河南省普通高中2022-2023学年化学高三上期中调研试题（含解析）

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2022-2023
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✏ᓄᔠᱥᦑA┯Bஹ᪷ᱥḄ᪀ᱥḄᑖCi8Hl6O2N2,ᦑB┯Cஹᱥᨵᡠ!"#$%ᑴḄ'(ᓄ)*+,-./ᡂẈ2⁐45ᦑC┯Dஹᨵ6ᱥ7ᨵ889:;<=!>⏚ឋA═⏚CD,E⁐ᦑDFGHIᡠJK⚪.⌱D஺11ஹBூᑖ᪆௃^(Lv)R᪶᜜ᨬ᜜VᵯᦪY6,ZY[VIAḄᐗ]ᵫ_`ab118cᐗ]aᐗ]ᕜe⊤[gᕜe_ᑣ116cḄ^(Lv)aᐗ]ᕜe⊤[gᕜe[VIAiᑖ᪆஺ூ⚪jkl௃A.ᵫᑖ᪆Lvaᐗ]ᕜe⊤ᕜe[VIAᦑAFGB.mnᐗ]ᵫIopq
ឋ⌲stuᑣLvᙠmnᐗ]q
ឋᨬuᦑB┯C.ma]Rᦪஹᵯᦪwmᦪ"mᦑCFG

12D.gᦪZ177ḄLv᪶ê¸Lᦪ=116+177=293,ᑣ᪶êìíZ5Lv,ᦑDVw$ᫀ⌱B஺12ஹDூ⚪d(*௃A.SChஹSiChZ⏚ឋtᓄᱥCOhᡂïtᓄᱥ஺A┯vwB.Ùðñஹấ⏚óôwõ²ᓄy®½ᑣ®½B┯vwC.ö÷NaOH÷óᵯ*¸wøù⏚ú§Ḅù⏚⏚óᵯ*¸wõû²ᓄÃüᵯ*¸஺C┯vwD.ý¿þ᪍ᵬḄᴻấ⏚ḄḄᔠᱥ஺D⚪ᫀ⌱D஺13ஹBூᫀ!᪆௃$⚪ᑖ᪆&জ()Ḅᨬ+,-CH2ঝ(⏣Ḅ0᪀+,C2H5OHᡈCH3cH20Hঞ34ᓄ6Ḅᵯ8,-HH:ci஺Mট(;Ḅ0᪀+,CHCH3coOCH2cH3ஹCH3CH2COOCH3,Dᫀ⌱D஺3216ஹAூ⚪!௃A⌱⚗FeOᐭ⏚fi-ᡂ⏚⏚fᐭKSCNr⁐ᦑAB⌱⚗FeCbஹCuCLfᐭdUḄᐜFeCbpi-ᡂ¢£8¤CuCLpi-ᡂ¥G

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16⏚ᐸC+4HNO3(5)3CChT+4NO2T+2H20஺᪷<ᐗ1Ḅᓄᔠ?@ᓄAB/ᐗ1Ḅᓄᔠ?ᓣDᑣ=/EFᑺ26⏚HIᐗ1Ḅᓄᔠ?JKᑣ6⏚ELᓄᑺᵫᓄNOᦪABLᓄᑺ4FᑺḄᱥḄ41;(3)AᓫPQRAᙠBḄ5TUH“Wᓄ”ᑣAYᡈ[B5\⏚ᡈ56⏚]AAT-XTUHᑣAYᵫAஹBḄᱥḄ14,3Y4^6⏚_ᡂ6⏚Yஹ*LᓄI`aFe+4HNO3(^bFe(NCh)3+NC>T+2H20஺জY26dᐗ1ᙠᙠᐗ1ᕜf⊤HḄ)hᕜfijY4^6⏚_ᡂḄklYNO
ঝnoFḄ6⏚YḄᱥḄx,ᑣ᪷c(H+),av_Ḅ5£¤-ᵯv_Ḅ5£ᑣC(A1O2-)>C(OH-),ᦑTUᜧ¤c(Na+)>c(Cl)>c(AlO2)>c(OH)>c(H+).ூ¨ᫀª«௃⚪ὃ¯°ᐗ1±ᓄᔠᱥḄ²³ஹᓄNḄ´ᑏஹ5£ᜧ¤¶,⌕¸N_¹៉P»ḄLᓄF±P»ᱥḄឋ¼½ᱥ¾᪀4ᱥ¿ᡂ±ឋḄᐵÁÂ$¨⚪ḄᐵÃ஺C1in-ca+NaOHCH=CH|+NaCl+H2Oᡈ+NaOH-:+NaCl+HOÅÆÇÈÉÊ^\⏚/ÄᡈNaOHTU/2ÄL*CHj—CHjfCHz-CHjᓄᑺOHOHூᑖ᪆௃᪷<ᔠᡂÍÎᑖ᪆ABAᐜÐ_ÅÆᑮᓴÆÓÔᙠLᓄḄ⏣TUHÄÐ_Öᑮ×

