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1、双脂肪胺钌卟啉的合成,结构表征和晶体结构第2期l997年6月④}无机化学JOURNAL0FIN0RGANICCHEMISTRYv0I.j3.K..22une.1997双脂肪胺钌Ⅱ卜啉的合成,结构表征和晶体结构李早荚(武汉大学化学系,武汉430072)支志明(香港大学化学系,香港)恨车文讨论了一系列双脂肪胺钉卟啉配合物,包括Ru()(Por)(HNR):和Ru(,,)(Por)(HNR'):~Por=四苯基卟啉(TPP),中位一四(对甲苯基)卟啉(TTP),中位四(对氯苯基)卟啉(
2、cI—TPP);R=敦丁
3、基,异丙基,环己基,正辛基,正十二烷基,RJ一甲基和乙基]的合成.结构表征和晶体结构测定钉羰基叶啉与间一氯过苯甲酸的反应混合物用过量的脂肪胺处理,得到高收率的积脂肪胺钉卟啉配合物.所有的新配合物经棱磁共振光谱,红外光谱,紫外光谱以及元素分析得到证实其中,配合物Ru(")(Pot)(H-NBtl—t):的结构已由x一射线晶体结构测定.在Ru(")(Pot)(H}NBu—t)}分子中,Ru—N(Pot)和Ru-N(H:NBu—t)键长分别为2.04l^和2.j75A.西己合物关键词:.!堕旦噬合成结构表征墨结构
4、测定BIS(ALIPHATICAMINE)RUTHENIUM(i)PORPHYRINSSYNTHESIS.SPECTROSCOPYANDCRYSTALSTRUCTURELiZaoying{DepartmentofChemistry,WuhanUniversity,Wuhan430072)CheChiming(DepartmentofChem~try,TheUniversityofHongKong,HongKong)Thesynthe~stcharacterizationandreactivitiesofas
5、eriesofrutheniumporphyrinsin—eludingRu(Por)(H2NR)2andRu(Por)(HNR2)2[Por—tetraphenylporphyrinato(TPP),rcte~otetrakis(p—toIyI)porphyrina协(TTP),搬瑚一tetrakis(4一chloropheny1)porphyri—nato(4-C1一TPP);R=tert-butyl,isopropyl,cyclohexyl,—oetyl,—dodecyl,R=methyl,ethyl
6、aredescribed.ThereactionofRu(Pot)(Co)(MeOH)withm—chloroperoxylbenzoicacid(m-CPBA)followedbytreatmentofthereactionmixturewithexce璐aliphaticaminesreadilygavebis(aliphaticamine)ruthenium(Ⅱ)porphyrinsinhighyields.Allthenewcomplexeshavebeencharacter.2cdbyHNMR.{
7、R.andUV—Vislblespectroscopy.ThcX—raycrystalstructureofRu(TTP)(H2NBu)2hasbeendetermined.TheRu—N(Por)andRu一iveflt199:.':1996…5lLiZaoyins?female?inJuly1949?ar~cviatepTof啪.eut~fltresearc~
8、nr【islnthestudyonsynthesr~andpr~crtlcsofmacroc~,elicpolyamin~andmetalcom
9、0l~~-?l36?无机化学第l3卷N(H2NBu)distancesinRu(1vrP)(H2NBu)2are0.204lnmand0.2175nm,respective—.,Kevw0rds0Introductionalhati~aminerutheniumpotphyrtnsynthesischarach~rizeationcrystalstructuredetcxmlnationAlthoughthechemistryoftransitionmetalaminecomplexeshasbeenint
10、ensivelystudied,reia一'tivelyfewreportshavebeenmadeonthebis(amine)adductsofmetalloporphyrins,andsuchreportshavemainlyconcentratedonaromaticaminesaxialfig,ands.suchaspyridlneandimidazolel1_.Thefirstbis(aliphati
