江西省浮梁2022-2023学年高三化学第一学期期中复习检测试题（含解析）

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2022-2023
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113ஹAூ!ᫀ#᪆௃A⚗'(Mg)*⏚+,Mg+HSO4=MgSO4+H2T,'(MgCO2+,2Mg+CO22-=2MgO+C,.ὅ012ᣚ+415ᓄ++789:A┯<B⚗=*⏚>+?ᡂ*⏚>AB*⏚⊤D⏚ឋ?ᡂSO2,AB*⏚⊤DF5ᓄឋBC⚗GᙠI5JKL?ᡂFe3(h,GMNOP+?ᡂFesChMH2,ᦑCD⚗SthPQRᐭBa(NO3)2TUJ+VWXYZ3SO2+3Ba2++2NO+2H2O=3BaSO41+2NOf+4H+,ᦑD஺34ஹCூ⚪[\#௃A.er2஺g]^_⏣5ᓄᡂ_⏚A┯<B.Ca2+SO+?ᡂCaSChbcB┯<C.ᔜVWef+]ᜧᐳiCD.ᵬklml⁐⏚ឋᩩpCOf]ᜧiᙠD┯<!ᫀ⌱C஺5ஹCூ!ᫀ#᪆௃A.ᔣFeCbTUJrs)tNDu1v⁐ḄTUJ?ᡂwx⋎⁐bcz{1?ᡂw|5ᓄGbcAfB.}M=*⏚s~ᡠPQᱥRxTUMᮞNᑮxTU⁐ஹᮞNABPQᱥJᨵSth,1f]ᨵCO2,SCh4]ᮞNBfC.ᔣTUJrsK3[Fe(CN)6]TU?⁐bcABTUJiᙠGVWCD.ᓄỚNᔠ¡₩£☟2ᑖ¦ᑮᨵ§¦m¨⁐ஹN¦©⁐1f]AB1ᓄ^Ớ⃓«ᑮᨵ§¦JᓄJᨵf⛳MLỚ?sᡂ+ᐸ+Ḅᱥ4¯⃓«ᑺDf஺⚪⌱C஺6ஹDூᑖ᪆௃᪷²ᓄᔠ³Ḅᓄᑨµᓄᔠ³ᓄḄᦪ¶·¸AB?5ᓄ+¹ᑮḄᵯWᦪ[·»ᑣ½ὑ¾Ḅᨬ»஺4ூ⚪[\#௃A.MnO2~Mn,?ᡂImolMn,◤⌕4moiᵯW½ὑmolAl3B.WO3W,?ᡂImolW,◤⌕6moiᵯW½ὑ2moiA1C.CrzChCr,?ᡂImolCr,◤⌕3moiᵯW½ὑImolAl88D.C03O4C஺?ᡂImolCo,◤⌕molᵯW½ὑmolAl,39zᔠᑖ᪆½ὑA1ᨬ»Ḅ1CO3O4ᦑ!ᫀ⌱,D஺7ஹB

