江西省顶级名校2022-2023学年化学高三第一学期期中质量跟踪监视模拟试题（含解析）

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2022-2023
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㯢ᨵHBrᡂᙠ°µᩩ(%
HBr:CH3cH20H᧕ᢵᦑᡂᱥ¯ᨵHBrஹCH3CH2OH⏣ᙠæ´⏚°µḄᩩ("1ç
ᡂCH=CH2,Þ"ᑖῃᡂCH3cH20cH2cH3,2ᓽ£ᱥ¯ÞéᙠCH2=CH2,CH3cH20cH2cH3(5)n¾A¯êÀḄᨵIᱥᕈì⁐@ᵫíæ´⏚ᐹᨵïRᓄឋðHBrRᓄᱥBn,£ᱥñÑᨵᓫNºóôÖõᐰ◀çᩖNÙ0ùÔúû*QRᓄTØ᧕iü*ýþᓄU¢ÿᐭ
Ḅᩖ⏚ᓄᡂHBr⏚᧕ᑖᡠd!⏣ᙠ$⏚%&Ḅᩩ()*+ᡂCH2=CH2,,)-./⏚0123⁐(6)$⏚ᐹᨵ7ᓄឋ9HBrᓄᱥB஺ᡂḄB஺ᐹᨵ7ᓄឋ<ῖ⇨?@ᵨBᴻDE஺26ஹ◀+HIJḄHC1a2MnOL+lOCr+16H+=2Mn2++5CLT+8H2O-ᡂḄSnCLIᓄᨵᑭMNO

19ᔠᱥJᑖQᩭSMᙠTᜐVᓾᦈYᔾᦈ[ḄHI■]^_`᛻bcᔾᦈdIJḄefI■]gᐭᦈYSnCkḄhE-ᐸejAB91.2%ூᑖ᪆௃(1)$n⏚ᐹᨵᢵឋpq⌮sᳮuᐭVve(2)AJw2KMl1O4+I6HCI($)—2KCI+2M11CI2+5CI2T+8H2O;(3)%&z{|}gHI┱-ᡂḄSnCLI᝱SMᙠTᜐVᓾᦈY(4)ᔾᦈ[ḄHI■]^_`᛻bcᔾᦈdIJḄefI■]gᐭᦈYSnCLḄhE-ᐸej(5)ᵫMSi?+᧕Fe3+,)-ᵨᓄឋḄFe஺12(ᨵKSCN)ஹe᪷⁐ᓄᑨ(6)᪷SnḄSnCkḄᳮ᳛=▭/ᳮX1()()%஺ூ⚪j௃(1)$n⏚ᐹᨵᢵឋJ⛳neḄᵨ◀+HIJḄHC1pq⌮sᳮuᐭVveᵫauᐭVveVvEᐙVveᐙᑖgVᓾ(2)AJw2KMnO4+16HCl($)-2KCI+2MnCL+5CLT+8H2O,¡¢w2MnO/+lOCᔆ+16H+=2Mn2++5Clt+8HO22(3)᦮¦{|JᐙHIcᓽz{|ᐙ¨©⁐Iª«%&ᰚᓄ┱ᔠᡂSnCL,%&z{|}gHI┱bc-ᡂḄSnCLIᓄᨵᑭMNOᔠᱥJᑖQᩭSMᙠTᜐVᓾᦈY(4)®{|ᵨwᔾᦈ[ḄHI■]^_`᛻bcᔾᦈdIJḄefI■]gᐭᦈYSnCLḄhE-ᐸej(5)A.FeCb12(ᨵKSCN)Oᔠ¯Q°±⁐ᑣ³ᨵSnCL,ᔲᑣµSnCL,ᦑA!BஹeOᔠ·¸⁐3+ᑣ³ᨵSnCL,ᔲᑣµSnCL,ᦑB!Cஹ-ᵨAgNCh12)¹ºH¯»¹º¼½┱ᦑC┯¿ᦑ⌱AB(6)ᵨ+┱1.19g,ᐸᱥḄ1.19g+U9g•mol-LO.Olmol,᪷SnÁឤᳮᡂSnCLO.OlmoLᑣSnCLḄ᳛2.38g+(O.Olmolxieigmor1)xl00%=91.2%.ூÃᫀÅÆ௃Ç⚪ÈMᱥᑴᜓºj⚪ᐵÌwÍÎÏᘤ-ᵨஹ¡¢ÑᑏஹÓᳮ{|Ḅᑖ᪆Ô½ஹᱥ¹ºᫀÕஹÖ×Åw▅Ù⚪ÚqÛÜÝÞßàᵨ஺27>Ca(C10)+2HCl=Cl1+HO-KaClá⚠ãᧅJ2☢æçèᓣêᡂeëd¨(ᡈ¸)12í⁐E2222ᜐ[»᣸◀DJïCkḄð᡾|ᣚQLCLuᐭNaHSOs12J<S02,^_dIூÃᫀj᪆௃(1)óôõḄö⌕ᡂᑖᨵøH⏚┛Hᓄ┛ᐸJøH⏚┛$n⏚ᡂHI(2)ú{|JIªû7ᓄá⚠ãᧅJ2ª2☢ᓄᑖ᪆ᑨw(3)úHIµóôᵨHIeᡂøH⏚ᐹᨵóôឋgºÕ(4)úHIüᓄᡂᓫ2ªᓫỚᓄ012JḄỚᓄ0ᡂỚᓫÿᔠ
Ḅ⁐Ớ

