河南省安阳市2022-2023学年化学高三上期中经典模拟试题（含解析）

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2022-2023
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Ḅ+ᔠH@ᨵyc(NH4+)+c(H+)=c(CT)+c(OH-),®H@pH=7,ᓽc(OH)=c(H+)=lxlO'7mol/L,ᡠ°c(NH4+)=c(Cr)ᓽᨵc(C1)=c(NH4+)>c(OHT)=c(H+),B⚗┯mC.®pHx±ᓽH@c(H+)x±²⏚Ḅᵯ/ᔣ¨©³H@H+¤¥ᐰ´ᩭ¶²⏚ᵯ/KᩭḄH+vw··H@ḄH+H@஺¸NH4clH@ᙠ2⊝Ḅᵯ/⊝ᔣ¹©³H@ḄH+ᐰ´ᩭ¶Ḅᵯ/ᡠ°²⏚Ḅᵯ/w·ºᓄ»H@Ḅᵯ/wC⚗┯mD.pH=llḄNaOHH@c(NaOH)=c(OH)=^r=¼*=10-3mol/L.®¾⏚¿^⏚ÀÁ´ᑖᵯ/ᙠpH=3Ḅ¾⏚H@¾⏚ḄÂÃvw·ᜧlO+mol/L,®ÄyopÅH@CHjCOOHḄᱥMḄ¢·ᜧNaOHḄᱥMḄ¢,᪷()0CH3COOH+NaOH=CH3COONa+H2OXYtq¾⏚>¢H@Æ⏚ឋᡠ°+ᔠH@ÇᐭÈÉH@ᕈÊ⁐D⚗3ᫀ⌱D஺15ஹDூ3ᫀ2᪆௃A.᪷ᓄᔠÌḄ¦ᓄOᐗÎḄᓄᔠÌᵫ-2-0,ᓄᔠÌᓣ!ÐBᓄ02¿BᓄÑᱥ஺ᐗÎḄᓄᔠÌᵫ+5-+7,ᓄᔠÌᓣ!ÐBᓄHCKh¿BᓄÑᱥC1ᐗÎḄᓄᔠÌᵫ+5-0,ᓄᔠÌÒÓÐÔÕCL¿ÔÕÑᱥᡠ°HCKhÖ¿Bᓄᑺ׿ÔÕᑺHC1O4,02¿BᓄÑᱥஹCL¿ÔÕÑᱥBᓄᑺḄBᓄឋØBᓄÑᱥ,ᦑAB.ÙᓄÚÛ¢ᦪa=8,b=3,ᓄÚ()08HClO3=3OT+2CIf+4HCIO4+2H2O,ÔÕÑᱥÀᨵCh,ᵫ22HC1O3->C12,ClᐗÎᓄᔠÌᵫ+5ÌÒÓ0Ìᦑ&ᡂ2moicLbÜ©ᵯ~ḄᱥMḄ¢2molx2x(5-0)=20mol,ᓽÝ()ᵯ~Ü©ᦪh209,ᦑBC.ᵫ&ᡂḄImolCbt+ᔠÞoM¢45g,ᑣn(CI2)+n(O2)=lmol,n(Ch)x71g/mol+n(O2)x32g/mol-r[n(CI2)+n(O2)]=45g/mol,2n(Cl)n(O)=21,ßb=2c=2,ᑣᵫᵯ~ឤdx(7-5)+bx4=cx2x(5-0),ᓽdx(7-5)+2x4=lx2x(5-0),22

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2025ஹ@))))3s23P$57ghᕜjklFeᐗḄmn%S2>C1᩽ឋqr᩽ឋᑖSiObdA1(OH)+NaOH=NaAlO+2HO,stuឋNaOH>AKOHbo.Nv2322ᕜjᐗwOᙠNḄxyvzᕜj{ᑮxr}~ឋ⌲ᡠHr}~ឋOᜧNூᑖ᪆௃᪷Rᐗᙠᕜj⊤Ḅᑖ᪆GAHᐗDCᐗEOᐗGNaᐗQSiᐗ,MSᐗRC1ᐗᔠᐗᕜj.ᱥḄ᪀.