2022-2023学年北京市某中学化学高三上期中联考模拟试题（含解析）

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2022-2023
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ᜐ\]^᝱ᐹᨵaᓄឋcdefᡂFe2+Fe?+ᜐg^᝱ᐹᨵfឋcdeaᓄ.Fe3+,ᦑC?@D.Yhi%:jᙠ]lᩩno+,ᡂpaᓄqYrsjᦑD┯tuᡠwAᫀ.Co14ஹD507஺ூ⚪GH*௃A.50.7gMnSO4H2OḄᱥḄx.77TT^7=S3mol,ᐸzᨔ%Ḅx.().3molxl8g/mol=5.4g,|169g/molᨔ}ᐰᜫzᨔ%}Ḅx,.50.7g-5.4g=45.3g,ᵫ-cᙠᑮ850࠷$ᨔ}ᜫzᨔ%ᦑᜫ▤Ḅzᨔ%ᦑA?@B.ᵫA⚗ᑖ᪆ᑮ500࠷ᑮ45.30gMnS(h,ᦑB?@C.l.850࠷}x.26.1g,|ᑮḄ}.MnCh,ᵫMnᐗ
ឤcMnChḄᱥḄx.0.3moL85()࠷ᑣMnChḄx.0.3molx87g/mol=26.1g,i▭ᑣ850࠷(+,Ḅᓄ/.MnSO^=4MnCh+SO2bᦑC?@D.l.1150࠷}x.22.9g,|ᑮḄ}.MnO,ᵫMnᐗ
ឤcMnOḄᱥḄx.0.3mol,ᑣMnOḄx.0.3molx71g/mol=21.3g,i▭0ᦑD┯ᦑ⌱D஺15ஹBூ⚪GH*௃Aஹsjfaᓄ¡¢ᶇoḄ¡0¤¥¦᣸ᙠ¦¤¨ឋ©ªsḄ¢☢0¬r®⏚+,ᦑA┯Bஹ:(ᐭḄL}0¬°±ᘤ±³Ḅ´L}c¬µ¶ᦑB?@Cஹ·Ḅ¸¹%Ḅ¸ºᑖ»¢%»ᙠo»ᑖ»¼½uo»L}¾ᔠᑣᐜᑖ9¶%ᨵÀ»ÁuÂ᎔¶ᦑC┯Dஹ]Ä⏚ÅKLᕈ⏚ឋÆᨵÇaᓄឋ⌕ῖ⇨ËÌ,ᵨ⏚PÍÎÏÐᦑD┯஺Aᫀ⌱B஺16ஹCூAᫀ*᪆௃জ%&¦ÒÓÔᱥᦑজ┯ঝÖR×Øᐗ
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12┯ঞNO0⏚ឋaᓄᱥNazOÚឋaᓄᱥÛNazOz0Úឋaᓄᱥᦑঞ┯ট6Þ
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éç}ᦑঠ?@ডì®⏚Ḅaᓄឋ0Çᐸaᓄឋ}íᙠs9àuᦑ.îaᓄឋ⏚ᡠdড┯ঢHDsᐗ
çᡂḄᓫ0ᓄᔠᱥᦑঢ┯ণKLḄñᵯឋi9àìr9àḄᵯ₹ᨵᐵiÇõᵯ*öᐵÇᵯ*ḄKL᝞ø9àìùºñᵯ¬úûcdùõᦑণ┯তᐳ^ᓄᔠᱥᙠᰚᓄÿ᝱
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ᵯḄᓄᔠᱥᓄᔠᱥᦑতথᨵᓫḄᡈᨵᓫḄ!"#$ᓄ%&᝞()*+,-Ḅ.ᓄ#/$ᓄ%&ᦑথ┯1ᡠ3Ḅ#ঠত5ᫀ⌱C஺9ஹ/⌱;⚪(>⚪ᒹ@5A⚪)CHCHa^2217ஹ(CH)CHCOOH⏚DEFGIJ52K!'