵨãmஹnḄýᦪ4⊤Õ஺2022-2023nÿ
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7cஹKL%67>?0ᐭNO⍗ᑮᵯS"#T)*UVWXYᡂ[\]0^>?ḄឋSᨵᐵ0CaFIDஹᵯbWXcd>?ABeᵯ₹0D┯ᜮ'(ᐭzn{v0D┯<஺ᫀ⌱B஺3ஹDூ⚪h௃A.᪷BឤMH2O,ᦑAaFIB.Snᵫ+2ᓣᑮ+40SnCLᑺ0Asᵫ+3ᑮ()0H3ASO3ᓄᑺ0|}3moiᵯB0ᦑBaF;C.ᵫᑺḄឋᜧ7ᱥḄឋ0ឋAs

85ஹBூ⚪h௃A.Na2sO3"#(^SO2©/0ᦑêëBvḄᑺ'(2Na2sCh"#0ᵨ⛳$NaHSCh"#0A┯:Ḅ0Ḅᨵ@ᱥB9ᡂA⚗⌱(B.EF8GᔾᦈᜧKḄLMᵨOᑴQᑺSᨵ@ᱥB9ᡂB⚗⌱(C.TUVWḄCa(ClO)2XYZWḄ:FZ[CO2#9ᡂHC1O,HC1Oᐹᨵ]^ᓄឋ`ᵨOabᑺᨵ@ᱥB9ᡂC⚗⌱(D.9ᮞX:#9ᡂCa(OH)2,ᨵ@ᱥB9ᡂD⚗⌱(*ᫀ⌱B஺7ஹBூ⚪012௃AஹᵨCLcNaOHd#ᑴeTfᦑAgh(Bஹ᪷jklmnop⛳cNaClOdḄpHr'11,sdpH=12>U,ᦑ⌕!'abWtᨵuvKḄNaOH,ᦑBᔠᳮ(Cஹ᪷jHC1cHC1OWCIḄᓄᔠyᑖ᪆^ᓄ|}
&Ḅ~ᑏghᦑCgh(Dஹ᪷jTfUTfOᵨḄ}ᳮᵨḄ]⏚ᑴe⏚ᦑDgh஺*ᫀ⌱B஺8ஹCQcm૙Tூ⚪012௃᪷j#LḄ0)`o⏚#ḄWcLG◤⌕Ḅᦪjᨵ:Lcஹ#dḄBK[9ᡂ:ḄᱥBḄK஻ஹ#᪷j#Ḅ#ᓄ*ᫀ⌱C஺9ஹCூ⚪012௃A.ᵨLḄdᾦᙠ^ᓄdW:29ᡂd:ḄᱥB⏚d#:29ᡂ^ᓄឋNa2cCh`¡X#⌱⚗A┯(B.TfUWᨵᦔᡂᑖ£¤⏚┛cYZW¦^ᓄ:#9ᡂ£¤⏚c⏚┛£¤⏚§ᐝᑖ2TfUᜫᦔ⌱⚗B

9┯(C.K2c03XNH4a89«¬:2¦ὅ®ᔠ¯ᵨᔲᑣ²³´ᦔ⌱⚗cgh(D.FeCbXCM+#ᑴO¶·¸Ḅ}ᳮ'Fe3+ῖ⇨»89#'2Fe3++Cu=2Fe2++CiP+,2¼┯⌱⚗D┯(*ᫀ⌱C஺10ஹCூ*ᫀ2᪆௃½⚪ᑖ᪆pd⊤¿WឋÀ4c(H+)=c(0H-),ᓽc(H+)=®olᦑ⌱⚗Cgh஺ὃÃpὃÄd⏚ឋḄᑨÆÇoÈ஺11ஹCூ*ᫀ2᪆௃A.᝞ÊË⏚]⏚ᑣMG0.1mol/LË⏚dḄpH=LᡠMG0.1mol/LË⏚dḄpH=3,Í4Ë⏚⏚(B.¯Î⁐нÑÒḄdឋdMG0.1mol/LḄË⏚dᕈឋÍ4Ë⏚⏚;C.uᐗ⏚X^ᓄÕÖᢥ᯿ᱥBḄK1:1ÙÚ#O.lmol/LḄË⏚dXÛÜO.lmol/LḄ^ᓄdាÞ#Í4Ë⏚⏚(D.ßÛàḄË⏚Xá⏚Ë⏚dḄâᵯឋá⏚À4Ë⏚Ḅᵯ$ãäá⏚Í4Ë⏚⏚஺ᦑ⌱C஺ÃåpÍ4Ë⏚⏚Ḅ
pßÛàḄá⏚cË⏚Ë⏚âᵯឋá⏚(ßÛàḄá⏚cË⏚Ë⏚pHᜧá⏚(Ë⏚dᕈឋ(æᑴO.lmol/LḄç⏚dèvdḄpH

