河南省濮阳市2022-2023学年化学高三上期中检测试题（含解析）

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2022-2023
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⏚ᨵC.FeSCh
ᐭNaClO⋎⁐D.ᵯᨵḄ⛳NaCl□᩽▬!⁐7ஹ#ᑡ%&ᐳ()*ẚ,Ḅ-A.Ớᓣ0B.23*ᩈ5ᔾ▬C.⏀89:D.;ᓄ=>9:8ஹ?4.9gMgFeḄ@ᔠᱥᙠ%DḄE⏚FᐰHIJᑮ᪗MNO#NO2.24L,ᔣHIQḄ
ᐭRDḄSTᐙᑖHIᨬQᡂḄḄYD-A.8gB.10gC.10.2gD.11.2g9ஹᐵ9ᨵ[ᱥḄ\]^_-()A.CHQbC3H8஺de-fgᱥB.fᑖh᪀>deᐹᨵklḄᓄmឋYC.FᐰoSpYDḄqbqrsὑuDkfD.ᔣvrw
E⏚xy⁐

210ஹWஹXஹYஹZ-z{|ᦪ~ᜧḄᕜᐗ஺ᐗWbZᡂḄᓄᔠᱥᐹᨵzឋ9:Qᐸ:⏚ឋ஺WᡠᙠᕜᦪᦪkfWbYfஹXbZf஺#ᑡ^_\]Ḅ-A.ᨬᓫ᝱=ᓄᱥḄeឋXH2so4,ᡠåæÒÓឋC1>SঞÂç#èéêëoìí¶·ᙠ¡ᵯ¢îbuHIᑣæÒÓឋP>Nট{ᓄᔠᱥðêåÅᨵ᩽ឋᐳ()ñêåÅᨵæ᩽ឋᐳ()ঠó³ᑮ#ᓴᐗḄæÒÓឋ⌲ö÷øᡠå⏚ឋHC1>HIড{úûK+>cr>s2ঢCஹPஹSஹCIḄᨬü(uᓄᱥ¦I:ᓄᱥḄ⏚ឋ⌲öণẬᓄ=(H2Se)-ÿ⁐ஹᨵH2sḄA.1B.2C.3D.4

315ஹ100mL0.Olmol/LḄ⏚10mL0.Imol/LḄ⏚ᑡᦪὅᜧὅḄ!()A.OH-Ḅᱥ%Ḅ&B.CXV-Ḅᱥ%Ḅ&C.C(HCO")D.ᵫ)ᵯ+Ḅc(OH-)316ஹNA,-./012ᦪᑡ3456Ḅ!()A.ILO.lmol/L7⏣)9:ᙠḄ<=>?ᦪ,O.INAB.@ᦪ,NAC.16.0gCuOOCu2sḄPᔠᱥ9R□+>ḄᦪT,0.2NAD.ᙠ᪗JKL2.24LUVRU=>ᦪT,0.3NA17ஹᑡᨵᐵᓄYᵨ[⊤]56Ḅ!A.^_Ḅᵯ>`«O♦♦HB.CO2ḄabcdOoOC.᪶ᑁᨵ89>Ḅ=>ddCCH,—CH—OHD.Ḅgh!d2-^_ijCH»18ஹᓄYklஹm᛻oᑗᐵ஺ᑡᨵᐵrst56Ḅ!()A.uvᐹᨵxyḄᔾ▬|}~ᵨᔾᦈᑁḄᨵB.Ẇᵨᦔᵯ}|ᔾ᳛C.t|¡⊈᪆ᑭᵨ¡¥ᨵᱥ%N¦᜜D.Ớ⏚©ᐹᨵªyḄ<ᓄឋᙠ«¬9/ᐭ〉&Ớ⏚©~ᢙ°ὁᓄ19ஹ²⊤]³´µḄᓄYᵨ[!2s2pB.X:XC.ns'D.X-X20ஹᑡᐵᩩ·Ḅ+>¸¹`ºᑏ56Ḅ!A.¼0½ᑴAsḄ¿ÀÁ³dNa++CO2+NH+HO=NaHCO3l+NH*32B.ÂÃÄÅᘤ=ᳮd2Al3++3CO+3H2O=2Al(OH)31+3CO2TC.⏚@╅9É/&ḄÊAdMg2++2HCO-+2OH-2HO+MgCO1+CO23D.³&ḄËÌ9É/Ba(OH)2kᡂÎÏ%&ᨬᜧd2Al3++3SO+3Ba2++6OH=2Al(OH)31ᓝ3BaS(M21ஹᑡᨵᐵᓄYᵨ[⊤]56Ḅ!