20Ḅ⁐ᑖ᪆মᔣᑖ᪆EDᜐ!"᣸◀%Ḅ&᡾Fᜐ!"ᔾᦈ*ᡂḄ,-ឋ/0ᓄ2ᑖ᪆஺ூ⚪67௃(1)9:Ḅ;⌕ᡂᑖᨵ>%⏚┛%ᓄ┛>%⏚┛AB⏚*ᡂ%CDEFGCa(ClO)2+4HCl(A)=CaC12+2ChT+2H2஺
ᦑᫀFCa(ClO)2+4HCl(A)nCaCH+ZCbT+ZHhO;(2)BḄLᵨNOPQᐰSTUVWXYZCPᔲ\*ᛋ^_ᛋ^AB`abᜧdeBḄf`ᐭh⚠jᧅlᡂmᦑᫀFh⚠jᧅf☢opᓣlᡂmব%s9:Lᵨ%*ᡂ>%⏚ᐹᨵ9:ឋ஺aஹ%vwBxᩭdzᨵ{&|ᨵ⁐}ᩩd⁐ᮞ%dᔾᦈWsW%Pᔲᐹᨵ9:ឋᦑa┯bஹ%vwBxᩭdzᨵ{&|ᨵ⁐}ᩩd⁐ấ{dᔾᦈ⍗ᑮḄᨵ⁐}ᩩd⁐!"oᐸ9:LᵨḄᱥᦑb┯cஹ%vwBxᩭdzᨵ{ᨵ⁐}ᩩd⁐UlᐭA2⏚!"Xᐭ☢!"o%Pᔲᨵ9:ឋᦑc┯dஹ%vwBxᩭdzᨵ{ᨵ⁐}ᩩd⁐,&|ᑺ%ᓄ┛ᔾᦈ⍗&|Ḅᨵ⁐}ᩩ!⁐o%s9:ឋᦑdᦑᫀFd(4)DP
ᓄᔣDᐭ¡¢%Z%£ᓄ*ᡂ¤ᓫ¦§¨ᑮs⁐©f⌲«¬Fᡠ§¯°FG©fvs⁐¬ᓄF⁐G0ᓄ±²0ᓄᑺḄ0ᓄឋᜧ³0ᓄ´ᱥµo%Ḅ0ᓄឋa³
ᡭ·¸^¹DzºᓫḄ¡¢©fᐭzỚᓄ»©fḄE
ᓫỚᓄ»*ᡂỚᓫỚᓫ⍗¬¼ᦑᫀF(ᡈ¾)©f¬¼⁐মᙠW
ᓫ0ᓄឋᜧ³ỚᓫḄVWWC!"᣸◀%0ᓄỚÀÁḄ&᡾LᵨᨬF%ᐭd*ᡂB⏚B⏚Ã2⏚Ä*ᡂ/0ᓄ2,-!"ᔾᦈᦑᫀFজEᜐÆ"᣸◀D¢CLḄ&᡾ÇᣚxL;ঝCLᐭNaHSCh©fd´*SO2,,-É஺ூᫀÊË௃Ì⚪ὃÎÏ%ḄVWЧÑ%ᓄÒឋḄᵨ஺Ì⚪Ḅ᧕┯ÊF(3),⌕ÔÕ9:LᵨP>%⏚Ḅឋ!P%Ḅឋ஺28.0.042mol•L'1•min19/16(ᡈ0.5625)<Ö0ᓄᱥ/NOxᡈNOஹNO?4NH(g)+3O(g)=2N(g)322+6HO(g)AH3=-1269.02kJ•mol-1Mn200࠷2c(SO32-)+c(HSO-)□NaOH23SOs^e+H^SO/^H*ூᫀ᪆௃(1)Ø⚪ὃÚᓄÛÜ᳛ḄÞßஹᓄÛà⊝âᦪḄÞßஹäåᱯᑡèᳮḄᵨ
জ᪷íᓄÛÜ᳛ḄᦪÛ⊤fï
v(NO)=(l—0.58)/10mol(Lmin)=0.042moI(L-min)ᙠ20minfᑮà⊝

