江苏省常州市某高级中学2022-2023学年化学高三上期中调研试题（含解析）

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2022-2023
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,ᙠ⚪Rᢣ᝱A⚗┯nJBஹNa2SCh+H2O2=Na2sO4+H2O\ᓄ|./B⚗HIJCஹZᵬ⏣LMNᙳVឋfa@OPa@TVT⏣VC⚗┯nJDஹBaSO,_ᦑ_`aᵯᙠᰚ᝱{~ᐰᵯ{ᵯyᵯ7fJᦑ⌱B஺12ஹBூ⚪Rq7௃A.ᵫ_`¢£ᐭ¥!ḄYlᡂ[\ᓄ¦§¨ஹW⏚[^{ª_`¢B«¦⏚^_`ஹbFYB:\ᓄWᦑ¬ᑺXB[\ᓄ^_`a{MB®⏚ᦑA┯nJB.¥!Ḅ:\ᓄWZ«¦⏚^./lᡂ[\ᓄ¦§¨ZW⏚[^./¯>Bi

14NaAlO+CO+2HO=A1(OH)I+NaHCO,=¯>BiCO+AlO-+2H,O=A1(OH)+HCO,ᦑ2223323BHIJC.°ᔠf=ḄM²³y?/Ḅ⏚´µf=ḄM²¶³·ᐸ¹/Ḅ⏚Ḅ⏚ឋ¶³·´µf=ḄM²HCOJ>A1(OH)>HO,ᑣ°ᔠf=M²iOH->A1O>CO-,ᦑC┯nJ32D.»ᓄ¦ᑖ=ᨔFᰚaᵯaM½ᵨᵯ7ᰚḄ»ᓄ¦¿À¦ᦑD┯nJ5ᫀ⌱B஺13ஹCூ⚪Rq7௃A.CON2ᙳÁX=ᑖ=ÂÃÄÅy-22.4LCON2ḄÆᔠbFḄᱥfḄ!{MBlmol,KᨵḄ=Çᦪ{MB2NA“AHIJB.ᙠ᪗ÈÉ-2.24LÊbḄᱥfḄ!BO.lmoL./ËᐗÍᵫ0ÎÏÐᑮ-3ÎᦑÒḄᵯ=ᦪB0.3N\,BHIJC.1LImol/LNa2cChKᨵḄ\=ᦪB3NA,_ᑺ|Kᨵ\=ᡠe1L1mol/LNa2cCh_`KᨵḄ\=ᦪᜧ3NA,C┯nJD.᪷
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163A1(OH)3ᐰ©ᓄªᡂ¯E⏚ªA1(OH)3+NaOH=NaAlO2+2HO,AI(OH)3ᨬᜧ²³0.05moLᓽ20S,⌱⚗B┯-.Cஹ/ᕜ<ᐗ=>?@2AᑮB⌲D9E00,⌱⚗C┯-;DஹH2s04GᵫWஹYIᡂḄᓄᔠᱥH2O2SO2LMᑴO⌱⚗DPQ஺Rᫀ⌱D஺21ஹDூ⚪#$%௃A.ßà5áàÄâãaᙳäᡂ1ÎᐳᵨᵯÎÄâ©äᡂ1ÎᐳᵨᵯÎ<2.8gßà5áàḄ}ᔠSÊã0.2moLÊHO.4mol,ᨵ0.6NAâᐳᵨᵯÎᦑA┯?@ᡂBCBCᐹᨵᔾ▬ឋᦑJᵨ9KᑺM=>ḄᓄឋNᨵᐵPD┯RSᫀ⌱D஺WஹX⌱Y⚪(ᐳ84ᑖ)23ஹ_`b஺c஺de/BHBrঞNaOH;<ஹghᡈஹᔆCH஺