12ூ!ᫀ#᪆௃A⚗ஹÃ☘1Å■N■ÇM■ῖḄᨵ§ÉÊᩞᧇᦑA┯<B⚗ஹÍÎ1Gᔠ'(Ï©§ᩞᧇᦑBC⚗ஹᜩᯠÒÉMᔠᡂÒÉ1ᨵ§ÓᑖWᩞᧇᦑC┯<D⚗ஹÔ_ÕÖ×1ᔠᡂᨵ§ÓᑖWᩞᧇᦑD┯<ᦑ⌱B஺8ஹCூ⚪[\#௃জ»'(ÙÚiᙠ᯼Jজ┯<ঝ=⏚Ýᐝ᧕ᑖ#àáᙠâ⁐ãᑺäJঝ┯<ঞ»'(æÚiᙠ᯼Jটট|5ᓄÙTUàáᙠèᨵÒÉéḄãᑺäJটঠëNÝᐝ᧕ᑖ#iáᙠèìᴻéḄâ⁐ãᑺäJঠ┯<ড}⏚ÙïQÚiᙠèÒÉéḄðñäJড┯<!ᫀ⌱C஺9ஹCூ!ᫀ#᪆௃জᙠëᓄ¾TUJrsNaOHTUòḼNaOHTUḄfµsᐭ,?+:AlCl+3NaOH=Al(OH)331+3Na஺ஹAl(OH)+NaOH=NaAlO2+2HO,]ᑮḄDu1ᐜ?÷⁐bcøbcT#জùᔠ⚪ú32ঝᙠû¾⏚ÙTUJsü⏚òḼü⏚Ḅfµsᐭ?+,NaAlO2+HCl+HO=NaCI+Al(OH)3ýAl(OH)2+3HCl=AIC13+3HO,]ᑮḄDu1ᐜ?÷⁐bcøbcT#ঝùᔠ⚪ú32ঞᙠNaOHTUJrsëᓄ¾TUòḼëᓄ¾TUḄfµsᐭ?Ḅ+,4NaOH+AlC13=3NaCI+NaAlO2+2HO,3NaAlO2+AlCl+6HO=4Al(OH)1+3NaCl,]ᑮḄDu1ᐜ©BmD2323uø?÷⁐bcঞfùᔠ⚪úটþ÷TUJrᐭ*⏚>TUþ÷?ឋᑮḄDu1?bcஹbcfÿ
টᔠ⚪ঠᓄA1C1+3NH3HO=A1(OH)i+3NHCl,ᑮḄ!"⁐$%ஹ'3234$%(
ঠᔠ⚪ড*⏚,-ḼḄ/ᐭ12AgNO3+NH=H2O=AgOHl+NH4N()3ஹAgOH+2NHyH2O=[Ag(NH)]OH+2HO,ᑮḄᐜ!"⁐$%4$%
567ডᔠ⚪322ঢ9⏚:;ᵯ
=ᙠ?@ᓄABC9⏚BCD$ᑮ!E⋎⁐$%GHᐭ9⏚2Fe(OH)3+3HSO4=Fe(SO)3+6H2O,ᑮḄ$%
IJ⁐ঢᔠ⚪224Kᫀ⌱C஺10ஹDூKᫀ
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_ᓄB┯WCஹỚabᐭcKIO3,C┯WDஹaefᨵe⏚hᵨ;7ZjkḄlDmnKᫀ⌱D஺11ஹCூKᫀ
᪆௃A.opCuqr᩽ᵯtuᔣᵫAgzOxyzᑮCu,ᦑA┯WB.|}~ᳮAgzO~m᩽ᦑB┯WC.r᩽Ḅᵯ᩽2Cu+2OH--2e-=CuO+H2O,ᦑCmn஺D.ᵯqOIFᔣr᩽(2

13□᩽)ᦑD┯W஺ᦑ⌱C஺ᙠ~ᵯᵯᵫr᩽ᔣm᩽▢□ᑖᔣ□▢᩽஺12ஹDூKᫀ
᪆௃AஹᧇḄᨵᓄᦑAmnBஹ◌ᘤᑴ¢£ᨵTḄấ⏚bᡂ:;ᓄ5ᓄᦑBmnCஹ¦§¨©ᢣA«9⏚©ᡂ©ᓫ=ᦑCmnDஹᡭ®¯°ᑴᢣᓭ┐³ᦋ5ᱥ=Ḅ᜜¶·ᨵTᱥ=ᡂ:;ᱥᳮ5ᓄᦑD┯W஺ᦑ⌱D஺13ஹAூᑖ᪆௃ᵫᐗ¹ᙠᕜ»⊤Ḅ½ph¾WஹX¿Àᕜ»YஹZ¿Áᕜ»ÂYḄᨬ᜜Äᵯᦪn,ᑣWḄᨬ᜜Äᵯᦪn+2ஹXḄᨬ᜜Äᵯᦪn+3ஹZḄᨬ᜜Äᵯᦪn+4,ᑣn+n+2+n+3+n+4=2L4n=12,n=3,ᑣYAlᐗ¹WNᐗ¹XOᐗ¹ZClᐗ¹஺ூ⚪ÇÈ