4A.
ᓄḄᵯNa'OHB.ᦪ53ஹᦪ78ḄỚC.ᑖD.ᵬḄ᪀N0Q-C%r22ஹᙠ100࠷!"5LḄ#$%&!ᘤ(ᐭ*+,ḄN2O4,!ᘤᑁN2O4.NthḄᱥḄ,0ᓄ᝞⊤ᡠ4:=/S0210306090n(N2O4)/mol0.3c0.150.125b0.12n(N0)/mol0da0.350.360.3626ᑡ89:;ḄNO2?@0ᓄ⊤4ḄABCD᳛0.006mol-LL5B.AF@6BC2NO2g=N2O4gḄG⊝IᦪK=0.216C.2s!ᘤᑁJKLMBCNḄ1.1O>PD.ᐸRᩩTU090sVᔣ!ᘤX(ᐭ0.3molNO2,YZ[G⊝\G⊝]^_Gᙳaᑖ,bcdஹe⌱g⚪iᐳ84ᑖk23ஹ14ᑖklᨵ6ᑡ⊤nḄopq□qAl3+ஹFe3\Cu2+>Ba2\K+▢qNO3ஹOHஹCl\CO2\Xn'(n=lᡈ2)3AஹBஹCஹDஹE<ᵫRwxᡂḄzp{|ឋᱥRwᡠ~Ḅ▢ஹ□qUa஺
1]ᑖ᪆{ᑨᐸᨵḄpᱥ<—.iᓄk•
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3Cuᢗᐭ¯ᨵ¢,D|Ḅ°±CuU|¥X¡(£H2s04,Cu⌲³|¥±´▬¶ᨵ·¸⁐^_¹l,ᑣᱥD*+~ᨵP»qḄiaCḄq¼½kᑏ¹Cu|¥Ḅq¿À_______»
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ᐙᑖ⍎H?SঠBḄᔠ᎔ᐭᐭ⏚⚞◀⏚ᑡ!"#ᑮNaiᡂ&.()*ᑡ+⚪-(1).⏚/30%NaOH0Ḅ1ᘤ3ᣚᡂᑖ5ᧅᐸ89:.(2)A;<=>?@ḄABCDEF,C;<Ḅ"ᵨF.(3)HIঝKLMᑮḄNO:.(4)ᑴ#NalO,ḄABCDEF.QᐭHSR⛳/TNaIO?@ᑴ#NaiḄABCDEF.23(5)HIঠḄ“ᑡ!"”ᒹXYஹ[\ஹᔠ]Y/[\ஹ^!".(6)_⚠aᐭ5.08gỚᓫd3ef?@Ḅg᳛F88%ᑣᨬk#ᑮg&ḄdF.26ஹ(10ᑖ)mno:pᓄrsᧇ஺vwxyzᑭᵨ᝞*;<ᔠᡂmno஺

6=>Ḅ?@᝞*:CH3cH2cH2cH20HCH3cH2cH2cHo?@ᱥ/gᱥḄᐵᦪᑡ⊤᝞*-9/࠷/(gcm஺)0ឋmn⏣117.20.81090mno75.70.80170wxHI᝞*-6.0gNa2Cr2Chᐭ100mL30mL0᠒ᐭ5mL⏚ᡠ#0yRB஺ᙠAᐭ4.0gmn⏣/
஺ᨵN¡¢£B0஺£D¤ᢝ?@¦F90—95࠷,ᙠEᦈ¨90࠷©*Ḅªᑖ஺ªᱥ᎔ᐭᑖ5ᧅᑖ«ᨵ¬«®¯ªᦈ¨75-77C✄ᑖg2.0g஺()*ᑡ+⚪-(1)wx±ᔲNazCnO,0ᑮ⏚³´ᳮᵫ____஺(2)ᐭḄ"ᵨ:o3
¯=N¸@¹ºḄm»C¼:.(3)½¾;<¿B1ᘤḄÀÁ:,D1ᘤḄÀÁ:o(4)ᑖ5ᧅÂᵨÃÄÅÆÇḄ!":(Ém»)ᫀ᪗Ì)஺a.ÍÎb.®c.Ï5d.᪗Ð(5)mnoÑg&<Òᑖ5ᧅᑖᙠ_____«(É“½”ᡈ“*”)(6)?@¦@¤ᢝᙠ90—95C,ᐸsÔ:o(7)ÕwxmnoḄg᳛F%஺27ஹ(12ᑖ)F×ØCLஹB஺ஹFe3+ḄÚᓄឋÛÜvᓄÝᐶßyzàáâ᝞*wx:

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ᓄᐭ⏚DஹEᙳḄᓄD⁐᠒᠒஺ECCL,ᐜᵫ#⁐$%⁐&'⁐⌲)ᡂ⁐஺$+,-./012Ḅ3456789:;ᧇ᝞>I
SCN”ឋ4@ᓴBCDEᓄឋC12ᜧG
SCN2,HSCNḄᵯJK$'NNOIIAgCKஹAgBrOᙳPQGRHICLSBrzTUᡂBrClஹBrClᕈ⁐WXY$5࠷,@RRZTUজ5678\$D⁐Ḅ]^_ᵫGSCN-aCLEᓄbcde_fᐗBaEᓄhḄᳮᵫ_ঝkl/0m/5678noḄᔠᳮឋqᵨs⊝uv]ᳮZwCLlxyDQz⁐Ḅ]^ঞ|+,E}⏚&'⁐ᓄḄ]^~/0᝞>ᵨᑖzᧅᑖEḄ>Qz⛷ஹᦈ⁐ᱥ4x}ᐭAgNChQzᑮᨵ⁐஺qᔠᓄ8ᵨZw⁐Ḅ]^

