2022-2023学年某中学化学高三第一学期期中调研模拟试题（含解析）

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2022-2023
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110·஺-y-U+;°±"#;ᡂḄ²ᑖyᓄᔠᱥᐸ©᪀«{B5ஹ°0(2)"#ঝBºº»)Ḅᡂ"#ABᵬব"#জB¾¿ÀḄ®"#"#ᩩÂ-ᓄ⏣nuஹ/"#ডBC6H5-CH2cH(OH)COOHdḄḄ®"#ÃÄ{B஺஺iÅÆFÇÈÉ(+HQ(4)᪷¢DḄ©᪀«{ᐸᑖy{BC9H8஺2,Dd³ᨵºº»ஹᑖÊËÌᑮ§ÎFAÏᑮÐᑖÑ᪀Òᐸ³ᨵ§ÎḄᑖÑ᪀ÒBÓKHY^^COOHOH(5)᪷¢£¤II,Ô¨Õᐜ;ᡂ¨⏣¨⏣ᓄB¨¨HCN"#;ᡂ)·HCC×ᙠ⏚ឋᩩÂÙ)2ᓽ஺0HCH,CH,Bi-CH,-OH-^-»CH,-CHO-^>CH,-CH-CNJZAJZAJ2"#ÛÄcuOHCH,-CH-COOH18ஹ(1)FeFeO4FeChFeChFe(OH)Fe(OH)323(2)4Fe(OH)2+O+2HO=4Fe(OH)2232Fe2++Ch=2Fe3++2C12Fe3++Fe=3Fe2+ூ⚪OP2௃Ü⚪ᑖ᪆BÝ⁐ᨔÒ#BFe3Ch,àHC1"#;ᡂFeCL>FeCb,á⋎⁐ãÒFBFe(OH)3,ᑣEBFe(OH)2,CBFeCL,DBFeCb,ᡠAABFe.(1)ᵫAFᑖ᪆¤ABFe,BBFeO,CBFeCh,DBFeCb,EBFe(OH),FBFe(OH)rᫀBFeFeO;342J;34FeChFeCb;Fe(OH)Fe(OH)32(2)ETFBFe(OH)2o"#;ᡂ"#ḄᓄpÃÄ{B4Fe(OH)2+O+2HO=4Fe(OH)322C-DXᓄᵫ¾o>¾ᓄæç"#;ᡂ"#ḄxyÃÄ{B2Fe2++Cl=2Fe3++2Cl2D-CXᓄᵫFeCbFe"#;ᡂFeCh,"#ḄxyÃÄ{B2Fe3++Fe=3Fe2+,ὃ}ὃéçêᐸᓄᔠᱥḄឋë஺19ஹìíஹîᴻðஹ500mlñòóஹôᜮö÷2.0gBCAEDACBDEFHGூrᫀ2᪆௃Ü⚪ᑖ᪆(1)øNaOH◤⌕ᵨìíᤅü>ýÛ◤⌕ᵨîᴻð6ñ◤⌕ᵨôᜮö÷>500mLḄñòó஺