17CH=CH2CH2CH3H=CH2CH2CH2OHCH2CH2OH~h00),ᑣA~(Ýᓄ(ᓄஹᡂᑮ$CH3C—0-CCH3CHCHO-CCHCH2CH2O-CCH3223/-.ᑮ$⏚ᙠ⏚ஹḄᩩp/ᓄ(ᡈ)-.ᑮOOCHCHOH22HCHO-CCHCHCHO-CCH223223ᙠNaOHD,ஹ/l-.ᑮ,iᑖ᪆l⚪;CH2cH3ூ⚪jkl௃(1)ᵫIJᑖ᪆A~ᐸ᪀,ᵫAᑴ~◤⌕¡-.,[¢¡Ḅ-.£ᑺ;ᩩCWᐝ᯿ᑮᓴ¨[©¡Ḅ-.ᓴªᙠ'(ᓄ«Ḅ⏣D,/®-.CH2cH2clCH=CH2CHC1CH3ᑮ~-.¯°±CH3cH20H+NaOH+NaCl+HO²ᡈ4-A2CH=CH2NaOH-ᔩ´+NaCl+HO

2OCH2CH2O-CCH3CHCHO-CCH223(2)1$⏚ᙠ⏚ஹḄᩩp/ᓄ(ᡈ)-.ᑮ;ᵫ—OHᐹᨵ·NO2Rឋ#$⏚/(ᓄ·R-.ᦑ¸¹-.জஹ-.ঞḄjḄY|»¼¢OH,■¾ᐸ¿(ᓄ;CHCHOH22(3)-.ঞᙠNaOHD,ஹpÀÁlᑮ;ClhCOONa,ÂᯠÄ!ᙠÅ⏚ஹCHCHOH22ᩩp/l-.ᑮ;~⏚;NO2(4)᪷⚪ÆÇÈÉÊËᵫ1,3—É©(CH2=CHCH=CH2);~ᐳÍᑮᑣÉÊËḄ᪀CH—CH-CH—CH|';0