828ஹ(14ᑖ)⏚(H3P02)_c
ᓄᐹᨵ¡¢]ឋ£¤>ᑡ¦⚪(1)H3P஺2_cᐗ¡⏚ᑣH3PO2(aq©JªḄ«¬$:஺(2)H3P02®NaH2PthᙳP¯QzḄAg+¢]$°±²PᵨGᓄ8╄°জH3P02ᐗBḄᓄᔠ´$ঝᑭᵨH3P02¶·ᓄ8╄°TUEᓄᑺ@¢]ᑺḄᱥ4Ḅx¹º$4:1,ᑣEᓄᱥ$c(¼ᓄ8K)½ঞNaHPCh$___(¼“À”ᡈ“⏚K”)ᐸQz_____(“Ä⏚ឋ”“ឋ”ᡈ“ÄÅឋ”).(3)H3P02ḄÇᑴÉ_¯(P஺@Ba(OH)2QzTUᡂP%ÊËSBa(H3Po2),&ὅÍ@H2sTU஺ᑏ@Ba(OH)2QzTUḄᓄ8ÏÐK:o(4)H3P02ÑPᵨᵯÒ᪆Éᑴᜓ“ÕÖᵯÒ᪆É”×]ᳮ᝞ØᡠÚ(□ÜS▢ÜᑖÞßᐕá□J▢Jâl)□᩽ÖÖ]ᧇÖ▢᩽Öজᑏ□᩽Ḅᵯ᩽TUK__________ঝᑖ᪆ÖP:ᑮ113Po2Ḅ]^:(5)⏚(H3P04)ᙠRQzᔜæᙠçKᱥ4Ḅxᑖᦪ6épHḄᓄêë᝞Ø:জᔣNa3PO,Qzᐭí⏚&pH±10îïᑮ5ḄlÐḄð⌕TUḄJÏÐK$oঝ±ØnòNaH2P()4Qzᔜóôªᜧ5ᐵöÀ÷Ḅ_<,(¼⌱⚗üý)Aஹc(Na+)>C(HPO)>C(H+)>C(HPO2)>C(HPO)24434Bஹc(Na+)>C(HPO)>C(OH)>C(HPO)>C(HPO2)24344Cஹc(H+)+c(Na+)=c(OH)+c(HPO)+2c(HPO?)+3c(PO?)+c(HPO)2434Dஹc(Na+)=c(HPO)+c(HPO2)+c(PO43)+c(HPO)24434ঞᎷ~ᙠ25'Cyo:0.1mokUNa3PChQzḄpH=12,ÿ
Na3P஺4Ḅᦪ(ᵨKh⊤)

9Kh=molL“ᶍNa3Pthஹᶇᨵᦔᦪ#$஺29ஹ10ᑖ$ᙠ'()ஹ*+,ᔣ./0ᘤ2ᢗᐭ'5N26789:;2+3<'஺2NHjAH<0஺
19:>?▤AvB$C“ᡈ“="$v⌮$HIvB$________⌲LC“Mᜧ”ᡈ“PQ”,,S$v⌮$⌲L,9:TᑮV⊝XvB$Cᡈ“="$v⌮$஺
2TᑮV⊝IYB9:Z᳛ᵨvᵨ$⊤⌮9:Z᳛ᵨV\$⊤ᑣv
N2=VH
O2
3,ᑡ_`2abc9:Z᳛defghḄiᓄ᳛ḄkC#l$஺AᐸnᩩpqrX*s0ᘤtuBᐸnᩩpqrXᓣf9:tw()Cxᵨᔠ〉Ḅ{ᓄᑺDᢝ0ᘤtuqrᐙᐭ'5Ḅh
4▭82◤⌕()ᑴᙠᔠ〉Ḅᑖ᪆()qfqḄko2022-2023ᔁὃᫀ᪆$ஹ⌱¢⚪ᐳᒹ¦22Q⚪஺§Q⚪ᙳ©ᨵªᔠ⚪«Ḅ⌱⚗$1ஹDூ⚪®௃A.᪷±²³´Yᵯ᩽·ᵯ¸Ḅ¹᩽º»¼▢᩽A┯¿ÀB.Xᵯ᩽·ᵯ¸ḄB᩽º»¼□᩽78Âᓄ9:XᜫÄᵯÅ□᩽ḄÆ5PQB┯¿ÀC.Yᵯ᩽¼▢᩽ÇÈ2ḄCM+ÊËᵯÅ78Ì9:C┯¿ÀD.Xᵯ᩽¼□᩽ᜫÄᵯÅY¼Íឋᵯ᩽XᜫÄᵯÅY¼Ïឋᵯ᩽ᑣÇÈ2Ḅᙠᵯ᩽Ð⊤☢ᜫÄᵯÅrCL,78Âᓄ9:DBÒÀᦑᔠᳮ⌱⚗kD஺2ஹDூᫀ᪆௃⚪ᑖ᪆;AஹÇÈஹÕtÖkᕈᵯ2ឋḄᑖᦣwÕtÙÚᔾ▬Ýᵯ₹ßÅᦑA┯¿ÀBஹÇÈ2àáᐝãäᨵᱯæçèÕt2àáᐝãçéêᐝëᦑB┯¿ÀCஹÇÈ2ÇÆÚÅaàìíÕt2ᑖᦣÆÚÅaàìíᦑC┯¿ÀDஹÇÈ·ÕtḄîÆïðᙠñᑖᦣÆÙÚòóᜧQôὅQñInm,IὅöñInm100nm÷øᦑDBÒÀᦑ⌱D஺ὃù;ὃúûÇÈஹÕtḄîÆᱯüḄýᐵ´ÿ஺3ஹBூ⚪௃A.lOminᱥᡂᱥᜧᜧᯠᱥ⌲!"ᡂ

