陕西某附中2022-2023学年化学高三上期中综合测试试题（含解析）

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2022-2023
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§ïῃñᑴ§êᐹᨵY℉ḄõöÆ÷øùú஺ûü½ᑡý⚪஺প
I.2C3H8g+O2g=2C3H6g+2H2஺AH,=—238kJmoLn.2H(g)+O(g)=2HO(g)AH=-484kJmor'2222ᑣῃᑴC3H8g
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0.5moLGI0.325molO2ᔠ:>?ាRᒕrJᡂḄᨵᓄᓄ
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0.4moL2322ὑ8⏚
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O.lmoLὑ8⏚
0.2mol,ᐳὑ8⏚
1.8mohC⚗018ஹDூᑖ᪆௃#PWজ<¡J
2Na2O2+2H2O=4NaOH+%O2,2H2஺2=2%0+஺21ঝ<¡J
2KMnO4+5H2()2+3H2sO4=K2so4+2MI1SO4+5O2t+8H2Oঞ<¡J
HO2+BaC12=BaO2+2HCl2ট<¡J
BaO2+HSO4=BaSO4+HO2,2HO2=2HO+O2t2222ঠ<¡J
2H2O2§(2H2O+O2tூ⚪}௃A.জஹঠ<JḄ
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8⏚ᦑD⚗012ᦑ⌱B஺10ஹDூ⚪}௃A.ᔣÍ:;<ÎᐭKSCN:;ÏᑴḄÊ?:;Ñ
⊈⁐ᑣ,:;<#_ÓᨵFe3+ᡈFe2+ᡈὅÖᨵᦑA┯\2B.ᔣÍ:;<Îᐭ¼⏚RMNJᡂHÎÊᓄ⚞:;JY⁐MN:;<#_Óᨵ⏚¼×#_Z⏚ᦑB┯\2C.ᔣÍ:;<ÎᐭØ'¼⏚ÙᨵJ_VÚÛÜᮞ?ÑÞßḄ:;<#_µÓcoᡈSO.×#_µÓHCO3-ᡈHSO3,ᡈὅÖµeᙠᦑC┯\2D.ᔣÍ:;<ᐜÎãäN:;R@XåῃÙᨵỚᓫ&HäÊ?:;ÑèᨵỚJᡂᑣ:;<ËÓᨵr,ᦑD012ᦑéᫀDo11,Dூ⚪}௃A.ÄÅDëì?ḄpH=7,íî<ïð?ḄpHñ>6.5,Åòg>ÄÅA┯\2B.ᵫóðÀḄᦪôᑨUëì?ḄpHµ#_ᜧ>8,ö÷ḼḄùúpHûᜧᑣü⊤þ:;pH÷ÀÿᓄḄB┯C.50sḄpH7.5,ḄpHᜧ8.2ᐭpH8.2ᐭ⏒⁐C┯D.Mg(OH”ᱥḼMg(OH”Ḅ!Ḅ"#$%!ᓽ150s"#%!'()ᡂḄMg(OH)2!D+,-ᫀ⌱D஺12ஹDூ-ᫀ3᪆௃᪷7⚪9:Cu2s;<=Ḅ>?⏚AB)ᡂCu(N03)2ஹH2s04ஹNOCH2O,ABCuᐗEᓄᔠGᵫ+1GᓣJᑮ+2GSᐗEᓄᔠGᵫ-2GᓣJᑮ+6GᑣnmolCu2sᐳᜫPᵯRnmolx(2x1+8)=10nmoLNᐗEᓄᔠGᵫ+5G!Sᑮ+2GᑣTUABḄ?⏚VWXḄ?⏚ḄᱥYḄ=Zmol஺ᦑ-ᫀ⌱D஺13ஹC