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ᔠ⚪C.ᐭCH3coONa⏚᪷ᜧᢓᑴ⏚ḄᵯḄpHᜧᦑC!"
ᔠ⚪D.#NaOH$%&'(ᱥᧇ+ឤn(CH3co(T)-n(CH3COOH)./0120.1mol,ᦑD!"
ᔠ⚪ᦑ⌱4B஺15ஹCூ⚪89:௃A.⚪&<=>?ᔲ2᪗BᩩDᦑEFGᵨVm=22.4mol/LIJKᐵMNA┯PB.᪷(ᱥᧇ+ឤQ&ᨵn(Na+)=n(S(h2-)+n(HSO3-)+n(H2so3),ᑣ&Na+Ḅᦪ8ᜧUNA,B┯PᓰWC.᪷(ᓄYZ%[CHt+ZOz=COz+ZHtO,Q\]^ᑖ`ᦪ"a᪗Bb22.4LḄᵬd/efḄgᔠfḄhᱥiḄ2Imol,ᡠkQgᔠflᐰ\]nᱥḄᑖhᦪop2NA,CD.D2OᑖḄiᦪ/&ᦪᙳ2210,ᦑlOgDzOᡠrḄiᦪ/&ᦪs25NA,D┯Pᦑ⌱C஺16ஹBூtᫀ:᪆௃Aஹwx᪵zᨵaiBa(CIO)2ᐹᨵ|eᓄឋ~Na2sCheᓄᡂNazSCh,Na2sO4-Ba?+ᡂ"U⏚ḄBaSCh┯PBஹCO2O3&#ᐭ⏚n⁐fᑣ⏚eᓄᡂC12(C122eᓄnᱥ)CO2O32eᓄᑺ᪷(o\]&eᓄឋ4eᓄᑺுeᓄnᱥeᓄឋ4CoO3>Cl,22Cஹ&'#ᐭ/KSCNa2⁐&~ᨵFe3+"rFe2+,Fe?+]ᐜKSCNE>a┯PDஹNaHCCh&#NaAKh¢\]4NaHCth+NaAKh+HzONa2cO3+AI(OH)ᨵ£⁐"?¤:\]?“|ᑴ¦”Ḅ¨ᑖ:\]┯Ptᫀ⌱B஺©ஹª⌱«⚪(⚪ᒹ¯5°⚪)±±¤²ஹ³´CH-^CH+NaOH.Aai-tJcH+H0+NaClH2:322217ஹ-CH3

11CH3HOOC<-CHzCOONa᝞¹ᐜº»eᓄᑣeᓄ¼´½±±¤²¾~eᓄOHCHCH33EC%-j-CH2-CH=CH-CH?¿ᡈÁoCE—CHz-CH=CH-CH?¿CHCH33CH2=CHCH20H1^CH3CHC1CH20HKMn0.CH3-CHCICOOH»CH=CHCOONaH^CH=CHCOOH42r2CH3ூᑖ᪆௃C-NaCN¢ÂÃপḄ\]ᡂD,᪷(DḄÅ᪀~ÇC2CH”tCH"ᵫBஹCḄᑖ[~ÇB°ῃ»1ᑖHC1¢º»\]ᡂC,ÅᔠAḄᑖ[~ÇArᨵC=C¤²-f¢ᡂ\]ᡂB,ᑣB2nḄ3ஹA2ÊËᓺᵫFḄÅ᪀~ÇD-f¢ᡂ\]ᡂE,E¢ÂÃ(2)&Ḅ:\]ÍCH3ᑮF,ᦑE2fH<£HCN2■м´eᓄ½C=C¤²eᓄᦑFᐜ¢eᓄ\]ᡂG,G¢º»\]ஹClC1CH,⏚ᓄÍᑮM,ᦑG2HOOC4cHCOOஹa,(Ñᑖ᪆:t஺0Hூ⚪89:௃(1)ᵫÒÓᑖ᪆~ÇA2H3cm᪷(M(H0Qc3rIS00H)ḄÅ᪀~ÇrᨵÔÕ24±±¤²ஹ³´ᦑtᫀ24H3C4F4H3±±¤²ஹ³´;CHaCHa3(2)B—CḄᓄYZ%[24CH«-CH3+NaOH:ACH-t^CH+H0+NaCl,GḄÅ᪀Ù[2:2226ClClC/CHjaCHaHOOCÛHCOONa,ᦑtᫀ24CHr^-CHj+NaOH►CH-t^CH+H0+NaCl:22OH&cidCHjHOOC-4-CHzCOONaOH(3)᝞¹ᐜº»eᓄᑣeᓄ¼´½±±¤²¾~eᓄᦑ\]a-\]bḄᐜÜ"Ý᎔ᦑtᫀ24᝞¹ᐜº»eᓄᑣeᓄ¼´½±±¤²¾~eᓄভᵫA