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ᨵNaOHḄᡂNaCK
ᐹᨵஹᵨᵨFeஹC
ᑴ!"#ᵯᓄῖ⇨CKK(ᵯ)*᩽ᡂC,ᑣ*᩽.Ḅᵯ᩽/0123ClO+2e+HO=Cr+2OH-,ᦑ25ᫀ23ClO+2e-+H2O=C,+2OH-஺27ஹᑖ:ᧅ<=>⏚@ABCᱥEᔲᨵ=GHIJ@KLMNOᓄPQRSTᨵḄCO,◤⌕ᵨWXY◀[CH+4CUO^4Cu+2H2O+CO24=ூ5ᫀ]᪆௃]1
`ᘤa2ᑖ:ᧅb]2
cd!efAgRhឋᡭkaḄlmnopᜳK,=rᐭXtAl4c3#ᡂCHuᐜᑭᵨCH4᣸y!eḄzR■|OR}᡾B஺zR᣸yWcng,tCuO#஺eᵫᑣe2<=>⏚@AB=ḄCbfᑣCCO2஺BᐜᰐcᜐḄ⏀ᐭᵬdᓾᰐg,E᝞ᓽ|ᐭᵬᑣIJḄ@KᨵSTLMNOᓄB¡0ST"CC0,᝞ᓽᰐg,CO¢Tᨵᦔ◀[஺ᦑ5ᫀ2ABCᱥEᔲᨵ=bGHIJ@KLMNOᓄPQRSTᨵḄCO,◤⌕ᵨWXY◀[஺]3
ᨬᙠgᜐWḄR¦2CH4,ᑣ§B¨ᨵCC0,ᦑCᱥ©ᨵCuஹCO2nH2O஺/0123CH”+4C“C_^4Cu+2H2O+CO2஺CH3cHeN28ஹ^^-CH=CHj16জঝ+NKN►♦NaBr⏣23CHXnCltCN/"X,QHCKQH_6`ujaQCHHOOH2bQ^coocft-Qூ5ᫀ]᪆௃°⚪ᑖ᪆3᪷³CḄ´᪀¶1⌮¸BEQ_CHBrCH3CHiCHCOOCHjCH3cHeOOCH3AE¹º»b,ᑁ¾¿E,᪷³)Àឤ,SÂÃÄÅCᱥEºÆ⏣;Éᔠᑖ᪆জঝঞটঠDঠHBrᑖÐEÑᡂஹÑᡂஹÒÓஹÒÓஹÒÓ஺]᪆3᪷³Ô.ᑖ᪆]1
AE¹º»´᪀¶12CHcH=CH2,ᑖ)¹Õஹº»ᑖÐ22Ö×☢ᓫÚSÛÜᡠÔᡠᨵ)STᜐÞßÄ×☢ᨬàᨵ16Ö)ᐳ×☢஺2
EâTãäåEæçজèটᑖÐEÑᡂஹÑᡂஹÒÓஹÒÓéÞÑᡂḄEজঝ஺

21CHsCHCN(3)ঞḄᓄefghHBrCHs+NaCN+NaBr°CHJCHCOOCHJCH5CHCOOCH3FQ(4),஺ঠê,᪷k=>lឤnopᱥq⏣஺CHiBr(5)জtFeCh[%uv⁐xyzᨵ|}~.ঝtuxyᵫ~;ঞᑖ>ᨵ1
ᐳ23o஺(6)᯿EḄᔠᡂoᵫQ~CH:OHᔠᡂ~CHCOOCH-^Ḅᔠᡂ஺©YHjOHHC1ᡂ/0/04NaCNᡂ0%W,0•᝞S$@3&Uᨬট᝞ᵬ⏣uᓄᡂOCHHOOCH:஺ᡠᔠᡂCHjClCH2CNz=xQcifcOH6¡gQCH^OOH\ì£í.QCMOOCHQ'¢cᙠ¤ᑏtuḄᱥ¦ូ/ᑖ¨᪀ªtᨵ«ஹᵬ⏚ஹᵬ⏚«஺29ஹP¬☢®1NOSCN-Fe3*C

