江西省吉安市2022-2023学年化学高三上期中教学质量检测试题（含解析）

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2022-2023
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8I.ῃḄ285.8kj/molN(g)+20(g)=2N0(g)AH=+111kj/mol222H0(g)=H0(l)AH=-44kj/mol22(1)ᓄᑺᙠNO2ᡂ!"#ᐸ%&'ᱥ(Ḅᓄ)*+,oU.ῃ-(2)ᔣ2Lឤ0120ᘤ45ᐭ2mol7ஹ6molH,ᙠ〉9Ḅᓄᑺ:ᵨ;<=CO(g)+lH(g)CHQH(l)222+H0(l)»ᑡ?@ABCD<=EᑮG⊝I᝱ḄK஺2A.Lᔠ"NḄGᙳ,PᢝRSB.CO,#4ḄNTᑖᦪᢝRSC.(%#ḄYᓄ᳛[\D.Lᔠ"NḄ1]ᢝRSE.1molCO2ᡂḄ^_ᨵ1molH—Habc(1)ᙠTJC_,NT2LḄឤ00ᘤ4ᐙᐭᱥ(ḄPf#ImolḄg#C0,;<=CO(g)+2H?(g)=CHQH(g)<=EᑮG⊝_CH.OHḄNTᑖᦪ(ᔛ)jn(H)/n(C0)Ḅᐵl᝞nᡠp஺2(mAজ9tun(Hz)/n(C0)=2,vw5minEᑮG⊝COḄYᓄ᳛0.4,ᑣ0Õ5minᑁGᙳ<=z᳛/31=஺|D_}ᔣ0ᘤ45ᐭCO(g)#CHQH(g)ᔜ0.4moLEG⊝_ḄYᓄ᳛(⌱“ᜧ”ஹ“”ᡈ“RS”)ঝ9tun(Hz)/n(C0)=l.5_EᑮG⊝I᝱CHQHḄNTᑖᦪAKn4Ḅ(⌱"D”ஹ“E”ᡈ“F”)m.ῃ(4)᝞nᵯ4ḄNOஹSO?ᑖYᓄ▲*#SO/஺ᱥ(AḄᓄ),,▢᩽Ḅᵯ᩽<=,K29ஹ(10ᑖ)CKh"NKᵨḄ'ᑺ,ᡃ¡¢2000£t⌲¥ᵨC1O2¦§¨"©ªᵨ«¬'.প'_,C1O24ḄFe2+ஹMi?+\YᓄᡂFe(OH)3#MnCh\°±ᱥ◀³ᙠ´µw+4Fe2\Mn2+Ḅᓄᔠ¶ᓣ¸BCCKhᐹᨵឋ.ফ¼½¾¿wᑡ*ÀᑴÂCKh,ÃÄᡂÅᓄ)<=*+,2KClO3+SO2==2CKh+஺বÇCh#HO(g)¿wÈḄÉÊᡂHC1#COᑏÌᓄ)*+,:22

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᪆௃}ᔠᱥ¡,()8H++HCO3=COT+HO,ᵫজঝᦪnr3¶·¸ᜧ}ᔠᱥḄo©3¹ºḄº»¸ᜧ,22½¾¿জ"G⏚ᨵᒕÁஹº}ᔠᱥhᐰ()஺Ãঝ"G⏚ᨵᒕÁ3¶·¸ᜧ}ᔠᱥḄo©3¹ºḄº»Ä¸ᜧ3ÅC᪷nঝঞᦪnr3¾¿"¹ºḄº»£Æ3½¾¿ঝ"G⏚hᐰ()3᪷n¾¿জḄᦪnr3,ᡂ3.36L^¥ᓄÇ◤⌕º}ᔠᱥḄo©+9.2gx(3.36L4-2.24L)=13.8g<16.56g,½¾¿ঝ"G⏚hᐰ()ஹº}ᔠᱥᨵᒕÁ3nX