12ùú2CH,=CHCH,OHHCIrCH3-CHClCH20HKMn°.4CH3-CHCICOOH»CH2=CHCOONaH-CH=CHCOOH,ᦑtᫀ24r2CH7=CHCH.OHHCICH3-CHClCHOHKMn04CH3-CHCICOOH^l()^r»CH2=CHCOONaH-CH2=CHCOOH.r2r18^OH+HSO3-SO32+HObdNa+Rgû:]Na+i2ab2ூᑖ᪆௃(1)wA2ýþḄÿᓫᵫᯚ⁐ᕈ⁐ANa,ᵫX⁐XSO2,ᡂᓄᓄᓄᑣBஹCᓄᓄᓄᡂ#⏚ᑣD#⏚#⏚ᓄᡂ#⏚ᑣE#⏚%(2)&A'(ᕜ*ᐗ,-ᡂḄᓫᵫ/ᐗ,Ḅᨬ12ᓄᱥḄᓄᱥ⏚ឋᨬ5A66ᡂ7⏚86⏚7⏚5⏚9⏚7%(3)&A':⁐;<ᵫ:⁐=>A'?ᓄ?ᓄ'@AᓄᔠᱥᵫX'CDᨬEFḄ⌼ᡂHIᦔḄ>X'ᓄKᑣCᓄᓄᓄKᡂK⏚K⏚ᓄKᡂK⏚ᑣDK⏚ஹEK⏚%(4)&AᓄᱥXLᵫDMNᐭPᓄQR⁐STDMUᨵW2L@AᵫAᡂ⏚XCDᱥA'ᓄYஹB'CᓄYஹC'Z⏚ஹD'Z⏚LஹE'Z⏚#L஺ூ⚪^_`௃(1)&A'EFḄᓫᵫᯚ⁐ᕈ⁐ANa,ᵫX⁐XSO,ᡂᓄᓄᓄᑣBஹCᓄᓄ2ᓄᡂ#⏚ᑣD#⏚#⏚ᓄᡂ#⏚ᑣE#⏚ᓄ#⏚ᡂ#⏚Ḅ@Abcd'eOH-+HSO3XSO32-+H2O,ᦑgᫀ'OH+HSO=SO32-+H2O3(2)&A'(ᕜ*ᐗ,-ᡂḄᓫᵫ/ᐗ,Ḅᨬ12ᓄᱥḄᓄᱥ⏚ឋᨬ5A66ᡂ7⏚86⏚7⏚5⏚9⏚7ᵫ⚪jkᓄᐵmX'K⏚K⏚n7⏚ᡂᓄKᓄKnK⏚ᡂK⏚ᑣX'K⏚ஹD'ᓄKஹE'K⏚%Xo'pq⏚pq⏚n7⏚ᡂ6ᓄq6ᓄqnpq⏚rs`ᡂᓄqtu6ᓄᑣX'pq⏚ஹD'6ᓄqஹE'ᓄqᦑgᫀ'bd(3)&A':⁐;<ᵫ:⁐=>A'?ᓄ?ᓄ'@AᓄᔠᱥᵯAd'Na+Rgw:]>Na+,ᵫX'CDᨬEFḄ⌼ᡂHIᦔḄ>X'ᓄKᑣCᓄᓄᓄKᡂK⏚K⏚ᓄKᡂK⏚ᑣDK⏚ஹEK⏚aஹK⏚7⏚ᐜ{ᡂ>|}>K⏚7⏚~ᓽᡂ>ᦑ%bஹK⏚6ᓄ{K⏚6ᓄ⚞ᡂ⁐tuᦑ;