14ூ⚪]^3௃A.(_`Ḅa⏚b$UᒓdeḄfᡂ஺SO?CghᓄᱥᙠZjᩩl%mno)SOoᡠnqᑴSO?CghᓄᱥḄ᣸t'uᳮdeḄᨵᦔyzᦑA+,B.AB{জSO?WXᑺNO?hᓄᑺᵨᔾᦈm)ABS0+2N0+2H0=HS0+2HN0,ᦑB+,C.ᵫ:b«d>a«c,ᐭNO2,ᑣᨬ222242ᑮSOom:a⏚bḄfᡂ⌕;N&ᨵᐵᦑC┯D.᝱g᧕ᢵo)`஺ᵫ:Ḅᦪ7ᑖ᪆m:ᙠᔾᦈḄᩩl%SO?CNO?ᢥZj¡¢£ᔠo)SOoḄ¤#¥ᜧ¦_`Ḅa⏚b§$UᒓdeḄfᡂ஺ᡠn¨©)oᜧ=ªᵨ┤᝱gm¬$UdeḄfᡂᦑD+,-ᫀCo14ஹBூ-ᫀ3᪆௃Aஹ®¯;°Ḅ±²)AB³ᑮP¯Ḅᦔ´ᦑAµᔠ⚪9Bஹaᙠ⏀·Ḅ3#ᜧ¸;⏀·ABamᵨ°Ḅ¹hᓄº»¼ᦑBµᔠ⚪9Cஹ½mn;>?⏚)hᓄWXAB(¾mᵨ>?⏚»¼½¿ᦑCµᔠ⚪9DஹÀᓄ½)ᡂAg(N%)2CIÁᔠᱥABÂÃÄAgCl+2NH3H2O=Ag(NH3)2Cl+2H20,ᦑDµᔠ⚪9ÅÆᡠÇÈ⚪B⌱B஺15ஹCூ-ᫀ3᪆௃A.?⏚ᐹᨵÊhᓄឋᔣ>HNO3UNa2sChAB)ᡂa⏚ᦑA┯B.CaCChᱥY¬ᑏᡂÎRᦑB┯C.ʲឋNaClOFe(OH)3hᓄFeO?,ÎRÂÃÄ3C1O-+2Fe(OH)3+4OH=2FeO2-+3C1-+5HO,42ᦑC+,D.NaHCChU<=Ba(OH)2¬ᒕÐÑ⏚᪷ÎRᦑD┯-ᫀ⌱C஺16ஹCூ-ᫀ3᪆௃A.Ò⏣;£ÔÕ#¡ÖÔÕ#¡ᜧ×mU␺ÙA+,B.Ò⏣᧕Ñ⏚º;Ò⏚AB)ᡂÚhᓄÑ`Ò⏚ÒÛ⛳CÑ⏚ºᑖÝmᵨÑ⏚º␺ÙB+,C.Þß'ᔠᡂJᑖRᓄᔠᱥà⌼âã'ᜩᯠJᑖRᓄᔠᱥC┯D.æçᜩᯠ`Cᓄè®`éêoᱥëᨵஹÚhᓄÑ(¾'ᡃíîïðªᵨḄñòéᧇD+,ᦑᔠᳮ⌱⚗'Co17ஹCூᑖ᪆௃õÑÑö÷Ḅᨵøᱥ;¹`)UᡂAB¸UᡂÑùúû)ᡂ3-ᵬýþÿ
ᩭ஺ூ⚪௃A.ᡂᡂ2-ᵬᦑA┯B.ᡂᡂ2-ᵬᦑB┯

15C.2!!"#ᙳᡂᡂ3-ᵬ%ᦑC&'D.ᡂᡂ2-ᵬᦑD┯ᫀ⌱C18ஹCூᫀ᪆௃,⚪ᑖ᪆.জ01234⁐6789ᓄ;Ḅ=>ឋঝ⏚ឋKMnOB234⁐89ᓄ;9ᓄCD67ᐸCDឋঞGH4⁐89ᓄ;9ᓄCD67ᐸCDឋটJᨵL⏚ḄNaOH234⁐MN89ᓄ;O67ᐸ⏚ឋ9ᓄᱥḄឋQঠLḄST234⁐89ᓄ;9ᓄCD67ᐸCDឋUᯠঝঞঠWQXYᦑ⌱C஺ὃ[.