ឋḄᐵ\ᑖ᪆K஺ூ⚪*+,௃(1)᪷RGᐗ%Ḅ᪶᜜ᵯᦪᨬ᜜ᵯᦪḄ3ᑣᐗNa,ᐸ%᪀®1)))>RC1ᐗ%&ᦪ17,ᐸᨬ᜜ᵯ᣸3s23P5>ᵯ᣸Is22s22P63s23P5,6vḄ7ᡠᐹᨵḄ76vᦑ%᪶᜜ᨵ576vḄᵯ>¡¢ᵯḄ£¤¥᝱ᙳ6mv¨©C1%ᨬ᜜ᨵ76v£¤¥᝱Ḅᵯ>(2)ᐗFeḄ%&ᦪ26,ᙠᐗᕜj⊤ḄghᕜjVDIl55.85⊤FeᐗḄmn%>(3)ArḄ%᪀ᑣªᐗ.Arᐹᨵmvᵯ᪀Ḅ«¬S2®C¯¨vᕜjᐹᨵmvᵯ᪀Ḅ°ᓫ¬᪶ᵯ₹ᦪ²³ᐸ´µ²ᜧᦑ¶ὅḄᜧ³¸&s2>cr>(4)MஹDᑖ¹S®C,¶ὅºᡂḄᓄᔠᱥCS2,ᵫ2n¼B½qºᡂḄ¾¿À᪀ᵫ᩽ឋqÁᡂḄr᩽ឋᑖ>DஹQḄᨬÂÃᓄᱥºᡂḄᨔÅᑖ¹CO2®SiO2,¨CO2ᑖᨔÅÆSiCh%ᨔÅᑣᰚÈḄSiO2!(5)⊤}~ឋᨬḄᐗNa,.AlmÉa.NaᙠÊ45✌ᐜ.Í236ÎᣚÐÑ67ᑨ^ÒRa⚗┯=>b.A1(OH)37ᔲ4,ᙠNaOHÕtNaOHuGᑨ^ÒRb⚗IJ>c.ᓫ.Ö×ᓄᔠḄØ᧕ÚÛᑨ^r}~ឋÜḄÒRc⚗┯=>d.ᓫ.vÝÛḄÞÊ⏚0123ḄᒓàÚÛÅáâ}~Ḅã¤ឋÜᓽ}~ឋÜd⚗IJ>ᦑKᫀbd>(6)ᐜå1æ⁐EFᯠéæ⁐EF⌲êᜫÕtNaOH4,âA1(OH)3,ᐸᓄìÚA1(OH)+NaOH=NaAlO+2HO,ᦑuឋÉÈNaOH>A1(OH),ᓽ}~ឋNa>Al>O.Nvᕜjᐗ3223wOᙠNḄxyvzᕜj{ᑮxr}~ឋ⌲ᡠHr}~ឋOᜧN,ᦑKᫀA1(OH)+NaOH=NaAlO+2HO,stuឋNaOH>A^OH%>O.NvᕜjᐗwOᙠNḄxyvzᕜ322j{ᑮxr}~ឋ⌲ᡠHr}~ឋ஺ᜧN஺

2126ஹᐵᑖ<ᧅᜮஹy■D#;<᎔ᔾᑮB#(ᡈᐰ)2C10z+2Na0H+H0===2NaC10+0+2H0ᔾᦈḄCIO?(ᡈCIO2ஹSCO,■RF஺22222ூᫀ᪆௃B#ᑴᜓ~ᑮC102,ᡠ¤B#¥¦8NaClOssNazSOsᙠ§HS0Ḅ¨ᵨªᡂCIO,sNa2s04C248ᐰD¥¦«Ḅ;<¬~NaClOzᨔlD#ªᡂNaClOz,C1ᐗḄᓄᔠ(®¯h:¦⊤&°Kឋ,ᨵhFªᡂE8ᔾᦈḄFl■RFA]ᔾᦈB#ᒕFl஺(1)³´µᘤ«·¸᦮ᝅFºឋḄ»¨]9ᐵᑖ<ᧅᡭ½KiஹK,ᯠ«ᔣAஹE#À:dÁÂ2ÃÄᵨ⏀ÆÇÈÉ⚠ËÌAஹEᜐᨵFÎÏÀ,ÐÑ@«AஹEÁÂᑁᡂ,ÐÓÔḄ:ÕÖ×᦮ᝅFºឋØ´f(2)᪷Úµᘤᵨ⌶⌱_µᘤf(3)CḄ¨ᵨ]ᐰᨵ■᎔ᔾ¨ᵨf(4)D#CIO?shᓄÝஹ¯h:ªᡂNaClOz,ClᐗḄᓄᔠ(®¯h:¦⊤&°KឋᨵhFªᡂÚÞßᑏf(5)áDḄ;<¬~NaClOzᨔl◤⌕äåZᨔஹஹæçஹÁÂf(6)èéZêÑᡭ½Ki,ᐵযAḄ¨ᵨ]9ᔾᦈḄCIO?(ᡈCIO?ஹS0),■RFᦑᫀ892ᔾᦈḄCIO?(ᡈC10,SO2),■RF஺2ூ⚪*í௃(1)³´µᘤ«·¸᦮ᝅFºឋḄ»¨]9ᐵᑖ<ᧅᡭ½îஹïᯠ«ᔣAஹE#À:dÁÂÃÄᵨ⏀ÆÇÈÉ⚠ËÌAஹEᜐᨵFÎÏÀ,ÐÑ@«AஹEÁÂᑁᡂ,ÐÓÔḄ:ÕÖ×᦮ᝅFºឋØ´஺ᦑᫀ89ᐵᑖ<ᧅf(2)ᵨ50%¯h:Xᑴ30%Ḅð஺2;<◤⌕ḄµᘤᨵyஹËñஹòᴻôஹlᡠ¤°◤⌕yஹᜮfᦑᫀ89ᜮஹyf(3)CḄ¨ᵨ]ᐰ■D;<᎔ᔾᑮB#fᦑᫀ89■D#;<᎔ᔾᑮB#(ᡈᐰ)f(4)D#C102shᓄÝஹ¯h:ªᡂNaClOz,ClᐗḄᓄᔠ(®¯h:¦⊤&°KឋᨵhFªᡂ;<8õឋ;<ᑣåªḄö÷\892C102+2Na0H+H202===2NaC102+()2+2H20,ᦑᫀ892C10z+2Na0H+H0^2NaC10+0+2H022222(5)áDḄ;<¬~NaClOzᨔl◤⌕äåZᨔஹஹæçஹÁ»¨ᦑᫀ89f(6)ᔾᦈḄCIO?