௃A.WNᐗ¹XOᐗ¹ᓫ=ÉÊឋX>W,ᦑAmnB.@ᓄᱥÌᓄᱥḄ⏚ឋYA1,ÌḄ@ᓄᱥḄᓄᱥAl(0H)3:;Íឋ?@ᓄᱥWN,ÌḄ@ᓄᱥḄᓄᱥHN03:;Î⏚ᦑB┯WC.ᓄᔠᱥᰚALO3ᓄᔠᱥAlCbᐳÑᓄᔠᱥᑣᓄᔠᱥḄᰚÒÓᦑC┯WD.WNᐗ¹ÌḄ?ᓄᱥᑖÔÕh¶ᡂ?Ö×ØHC1ÓᦑD┯W஺ᦑ⌱AoூKᫀ௃Ù⚪ὃÛ½pÜ᪀ឋ=ᐵßᵨ
⚪ᐵÖᐗ¹Ḅà̽pá᪶᜜ᨬ᜜ÄᵯḄᐵßãnäᕜ»ᐗ¹ᙠᕜ»⊤Ḅ½pᩭæ/᧕┯C,AW)3ᓄᔠᱥA1CLᐳÑᓄᔠᱥ஺14ஹDூ⚪ÇÈ
௃A.CHBr-CHBrèé1,2—Àëìí┯W22B.CHOOCCHèéì⏚ᵬï┯W33CH-C.Ièé2-ᵬñòí┯WCHLCH-CH8CH3D.CH—C——CH-CH,èé3,3-Àᵬñ-2-ó⏣mn஺3CH,0H3KᫀD஺15ஹBூKᫀ
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14ூ⚪ÇÈ
௃জ°ü⏚ýþ:;ÿᱥஹ᪍ᵬḄᔠᱥஹᴻấ⏚Ḅᔠᱥஹᓫᱥজ┯ঝCaCLஹ!ஹ"#$ᓄᔠᱥHD&'ᑖ)*ᓄᔠᱥঝ┯ঞ-.ᓝ0ᔠ1⏚23ᨔ5ஹ67⏚⏚ஹ1⏚89:ᵯ<ঞ=>ট@60AᓄBᱥஹ6ᔠᱥᱥஹC1⏚ᔠᱥஹᨔ0Aᓄấᱥট┯ঠEᳫ$ஹGHஹIJGᵫCᐗMNᡂḄឋ*QḄᓫQMRN5ঠ=>@CHO,C2H4O2,C3H6O2ஹc4H8஺2,TᡂUVCH2,W᪀*YZU[ᡠ]*YZQ^ᱥড┯জঝটড22┯`ᫀ⌱D஺17ஹCூ`ᫀ<᪆௃AஹজḄfgh⏚Ḅhijkil⏣nopᡂfgᦑA=>BஹঝḄfgjrstiQuvᙠQYBx)ynoz{fgῃᦑB=>Cஹ᪷~ᓄfgḄᵨRi80HfgᱥᱥR'CO18ORHzO,ᦑC┯DஹᓄjᵨC1⏚ᔾᦈfgoᡂḄfgḼᨵᑭoᡂḄR'COORḄᔣᨵᑭঝḄᦑD=>஺=>`ᫀ⌱C.18>Dூ`ᫀ<᪆௃ᵯ<ᙠᵯ⊝ᓣᵯ<Ḅᵯ⊝ᦪᜧ¢-£¤ᵯ<ᵯᑣᵯ<Ḅᵯᔾ¦~§ᑖ᪆<`஺ூ⚪©ª<௃A.ᓣᐸᵯ⊝ᦪᜧ¢-ᐸᵯᜧᡠ]c(A+)¬ḼᓣᓣA┯B.᪷~ᵯ®AB=iA++B-¯°ᙠᵯ<ABjc(A+)=c(B),B┯C.ᓣᐸᵯ⊝ᦪᜧ¢-ᵯ<ABḄᵯᜧᡠ]ABḄᵯ(25C)<(35C),C┯D.