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௃}ᔠᱥ¡,()8H++HCO3=CO2t+HO,ᵫজঝᦪnr3¶·¸ᜧ}ᔠᱥḄo©3¹ºḄº»¸ᜧ,2½¾¿জ"G⏚ᨵᒕÁஹº}ᔠᱥhᐰ()஺Ãঝ"G⏚ᨵᒕÁ3¶·¸ᜧ}ᔠᱥḄo©3¹ºḄº»Ä¸ᜧ3ᵫঝঞᦪnr3¾¿"¹ºḄº»£Æ3½¾¿ঝ"G⏚hᐰ()3᪷n¾¿জḄᦪnr3,ᡂ3.36L^¥ᓄÇ◤⌕º}ᔠᱥḄo©+9.2gx(3.36L4-2.24L)=13.8g<16.56g,½¾¿ঝ"G⏚hᐰ()ஹº}ᔠᱥᨵᒕÁ஺A.ᵫÊËᑖ᪆r3¾¿জ"Ḅº£Ì3hᐰ()3G⏚ᨵᒕÁ3⌱⚗Alm

11x=0.05mol,y=0.05mol,ØÙNaHCChqᨬ£᪷ÛNaHCCh,ÜḄAᑮNaHCChḄᑖᦪq⌱⚗Dßàᦑᔠᳮ⌱⚗[Coூäᫀoå௃ç⚪ὃêBᔠᱥḄØÙ஺᪷Û$¼ᓄHḄ?@ëᓄᑨíî⏚[ᔲÓᐰ-.[ñ⚪ᐵóqôõgὃê^/fᐗ÷ஹᓄᔠᱥøùúûᦪÛᑖ᪆:ᜐᳮþÿ
ḄὃḄ஺4ஹBூ⚪௃A.ᙠ⏚ឋᩩNOᨵᓄឋᑣX!"#ᨵFe2+,$%&#ᨵFe3+,ᦑA⚗┯*+B.,-./01ᡂHC1O,"3456⁐89$ឮ;ᑣ<=HC1->!#ᨵC12,ᦑB⚗?@+C.AB1CDFe3+ḄᓄឋELᦑC⚗┯*+D.89NH4clF>NH4஺᧕ᑖDNH3IHCLJKὅᙠMNOPᓄᔠᡂNH»C1,RSTUVWᓣYᦑD⚗┯*+ᦑZᫀDB஺5ஹCூᑖ᪆௃᪶01^ᵯ`᪶aᓄᡂᵯ113ஹ115ஹ117I118bcdᐗfᙳDhiᕜkᐗfᑖlDHIAmஹVAmஹWAm.nmᐗfAᔠomᐗf⌴qrsZ஺ூ⚪௃A.᪶01^ᵯ`᪶aᓄᡂᵯA⚗┯*+B.hVAmtuᕜkḄᐗfᵫwxyzD{ஹ|ஹồஹ╋ஹᑣ115ᐗf`hiᕜkhVAmḄᐗf,B⚗┯*+C.hVDAmtuᕜkḄᐗfᵫwxyzDஹ,ஹ
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14ூZᫀ᪆௃M⚪ᑖ᪆¤A⚗pH=OḄᕈ⏚ឋw"ᐳ¬+B⚗cOH-
=lxlO“mol♦L“®ឋHC03-$¬ᙠ+C⚗®ឋCu2\Fe3+$¬ᙠ+D.ᙠA1CL±⏚ឋA1OH4²$¬ᙠ஺ὃ§¤ᐳ¬§³¤ᑨµ`ᔲ"ᐳ¬1Ḅ⏚®ឋ·¸`ᔲ^01Ḽº஺16ஹCூᑖ᪆௃ᵫXஹYஹZᨬ᜜½ᵯᦪID17"¾¿ᐗfXDᐗf+YᐗfDÀᐗfZD,ᐗfQDhbᕜkVA,ᓽDÂᐗf஺ூ⚪௃Aஹᐗfᕜk⊤oÄmwᑮÆÇyzÈᜧoᕜkÉᔣËyzÌ¥⌱⚗A?@+BஹᐗfᡠᙠḄᓄᔠᱥᵬÎஹ%ᓄஹKᓄᡠÏ1ḄᓄᔠᑖlD-4,+2ஹ+4,⌱⚗B?@+CஹÀᐗfÏ1ḄᓄᱥKᓄÀḄ/ᓄᱥÐÀ⏚VW`⏚⌱⚗C$?@+DஹVAᨬ᜜½ᵯᦪD5,ᦑᨬÑᓄᔠD+5,⌱⚗D?@஺Zᫀ⌱C஺ூZᫀ§¨௃Ò⚪ὃᐗfᕜk⊤ஹᐗfᕜksḄÓÔᑖ᪆ᐗf`⚪ḄᐵÕ஺᧕┯§D⌱⚗D,1ᑖ᪆QDVAmᐗf᪷ᐗfឋÖḄ×Øឋஹ⌴qឋÙÚᑨµ஺17ஹBூZᫀ᪆௃A.ᰚÜÝ®Þ$3ᵨàáâãäåDKὅ01¤SiO2+2NaOH0=Na2SiO3+H2O,A?@+B.ᙠæçᮞḄé¿ê#ᨵr