\⚪ὃ]89ᓄ;Ḅᓄ^ឋQ஺19ஹDூᫀ᪆௃Aஹ_`aᙠcdeᵨCOCDFe2(hḄghijgA&'Bஹgᙠk9lmnᡈcdepHqᙳrsᑮB&'Cஹu᧕w9ᓄx9ᓄuyᵨuᑴ0⊤☢⌚~Ḽ9ᓄᑁᵨC&'Dஹᓄg23lgHᡂ66ᐹᨵᔾ▬ឋᦑᵨHᑺgḄ9ᓄឋᨵᐵD┯ᫀ⌱D஺20ஹAூᫀ᪆௃,⚪ᑖ᪆.AஹOH-ᐜpAF+ᡂSp╆᪷S2NH4Al(SOD2pBa(OH)2ᱥQḄx1:2Ḅ¡x.NH++AI3++2SO2+2Ba2++4OH=2BaSOi+AI(OH)4443i+NH«HO,A&'BஹFeCL⏚ឋ23¢ᙠ£l¤QḄ¡x4Fe2++4H++O2=4Fe3++2H2஺B┯32CஹᵨCH3coOH2CaCChḄ¡xCaCCh+ZCH3coOH=Ca2++2CH3coO+H2O+CO2TC┯DஹᵯᵯMgCLH23Ḅ¡.Mg2++2Cr+2HOMg(OH)21+H2T+CLTD┯஺ᫀ⌱A஺2ὃ[.¡21ஹCூ⚪௃A.W¦§¨ᵨ©9ᓄᑖᑴ9ᡂImoKhª«ᵯᦪx2NA,ᦑA┯B.500mL0.2mol-LrK2sCh23lᨵO.lmolK2sCh,ᨵ0.2molK+,K2sO3O®⏚¯ᙠH23°rHSO32-+H2OUHSO+OH-,HSO3-+H2OUH2SO3+OH-,▢ᦪᜧ³O.lmoLN23lᨵḄ´ᦪ3µ³0.3NA,ᦑB┯C.Imol¶⏣pImol¶¸ᑖ¹ºᐰmn¼ὑḄ9¾M3mol,ᡠ
Imol¶⏣p¶¸ḄÀᔠᱥᐙᑖmn¼ὑḄ9ḄᱥQḄx3mol,¼ὑ9ḄᑖᦪxÃÄx3NA,ᦑC&'D.2³HÆ23Ḅ6ÇÈÉY³2ᑺḄ6Çᦑ23Ḅ6ÇÈM1L,ᑣËÌ´ÍÎÈM0.2mol/L,ᦑD┯ᫀ⌱C஺

1622ஹAூᫀ᪆௃জÏ⏚Ḅᵯ¡xᦑজ┯ᨵ#ḄᓄᔠᱥMᓄᔠᱥᦑঝ&'.ÉQḄ0203l9DḄᦪx11,ᦑঞ┯ÐஹѾM6ÐஹÑᙳrÒÓÔᦔᦑট&'ÖZnᵯ×ḄØ᩽XÚZnÛ▢᩽■ÝZwῖ⇨ᦑঠ&'à;⏚ஹáH¾MÀᔠᱥâÈMᵯQãÈMäᵯQᦑড┯⌱A஺8ஹä⌱æ⚪(ᐳ84ᑖ)23ஹNa+[OH]-Si+2OH+2HO=SiO32+2HTNaOH,Na2cO30.05ᐜᨵ>⁐SᡂêÆS⌲ì22íîᨬð¼ᜫ3cl2+8NH3===N2+6NH4clH+ஹAp+ஹNHஹSOc(H+)c(Al3+)c(NH)c(SO:)=1123ூᑖ᪆௃(1)CᙠDlmnòó>⁐ôᯚxᡂHCLö÷CxHzஹDxCLஹFxHC1,MMy¨ølÈùîḄúᕡ0ᵫªᓄᐵ÷,MḄ23ᵯᡂஹB,ö÷MxNaCkBxNaOH(2)þAMÃÿ
ᓫᵨᑴ⌼ᩞᧇᑣASi,SiNaOHḄᡂNazSiChH2;ব!0.4L0.6L"NaHCCh+HCNNaCl+CChT+HzO,#▤%&ὑ(⏚200mL,*+,-./ᓄ12&ὑ(⏚400mL,ᜧ200mL,ᡠ5ḄᡂᑖNaOHஹNa2cO3;(4)8A9:;<=