ᓣ⊝ᔣᔾ¦fgᔣABḄᵯᜧᑣABḄᵯᔾ¦D=>ᦑᔠᳮ⌱⚗D஺ூ`ᫀ³´௃µ⚪ὃ·ᵯ<Ḅᵯ->ᵯ<ᵯᱯ³<µ⚪ᐵº᪷~lᵯ⊝ᦪḄᐵ^ᩭᑖ᪆<`¼½ᵯ⊝ᦪlḄ⏚!ឋ¾ᐵ¿lᨵᐵ஺19ஹAூ⚪©ª<௃A.fgᱥjFeᐗMḄᓄᔠÀᓣᜫ{ᵯ)ÂxᑺᑣÄÅজঞjḄÆ┑¿ÂxᑺA=>;B.Fe+CuSO4=Cu+FeSC>4fgjCM+AᓄᑺFe?+AᓄᱥᑣAᓄឋÊCu2+>Fe2+,B┯

15C.ঝFeᐗåḄᓄᔠæᓣᜫéᵯ6ᑣFe2+ìíJឋC┯ïD.ঞ᪷ñᵯ6òᜫᦪ,ô{õö~Ḅ567'8Fe+2Fe3+=3Fe2+,D┯ïᦑᔠᳮ⌱⚗!A஺20ஹAூÛᫀ᪆௃জ1ᓄdhü1ᓄý~¸ᡂþd⏚ýhÏþd⏚ýhÿᓄᡂ⏚ᓄᦑজঝᡂᓄᓄᦑঝ┯ঞ⛳ᓄ!"#$ᐭ&'ᓄ()*ᑮ⏚⏚,-ᑖ/ᡂ⏚ᦑঞটᓄ12⏚ᡂᓄ13ᓄ1!"4-5*ᑮᓄ16*ᑮᓄ1ᦑট┯ঠᓄ╅9ᮞ;ᡂᓄ╅ᓄ┛ᓄ╅ᰀ>*ᑮᓄ╅3ᦑঠ஺@AᱥCDᓄᙠFGᩩIJ5KLḄজঞঠ஺ᦑ⌱Ao21ஹDூQᫀ/᪆௃Aஹ9UᙠVWJᡂSiCO,ᦑA┯BஹXYᴻ[\ᑮḄᨵSiCh+Na2cChḂNaSiO+CO2tSiO+CaCO^•CaSiCh+CCh3ᐗaᓄᔠc2323dᨵefᓄᓄghᦑB┯Cஹijkl□᩽opkpk#᝞rᨵsCutuḄᩖCwxyᩖCᐜ{ᵯᡠ)D~0.2molᵯl□᩽CḄGImolCuḄCᦑGo6.4g,ᦑC┯DஹᑴᜓấḄ#ᑭᵨᑖSiCkᩖC#ᩭH2eᣚ*ᑮVấᦑD஺ᦑ⌱D஺22ஹCூ⚪/௃A.ᓄấx⏚ឋᓄᱥ2⏚5KLᦑA┯B.ᓄ3ᡂ¡⏚¡⏚¢ᓄᡂ⏚ᓄ35DᓄᦑB┯C.£''ᙠ¤ᓄᑺஹVWV¦ᩩIJᡂ&'&'§ឋ'¨2⏚ᡂᓄ╆ª5KLᦑCD.⏚╅!2⏚ᡂᓄ╅!"ᓄ╅!"ᵯ/*ᑮᓄ╅''5«¬*ᑮwx╅ᵯ/ᰚ®¯᝱Ḅᓄ╅*ᑮwx╅ᦑD┯ᦑ⌱C஺ஹ±⌱²⚪(ᐳ84ᑖ)23ஹO=C=O3IANaO+H0=2NaOH2H*+2e~=Ht(ᡈ2H£+2e~=Ht+20H-)Fe—2e-=Fe'aCl2222

16ூᑖ᪆௃¸ᕜºᐗaAஹBஹCஹD,AᐗaḄhᨬ᜜ÂᵯᦪᑁÂᵯᦪḄªÅAoCᐗaBoᙢÇ#ÈᨬÉḄᐗaBo0ᐗaChËÌᨬᜧḄ¸ᕜºÎÏᐗaCoCDÐᡂḄÑᓄᔠᱥNaClÕᵨḄÖᕡØ஺ூ⚪/௃¸ᕜºᐗaAஹBஹCஹDᑖÙoÚCஹOஹNa,CL(1)ᓄ#Ḅᨬ᜜Â4ßᵯᑖÙ0ÐᡂªßᐳcàAB஺Ḅá᪀ãgC=O,Cᐗaoᐗaᙠᕜº⊤#çè3ᕜºIAÏ(2)BஹCìᡂḄíᓄᔠᱥᓄ3eᓄᔠḄᓄîïãoÚNaO+H0=2NaOH22(3)ᵯ/NaClḄ⛳!"Xo9óᵯ᩽ᵯôõ᩽ö÷ø▢᩽Xᵯ᩽Ḅᵯ᩽ão2T+2e-=H2f(ᡈ2H2஺+2e-=Ht+20H-)oYᵯ᩽ᵯ᩽ᓄ஺Yᵯ᩽Ḅᵯ᩽Fe—2e-=Fe'2(4)!"