10ᱥ$%⊝'ᔣ)*ᑣ,-.ᱥ/Ḅ1!"Ḅᑣn=l,ᦑA'34B.᪷678ᦪ6:;lOminᱥᡂᱥᜧᑣlOminᜧᦑB┯=4C.᪷678ᦪ6:;lOminᱥᡂᱥᜧᑣlOminᜧᦑC'34D.ᙠ5minXḄᱥ/Ḅ1?L6mol/L,05minXḄᱥ/Ḅ1Ḅ@ᓄ?2moi/L-L6moi/L=0.4mol/L,ᑣ,0.4mol/LBXḄ%ᙳD᳛?v(X)=~~~~:-----=0.08molL"min",ᦑD'345minᦑ⌱B஺4ஹA0.4molூGᫀ᪆௃A.v(M)=2L=114mol-L>.min»,JᑁLMNᱥ/ḄD᳛OPQRᐸT1ᦪ5minOP15min,Y%ᙳD᳛=2v(M)=2xl.l4mol,L"miiri=1.18molL"min-i,ᦑA'34B.,UVMWᘤḄ.YN@-.Ḅ/1N@Z[-.Ḅ\]^N@WᘤM_ᔠ-.\N@Nabᑮ%⊝d᝱ᦑB┯=4C.ᓣghiᓄᑖklᑖᦪᜧᡠn'⌮D᳛pᜧᦑC┯=4D.,?:⌮ᡠnXஹYNaqᐰsᓄ?ᡂᱥbᑮ%⊝d᝱XtὑḄᱥ/Ḅ1"RImoLᡠnvwḄx1"RakJ,ᦑD┯=4Gᫀ⌱A஺ூGᫀyz௃{⚪Ḅ᧕┯y?B,⌕~᪷6ᓄ%⊝Ḅᱯᑨ%⊝d᝱⌱Ḅᱥᳮ1◤⌕ḼḄ@ᓄ@ᓄ஺5,Cூ⚪௃A..YNaTḄᦪA┯=4B.CLNaOHV?Ch+2NaOH=NaCl+NaClO+H2O,:ImolCLᐙᑖs)ᵯkᦪ?NA,B┯=4C.4.6gNaḄᱥ/Ḅ1OZnol,Na2(hNa?஺M□k▢kḄkᦪPp21,ᡠnᨵ0.2molNa+Ḅ_ᔠᱥMᨵkᦪ?0.3NA,C'34D.50mLi8.4mol/LḄHSOMᨵ/Ḅᱥ/Ḅ1n(H2so4)=18.4mol/Lx0.05L=0.92mol,¡¢£⏚¥qᐰ,24ᡂSO2Ḅᱥ/Ḅ10.46moL§ḼḄ¨©£⏚@ª«N¬Z[®ḄSO2ᑖkᦪ"R0.46NA,D┯=4ᦑᔠᳮ⌱⚗Co6ஹCூ⚪௃A.°±xḄFe²³ᐭᑮµCI2Ḅ¶-·M®¸±⁐ºᦑA┯=4