ᓫ>NaOH?@ᑣAAl,ENaAKh,ᑣABCḄHC1⌲EFᐭNaAKhᐜᡂI/ᓄJ*KI/ᓄJLM(5)8A9:;NOPQRᵨANaOHᑴSTE,ᑣENH3ஹAU(E>VTW⍗ᙳᑈ[\ᑭᵨE>VTḄ^Q_〈VTḄa⍝9ᔲd☄ᑣfT>VTᡂVᓄgh2ᡂNTM(6)ᵫjk+,FᐭNaOHlᨵnoT-ᑣ:pᨵH+,:plᨵCO3*,Kᩭᨵno-ᨬK&ᜫᑣ:plᨵMg2+ஹFe3+,:ptᨵA13+u%noḄCvwNH4++OH-=NH3%OḄᑣtᨵNH4+,ᵫᵯ₹zឤk:ptᨵSO4”᪷}ᔜ▤%&ὑḄNaOHᔠn(H+)n(Al3+)n(NH4+)ᔠᵯ₹zឤ>n(S(h2-)Ḅᐵ}஺ூ⚪L௃(1)BNaOH,ᐸᵯNa+[0HMফASi,SiNaOHḄᡂNazSiChḄSi+2OH+2HO=SiO32+2H?M22(3)!0.4L0.6L"NaHCO3+HCl=NaCl+CO2T+H2O,#▤%&ὑ(⏚200mL,*+,-./ᓄ12&ὑ(⏚400mL,ᜧ200mL,ᡠ5ḄᡂᑖNaOHஹNa2cO3;ᡂO.OlmolCCh◤⌕Ḅ(⏚—:HFO.Olmol200mL,ᔠᳮNaHCCh+HCMNaCl+CChT+HzO,ᑣc(HCl)=------------=0.05mol/L0.2Lz(4)8A9:;<=
ᓫ>NaOH?@ᑣAALENaAKh,ᑣABCḄHC1⌲EFᐭNaAlChᐜᡂI/ᓄJ*KI/ᓄJLᦑ£ᑮḄ¥¦§⌲¨ᨵ[⁐ª«noᡂv¬ᙢ®

17F¯Kno⌲¨Lᨬ°&ᜫM(5)8A9:;NOPQRᵨANaOHᑴSTE,ᑣENH3ஹA╄(E>VTW⍗ᙳᑈ[\ᑭᵨE>VTḄ^Q_〈VTḄa⍝9ᔲd☄ᑣfT>VTᡂVᓄgh2ᡂNT§3Cl2+8NH=N2+6NHCl,34(6)ᵫjk+,FᐭNaOHlᨵnoT-ᑣ:pᨵH+,:plᨵCO3*,Kᩭᨵno-ᨬK&ᜫᑣ:plᨵMg2+ஹFe3+,:ptᨵAP+u%noḄCvwNH4++OH-=NH3H2()Ḅ²UtᨵNH³+,ᵫᵯ₹zឤk:ptᨵSth%"H++OH=H2O,I&ὑNaOHḄ1"A1J++3OH=AI(OH)3bJ&ὑNaOHḄ3NH++OH=NH*HO,g᪷&ὑI/ᓄ¶4322,ᑣn(H+)n(Al3+)n(NH+)=l:1:2,ᵫᵯ₹zឤkn(H+)n(Al,+)n(NH+)n(SO2)=l:1:23,444ᦑc(H+)c(Al3+)C(NH+)
C(SO2)=1:123஺4424ஹN[Ar]3d,04s*NH3NH3ᑖu·ᙠI¹ᨔcde»¼┵¾sp3CuN631034a¿ூÀᫀL᪆௃AஹBஹCஹDÃᦪÅÆ®ᜧḄÇÈᕜÊᐗÌ஺BA3?ÍÎÏḄÐ⁐ÑÒÓÔwÕNH3,ᡠ5AH,BNAஹBஹCḄᵯÖ25,ᑣCClDCᨔD+Ḅ3d?×ØᵯᐰᐙÛ஺DC1VÜ-1Ý,ᑣD+1Ýᡠ5DCu஺(1)᪷}ᐗÌᕜÊÞkHஹNஹCkCuß4;ᐗÌà:ᵯ?