#$%&Ḅ0.2mol-L-NaCl010.lmol•34ᵯ(1)301789:ᦪ$<⏚᪷?ᑖAB▢9:DᦪEF89:D9:ᦪGHIḄJNaCl01஺BrBr24ஹᵬMNO4ᡂ/RுCH.CICH-CHO⏚ឋU═⏚W014CHCCI,“Í\CHCChÎnOI+CH3co0H\♦+H2OOH3OOCCH,CH,CHOCHOCOOH/ஹ-----------------y-KIÒ/0cly/-VCCHj—C—CH,HNaOHFᓄᡂḄG~ᑖ᪆B஺BrBrூ⚪GB௃প᪷ᑖ᪆fgAᵬMGஹᑣG7¡¢NOᦑᫀᵬM;NO;OII(2)ঝMᵬ¦§4ᡂᡂCH,᪷¨©ᑖ᪆BªFḄ᪀¬ᑖᦑᫀ4ᡂ;

173
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19ூ⚪©ª<௃(DMgCChlÝ1⏚fgoᡂ1⏚╅ஹ0AᓄBfgḄ)®ßMgCO3+2H+=Mg2++CO2t+H2O(2)0Aᓄấ*Ý1⏚ᑣàá1Ḅᓄâ®ßSiO2(3)pᐭH2O2Aᓄuᙠ⏚ឋjAᓄ1⏚äÆfgḄ)®ß2Fe2++2H++H2O2=2Fe3++2H2O(4)å⁚pHuᵨpHçèḄᐹ5êëYìᙽpHçèîᙠïḄᴻᱏyᵨï@ñḄᴻò↾ëôõ³ᙠçèḄjö÷lø⁐ᓱû᯿ýþÿᦪ
⁚pHᓄᓄᑣ2◀ḄMgO᜜ᨵḄᱥFe(OH)3(5)᪷!"#$%&'()ᑮḄ+,-⌕ᨵSO2ஹCO,CO,S,01Ḅ+,23ᑖ5ᔾᦈᡈᦈ9ᡠ;<A=>2?+@ABᩭD<BEFG═⏚JKLᔾᦈMᓄ><CḄᓄNKLᔾᦈMᓄOᨬQᒕSTᓄO+,ᙠDᦈ9
জCOVKWXDᦈ9Ḅ+,%;COঝEFBᔾᦈMᓄ>ᵫWMᓄOஹMᓄ>ᙳ\ᓄNKLஹO⏚NKL]^_`⏚abMᓄ>ᓄcd1ᡂNO+,ᡠ;BfgḄKL⌱iKMnChKLᔾᦈMᓄ>ᦑkᫀdoூkᫀno௃q⚪ὃt╅ஹvᐸᓄᔠᱥஹMᓄ>ឋ^ᵨ{ᔠᱥᑖ"|}~"|ᱥឋ⚪Ḅᐵ(5)+,ᔾᦈḄᐜQᑨkḄ᧕┯n}Vn஺28ஹCH2-⏚]^ஹ1016CHjCC(X)HCOOCH3+nNaOH2rH+nCH30H5CH2XHCOOH+CH0H-Âa.CH=CHCOOCH+HO3232-£CH2—CHiÅCOONa.KMnO,Cll,^°ᓄ។¡SO,CH>C(XXHCH