18(5)ᵫ1,3—á+âᧇᑴᜓ1,4*á+⏣Aæᵨ1,3*á+â4çÐ_1,4—ᡂᯠya_ᡂâ⏣Ô4kᡂᓽAᔠᡂÍÎCH=CH-CH=CHCHBrCH=CHCH2Br22t2--------------|_►HOCHCH=CHCHOH—>HOCH2CH2CH2CH2OHo22425ஹ1:5Ch1.22C12+2Ca(OH)2=CaCh+Ca(ClO)2+2H2O2Fe2++Ch=2Fe3++2Cr'CaCO4(s)+22H+(aq)+SO2(aq)CaSO(s)+HCO4(aq)2562118HO44222ூᑖ᪆௃(1)ᑖ᪆LᓄFHᓄᔠ?@ᓄéqLᓄᑺஹFᑺ±êḄᱥḄ஺(2)᪷<ᑖ᪆ëìᵯᦪí஺(3)aᜐ$k4Lᓄ┛_ᡂᓄ┛ஹ%⏚┛`a஺(4)bᜐ$k4ᓄxY_ᡂᓄY஺মজCaC2(hT$*(Tð⊝ëᓄCaC2()4(s)4H2so4(aq)_ᡂCaS(h(s)`H2c2O«aq)ঝD═⏚᪷JK5(?᝱₝⏚Hr(/ᓣD1(?᝱ᐳᓣD2(?᝱᪷<ᜫᵯöឤøð஺ூ⚪íù௃(l)KMnO4HMnᓄᔠ?JKLᓄᑺᨵ2moiLᓄᑺHC1HC1ᓄᔠ?ᓣDFᑺ16moiHC1ú4ûüᨵUmolHClᓣDFᑺllmoLýLᓄᑺ4FᑺᱥḄ2:11=1:5,ᓄᔠ?ᓣDᑮḄvᱥLᓄvᱥýLᓄvᱥC12ᦑ¨ᫀ1:5Cl»2ফ᪷<Bëì"molᵯ_ᡂ5moicL,ýv_1.1molCL,ëìᵯḄᱥḄ1.2molᦑ¨ᫀ:1.2஺(3)aᜐᓄ┛ᡂᓄ┛ஹ⏚┛ᐸᓄ2cl2+2Ca(OH)2=CaC12+Ca(ClO)2+2HOᦑᫀ2a2+2Ca(OH)2=CaCL+Ca(ClO)2+2(4)bᜐᓄᡂᓄᐸ!2Fe2++Cl2=2Fe3++2C"#ᦑᫀ2Fe2++CL=2Fe3++2Cl-oমজCaC2O4$%&'()$%&'*⊝,ᓄCaCzOMs)H2sO«aq)ᡂCaSO«s)H2c2()4(aq),ᐸ!CaCO(s)+2H+(aq)+SO2-(aq)CaSO(s)+HCO4(aq)ᦑᫀCaCO4(s)+2H+(aq)+SO2-(aq)24442224\ஹCaSO4(s)+H2czOMaq)஺ঝ0═⏚᪷345)5᝱₝⏚89):ᓣ01)5᝱ᐳᓣ02)5᝱᪷=>ᜫᵯ!AឤC*>ᑮ0═⏚EFG₝⏚Ḅ!2MnO"+5H2c2Ch+6H+=2Mn2++11CO2t+8H20ᦑᫀ2562118HOO2ூᫀJK௃⌕ᑖOPᓄQRSḄT(GᐰᓄᑺᡈQRᑺ(G⌕ᢕY34ᡈᓣ0ḄZC*ᡈ!(G⌕᪷=>ᜫᵯ!AឤḄ[\ᩭᑖ᪆஺