ᨬᜧḄ9N,á᝱CuḄ᪶᜜ᵯ᣸æls22s22p63s23p63d104s,,ᦑÀᫀNls22s22p63s23p63d104s'(2)ᙠNH3ஹHC1ᵫfᑖuᨵI¹ᡠ5çèéêḄ9NH.“CuHtᨵ▢□ᓄᔠᱥᙠî᝱2᪀ᡂᨔᦑÀᫀNH3fᑖuᨵI¹MᨔM(3)NH4aᨔtᨵ¹ஹ᩽ឋ¹òó¹ᦑ⌱cde(4)ᓄᔠᱥNCbNḄÝõᵯöᦪ2=4,ᨵ:ö÷ᵯöᡠ5ᑖḄø᪀ù»¼┵¾úḄ2ᩖᓄüùSp?ᩖᓄᦑÀᫀ»¼┵¾MSp'(5)জ᪷}NஹCu¾ᡂḄᨔḄᨔþjᨔþtᨵḄNÿᦪ=8X=1,Cu
ᦪ=12X=3,ᨔᓄ84CUN,ᦑᫀC113N3ঝ᪷NஹCuᡂḄᨔḄᨔN
ᕜᨵ6Cu
N
Cu
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1825ஹ3ᡂ45ឋḄNaOH78⍗5:;3ᡂḄHBᨵ<=ឋ2H0^22HO+O1"⚠?ᧅᔾB2222■DE3ᰦGঞIJKLMNᔲᨵB3ᡂூᫀQ᪆௃TUᓄVBKL3ᡂWUᓄVUXᙠZJMIJWXNᔲTUᓄVKL[\ᵨ^_ḄWXTUᓄVKL`NᔲᨵB3ᡂ஺5bᮞdᔾᦈWXMḄBf⏚hdIJiᱥNᔲᨵB஺ூ⚪lmQ௃(1)জ78⍗5:;ᡠ\pq:;rs3ᡂ45ឋḄNaOH#tTUᓄVBKL3ᡂTUᓄWWUᓄV3ᡂḄHQ?ᨵ<=ឋᡠ\;⁐v⁐wঝxᐭzUᓄ╨TUᓄWᑖQ3ᡂBUX}~2H2Hw(2)জ⏚Ḅᘤ"⚠?ᧅw5bᮞ[\ᔾᦈWXMḄBXwঝWXN᧕Xᡠ\IJWXḄ)■DE3ᰦGwঞf⏚h⍗B:ᡠ\[\IJKLMNᔲᨵB3ᡂ஺26ஹaf⏚BD2C1SO3H^SOC12+HSO4SO2cL=SCh+C12,ᑖQi3ḄXpQᙠ22ᐸM75%ூᑖ᪆௃ZJlḄNᵨ^_ḄCLSO2ᙠឋᓄᑴf⏒ᵬᑴzUᓄf¢£ᑴX¢,¥¦ᙳ◀ᩖ¢ªᔾᦈ«XMBX¢ᔾᦈ¬X஺(6)M᪷ᱥ%Ḅ&®¯°ᓄ}~M±&ᦪ®[²³´ὑXḄ&¯°ᳮ·3ᡂf⏒Ḅᱥ%Ḅ&¸¹±ºf⏒Ḅi᳛஺ூ⚪lmQ௃(1)ᘤC¼½BḄ¾ᔣN“¸Á”ᡠ\¢Ä¼½ÅḄ¸BᐭÆaÇ⚪ÈÉᫀNwa(2)¥ḄÊᵨN^_SO2,¦ḄÊᵨN^_Xᡠ\¥ஹ¦MḄËᑺÍNf⏚wÇ⚪ÈÉᫀNf⏚w(3)A.98.3%f⏚ÎÏBf⏚ᵯÑÏᜧÓ\ᑖÔᙠ¹NazSCUs)ASO,ḄKLNᙠH2SO4ᵯᡂḄÕÖ×dØᑭ¸ÚᦑA┯ÜwB.ÝÞÝßZJMàTáâ¥ஹ¦ãÅÆi3XäḄå᳛æ¯[çᑴèéKLᱥ'æ¯ᦑBÈÉwC.¢£Á}ᑖq?ᧅMᨬë⌱ᵨ⛳NaClpq×dîïXḄpQ)ᦑC┯ÜwD.¢ª[ᔾᦈzUᓄfX■DðñÝ0ᔾᦈ«XMḄB■Df⏒:%ᦑDÈÉ஺Ç⚪ÈÉᫀNBD(4)ò⏚(ClSOjH)xóᑖQôdᑴ³f⏒᪷%&õឤ8÷KL}~2C1SO3HAsO2CI2+H2s04,Ç⚪ÈÉᫀN2clsO3HASO2CL+H2so—(5)ᵫᑖQKLSO2c12=SO2+C12[úᑖQi3Ï&XXûü⁐pQᙠᐸMýãþf⏒EûwÇ⚪ÈÉᫀNSOC12=SO+C12,ᑖQi3ḄXpQᙠᐸMw22(6)ÿ