11B.ᔣNa2cChM⌲»»$¼»ª½⏚¾ᨵ-¿®ᐜNazCOs+HCbNaHCOs+NaCLᦑB┯=4C.FeSO,M$ᐭNaClO6Fe2++3C10-+3H0=2Fe(OH)+3Cr+4Fe3\®±⋎⁐ÂÃᦑC'3423D.ᵯ»ᨵÄÅḄ⛳NaCl□᩽2CÈL2e-=Cbt,▢᩽2H2()+2e-=H21+20H,▬Êw˱⁐ᦑD┯=4ᦑ⌱C஺7ஹDூGᫀ᪆௃Ì⚪ᑖ᪆A.ỚᓣÏᓽLᵫÒ᝱@?-᝱ẚÔḄLᑖkḄÕᵨ×A⚗┯=4B.ØÙ-ÚᩈÜᔾ▬ÞRᱥᳮ@ᓄ¾ᨵẚÔᓄßB⚗┯=4C.⏀áRâã⏣ᑖkåÚẚÔẚÔḄᑖkÕᵨ×C⚗┯=4D.HC1-.RâᙠâᑖkḄÕᵨæᡂH+ஹC1,ẚÔçஹèékḄᐳëßD⚗'34Gᫀ⌱D»ὃyὃíᓄßḄîïẚÔ஺8,BூGᫀ᪆௃n(NO)=0.1mol,ᡂO.OlmolNO,s)ḄᵯkḄᱥ/Ḅ1?n(e-)=0.1molx(5-2)=0.3mol,Mðᙠ:Mg—Mg2+—Mg(OH)2,FeTFe3+—Fe(OH)3,òwn(e-)=n(OIT),óm(ÂÃ)=m(_ᔠᱥ)+m(OH-),ᡠnm(ÂÃ)=4.9g+0.3moixl7g/mol=10g,ᦑGᫀ?B஺9ஹCூ⚪௃A.CWOLöᵬ⏣4C3H80:a⏚øaùNNLöúᱥA┯=4B.û᪀ýöឋ/û᪀Nឋ/NLöJÿB┯C.ᵫᯋḄᙳCH,ḄCஹHḄᦑᐰὑCD.!"#$ᨵ&'()*⏚,-./01D┯஺3ᫀ⌱C஺10ஹCூ3ᫀ7᪆௃WஹXஹYஹZ:;(<ᦪ>?@ᜧḄBᕜDEFᐗH஺ᐗHW)ZIᡂḄᓄᔠᱥᐹᨵO;ឋQ-RSᐸR-.U⏚ឋWᡠᙠᕜDᦪEF<ᦪᑣWHᐗHZSᐗHQW)YFஹX)ZFᑣYNaᐗHXOᐗH஺A.YZ[ឋ\]ᨬ_ᓫa᝱cᓄᱥḄdeឋ\]ᑣcᓄᱥḄdeឋX>Z,ᦑA┯B.f'(ᨵ2gᵯ(ij'(ᨵ3gᵯ(iᵯ(ik᪀/ᦑB┯CX)YIᡂḄ'(ᓄᔠᱥᓄfᡈnᓄfoὅ#▢□'(Ḅᦪstuᙳ12,ᦑCD.cj⏚v⏚ᦑD┯ᦑ⌱C஺11ஹBூ⚪sx7௃জFeᐗHᓄᔠyᵫ0yz+2yஹNiᐗHᓄᔠyᵫ+4yz+2yᑣFe{)|᩽01Ni(h{)᩽01ᦑজঝᵯ;ᵯ;ᵯ#ᵯ7-.#Ḅ▢'(ᔣ|᩽ᔣ□'(ᔣ᩽ᦑঝ┯

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ᓄBCᵯ᩽BCFe-28+2OH-=Fe(OH)2,ᦑঞ┯Þßটᵫ¿À{áâᵯãÖឋᵯãᵯ᩽◤⌕æᙠÖឋᵯ¥|ᦑটÎ;ß┯ÞḄᨵঝঞᦑ⌱B஺12ஹCூ⚪éê¥௃AஹNaClO|CKT¥ᦑ~CKTḄ?@cìO.lmol/L,A⚗Î;ßBஹ᪗ïðñ622.4LòóS,MHC1OᓄឋᜧPH2sQᐵ%STU,ᐗ=ᨬWX⏚Ḅ⏚ឋJKU,ᐗ=IឋJKᦑঝ┯ঞNஹPEZ[ᐗ=IឋJKLN>P,MᓫB]^_ḄᩩaQᐵᦑঞ┯টdAᓄᔠᱥ%ᵫ]Iᐗ=fᡂh%ᵫIᐗ=fᡂi᝞NH4NO3.kl᪀nᨵIᐗ=pᡂḄ.Aqrstᙠᐳvi᝞NaOHnXdAvஹ᩽ឋᐳvNazOznXdAvஹI᩽ឋᐳvᦑট)*ঠᓴ[ᐗ=zᑮ|Iឋ⌲~Kᑣ᝱ᓄᱥឋ⌲~KᓄᱥḄ⏚ឋᦑঠ┯ডdAḄᵯAl᪀DEr᪶ᵯ₹ᦪᜧᵯAᦪErᦪdAᜧᑣ;dAᜧLS2>C1>K+,ᦑড┯ঢ;ᐗ=_ḄᨬWᓄᱥḄᓄᱥḄᓄᑖLH2CO3ஹH3PthஹH2s04ஹHC1O4,K⏚ஹnJ⏚ஹJ⏚ஹJ⏚CIḄIឋᜧPS,ᑣ⏚ឋJKLHC1O4>HSO,4;ᐗ=_ḄᨬW⏚⏚ឋ⌲~Jᦑঢ24)*ণS]SeEZ[ᓄQ⁐ᨵᑣẬᓄ(HzSe)Q⁐ஹᨵᐗ=ḄIឋKᐸᓄᱥSeḄIឋPS,ᑣẬᓄ(HzSe)᝞H2sᦑণ┯¢টঢ)*