!ë8H2O2ìᑮL:2r+HO2+2H+=l2+2H2O,B┯*+2C.59Ḅíî./ïð⊤☢òᡂóô⁐êᡈô⁐ö÷ø½bᓄùí¤3Fe+4H20q=Fe34+4H2,C?@+D.“84úû”êᨵᦔᡂᑖNaClO
I“þᔓᮣ”⌕ᡂᑖ⏚ᔠᵨᓄCIO+C1+2H+=C12T+HO,D2ᫀ⌱B஺18ஹAூᫀ$᪆௃XஹYஹZஹWஹR'()ᕜ+ᐗ-./0ᦪ234ᜧ.X/6ᡠᨵ/9:;ᨬ=Ḅ.ᑣX@Hᐗ-Y/Ḅᨬ᜜Bᵯ/ᦪ63᜜BḄ3D.ᑣYᨵ2Eᵯ/B.ᨬ᜜Bᵯ/ᦪ@6,ᦑY@Oᐗ-YஹRGH,ᦑR@Sᐗ-ZஹWஹRGᕜ+.ᑣJᜐLMNᕜ+.Z6OPḄQR.ᐸTᓄᱥVWLXYWZ[\WL]^,Z@A1ᐗ-Wᓫ`6abcd□Vfg@ᵯVḄOᵨᩞᧇ.W@Siᐗ-஺AஹH/:;ᨬ=.Gᕜ+jklm/:;n=.GHjolp/:;4ᜧ.ᦑ/:;H

153S2+6H2O=2A1(OH)31+3H2St,ᦑC┯DஹX2RH2S,XzYH2O,XzYᑖ:;<ᙠ8>?H2sᑖ:;@ᨵT.ᦑH2OḄABCH2ODᦑD┯஺ᦑ⌱A஺19ஹDூᫀ᪆௃XஹYஹZஹWEᕜGᐗḄH7IJ5ᐗXᐗḄ*ᡂḄKL./$ᑣXHY*Ḅᨬ᜜PᵯᦪᑁPᵯᦪḄ2RᑣYCMᙢT1UᨬDḄJ5ᐗᑣMAlZஹWᙠᐗᕜG⊤ᜐ6)XḄ-YZ[Ḅᓫ$ᙠ\]^ᙳ`⁐a(bYஹZஹWஹMḄ*cᦪdefᜧᦑZN,WO஺hiᡠkXH,YC,ZN,WO,MALA.XH,ZN,WO,lᐗᡂḄᓄᔠᱥNH4NO3KᓄᔠᱥᦑA⚗┯B.XjtH,YC,ZN,WO,MA1,ᐸ*rstᜧᑮvḄwcA1>C>N>O>H,ᓽM>Y>Z>W>X,ᦑB⚗┯C.ᓄᔠᱥYW2ஹZW2ᑖyC02ஹNO,CO2⏚ឋᓄᱥNCh!⏚ឋᓄᱥ,2ᦑC⚗┯D.ᵨA1ᓫ$|□᩽|▢᩽ᵯNaHCOsᵯ.;ᙠ□᩽K3⏚8᪷⁐▢᩽8aᦑD⚗஺ᫀ⌱D.20ஹBூ⚪௃A.LiᙠaᡂḄᓄᱥLizO,NaᙠaᡂḄᓄᱥNazOz,ᦑA┯B.⏚ឋD═⏚¡¢⁐£ᐹᨵ)"Ḅ¥¦§¨©ª£«¨ᐸ¢⁐ᦑBC.CO2SiChᓄ¬)®¯ὅᑖᨔ(ὅ*ᨔ(±᪀!"ᑣCO2SiChḄᱥᳮឋ$!"ᦑC┯D.Fe´µ⏚¶·ᡂFe2+,Fe¸µ⏚¶·¹ᓄº»ᦑD┯ᦑ⌱B஺21ஹAூᫀ᪆௃Aஹ᎝½¾3¿ᦋᗐaḄ$U“ÃÃÄÅÆÇ⁐ÈÉ”ᦑABஹËÌÍÈÎÏÐ᣸ÒḄÓafÔ᧕⌼ᡂa×ØᦑB┯CஹªÙ᯼ÛÜÝ᧕⌼ᡂa×ØᦑC┯DஹᜧUᵨ1Þß⊟á⌼ᡂ(â⃩äᓄ⌼ᡂ(×ØᦑD┯ᦑ⌱A஺22ஹCூᫀ᪆௃AஹNaCNC+2åNa+1åᑣæᐗḄᓄᔠå-3,¶·¯Nᐗᓄᔠå!