[OOCHᡈ<-5:%-OOCH32HOHOaOHiiCH3yH3+2NaOHL->CH3CCH3+NaCI+HO2COOHCOONnூᑖ᪆௃ASTU(II)ᡂB,WXYᑮC,B[CSTU(DI)ᡂᵬᵫGḄ^᪀`aWX[b$ᓄcdᡂCWXcᑣBC1C(CH3)2COOH,A(CH3)2CHCOOH,ᵫfgᱯḄ^᪀`aᵬ[i⏣kᡂD^,nop5஺CHiூ⚪qrp௃(DA(CH3)2CHCOOH,ᦑ5ᫀ(CH3)2CHCOOHফ᪷nᵬḄ^᪀uv`aᵬwxᨵḄyz⏨DE|Gᦑ5ᫀ}⏚DE~Gবঝ#Sm.R1-ONa+Cl-R^-^,R1-o-R+NaCI(Ri-,R2-J⊤G)&[&IJo22IJᵫfgᱯḄ^᪀`afgᱯḄ᪶ᐳbᨵ5ᦑ5ᫀ}IJ5(4)ᵬᨵ(ᑖ*᪀,(3
ᩩ}জ1,3,5-IJWঝ[FeCb⁐S¡¢xᨵX£Gஹ¤GঞImol¥(ᑖ*᪀,ᨬ[3moiNaOH஺^ᔠঝ`axᨵX£Gஹᵬ⏚[X+ᡂḄGᦑ§¨-OHஹ-CH2cH2cH3ஹ-OOCH,ᡈ§¨OHஹ-CH2cH3ஹ-OOCCH3,©ᔠᩩḄ(ᑖCH2cH2/CH2cH*᪀,ᨵ2ᐸw!Ḅ^᪀uvOQCH,ᦑ5ᫀ}2;OOCH(5)BC1C(CH3)COOH,B[«NaOHḄᓄ¬®v:2aOHCH3CCH3+2NaOHq_^CH3CXU3+NaCl+HO,ᦑ5ᫀ:2COOHCOOlfe

13aOH+NaCl+H2O»COOH18ஹHC1Na+cCI2+2OH=CI+C1O+HO°⁐±²³´µᮞ·⁐ᨬ¸µ¹⋎⁐2ᢓᑴFe?½pFe3,+3H2O=^Fe(OH)3+3H.I¾«ḄE¿ÀwÁK3ூFe(CN)6],ÂÃÄÅ⁐±²ᑣÆÇÈ□Fe”ூᑖ᪆௃ÈAᯚ⁐Ë⁐ᦑAÈNa,i#Ë·⁐Ì,iCh,¹⋎⁐±²Fe(OH),ᵫজNa-3Ì,ᵬ+C,Na[½ḄᡂᵬH2,CNaOH,H2ECI2ᡂÌ,ÎÎHC1,DÏ⏚ᵫHC1+ÈBfE`aBÈFe,EFeCL,FeCE[CI2ᡂF,ᑣFFeCb஺nop5஺ூ⚪qrp௃(1)ᵫÐ☢Ḅᑖ᪆`aÎḄᓄ¬vHC1ᦑ5ᫀHC1(2)AḄ!$ᓄᱥÒË⁐Ó,Ô$ᓄc¥ᱥḄᵯvᑘ+×()%()%]2-Na+5ᫀ}Na+[H)%()ipNa+(3)CL[NaOHᡂfᓄcஹØf⏚cE½®vCL+2OH-=C×+CKy+H2஺5ᫀ}Ch+2OH=cr+cio+Ho2(4)ÂÙNaOH[FeCLÚᔠSᡂb$ᓄÛÜ°⁐±²b$ᓄÛÜᙠÝÌwÞ"°⁐±²³´µᮞ·⁐ᨬ¸µ¹⋎⁐5ᫀ}°⁐±²³´µᮞ·⁐ᨬ¸µ¹⋎⁐(5)FeChß⏚àáÏFe3+S½pᡂFe(OH)3FeJt+3HO=iFe(OH)+3H+,ᐜᐭ~äḄÏ⏚`ᢓᑴFe3*23½p5ᫀ}ᢓᑴFe3+½pFe3*+3H2O=^Fe(OH)3+3H+(6)åæᱥFeCLwFe”ç}I¾«ḄE¿ÀwÁK31Fe(CN)6],ÂÃÄÅ⁐±²ᑣÆÇÈ□Fe»5ᫀ}I¾«ḄE¿ÀwÁK31Fe(CN)6],ÂÃÄÅ⁐±²ᑣÆÇÈ□Fe*19ஹac◀éCO2wḄHC12NH4CI+Ca(0H)^=CaCl+2NH1+2H0NftÙêëḄ¹⁐ìí¿îï2232ᙠDÃðᜐ¿îµÅᑣòÇᨵóÌ⍎ÿîµÅᑣòÇõᨵóÌ⍎Ã(ᡈᵨ↾ᨵäÏ⏚Ḅøᴻú☠üDÃðᜐÂᨵ°ýᑣòÇᨵóÌ⍎ÃÂõᨵ°ýᑣòÇõᨵóÌ⍎Ã஺)CaCl+H2O+CO2+2NH3=CaCO23+2NH4CIூ5ᫀp᪆௃(1)᪷nþÿᱯ