13ᦑ3ᫀ⌱B.15ஹAூ3ᫀ7᪆௃Aஹ⏚᪷\ᜧR7\ᡠc᪷ḄᱥḄ:ὅᜧSὅABஹ⏚᪷\ᜧR7\-.#⏚᪷ḄᱥḄ:ὅSὅB┯Cஹ⏚᪷\ᜧR7\-.#⏚c᪷:ὅSὅC┯Dஹ⏚᪷\ᜧR7\Sὅ-.Ḅឋ]ᵫRᵯ'Ḅc᪷:ὅSὅD┯3ᫀ⌱A஺16ஹCூ⚪sx7௃A.ILO.lmol/L⏣R-.#ᙠḄ;(Ḅᱥᨵ⏣R⏣#;(ᦪO.INA,R#OᨵᜧḄ;(ᡠ;(ᦪᜧO.INA,A┯B.cឋᧇᵯ#᩽ὑ11.2L᪗a¡a¡02,ᐸᱥḄ0.5moL¢ᵯ(ᦪ2NA,B┯C.£ᵨ᩽¥¦,16.0gCuOCM+0.2NA,16.0gCuSCi?+0.2NA,ᡠ16.0g©ᔠᱥ#□'(Ḅᦪs0.2NA,2CD.ᙠ᪗ª«¬.¡/ᑭᵨ22.4L/mol¯°±²D┯஺ᦑ⌱C.ூ3ᫀ³´௃±²µ᝞⏣R-.#ᡠc;(ᡈ;(Ḅᦪsᡃ¸¹¹º»¼½¾#ᙠ-¿ÀÁÂÃ-ᑺ#ᡠᨵḄÅ;(ᡠᙠÆ⚪Çe⌕ÉÊËÌ/⌕ÁÂÍÎÌ⁚Ð⚪஺17ஹAூ⚪sx7௃A.ÑÒ:#ឋÒÓ;()c;(tÔIᡂÇÕᐳᵨᵯ(Õᐸᵯ(£×H,ᦑAB.CO2Ḅk᪀O=C=O,[ØÙk᪀uÚÛÜ#;(ÝÞᜧ;(ḄÝÞÀ⚪#CO2ḄuÚÛÜ#;(ÝÞ;(ḄÝÞᦑB┯C.;(Ḅ᪶ᵯ₹ᦪ6,᪶ᑁᨵ8g#(ᦪ6+8=14,ᡠÅ;(â⊤ä×C,ᦑC┯CH,—CH—OHD.ḄEåᨵ3g;(ÑÒᙠ2æ¿[⏣µçè:×2-é⏣ᦑD┯CH,ᦑ3ᫀ⌱Ao18ஹDூ3ᫀ7᪆௃êëᐹᨵì]Ḅᔾ▬½ᔾᦈᨵða¡ᦑAẆòóᵨôᦔᵯ½ö÷øâùú÷øûa᣸ᦑB⊈.þ᪆ᑭᵨÿ᪆
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14.ᑺ¥ᢙ§ὁᓄᦑD┯஺19ஹBூªᫀ᪆௃Aஹ®¯Ḅ᪶᜜ᵯAᦪ10,±²;®¯A┯Bஹ®¯B)*Cஹn³*%&⊤µ;®¯C┯DஹX%&⊤µFஹCkBrஹI¶D┯ªᫀ⌱B஺20ஹAூ⚪67௃A.·¸¹ᑴº#Ḅ^_»²¼⛳]NaCl¾¿ÀnSᐭCO2,ÂᡂÃ⏚1ÄÅ]2ᓄÆdAÇÈNa++CO2+NH+HO=NaHCO31+NH",A)*32B.ÉÊËÌᘤḄËÌ.ᳮ¼⏚¿Àn(ᐭÃ⏚1¿À^_AF++3HCO,=A1
OH31+3CO2TB)*C.ÏMgCCh®¿Pᓄ╅Ñ¿PÃ⏚╅¿ÀnÒ(TÓḄÔº¿À^_Mg2++2HCO+4OH-=2HO+Mg
OH2j,+2CO^,C)*2D.ÕÖ¿ÀnÒ(Ba
OH”ÂᡂÄÅBÓᨬᜧr_SO×ᐰÄÅ^_LA1J++2SO^'+2Ba2++4OH=A1O+2BaSO4i+2HO,D)*2ᦑ⌱A஺21ஹBூ⚪67௃A.ᓄ1PdAᓄᔠᱥᐸᵯAL◌Ú6Û-ᦑA┯;B.BÓᦪ=BAᦪ+nAᦪBAᦪ53ஹnAᦪ78ḄỚ.ALáI,ᦑ⌱Bᦑ⌱B஺22ஹCூᑖ᪆௃᪷ã⊤äᦪã%å60sr^_æçèᑮé⊝ᑣb=0.12moL᪷ã^_N24g=2NO2g,10srN2O4ᱥBḄÓḄëᓄÓ=0.3moL0.l5moi=0.15mol,ᑣa=0.3mol,ãìᑖ᪆ª஺