çᦑA┯;BஹNaCN+H2O2+H2O=NaHCO3+NH3T¶·Oᐗt-1åè¾-2åᡠ¨¶·H2O2|ᓄᑺᦑB┯CஹHCN⏚ឋCH2cChêᡠ¨ëìíîᑴNaCN◤Ôᐭ〉UḄNaOHᢓᑴᐸᦑCDஹ`(ô`õö÷ᦑD┯ᦑ⌱C஺øஹI⌱ù⚪úᐳ84ᑖü23ஹ33l>ÔᡂýþQ-OC—OC—O4molC6H6+CH2=CH2AleI3/HCIQ~CH2cH3

16^=^^>-CH(OOCCH3)CHOOCCH+2H2O^^-CH(OH)CH2(OH)+2CHCOOH23CIHC-^^-CHCI322ூᫀ᪆௃ÿ⚪ᑖ᪆ᵫBḄᑖஹCḄ᪀BAia/HC1,ᑣAᡂB,3ᑣAICஹDḄ᪀Cῃ2ᑖHCL!ᡂ""#$%ᑮD,'()*+D,-.ḄᏔὶᡂE#C-C#E123ᡂ456789ᡂ1,4-:;<=஺?@%AᑡC:1
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ᨵ⚪[,-EজḄᓄ]^_C6H+CH=CHAia/HQO-CH2CH3062235
ᓄᔠᱥCḄ᪀GCHCICHKIᙠ1bᓄcḄdef.3gdh49%ᑮᓄᔠᱥF,᪀^^CHOH
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CH2OOCCHL2H9஺;6
ᓄᔠᱥCḄ᪀OcHQCHiClm✏ᓄᔠᱥG6CḄᑖo᪀pEᐸᑖ.rᨵstuᓄ]v᛻Ḅ1Eᦪy1:1,ᑣGḄ᪀CilhC-qj^CIhCi஺ὃ{ὃ|ᨵ}ᱥḄ~ᔠᡂ+ூI{௃⚪ὃ|ᨵ}ᱥḄ~ᔠᡂஹᨵ}PQஹ▲ᑴᩩᑖo᪀pᑏஹ,-ḄᵨE6ᨵ}ᓄ]<ẠḄᔠὃ|E6ᨵ}ᓄ]ὃ⚪QEFGHḄឋᓄ஺?Nᱥᩭ~ᱥ6ᨵ}ᱥ~Ḅ⚪QE¡ᵨ⌮~£ᢕ¥ᱥḄ᪀ஹឋஹ¦§¨©ஹPQªᩩ«¬E®¯ẚ±E²⚪y.ᔜᱥὶ´µᩭ¶·⌮ᔣ~¹E¶º%ᑮ»¼C஺)½Uᱥᩭ¾Eᨵ}ᱥᙠ¿Àᓄ⌕UÁḄᓄ]EḄPQᨵஹ3ᡂஹ*4*◀9ஹÃᓄஹ3ÄஹÅÄE⌕ᔜPḄᱯ{EÇÈ᪷?ᱥᑖ᪀ᱯ{4ᒹËFGHḄtP9ÌÍᑨNᵨ஺ᨵ}ᔠᡂϬḄÐÑh⚪^£UÒ¡ᵨᔠÓÔḄ^£EᐸÓÔ_ÕÖ⊤Ø8ᧇ->.Üᱥ-y᪗ᱥ஺ᓽßày᪗ᑖḄ᪀4y᪗ᑖḄ"áᱯâEãFGHḄtPNäå9-ᵫy᪗ᑖN8ᧇᑖᔠὃ⇋ÐÑᔠᡂϬ4ᵫ8ᧇᑖÌÍy᪗ᑖ"áḄ᪀çEÖãFGHḄèᐭᡈᓄ9-)uḄᔠᡂϬÌÍë⌱4ÖÍឋஹíîឋஹï⁐ᔠᡂÓñᢣ¹9஺UÁḄᨵ}ᓄ]<óஹᐹᜓUÁḄö]G÷ஹ,-G÷6hø⚪Ḅᐵ$E⚪yúû.஺24ஹcN2NH2Mg+CO^^2MgO+CHS+OH=S2+HO322