ὑḄ896mL(᪗)ḄᱥḄ0.04moLᵫᓄSO2+CI2=S02cl2

19ᳮ!"ᡂ$⏒0.04mol,ᡠ'$⏒Ḅᳮ(m=nM=--(32+32+7l)g/mol=5.4g,x22.4A/mol)*+⚪-./ᫀ1275%o27ஹ2Fe3++Cu=2Fe2++Cu2+0.144mL0.1mol/LFeSCh56ᔣᐸ9:39O.lmol/LKSCN56Cu2++3SCN-CuSCN+(SCN)23Fe2++4H++NO=3Fe3++NOt+2HO᠒4
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44mL0.1mol/LCuSO456ᔣᐸ9:39O.lmol/LKSCN56}~2
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"ᡂCuSCNv"ᡂ(SCN)2,
lm2CU2++3SCN-=CUSCN+(SCN),2ᦑ/ᫀo.l44mLO.lmol/LFeSCh56ᔣᐸ9:39O.lmol/LKSCN56KCu2++3SCN'=CuSCNj+(SCN)2(3)nolmᐹᨵឋ⏚ឋᩩM⏚᪷ᐹᨵOᓄឋ
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lm23Fe2++4H++NO3=3FeJ++NOT+2HO,ᦑ/ᫀ3Fe2++4H++NO3=3Fe"+NOT+2H2O2(4)জ56ᐜGb⁐<b⁐ᜫ56G=⁐
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20Fe2++NO=±±Fe(NO)2+⌮ᔣÉÊ-ᨬÌFe(NO)2+ÍᐰÏᓄFe3+,ÐÑᵫÓ⁐UÕ⁐;(5)ᑭᵨ~ᵯØ~ᳮ-hNO!Fe2+ᙠXÚḄᵯ᩽ÜÝDᡂ-ßàáâᦑäᫀὃçὃè~ᳮḄéêßàஹßàëᫀìíedᐵ
î஺28ஹ1.llmol/L-s1.12vᜧᔾ|abூᑖ᪆௃(Dóô61sLᑮ⊝-õ21sYḄᱥ]Ḅ^Uᓄ^1.3mol,íö÷ᑮBḄ`᳛-øᔠßà`᳛úûeüᓄýëþÿ
ᦪᑮN%(g)Ḅ᳛(2)⊝ᦪḄᭆᵨᡂᱥ⊝Ḅ◀"ᱥ⊝Ḅᑮ(3)#ᜧᱥ%&᳛#ᜧ&'ᐭA)*+#ᜧ,-./&#ᜧ./&⊝⌮ᔣ23&456ᓄ᳛8945⊝#ᜧ;(4);ᓣ=&BḄ#ᜧ&>ᔣ23&ᔾ@&⊝ᦪA;Bᓄ.ூ⚪FGH௃(1)J21sK5Ḅᱥ%Ḅ
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L1.3mol,ᑣ45ḄBᓄ
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