15ூ⚪!"#௃A.10sᑁ&N(h⊤(Ḅ*+,-ᙳ/᳛1v(NO2)=32■R.OOGmollIsL10s3143/᳛55LxlOs60.006mol-L7s“ᦑA┯9:B.᪷<ᑖ᪆,60s3+,?ᑮ-⊝-⊝3,NO10.12mol,NO10.36moLBC15L,*DEF+,2NO(g)#NO4(g)242220.12molC(NO)_24Ḅ-⊝GᦪḄᨵNc-ía7=4.63,ᦑB┯9c(NU?)(0.36mol)I5L)C.I10sᑁ&Nth⊤(Ḅ*+,-ᙳ/᳛1P(NO2)=(জ"=0.006moHJJK&L+,/᳛MN2s3N(h5LxlOsḄᱥḄO10.06mol,N2O4ḄᱥḄO10.27mol,PQᱥḄO10.33mol,RDRC3PḄSTUV6PᱥḄOWUᑣ2s3BᘤᑁST1+,IḄ"[=1.1\]^Ḽ+,Ḅ`a+,/᳛⌲cd5I2sᑁ0.30molḄᓄe+,/᳛ᜧ60.006mol-L'-s1,ᡠ&2s3hᡂḄNChḄᱥḄOᜧ60.06mol,PQᱥḄOᜧ60.33mol,ᡠ&2s3BᘤᑁSTjk1+,IḄ1.1\&lᦑCD.ᐸnᩩpqr90ssᔣBᘤuvᐭ0.3molNO2,x1BᘤCqrᐙᐭNO?ᡈN2O4{|N2O4ḄCᑖᦪ{ᜧ}~-⊝3
-⊝UP-ᙳᑖOᜧᦑD┯9ᫀ⌱C஺ஹ⌱⚪(ᐳ84ᑖ)23ஹK2cChBa(OH)2CNO33Cu+8H++2NOj-3Cu2++2NOt+4HOFeCh2ூᑖ᪆௃᪷<Ḅ+,(ᐳ)+,ḄᑨḄᔠᱥ஺ூ⚪!"#௃(1)ᱥ¡¢£▢uCO3?¥Ḅ¦K+ᡂ¢£ឋᱥᐸ¨□¡qᐳᡠ&ᐸu¥ᱥ1K2cCh,▢uḄOIT◀«K+ᐳ᜜¦Ba?+ᐳᡠ&¬¥ᱥ1Ba(OH”஺®ᱥ¯°±²³¢ᑨ(2)ABᑖ´1K2c03Ba(OH)2uḄ¥஺ᱥCuµᨵX",¶CAḄ£·¸ᔠ3¹hº⁐¼½ᔣ*¼½u¾ᐭ¿OÀHNO,¼½Áᑖ£#ᒕÃÄ⁐Å,ᑣ¢CuᨵCu2+,q£6Æ⏚ḄÄ⁐¼½,1BaSO,34ᡠ&X1SO4%C1CuSO4(3)CuᢗᐭÉᨵ¿OD£·ḄÊËuCuq£#v¾ÀH2s04,Cu⌲c£#ËÌ▬ÎᨵÏÐ⁐P,ᑣᱥD¥µᨵlÑuḄNO஺Ò⏚ÓÔ«H+,Æ⏚᪷ᙠ⏚ឋÖ᛻FᐹᨵTᓄឋ¢&ÙÚᓄ1Cu2+,Cu⌲c£#ÀÆ⏚Û
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ᓄB⏚ᡈ⏚C⏚ᡈ⏚ᦑC┯D.X஺2,Aᨵᱥ⏣A-B-CḄᓄ!A-C"#$ᓫ&'A-B-CḄᓄA-CḄᓄᦑD┯(ᫀ⌱B஺25ஹ,-./ᑭ12FeS+2H+=HST+Fe2+ᔾᦈH2s6.,■9:;<6=.>?>-ᵫAB⁐2DE⁐3I.+6OH=5I+IO+3HO3HS+IO=3S+I+3HOFGHᨔ5.28g32232ூᑖ᪆௃ᵫᑴᜓPQRSAQRᵫFeSTU⏚ᑴᜓHzS,BQRᵫỚWNaOH>-GX3I+6NaOH=NaIOj+5NaI+3H2O,YH2sZᐭB\NalCh>-GX]^_3HS+IO=3S1+3HO+I,ᔣᡠb>-cᐭ222U⏚defgᐙᑖ⍎jH2S,CQRᔾᦈklḄH?S,mQRB