17ூᑖ᪆௃ýXb2Eþᔠ@ᓄᐵ´ḄÿᓄᨵC(CH)—CO—CO2ஹN(NH)—NO-NO2ஹS(HS)TSCh—SChஹNa—NazO—NazChXᓄ4232ஹAMgᑣᨵ᝞ᓄᐵMg-CiCOXNaOHஹAH2sᨵ᝞ᓄHS^HS^S2,2ᑖ᪆஺ூ⚪௃(1)X"#$%ᙠḄ(ᓄឋ*⁐ᓫ-ᑣX02,a.AC./0᝞ᓄC—CO-CO2b.ANa./0᝞ᓄNa—NazO-NazCh;c.A1234567ᓄᐵd.AS./0᝞ᓄS-SO2TSO38C"9:⁐ᑣCNO2,ᓄᐵ.;"NH3-NOTNO2ᡈN2-NOTNC>2,=6ᡠ7ᫀCN2ᡈNH3(2)X"@ABCᑣXᓄᓫ-ADEF■HIᑣAHIMg,JKজ╅ᙠᓄ$NOḄJKJKPQR2Mg+CO2=^=2MgO+C,ᦑᫀ2Mg+CO2=^=2MgO+C(3)XTឋUᑣXNaOHA"ᐹᨵWXYឋᕡḄᑣAHS,ᡠ;ᓄᐵ:H2S^NaHS->NaS,22JKঝḄ]^PQRHS+OH=S2+HO,ᦑᫀHS+OH=S2+HO»22ூᫀ_`௃a⚪b⌕ὃefᱥ-hḄᓄijkᔠ⚪mnoᓄᐵḄᱥ-hḄᓄᨵpAqr@"ᓄstJKuv᝞wCஹNஹSஹFeᐗyḄᓫ-zᓄᔠᱥ{hḄᓄ"|ᑖJKuv᝞U-~@⏚Rஹ~@⏚R@1{hḄᓄ஺25ஹADBEᜧJKᱥ☢JK᳛JKᐙᑖ◀CLO$ḄCb2ch+Na2cO3=C12O+2NaCl+CO2(ᡈ2ck+Na2cO3+H2O=ChO+2NaCl+2NaHCO3)ᑴḄ⏚¡ᜧ¢£1.000mol/Lூᑖ᪆௃᪷4¥Ḅ¦#(2¨©JK)ᢥ¬13ᔠ®ᐭw£8%Ḅ⏚°$ᑴᜓCLO,²ᵨ£ᔾᦈCLO(2wCh)ᑴᜓ⏚Kᐜᵨ·¸AᑴᜓCL,¹®º·¸D◀ᔠ$ḄHC1»ᐭ#¦ᔠ®ᐭ·¸B,ᙠ·¸B$/0ᑴᜓCLOḄJKᯠ½¦ᑴ¾ḄCbOᐜ®ᐭ·¸C,;◀CLᩖ-ᨬ½®º·¸Eᑴ¾⏚;஺ூ⚪௃(1)᪷4¥Ḅ¦#(2¨©JK)ᢥ¬1:3ᔠ®ᐭw£8%Ḅ⏚°$ᑴᜓCLO,²ᵨ£ᔾᦈCLO(2wCL)ᑴᜓ⏚Kᐜᵨ·¸AᑴᜓCh,¹®º·¸D◀ᔠ$ḄHC1»ᐭ#¦ᔠ®ᐭ·¸B,ᙠ·¸B$/0ᑴᜓChOḄJK;ᯠ½¦ᑴ¾ḄC1Oᐜ®ᐭ·¸C,;◀2CLᩖ-ᨬ½®º·¸Eᑴ¾⏚·¸nÂÃATD—BTC—E,ᦑᫀADBE(2)pÄᳫÆᤅÈÉᙳ3JKᱥᐙᑖᜧJKᱥ☢JK᳛JKᐙᑖ·¸B$0ᡂCLOḄ»sÌᨵpÍḄCb⍎ÏÐCL"Ñ᩽ឋᑖ^᧕ÔÑ᩽ឋᑺÖᓄ×ᜐ·¸CᵨÙÚḄ

18Öᓄ¦CLᔾᦈᦑᫀᜧJKᱥ☢JK᳛JKᐙᑖ◀ChO$ḄCL(3)ÛÜ#2¨©JKᑣᑴ¾ChO;C12Na2c03JKᱥ/0ÝᓄJKᐸ$ᐗyß0àá+1àTàJKḄᓄãPQR2Cb+Na2co3=CLO+2NaCl+CO2(ᡈ2CL+Na2cO3+H2O=CLO+2NaCl+2NaHCC>3),ᦑᫀ2cL+Na2co3=CLO+2NaCl+CO2(ᡈ2C12+Na2CO+HO=C12O+2NaCl+2NaHCO3)s32(4)CLO©£JKḄᓄãPQRC12O+HO=2HC1O,CL£JKḄᓄãPQRCh+H2O=Ha+HClO,C1O22£JKä0ᡂHCIOåJK2.