1926ஹ_H2s஺4■ab8cஹCChdᐭUfghᔾᦈklḄCO2ᐰmnᐭUog870.4%BCDூᫀ'᪆௃ᵫqrstuvwngAᜐxxyᐭ(GzḄbᐜ|st8Ḅ}ᓄ:᣸NaOH&u◀b8Ḅ}ᓄ:┵o8᪵⏚Ḅᡂ}ᓄ:B8_⏚}ᓄ:Ufgᡂ}ᓄ:Ḅzg8Ḅᮞ■ab8Ḅcஹ}ᓄ:dᐭUfg8᡾zḄGᑣ(1)ᵫᑖ᪆uvB8sḄᑺ_⏚CstḄᵨ■ab8cஹdᐭUfghᔾᦈ#(2)ngAᜐxxyᐭ(GzḄbḄḄklḄCChᐰmnᐭUog8#(3)NaHCChNa2cChḄzᑖxgஹyg,ᑣx+y=1.90ஹx/84+y/106=8.8/44,ὶ'>x=12.6,¡¢£᪵8NaHCChḄzᑖᦪ12.60/L90X100%=70.4%#A.²³´(µ〉ᵨ·␺:⏚¹:⏚¹ºA┯¼#B.½¾ᐭBaCL&l$%ḄNa2cCh&:⏚¹ᓄ⚞TBÀÁ#C.:⏚¹Â⏚ᑖÃdÄ¡¢⌲F²ᐭÂ⏚ᓽlÇḄNaHCCh&CÀÁ#D.:⏚᪷Ḅ'Èᜧ·:⏚'᪷ᡠË_ÈÌÍÎ:⏚¹&Ḅឋз8⏚'¹pHᜧDÀÁᫀ⌱BCD஺27,Ca(C10)+2HCl=Cl1+H0KaClÒ⚠Ôᧅ8☢×ØᓣoᡂÙdÚ(ᡈÜ)&Þß⁐E2222ᜐáâ᣸◀D8ãzChḄ᡾ätᣚLCLæᐭNaHSOs&8çlSO?,èébூᫀ'᪆௃(1)êëìḄí⌕ᡂᑖᨵ⏚┛ᓄ┛ᐸ8⏚┛_Â⏚ᡂ#(2)ï=st8ðÐÞᓄÒ⚠Ôᧅ8☢Þᓄᑖ᪆ᑨò#(3)ï=óêëᵨᡂ⏚ᐹᨵêëឋdÄqrõ#(4)ï=öᓄ¹ᡂöᓫ#öᓫỚᓄE&8ḄỚᓄEᡂỚᓫùᔠûḄü⁐Ớ%ìḄØ⁐ᑖ᪆'#(5)ï=stýþᔣᑖ᪆EDᜐ᣸◀Ḅ᡾FᜐᔾᦈᡂḄឋᓄᑖ᪆஺ூ⚪"#௃(1)%&'Ḅ(⌕ᡂᑖᨵ+⏚┛.ᓄ┛+⏚┛/01⏚23ᡂ2345678Ca(ClO)2+4HCl(0:CaC12+2ChT+2H20,ᦑᫀ7Ca(ClO)2+4HCl(0)=CaC12+2CLT+2H2஺
(2)BḄ?ᵨABCDᐰFGHIJKLMCCᔲOᛋQRᛋQABSTUᜧWXBḄYSᐭ[⚠]ᧅ_ᡂ`aᦑᫀ7[⚠]ᧅY☢cdeᓣ_ᡂ`a(3)g%&?ᵨ.`23ᡂ+⏚ᐹᨵ%&ឋ஺aஹjk1`lᩭWnᨵ`opᨵ⁐rᩩWt⁐uvwxᮞzW{ᔾᦈz|}Jg~JCᔲᐹᨵ%&ឋᦑa┯bஹjk1`lᩭWnᨵ`opᨵ⁐rᩩWt⁐uvấz`oW{ᔾᦈ⍗ᑮḄᨵ⁐rᩩWt⁐cᐸ%&?ᵨḄᱥᦑb┯cஹjk1`lᩭWnᨵ`oᨵ⁐rᩩWt⁐U_ᐭ0⏚Kᐭz☢cCᔲᨵ%&ឋᦑc┯dஹjk1`lᩭWnᨵ`oᨵ⁐rᩩWt⁐uvpᑺᓄ┛ᔾᦈ`z⍗pḄᨵ⁐rᩩt⁐cg%&ឋᦑdᦑᫀ7d
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ᦪ=(6+2-2X4)/2=0,ᵯ
ᦪ=4+0=4ᵯ

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ᦪ=(6+2-2X4)/2=0,ᵯ
ᦪ=4+0=4,Sᵨsp?ᩖᓄḄ᪀0☢ᵯ

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ýþÿᘤᑁᐭamolC4H83amolC2H4ᑣᢗᧇ஻(C4H8)=amol+0.5bmol+amolஹ஻(C2H4)=2amol+0.5bmol+3amoLᑣ஻(C4H8)஻(C2H4)=2.5:5.5,ᱥḄᢗᧇᦪ!"#$⊝&ᡂᱥḄ()ᑖᦪᜧᓽ஻(C4H8)஻(C2H4)=11$⊝C3H6Ḅ()ᑖᦪᨬᜧ1.525./1:1,ᡠ12$⊝3C3H6Ḅ()ᑖᦪ425%஺ூ7ᫀ9:௃

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