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(5)0.8()17gcm-3,Ḅ(6)᪷⚪ᡠᱥᱥḄᦪ!"ᢝᙠ90—95࠷,%"&'()*+,-./ᐸ12345ᓄ(7)7Ḅ᳛x%,᪷ᐵ:;C4H10O-CHO4874724x2<=>x=51o27ஹMnO2+4H++2C@(B)0=Mn2++CLT+2H2ODᐰF(ᡈ■IJ᎔ᔾ)◀NOᓄPQJRSTQᜐᳮWXᵫᵯ[;>\ᜐ]^_ᨬa^bcd15ᓄe⁐gIhiᙠj⊝Fe3++3SCN-=^Fe(SCN)3,l-OQSCNmnSCN3Boj⊝ᔣ⌮rᔣstuv⁐BrCl+H2O=HBrO+HCl,Cr+Ag+=AgQ1,AgBrO᧕gᦑyzᡂAgCl|}ூᫀ<᪆௃(1)জAWXhᙊFh5ᓄ═B⏚zᡂOᓄ═ஹOQ[r;>MnO2+4H++2Cl-A_Mn2+4-C121+2H2O,ᦑᫀMnO2+4H++2Cr_A_Mn2++CbL+2H2O:ঝBWXDᐰF■᎔ᔾCWXhḄ⛳OᓄgI◀NOQhḄOᓄPQJᵫOQᨵ᣸ᑮQhᜧQ⌕ᵨIᔾᦈTQ¡¢WXhRSTQᜐᳮWXᦑᫀDᐰF(ᡈ■IJ᎔ᔾ)◀NOᓄPQJRSTQᜐᳮWXফজ᪷ᵯ[;F$CN¥>\ᜐ]^_ᨬa^bcd15ᓄ¦§DWXhe⁐vNḄ¨¦ᵫSCN-1CL5ᓄ©3ªc\ᐗ¬15ᓄᦑᫀᵫᵯ[;>\ᜐ]^_ᨬa^bcd15ᓄঝe⁐gIhiᙠj⊝Fe3++3SCN-=^Fe(SCN)3,l-OQSCN2SCN+CL=2Cr+(SCN)2,nSCN•BoᑣnFe3++3SCN-=^Fe(SCN)3j⊝ᔣ⌮rᔣstuv⁐ᦑᫀl-OQSCW2SCN+C12=2Cr+(SCN)2,nSCN-BoᑣnFe3++3SCN\=^Fe(SCN)3j⊝ᔣ⌮rᔣstuv⁐ঞl-ḄOQ²zᡂOᓄ³Oᓄ²c´ª᧕zᡂ⏚µ²⏚O[¶[zᡂ·⁐|}Oᓄ¶µ³⏚¶[zᡂµ³⏚¶᧕gᡠzᡂḄ·⁐|}Oᓄ¶ᦑᫀ

19BrCl+HO=HBrO+HCl,Cå+Ag+=AgCl[,AgBrO᧕£6èᐭAgNOj£·¦hᡂAgCl¼½஺2éê:ë⚪ὃí«ឋî²ÝᫀïMð+,
ᳮä#ë⚪ᐵò஺ë⚪Ḅóéä(2)ঞ◤⌕÷øùᓄúûhḄè#+,uhᡂḄ⏚Ḅü᪷c(HPO)>c(OH)+1ýH3Pþÿឋ2P4+3Ba(OH)2+6H2O=3Ba(H2Po2)2+2PH3T222HO-4e==Ot+4H+□᩽ḄT□᡽ᦣᧇḄHPO<▢᡽ᦣὅ222ᡂH3PChHPO2+H+=H2PO4ADl.lxlO-3mol/L4ூᫀ<᪆௃(1)¦H3P023ᐗh¸⏚yᨵ¹ᑖ»zᵯᵯr;H3PO2=H++H2P02ஹP[ᩭ½⏚ḄᵯḄᵯ⏚ḄᵯᢓᑴḄᵯᦑ[Bᜧᐵ:>c(H+)>c(HPO)>c(OH)ফজH3P஺2hPᐗ¬ᓄᔠ^+1ঝ᪷H3P02ÂAg+hÃὅᱥÅḄ22-ÆÇ14,4moiAg+ᙠh=ᑮ4moie@1molH3PO2ᑣᜫN4moie,ᡠPᐗ¬ÉÊ+5^ᱥH3Po4,ᓽ5ᓄᱥH3Po4;ঞ᪷H3PO23ᐗh¸⏚ᑨÍNaH2P஺2ÎÏ⏚¸¦H2P02.H++HPO=HPO2,zᡂH3PO2;(5)জᔣNa3PgIhçᐭè223⏚épHê10ëìᑮ5ḄlhHPO4”BoஹH2P04-Bíᜧᡠ»zḄHPO42+H+=HPOঝAஹ[cC(HPO)>C(H+)>C(HPO2')>C(HP0),2434⌱⚗AþBஹH2PoᔆᵯᜧᡠC(HP(V-)(HP0),⌱⚗B┯!"Cஹ#$%>c34&ᙠᵯ₹)ឤC(HD+C(Na+)=C(Off)+C(HPO")+2C(HPO?)+3C(POj)⌱⚗C┯!"Dஹ#$2%&ᙠᱥᧇ)ឤC(Na)=C(᧜0")+C(HPOZ)+C(POj)+C(HPO),⌱⚗D89":ᫀ⌱AD"34ঞPO?'(aq)+-0প=:HP("-(aq)+Off(aq)CDE(mol/L)"0.100LᓄE(mol/L)N0.010.010.01O⊝E(mol/L)N0.090.010.01»c(O")o.oixo.oi3Khc(PO"jW0.09~L1X1°m°1/L°[\N]⚪ὃ`aᓄbcdefᵯghஹᵯ᩽deghḄkᑏm஺o[pqrstWᐗ%v⏚ஹ8xஹy⏚vzxḄᳮ|eᵨ~fᵯ᩽dehḄkᑏmḄ஺

20]_29ஹᜧAD!ᓄ#$᳛᠒'(Ḅᡂᦔ᳛!*+,⊝3⌮ᔣ01ᱥḄ3ᓄ᳛!஺ூ⚪789௃প<=>?ᐭN2AH2,BḼDEᔣFGVHDIv
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2Nᑮ,⊝>D$᳛PQ⌮$᳛STUVᓄ#WᵨYUḄᱥZ⊤\ᓄ#$᳛ᐸᦪ_`aPQbcᦪ`aᓽvDe2=Vf
N2=V
H2
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