⌮£JK◀f0ᡂHC1Os0ᡂHCL²åJK.⌮ᡠ;ᵨCbO©£JKᑴᜓ⏚çÔᵨÔ£ᑴᜓ⏚Ḅb⌕è_"ᵨChO©£JKᑴᜓ⏚ᑴ⏚ஹ¡éᜧᦑᫀᑴḄ⏚¡ᜧ(5)ᵫ⚪.ÜChOᙠ42©;6Ìᑖ0ᡂC1202,ᦑ■ëJKìí½BºîïChOᑖ·¸B◤ìᙠ¢£$ᦑᫀ¢£(6)10.00mL0.80mol-L-'FeSOjM't1,n(FeS04)=0.80mol/Lx0.01L=0.008mol,24.00mL0.050OOmolL-'Ḅ⏚ឋKMnCh$n(KMn04)=0.050mol/Lx0.024L=0.0012mol,᪷JKMnO+5Fe2++8H+=5Fe3++Mn2++4HO20.0012mol═⏚òóὑõ⏚ö÷Ḅᱥ-ḄÚ0.0012molx5=0.006mol,ᑣøù½ḄlO.OOmLHClOóὑõ⏚ö÷Ḅᱥ-ḄÚ0.008mol-0.006moi=0.002mol,᪷JKHClO+2Fe2++H+=2Fe3++Cr+H2஺.Üøù½lO.OOmLHClO$n(HC!O)=—x0.002mol=0.001mol,t10mL⏚$2100mL“j8ஹ,0.01moln(HC10)=0.001molx----------=0.01mol,ᐸ¡--------=1.000mol/L,ᦑᫀl.OOOmol/L஺10mL0.0ILA26ஹMnO2+4HCl(¡)=MnCL+CLT+2H2O◀$Ḅᓄûc⏚ឋü⏚òNazSiChD$═⏚ò2ý⁐E$áþÿூᑖ᪆௃ᙠAᵨᓄ⏚ᑴᜓ᪷ᨵᓄᑖ᪆BḄᵨᑭᵨC12+2Fe2+=2Fe3++2C"#Fe+%&'ᓄ()*+,⁐ᑖ᪆᪷ᐗ/Ḅ012ឋ456ᨬ89ᓄᱥ;Ḅ<ᓄᱥ⏚ឋ456ᑭᵨ5⏚ᑴ=⏚ᩭ?@⏚ឋ5=6᪷ᓄABᨵᓄ&6ᓄ&CDEấ⏚G)*6◤⌕⏚ឋ8═⏚()*◀Lᓄ&6ᯠNOPᓄA஺ூ⚪STU௃(1)ᙠAMnCh⏚6VWMnCLஹCLஹHO,YZ[\]2AMnO2+4HCl()=MnCI+C12t+2HO22(2)ᑭᵨabᑴᜓcdḄ6efgᓄឋ]C12>Fe3+»ᵫi⏚ᐹᨵᢵlឋ6ᙠᑴmnᑮḄᨵᩖqHCk

19A(3)tᑭᵨCE&⏚lW]C+2H2SCM)=C(M+2s஺22H20,B\Na2s)*6lW]S(h+2H2s=3SI+2H2஺6fgS(hᐹᨵᓄឋCu,)*6ᑮ,)*⁐6fgSChᐹᨵឋDᐭḄKMnCh)*6ᓄ◀LSO26ᑮ)*Ḅ⁐⁐6ᑣfgᒕSO2,CO?஺ᐸᐭuᨵNazSKh)*ḄE6lW]Na2SiO3+CO+H2O=Na2CO3+HSiO3I,ᑮE)*22+6VW⁐6g⏚ឋ]H2CO3>HSiO3,fgᐗ/Ḅ012ឋ]C>Si»2ூᫀ¢£௃¤⚪ὃ¦§P¨ᑴᜓḄ©ᳮᑖ᪆஺ª«ᱥqឋqḄ?