,ூᑖ᪆௃q⚪ᨵ£¤⚪஺ᙠᨵ£]^¥¦]^ᱥ}0ᱥ᝞¨©ᓄcªvᑮḄq]^«¬®©ᡠ;ᨵ£]^Ḅ¯°q]^«¬kᨵ£¤⚪¬Ḅᐵ஺জ]^²ᨵ£ᱥᓄᔠᱥᑖ³ᡈḄ]^´ஹᯋஹ¶ஹ·ஹ¸ஹ¹ஹºᾦ¼½%;¾ᓄ³஺ঝ]^²ᙠT¿ᩩÁBᨵ£ᱥῃÃᑖ1ᡂᑖᨵÄᡈÅḄ⛳}ᨵ£ᱥḄ]^]^஺ঞ³ᡂÈᔠ]^²ÃᑖḄ´Éᡈ´ÊḄËÌÍ1ᱥᙠ³Î}¾ᓄᑺᵨB<³ᡂÐᔠᡂGᑖᓄᔠᱥḄ]^஺টÒᓄ]^²T¿ᩩÁB⏚}⏣1ᡂÒ}XḄ]^஺

20RR\KMnO\O4ூ⚪ÔÕ௃᪷!Ö&²C=CHR-—-+RCOOH%;¤×B||᪷!R/ÅR/CHCCOOH3DḄᑖ$ᑖ᪆%&DCḄÙÚËÌḄ0ᱥᑣDCHCHBrCOOH,CHCHBrCOOHᙠᓄNḄ33Û⏣KL³ÎÜ1]^1ᡂECH2=CHCOONa,E⏚ᓄQ)ÝIÞFCH2=CHCOOH,F\ᵬ⏣ᙠ>⏚¾COOCH3ᓄBÜ1Òᓄ]^1ᡂGCH=CHCOOCH,GᙠT¿ᩩÁBÜ1³È]^1ᡂHà6,T231
Xá´Ḅᑖ$CIOHM᪷!ᨵ£ᱥâãäå|CḄâãäå2-⏚
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BḄÐ᪀é$||஺3CHCCOOH3OqÃ⚪kᫀ²ìஹî
||஺CHCCOOH3P3Q᪷!æçᑖ᪆FCH2=CHCOOH,F\ᵬ⏣ᙠ>⏚¾ᓄBÜ1Òᓄ]^1ᡂGCH2=CHCOOCH3,ᑣ]88^ডḄᓄð]^"#$CH=CHCOOH+CHOH-Ê.CH=CHCOOCH+H2OHᙠNaOHXKLÜ1X2323COOCH—I3HO]^Ḅᓄð"#$+nNaOH-óô2T0õ“+nCHjOH.qÃ⚪kᫀ²+CHd2÷ACOONaCOOCHH,஺L-I3CH2=CHCOOH+CH3OHF⊤Í-CH2=CHCOOCH3+H2OḄ_U+ᵫ஺Ï(/H+nCH3OHo4
MGḄdᑖø᪀,ùa\NaHCCh]^1ᡂCO2,ᑣMᨵ%aḄÐ᪀ᨵCHCH=CHCOOHÑCH=CHCHCOOH^CH=CPCHQCOOHúᨵ]2ûø᪀üஹÓÑ-COOHᐳ5û஺qÃ⚪32223kᫀ²5஺P5Q2.ᵬ2ÿ
═⏚ᓄᑮ⏚ᡂᡂ2.⏣2.⏣⏚ᙠCHCOOCHCH33⏚ᓄ!ᓄᡂI,ᦑᔠᡂ&'CH3CH,CII)II5ஹ_C__O__H«roH,-—1WSOj\CK\HhCHjCXXrHCH,(:C-HCHj*+⚪-ᫀ(:ACHJCH,—ClliCOOH-------------------------------------------CH,-=O×M\CHÑ/HÉÑCØÙ0….CHjCXXrHCHjC-CH,CH,—CII^OOH------------------------------------------ூ-ᫀ34௃