222x80[CrNH34H2O2]ClTiO32Nabc-10-30Aூᑖ᪆௃AஹBஹCஹDஹEஹFîEᕜð⊤òóᕜðḄᐗõö÷Ḅ᪶ᵯ₹ᦪAᦪ+49,&
ᦪ+27,ᑣ=
ᦪ+22,E+Tiᐗ#஺Fᐗ#4@Aᕜᐗ#&BᡂCᵯ
ᦪᨬEḄᐗ#;
᪶᜜ᵯ
᣸H+IIs22s22P63s23P63d54si,J!|F+Crᐗ#/CrChLMN%ஹH2OᡂNOḄOᔠᱥQS+21,ᑣOR&ᨵ4TNMஹ2TH2O,ImolOᔠᱥMU>ḄAgNChVWXYLZᓽ\ᡂ3moiAgCL]^_T`
᜜abOᔠᱥ+CrNH34H2O2Cb,cdᑖ᪆f⚪஺ூ⚪ijf௃ᵫᑖ᪆mIA+Cᐗ#ஹB+Nᐗ#ஹC+Oᐗ#ஹD+Mgᐗ#ஹE+Tiᐗ#ஹF+Crᐗ#/5—1—1X4DNᐗ#ᓄᱥMHC1XY\ᡂḄnᨵNᐗ#o
+NHj,ᑖ
&N;
ᵯ
Cᦪ=4+---------------=4ஹN;
2+sp3ᩖᓄqnrCᵯ
ᦑᐸtu᪀v4wA☢R/F+Cr,;
᪶᜜ᵯ
᣸H+Is22s22P63s23P63d54s1ᐗ#;
Ḅᨬ᜜ᵯ
ᦪ+1T/ফN
ᑖyMCO2ஹᵫNஹOzᡂḄ{᝱ᓄᔠᱥ}+~ᵯ
RᑣNஹOzᡂḄᓄᔠᱥᓄ+N2O;N
▢
}+~ᵯ
R᪷cᵯ
ᦪ~ᵨSஹC;
2TN;
mb▢
+SCW,᪀Mco?▢
ᵯ
+§cM-<▢
ᵨ\&Ḅ<67□
67□
+Fe*3ᕜ@ᵯLᕈᜧ3ᐗ#;
2PLᨵ3Tᵯ
ᜐ¡¢£¤᝱ᵯ
L>¥3ᐗ#@ᵯL$!Ḅᐗ#Ḅᡠ@ᵯLᵫ§ᑮᜧḄ©ª+Cᦪᑖy+xஹy,ᑣ᪷cᵯ
²³´ឤᨵ5--3Xx=2y,ᡠxy=41,bXYḄᓄ·¸44Mg+10HNO3=4MgNCh2+NH4NO3+3H2O,ᡠbXY&,ᓄᑺM;ᑺḄᱥ=Ḅ>S41:4মCr;
᪶᜜ᵯ
᣸H+IIs22s22P63s23P63ds4slCr;
ᜫ»4sL1Tᵯ
ஹ3dL2Tᵯ
ᡂCr3+,Cr3+Ḅ᪶᜜ᵯ
᣸H4Is22s22P63s23P63d3,ᵫ¼½ᑖ᪆mCrCbᡂḄNOḄOᔠᱥᓄ+CrNH
H2O2C13s34

23যᵫᨔ²Ti=>³´µ⚔'3O=>³´3#·☢3¸ᑁ]ᨵ2º,1180ᦑᨔ²Tiᐗᦪ½=l+8Xw=2ஹO=>ᦪ½=2+4Xj=4,ᦑ¾ᓄᔠᱥᓄehTiCh,ᨔ²¦¿=2XÀg,Áᨔ82NA²ÂᦪᑖÃapmஹbpmஹcpm,ᑣᨔ²ḄÄ=aXlOikmXbX10-"cm=abc>g2x80ÇqNAg/cmN-abc-lO30AabcxlO-3Ocm3