@6ᐗ/ᕜ®Ḅᵨ஺¯°±¤²ᱥqឋqtU⚪ᐵ´஺27ஹµ⚠·¸¹ḄzENO6z;§P⌼ᡂx᡾½⌲¿)U6ᨵÀ⁐ÁVW6WᡂÂ⁐)*AᔾᦈᢵlḄÅ⏚6■ÇE½6;§P⌼ᡂx᡾2CU+2NO=2CUO+N3NO+7Ce4++5HO=2NO+NO+722Ce3++10H+11.2abூᑖ᪆௃§PÈÉÊᐜᐭÌ◀LᑁḄ¹6ÎÏNO¹Ḅx᡾§P6ᯠNᡭÈᑖ*ÑᧅÓÔ,%½EÖÅ⏚ᙠAVWNO,×BN◀LᢵlØᩭḄHNO3,×C◀L

20ᵯü6Ce4+äë©VᱥCe-%nᵯüᱥqḄ\]Imolᵯü6᪷nᜫᵯüýឤ6©üýឤ6ᵯ₹ឤᑏ3NO+7Ce4++5HO=2NO+NO+7Ce3++10H+,ᦑᫀ3NO+7Ce4++5HO=2NO+NO+722Ce3++10H+ঝNOᓄᡂNO1,NᐗḄᓄᔠᵫ+3+5,ḄOᐗᓄᔠᵫ0-2,᪷ᜫᵯᦪ$%,n(NOi)n(O2)=21,NOḄ'(agL",bL)*+n(NO)=amoLL"xbL=abmol,,ᐭ᪗/0ḄO2Ḅ1^=abmolx22.4L/molx—=11,2abLoᦑᫀ11.2abo228.4H(g)+2N0(g)=N(g)+4H0(g)AH=-U00.2kJ/molDE0.08mol/(L.min)23FH2SO42222N0+6H*+5e-=NH/+H2஺ூᑖ᪆௃I.(1)ᑏ:;<=⊤?Ḅ=ᓄ@ABCDজX4-ঝ-ঞX4ᑮFᓄᑺHᙠ0JKLN0?MᡂNOPᐸRSTᱥVḄ=ᓄ@W(2)X⌮ᑮZ[⊝]^⌮_᳛$%ᔜbᑖḄ'(ஹdefᵫghMḄᐸRijᱥᳮefᑨm[⊝ḄᱥᳮenopqMᓄ)ᱥᳮeᵫᓄᑮfᓄrsᑮZ[⊝W(1)জᵫCOu:vᱥVḄeஹun(H2)/n(CO)=2XwxyCOu:ᔜᱥVḄeᑭᵨ|}xy[⊝]ᔜbᑖᱥVḄeஹᔜbᑖᱥVḄeᓄe᪷v=Ac/Atxyv(H2);ᐜxy)(0[⊝ᦪK,xy'(ᖪQc,u[⊝ᦪK$ᑨmopᑖ᪆Xw:ᓄ᳛ᓄWঝᔠ%ᓄ@xeᦪ][⊝]MᡂᱥḄdeᨬᜧWID.ᵯXḄNOஹSO2ᑖᓄNH4+PSO42-,ᑣᵯ5so2+2NO+8H2஺(NH)2SO4+4H2SO4,᪷ᵯᔠᵯLᳮᑖ᪆஺4ூ⚪௃I.(1);<=285.8kJmolT,জH2(g)+1/202(g)=HO(1)H=-285.8kJ-morl2ঝN2(g)+2O(g)=2NO(g)H=+lllkJmorl22ঞH2O(g)=HO(1)H=-44kJ-mor12জx4-ঝ-ঞx4ᑮFᓄᑺHᙠ0KLNChMᡂNOPᐸRSTᱥVḄ=ᓄ@4H2(g)+2NO(g)=N(g)+4HO(g)H=-1100.2kJmor,222(2)CO2(g)+IH2(g)=CHiOH(1)+H2O(1),Aஹᔣ2L¡ᘤ£ᐭ2moicO2ஹ6molH,ᢥ᯿11Mᡂᱥᐰᕈ+᝱ᔠ1Ḅ[ᙳeª«¬ᢝf2f®rsZᑮ[⊝¯᝱ᦑA┯±WBஹᔣ2L¡ᘤ£ᐭ2moic஺2ஹ6molH,ᢥ᯿11ᡠw³C(hPH2Ḅ1´ᑖᦪª«¬ᢝfᦑ2