21*⚪ᐵ789:ᡂABḄ᪷=>?@ABC'C-CHRD᪀FḄC=CG7HI
═⏚ᓄᡂᡈ⏚,0KLMNB(||,=PQ-஺CHCCOOH329ஹT+247.1pi>p2>3TUVWXYᜧ[\ᓄ]^⊝ᔣabᔣcdᦑ^⊝eᔠᱥFgḄhiPᑖᦪlᜧ[\lᜧ<8.3x1032SO2+4H++2e=SO2+2HO13443242ூ⚪noQ௃I.পজCH4(g)+H2O(g)=^CO(g)+3H2(g)AHi=+205.9kJ-molTḄAH>0,AS>0,⌕stu3G=AH-TASV0,◤⌕Twstux᪷=জCH4(g)+H2O(g)=^CO(g)+3H2(g)AHi=+205.9kJmolT,ঝCO(g)+H2O(g)=^CO2(g)+H2(g)AH2=-4L2kJmol\᪷=yz{|}জ-ঝCH(g)+CO2(g)^=^2CO(g)+2H(g)AH3=(+205.9kJ-mol1)-(-41.2kJ-mo|-1)=+247.1kJ-molSᦑ-ᫀ(Tx+247.142H.(2)জᵫN2+3H2U2NH3HYᜧ[\^⊝aᔣcdᵫHᙠVWTU^⊝eᔠᱥFgḄhiᑖᦪভ)(P|>P2>P3,P[\ᐵ8P1>P2>P3,ᦑ-ᫀ(P1>P2>P3TUVWX[^⊝aᔣcdᦑ[\lᜧ^⊝eᔠᱥFgḄhiᑖᦪlᜧ[\lᜧxঝTUlᜧ[\lᜧ᳛lᜧ>P2,ᵫHBḄTUஹ[\ᜧᑣ᳛ᜧᦑ-ᫀ(VxPIঞN2+3H2=2NH3(mol)0.10.30ᓄ(mol)x3x2x^⊝(mol)0.1-x0.3-3x2x2x=0.667,x=0.08mol,ljB3N2Ḅᑖ[p(Nz)(——°஺——xlO5Pa=8.3xlO3Pa,ᦑ-ᫀ0.1-x+0.3—3x+2,x0.02+0.06+0.16(8.3x103m.জᵫH▢᩽ᐭh⌕sth",N⌕S2O45ᡠI▢᩽ᵯ᩽¢(2SO2+4H++2e=SO2+2HO,ᦑ-ᫀ(2SO2+4H++2e=SO2+2HO32423242ঝᵫ£NOᔾᦈᓄḄ⌕¦ᱥ(NH4+,NO~NH+~5e,§ᵯ&Fcc0.3mole1◤⌕¨ὑNO0.06mol,4᪗«¬hi(0.06molx22.4L/mol=1344mL,ᦑ-ᫀ(1344஺