(ᡈCIO2ஹS0),■RFᦑᫀ89ᔾᦈḄCIO?(ᡈCIGஹS0),■RF஺2227ஹøᑖ<ᧅ2NaBr+Ch=Br+2NaCI᧕ᢵåNaOHBr+2OH=Br+BrO+H2O22H2sO3ᨵᒕᡈH2O2§û5ᡈBl
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22ᡂ.⏚34567ᡂBr,.⏚ᓄ⚞ᡂ.⏚⚞!9:ᔿᐭᡭ<b,⌲>ᐭH2O2?$@ABH2O2ᐜ0ᓄ-.⏚ᦑBᐭrᓄs?$Ḅ0ᓄ670ᓄrtupvᓫxḄᓄyz{|pq2NaBr+C12=Br+2NaCl,ᦑOᫀpq2NaBr+CL=Br2+2NaCl2(3)ᔿᐭ}ᔿ~vᓫx+'᧕ᢵᓽ$vḄ᧕ᢵḄឋxᦑOᫀpq᧕ᢵ(4)iCBᔾᦈiB~ᩭḄ⌕BvA᣸ᑮ◤⌕ᵨ0ᓄs?$ᔾᦈtuz{|pBr2+2OH-=Br+Br(T+H2O,ᦑOᫀpqNaOHBr+2OH=Br+BrO+HO22(5)IILᐭ0ᓄᙠ⏚?$¥0ᓄvtupvᓫxḄtuz{|᪷Lᵯu§ឤஹ7u§ឤ©ª«ᑏpqHO+2Br+2H+=Br+2HO,ᦑOᫀpqH2sChᨵᒕ¤ᡈH2O2ᡈ¡H2O2᠒2222HO2+2Br+2H+=Br+2HO222য¯LH2sO3+Br2+H2O=H2so4+2HBrHO+2Br+2H+=Br+2HO0ᓄ670ᓄᑺḄ0ᓄឋᜧ±0ᓄ2222ᱥ0ᓄឋpqHO2>Br>HSO3,ᦑOᫀpq0ᓄឋpH2()2>Br2>H2s222ூOᫀ³´௃µ⚪ὃ·ᱥxឋxḄ¸z¹ºᑖ᪆0ᓄ67Ḅ¼½¾¿ᵨtuz{|Ḅ«ᑏz¹zᫀḄÀÁ¡ᑖ᪆N⚪ḄᐵÂBÃ7ᳮḄᳮNÃᱥxឋxḄÅÆ஺28.AX(l)+X(g)=±AX(S)A^-123.8kj/mol0.00017(^1.7X10-4mol•L-1•min-1)bcaᐭÇᓄ325ᑺÈ᳛ʪ⊝Ìᨵᦋ)ÎᓣÐÈ᳛ʪ⊝ᔣ⌮zᔣÓÔ(ᡈÖᘤḄÖ×ØpEᱥxḄÙᦋ)ÊØEÚÛ¼Üᜧ)2(1-—)Poூ⚪RSN௃(1)pÞḄᰚ³à³ᑖáp-93.6C76࠷,AXsḄᰚ³p167C,âÎFãp$᝱AXspå᝱,ᡂImolAXs,~}123.8kJ,çḄ}ᓄyz{pqAX(1)+X(g)=AX(s)AH=-123.8kJ«mor',M325µ⚪èéOᫀBqAX(1)+X(g)=AX(S)AH=-123.8kJ«mor325(2)জØEFAX3X2ᙳp0.2mol,ᓽn,>=0.4mol,ÚÛ¼p160KPa,ª⊝FÚÛ¼p120KPa,Àª⊝FÚᱥxḄpn,᪷LÛ¼ëìí±ᱥxḄëìᨵn=0.30molo᪷Lî᝞ðÁñqÀᡂAXsḄpx,AX3(1)+X2(g)=AXs(s)

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