122
þÿ◤⌕0.1mol/LNaOH450mL,᪷Ḅ◤⌕ᑴNaOH500mL,ᡠ◤NaOHḄ0.5Lx0.1mol/Lx40g/mol=2.0go3
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A.-ᵨ/0┤Ḅ2ṹ2ṹ4ᜧᡠNaOH4ᜧᡠ6789:B.NaOH᧕<=NaOH>ᙠ@ABC@Dᔾ▬GHᓄJᡠ%ᐭLMḄGHᓄJNO/ᡠ678P:C.QᐹᨵSTUḄឋGHᓄJ>SWᓾᑮYZ[S=ᑮᐭ\ᡂD^_Q`8a6789:D.b-ᨵOQcdᐭeḄGHᓄJḄfaᡠ678P:E.WLMOGHᓄJgᙠLMhGHᓄJḄi▭fa678P:F.!-klm7n^_Q`4ᜧᡠ678P:G.ᨬ*◤⌕!pqrsᨵOtuvw67xyz.H.᤯ᒴ*☢}~ᑖᶇᙠtuvm7n^_Q`8ᜧᡠ%678P஺ᡠ%8ᜧḄᨵAC8aḄᨵBDEFHxyzḄᨵG஺ὃᑴ!ᱥḄ67Ḅᘤஹᑖ᪆஺ூᨒ௃⚪ὃ/ᑴ!ᱥḄḄḄᑖ᪆¡ᑴ450mL◤⌕⌱ᵨ500mL,⚪¤7pᜧ஺20ஹ1
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CaClO2+4HCl¦6¥=CaCL+2C12T+2H2஺3ᑖ¥:3
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ÆÇᓫỚ◤ᙠZ7êPÌ70࠷}ÃÄ஺ëÌìᑴÃÄZ7ᑣÊËD〉îḄSÉv¯S஺ூὃ!ï௃ὃᱥᑴᜓḄᨵᐵñòḄ¶ó஺ூô௃ᑴõÇQḄÃÄᡈᨵÇQ÷ḄÃÄᙠÊᐭøùú✌ᐜ⌕üÊËḄÇýឋ஺þÿ
ᙠᵨᓄ═⏚ᑴMn€>2+4HC1=MnCL+CLf+2H20,!ᑭᵨ#⏚ᙠ⏚ឋᩩ&
Ḅᓄឋ⏚()CaClO2+4HCl*CaCl+2C12T+2HOᑴ஺,-◤⌕22஺ᑴḄ0ᨵᩖ3HC1456ᙠᵨỚᓫ3ᑴIC139:;■=ᩖ3Ḅ>᡾⌕@A◀ᩖஹDᓄᜐᳮGHᐜ◀JᐸLᩖ3MᨬO>P◀ᩖḄQᑣ“-T-U”WᵫYᨵZM[\]^᛻`abḄ56c[d)ḄICb():;■=ᑴᜓḄᱥ3g3`ahi^᛻⌕ᙠᱥ3ᑴjkOlmGnjkᵨᩭᔾᦈ456஺,rᑺtuᮞ஺d)ḄwᓄỚxMy᧕{|{}ᛋ(

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⚠ᧅ☢ᓣᦑBḄᵨ4■={}Ḅᵨ஺21ஹCC(s)+HO(g)=H2(g)+CO(g)AH=+134.5kJ/molTᜧTᜧ43[Fe(CN)]4+4Fe3+=Fe[Fe264(CN)]3tឋᩩ&
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(2)জI.FeO(s)+CO(g)#3FeO(s)+CO(g)Hi=H9.3kJ-moH342II.3FeO(s)+HO(g)^FeO(s)+H(g)H2=57.2kJmoH2342m.C(s)+CO(g)=2CO(g)H=+172.4kJ«mol123:àáâãäi+n+måᑮ}NᓄᱥçèéB"ᑴg´ê¾¿Ḅ¹ᓄ_ëC(s)+HO(g)=H(g)+CO(g)AH=M34.5kJ-mol1
ঝi.᪷:ì£íîyïðñ22570࠷ò¾¿Fe3€>4(s)+4CO(g)=3Fe(s)+4CO2(g),ðóñCOḄôõᑖᦪóñö⊝)ᔣù
,COḄúᓄ᳛ᜧii.ïð(570°C,üðᓣ(¾¿Fes஺(s)+C0(g)#3FeO(s)+C02(g)ö⊝)ᔣþö⊝ᦪḄÿᓄ
ᜧ1000CC0ᑖᦪ20%,ᔠᑡᑮ⊝C0lmol/L,ὑCOxFe0(s)+C0(g)£3FeO(s)+C0(g)342(mol/L)10ᓄ(mol/L)xx⊝(mol/L)l-xx]—x08--=20%,!"x=0.8mol/L,K=—=4
(3)জ[Fe(CN)6#-%Fe*'()ᡂFedFe(CN^b+⁐-.'(Ḅ0123:3[Fe(CN)]4-+4Fe3+=Fe[Fe(CNhbJ;ঝ6789:+ᔠᡂ;ᳮ=>?@ABCW,64CឋᩩFGFe"HCWᔠ)ᡂ[Fe(CN)6IJFe"KLMB02Nᓄ)ᡂFe஺[Fe(CN)6T1-HFe/'()ᡂ89:+PQRS+⁐஺