AᓄḄEḄফ᪷ᡂḄᓄᨵᓄᔠCḄᑖ᪆ᑨ"ব$%&ᑴ()ᵨᓄ᪶,ᓄ┛./ᑴḄᡂᓄ┛ஹ,1

14(4)᪷ᓄ,Ḅ34ឋᑨ"ᐜ7ᐭḄ9(5)᪷Ḅ:%;<ᑖ᪆4=(6)ᵫᱥ,ᡂᱥᑏA;BC஺ூ⚪GH4௃পA⏚┛LM⏚ᑴᓄᡠ◤PQRSᮞS,6mol/LM⏚ᦑ=ᫀac(2)⛳,NaHCCh3X◀ᣵᢵAᩭḄᓄᦑ=ᫀ◀]ᓄḄᓄ(3)$%&ᑴ()ᵨᓄ^,ᓄ┛./ᑴḄᡂᓄ┛ஹ,1;BC_2NH4Cl+Ca(OH)2qCaCL+2NH3f+2H2O,ᦑ=ᫀ2NH4Cl+Ca(OH)2^CaCh+ZNHjT+lHzO(4)᩽᧕3b1᧕bᓄḄᔾᦈᡠeᐜ7ᐭᦑ=ᫀN%;(5)Rfឋ9ghi⁐Sklmnog,pM⏚ᡂqrᦑ=ᫀᵨstḄi⁐SklmuᑮDAwᜐ᝞zlmnoᑣ|}⍎Aᑣ⍎A(ᡈᵨᴻ↾(pM⏚☠lwᜐᑮqrᑣ|}⍎Aᑣ⍎A)(6)3b1ᡂ13XᕈfឋᓄR⏚ឋ9g,fᡂ⏚⏚,ᓄ┛ᑖ4ᡂ⏚┛,ᓄ_CaC12+CO2+2NH3+H2O=CaCOjl+2NH4Cl,ᦑ=ᫀCaCl2+CO2+2NH3+HO=CaCO3i+2NH4CL220ஹ◀]ḄHC1a2MnOL+lOCᔆ+16H+=2Mn2++5CLT+8H2OhᡂḄSnCLᓄᨵᑭbᔠᱥᑖAᩭbᙠᜐᓾᦈᔾᦈḄ■¡᛻£¤ᔾᦈ¥Ḅ1¦■§ᐭᦈSnCLḄlhᐸ14AB91.2%ூᑖ᪆௃(DpM⏚ᐹᨵᢵឋ)(⌮«¬ᳮ7ᐭ®1(2)A_2KMnO4+16HCl(p)-2KC1+2MnCL+5a2f+8H2஺(3)./¯°§L┱hᡂḄSnCLn᝱bᙠᜐᓾᦈ(4)ᔾᦈḄ■¡᛻£¤ᔾᦈ¥Ḅ1¦■§ᐭᦈSnCLḄlhᐸ14(5)ᵫbSi?+᧕³Fe3+,ehᵨᓄឋḄFeCh3X(´ᨵKSCN)ஹµ1᪷¶⁐nᓄᑨ"(6)᪷SnḄ·¸¹ºSnCLḄᳮ»¼¸¼᳛=$▭¼¸/ᳮ»¼¸X100%஺ூ⚪GH4௃(1)pM⏚ᐹᨵᢵឋÁ⛳,ÂM1ḄÃᵨ◀]ḄHC1)(⌮«¬ᳮ7ᐭ®1ᵫaw7ᐭ®1®ᐙÅ®1ᐙᑖ§Æᓾ(2)A_2KMnO4+16HCl(p)-2KCl+2MnC12+5C12T+8H20,Ç;BC_2MnO/+lOOT+16H+=2Mn2++5C12T+8HO2(3)᦮ÉᐙŤᓽ¯ᐙÅËÌ⁐9Í./ᰚᓄ┱ÏᔠᡂSnCL,./¯°§L┱£¤hᡂḄSnCLᓄᨵᑭbᔠᱥᑖAᩭbᙠᜐᓾᦈ(4)ÐÃᵨ_ᔾᦈḄ■¡᛻£¤ᔾᦈ¥Ḅ1¦■§ᐭᦈSnCLḄlhᐸ14

