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1、双核钌-DMBA双芳香炔化合物的合成和电化学性质(英文)SusannahD.BanzigerEileenC.JudkinsMatthiasZeller任彤DepartmentofChemistry,PurdueUniversity在弱碱性条件下，双核钌(III)配合物Ru2(DMBA)4(N03)2(DMBA=tetrakis~N,N'-dimethylbenzamidinate)与不同芳香炔反应(其中芳香基团拈:NAPme，N-甲基-1,8-萘二甲酰亚胺;NAPiso,N-异丙基-1,8-萘二甲酰亚胺
2、;Naphth,萘;Ant,蒽)，制备了相应的端基炔取代配合物trans-Ru2(DMBA)4(C2Ar)2(Ar=NAPme,1;NAPiso,2;Naphth,3;Ant,4)o利用X射线晶体衍射测定了它们的结构。所有化合物的Ru-Ru键长处于单键范围(0.2450°.2491nm)，它们均是抗磁性物质。进一步通过1HNMR和UV-Vis-NIR光谱进行了表征。电化学研究表明，所有化合物显示出与芳香基团有关的2个可逆的单电子氧化还原过程(包括一个氧化过程和一个还原过程)。关键词：双核钌;炔基;1，8
3、-萘：：甲酰亚胺;萘基;蔥基;任彤poundswithHetero-andExtended-ArylAppendant:PreparationandElectrochemicalPropertySusannahD,BanzigerEileenC.JudkinsMatthiasZellerTongRenDepartmentofChemistry，PurdueUniversity;Abstract：Underweakbaseconditions，diruthenium(III)tetrakis-N，Nz-d
4、imethylbenzamidinate(DMBA)nitrateRu2(DMBA)4(N03)2wasreactedwitharylcthyncligands,wherearyl=NAPmc(N-methyl-1，8-naphthalimidc),NAPiso(Nisopropyl-1,8-naphthalimide)，Naphth(naphthalene)andAnt(anthracene)，toaffordfournewcompounds:transRu2(DMBA)4(C2Ar)2(Ar=NAP
5、me,1;NAPiso,2;Naphth,3;Ant,4).MolecularstructuresofnewcompoundsweredeterminedusingsinglecrystalX-raydiffraction,andtheRu-Rubondlengths(0.2450°.2491nm)areconsistentwiththeexistenceofaRu-Rusinglebond.Thesecompoundsarediamagneticandwerefurthercharacterizedw
6、ithlHNMRandUV-Vis-NIRspectroscopictechniques.CyclicvoltammogramsofcompoundsI1consistoftworeversibleone-electronprocesses,anoxidationandareduction,andtheirpotentialsdependonthenatureofAr.Keyword：diruthenium;alkynyl;naphthalimide;naphthalene;anthracene;0In
7、troductionConjugatedmetal-alkynylcompoundsareointeresttoboththeinorganicandmaterialschemistrycommunities[1-3]andhavebeenstudiedasprototypicamolecularwires[4~7],lightemittingmaterials[8~9]andphotovoltaicmaterials[10],Recentinterestingexamplesoflinearlycon
8、jugatedmetalalkynylormetalalkenylspeciesincludethosebasedonmono-andbimetallicRucompoundssupportedbyphosphine[11-14]andPtAu2heterometailies[15-16].Dirutheniumcompoundsbearingaxialalkynylligandsareknownfortheircapacitytounde