13Cஹlᓄmno⏚mVpno⏚lmpqᡂr

14ᐸḄᨔ᪆gᫀ'eᵞ⏚#LḄ`ᐸḄᨔ᪆%(6)W2L@AḄᑺ'PᓄQNᐭPᓄQ'⊈⁐ᑣSTUᨵW2L@Agᫀ'eᓄQ%(7)ᵞ⏚ḄᱥḄ=0.2Lxl.()mol-L=0.2mol,O.lmolḄK⏚#LM#L@AḄᱥḄ'O.lmoL᪷LAឤ0.2molḄᵞ⏚O.lmolḄK⏚#Lᳮ¡¢ᡂO.lnwlḄᵞ⏚#Lᳮ¡¢}ᵞ⏚#LḄe£▭}153g204gmolTx0.1mol=20.4g,}Ḅ'15.3g,ᑣ}᳛=ἠ§■ᓰX100%=B^X100%=75%,ᳮ¡}³20.4ggᫀ'e75஺20ஹ3mol•!/´Z⏚µZ⏚ᓄ¶ᐭCO2C·¸¹ᐵº»¼ᜳ¾¿ÀঠMÂÃ<ÄÅᐭ᎔ÀḄÇÈᑁCu+4HNO3(µ)CCU(NO3)2+2NO2T+2HO¾NChkᓄ'NO3NO+HO——2HNOj+NO¿ÀঞM☢¢b>×'222Ø⁐¿ÀটM☢¢b>ᵫØ⁐'Ú⁐aஹcஹdூgᫀ`᪆௃⚪ᑖ᪆eÜ⚪Ý⌕ὃàHNChḄឋஹᓄáâÜ£ãäå2æ஺(1)᪷¿Àᱯè£^Ḅ¿ÀঠᦈêNO,¿ÀডMìíNaOHᔾᦈNO2,ï'⌕ð´Z⏚{ᓄNO,ᡠò¿ÀঞM/ìí´Z⏚஺(2)ᵫó¿ÀMôõḄöᓄNO÷ø£}ù᡾ᡠòûNµZ⏚üý◤⌕¶ᐭC·¸¹CO2ÿ
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ঠᐭ᎔Ḅᑁ■ḄNO⍎஺(3)Cu"#$⏚ᡂCU(NO3)2ஹNChஹH2OCu+4HNO3(#)====Cu(NO3)2+2NChT+2H2O஺(4)
ঝ23H2O,4NO2"H2OᡂNO3NO2+HO====2HNO3+NO»2(5)NO567$⏚89:;<⁐Nth>?7$⏚@ABᓄNO,ᡠE237$⏚
ḄF☢HIJᨵL⁐MᓄᓽO>?P஺
ট23ḄR#$⏚9#$⏚ABᓄNO,ᑣ
টF☢ḄHIT;<⁐஺(6)⌕V?RCu(NO3)2#W6XᡈRZ[\N(h]
জZFᕈ`⁐aRObcZ[ḄNChd(aஹcIᫀ)fghL⁐Mᓄ஺iRjkZFNO2Ḅ#W(dIᫀ)gh8ḄL⁐Mᓄ஺ὃmn$⏚Ḅឋp21ஹNaOHZFCOq'217஻ூᑖ᪆௃xBᓄyAZz{|ZFᔣZF5ᐭ6~iBᓄAy⏚ᓄA1(OH)3xBᓄyᑮALO3,f᪷A1ឤcᐸ~஺ூ⚪[௃xBᓄyRឋxBᓄᱥAZz{|ZFᡠEZ[xBᓄyḄᑺRNaOHZFA1(OH)3"NaOHZFOZឋḄNaAKhZFᯠ8ᔣZF5ᐭ6~CO2

15NaAlO2+CO2+2HO=Al(OH)i+NaHCO,y⏚ᓄA1(OH)36ᩭ¡ஹ¢£ஹ,233xBᓄyᑮAI2O3,n(AhO3)=—=mol,᪷Alឤn[Al(OH)3]=2n(ALC)3)=2x?-mol=EmoLM10210251-he¨©—molx78g/mol26mᑣxBᓄyp~ᑖᦪ=51=--»--------------------------17nngூ«ᫀm¬௃⚪ὃ®\ᱥp~Ḅ¯°஺±²BᓄyஹxBᓄyḄឋpஹᓄ²ᵨᐗµឤI¶·¸ᱥp~¯°஺¹ºᐗµ²ᓄᔠᱥḄឋpᑭᵨᱥpឋpḄ@ᑖ½¾¿᪷ᐗµᙠÁ8@Mᑖ᪆c஺