15(5)A.LFeCb3X(´ᨵKSCN)ᔠAÑi⁐ᑣÒᨵSnCE,ᔲᑣÔSnCL,ᦑAÕÖBஹLµ1ᔠ×⁐Ø]ᑣÒᨵSnCL,ᔲᑣÔSnCL,ᦑBÕÖCஹhᵨAgNCh3Xe:%Çg:%Ù┱ᦑC┯Ûᦑ⌱AB(6)ᵨ]┱Ï1.19g,ᐸᱥ·Ḅ¸1.19g+U9g•molT=0.01mol,᪷Sn¬ÇÝឤᳮ»ᡂSnChO.OlmoLᑣSnCI4Ḅ¼᳛2.38g;(0.01molx261g-morl)xl00%=91.2%«ூ=ᫀ
ß௃à⚪ábᱥ·ᑴᜓ$%4⚪ᐵä_åæçᘤhᵨஹÇ;BCéᑏஹê¬ᳮLḄᑖ᪆ëÙஹᱥ·:%;ᫀì¹ஹ¼¸¹ºíî
_▅ð⚪Gñ(òóôõö÷ᵨ஺21>Cr(OH)+OH=2HO+CrO-HSiO2CrO2+2H+CrO2+HOgHC1g³CrO¼ᓄᡂNa2s0,322234272(NH4)2SO4ூᑖ᪆௃ᔣùúS.ᐭûf,02ᯏý2Cr(h+4NaCO+3O2þÿ4Na2CrO4+4CChஹNa2cCh+SiCh
NazSiCh+CCMᑮḄ1ḄᡂᑖFeO3,1NazCrOcNazSiCh;ᔣ1ᐭH2so4,2NazSiCh+H2so4=H2SiC>31+Na2so4,2Na2Cr()4+H2sChk^NazCrzCh+Na2sO4+H2O,2HzSiCh,2NazCoChஹNa2so—ᔣ2ᐭⅅⅅCoC”-!ᡂCr3+,ⅅ"#ᓄᡂCO2;CN+Ḅ&ᐭ'(Cr(OH)3Cr(OH)3)*ᑖ+ᡂCr2(h,,-ᑖ᪆/0(1)~(4)»᪷,Cr2ឤ4B5Ḅ6ᶇ᳛9:B5ᱥ<Ḅᓄ=>஺ூ⚪BC+௃ᔣEFGᐭHI402ᯏK2Cr,Oi+4Na2coஹ+3஺2ᡂL4Na2Cr(+4COஹNa2cCh+SiOzMNNazSiOi+CO#,ᑮḄ1ḄᡂᑖFeO3,1NaCrO4xNazSiCh;ᔣ1ᐭH2so”22NazSiCh+H2sO4=H2SiChl+Na2sCh,ZNazCrCh+H2sO4=Na2Cr2Ch+Na2so4+H2O,2HzSiOj,2Na2CrO,Na2so4;ᔣ2ᐭⅅⅅCnCh?-!ᡂCN+,ⅅ"#ᓄᡂCO2;CN+Ḅ&ᐭ'27(Cr(OH)3Cr(OH)3)*ᑖ+ᡂCnCh஺(1)Cr(OH)34AI(OH)3ឋAl(OH)+OH=A1O+2HO,322ᑣCr(OH)3RKOHḄSTUV>Cr(OH)3+OH=CrO+2HO.0ᫀYCr(OH)+OH=CrO+2HO22322(2)᪷,Z[ᑖ᪆2Ḅᓄ=>H2SiO3஺(3)\]ঞᐭH2sO4CrCV-_ᓄᡂCnCh%ḄSTUV>2CrO4*+2H+—`⏚bcᣚᡂe⏚fe⏚g"CrCV-#ᓄᡂC12஺0ᫀY2CrO4*+2H+aCr2O72-+H2Oe⏚g"CrOF#ᓄᡂC12

16(4)2NazCnChஹNa2s0hᔣ2ᐭⅅⅅCrzCh*!ᡂCN+CN+Ḅ&ᐭ'(Cr(OH)3ḄSTCr3++3NHrH2O=Cr(OH)31+3NHZ,3Ḅi⌕&CraO3o0ᫀYCriOiூ0ᫀ5p௃ᓄqrVsḄ+⚪tuvwY(1)x+᦮zrVḄBḄ{(2)|}᦮zrV~!ᧇ⚜ᜐᳮஹᱥ<ḄᑖS4Hஹᱥ<Ḅᑴᜓ▤{(3)ᐹᑖ᪆v\Ḅ4஺ᙠᑖ᪆V⌕ᢕᐗ2ឤᳮ஺*sḄ9:vwᵨᐗ2ឤᑡ>(᝞⚪ᵨCr2ឤ)஺