21B┯±WCஹᔣ2L¡ᘤ£ᐭ2moicO2ஹ6m0IH2,ᢥ᯿11CChPᵪḄᓄ᳛ª«$%f®¶ᔲZᑮ[⊝¯᝱ᦑC┯±WDஹᱥ¶1Mᡂᱥ¶+1ᔠ1Ḅ(¬ᢝfrsZᑮ[⊝¯᝱ᦑD^WEஹImolCChMᡂḄ¸]ᨵImolH-Hºm»rs^⌮_᳛$¸Zᑮ[⊝¯᝱ᦑE^WᦑᫀDE(1)জH2PCOvᐳImol,½¾ªn(H2)/n(CO)=2,XH22molஹCOImoL5minZᑮ[⊝]COḄᓄ᳛0.4,¿(]CO(g)+2H(g)^CHiOH(g)2¾ª(mol)120ᓄ(mol):0.40.80.4[⊝(mol)0.61.20.4¡ᘤḄ¡´2L,ᑣv(H2)=0.8mol/(2Lx5min)=0.08mol/(L*min),0.450)(0[⊝ᦪK=Âg]ᔣ¡ᘤ£ᐭCO(g)PCHiOH(g)ᔜ0.4moLg]'(ᖪ0.4+0.420“,ᔣ⌮ᔣopZÃ[⊝]H2Ḅᓄ᳛23WU.6+U.4[1.2I?2,পঝᔠ%ᓄ@xeᦪ][⊝]MᡂᱥḄdeᨬᜧᦑÄn(H2)/n(CO)=1.5]Zᑮ[⊝¯᝱ÅCHjOHḄ1´ᑖᦪ3CÆᦑ⌱F஺(4)ᵯXḄNOஹSChᑖᓄNH4+PSO4?-,ᑣᵯ5so2+2NO+8H2Oᵯ(NH)2SO4+4H2SO4,ᵫᵯXᱥVAÉ⏚ᐸᓄ@H2s0—ᵯ]□4᩽JÎᓄÉᜫᵯMᡂÉ⏚᪷ᑣ□᩽Ḅᵯ᩽¶SO+2H2O-2e=SO42+4H+,▢᩽ᵯ᩽NO+6H2++5e-=NH++H2O«429ஹᓄឋK2sCh2Ch+2HO(g)+C=4HC1+CO2C1O+21=2C1O+IC1O+41+4H+=C1+2222222I2+2H2O0.675ூ⚪௃(1)ᙠÑÒ³Fe2\Mi?+ḄᓄᔠᓣÔᑣCl(hḄᓄᔠÕÖᓄᑺᐹᨵᓄឋᦑᫀᓄឋW(2)VeឤX2KC1O3+SO2=2C1O2+K2sᦑᫀK2s஺4

22(3)ØCLP0(g),³Ù=ḄÚÛMᡂHC1PCCh¶Ü=ᓄ@2cE+2஺(g)+C=4HC1+CO,ᦑᫀ2cl2+20(g)+C=4HC1+CO2;2(4)জᵨ:ᓄÝ*+Þßឋᵫàgᩩâ0ãäåC1O2,C1O2£ᐭḄỚᓄçᓄ12,èéKLᡂCUE,2C1O2+21=2C1O/+12,ᦑᫀ2ao2+21-=2CIO2-+12;ঝᵫà?⊤spHß13]C1O2,rᓄᡂL,C1O2-+41+4H+=Cl+2I+2HOᦑᫀCKh22+41+4H+=C1+2h+2H2O;ঞS2O32rcio211i1.0x103mol/Lx0.01L1.0x105molm(CIO2)=n(CIO2)xM(CIO2)=1.0xl0-5molx67.5xl03mg»mol1=0.675mg,ᵫN᪵IL,ᡠwCIOḄ'(2°.675஻?g=஺675mgL\ᦑᫀ0.675஺