21᪷ᓄÒÙ⊝ÛᦪḄÝÞK=C(CO)XC(N)/C2(NO)=0.3X0.3/0.42=9/16ঝ30minZNOஹN>CO2Ḅ222ᱥḄ¢AßàáF0.40.30.3=111,ᓣâãßNOḄᱥḄ¢AßbᜧµoᓣâãßÙ⊝ᔣ⌮CᔣXYᓽCᔣPæçᓽQ<0(2)ὃÎçᓄÒCDPèéজ᪷ᵬ²ᳮÖḄ0ᓄᱥNḄᓄᔠìíîïðNOஹNO2L0ᓄᑺ6᪗ḄCDEF4NH+3O=2N+6H2O,জ4NH3(g)+5O2(g)=3224NO(g)+6HO(g),ঝ4NH3(g)+6NO(g)=5N2(g)+6H2O(g),(জx3+ঝx2)/5òxG24NH(g)+3O(g)=2N(g)+6HO(g)AH=-1269.02kJmor1ঝ᪷ôMnḄῃÖ᳛âZ÷Ḅ32223ãßàCrøᓄ᳛âZᡠ÷ḄãßḄîïðᨬùøᓄᑺPMn,ãßᙠ200C(3)Ì⚪ὃÎÀÁAßḄᜧúàû᪷ᵯ₹þឤc(Na+)+c(H+)=c(OH-)+c(HSO-)+2c(SO32-),
ឋ3
ᨵc(Na+)=c(HSO3-)+2c(SO32-);(4)⚪ὃᵯᳮᵯ᩽Ḅᑏজ᪷ᵯᳮ,ᵯ᩽▢᩽!ᵯ᩽□᩽C#ᑮḄ%&⏚
a□(b▢(□)*ᙠ▢᩽,-ᵯ,᪷-ᵯ./ᵯ᩽2H++2e-=H2t,
A#ᑮḄᱥ1NaOHঝ▢)*ᙠ□᩽,-ᵯ
C#ᑮ&⏚
SCV-ᙠ□᩽,-ᵯᵯ᩽SO32-+2H2O—2e-=SO42-+2H+஺567⚪Ḅ85%(4)ঝ
᪷)*-ᵯ./%OH-ᜧ:;<⏚᪷
=>?ᑏᡂ4OH—-4eA=஺2C2H2O,DᨵEFᑮ⚪GC#ᑮḄ%&⏚
-ᙠ□᩽,ᜫᵯ*IᓄᡂSCV-,
ᵯ᩽SO2+2HO-2e=SO42+2H+32O29ஹ3,4-MNOPᵬRROஹSOETHOOOCHsCOOHO»CHo+2A/—CHQ࠷4>CHO+2CH3COOHUᡈHOூᑖ᪆௃ᵫ\]^_AḄ`᪀b>=\DᑮEḄ%efgh>iᡂj%TkHO4CHOlMmn_ᩩpḄReRqrḄiᡂsᱥth>uv஺HOூ⚪Gw௃(1)AḄḄ`᪀b,xy73,4-MNOPᵬRzB{|}Ḅ%ROஹSOᦑᫀ3,4-MNOPᵬRzROஹSOz(2)᪷ឋ*Ḅ;✌ᐜᨵDᨵ⛳*tᡠḄ4m*ᡈ*}%ᔲ^EeO

22Ḅ*ឋ*ᦑᫀE(3)ᵫ^_Defgh>iᡂ>ᡂE,ᦑTᦑᫀT;(4)ᵫ\]^_A-BḄᓄ=H099CHCOO3HO2
>>=\+2CH3coOH(ᡈCH3coO4>CHOHOo0CHCOO3H஺XH஺஺’)=\+H1O,ᦑᫀCH3co^-CHOHO9oCHCOO3....……+2S⎀J>—>=\+2CH3coOH(ᡈHO\/~CHO/ஹ஺/ஹCH3coO~~~CHOHO00CHCOO3>=\+11ñᩩ)>+Ho2HO4^^CHOCHCOO-^^-CHO3HO0(5)DḄ`᪀uQ-cJr.H;ᨵmNOAm᷊OAmO,ᑖª᪀⌕¬ᨵ5m*ᙠAᩩ¡,¢ᨵ`᪀C£C-C,ᑣ¥¦,Dᨵᐸ¨⛳Ḅ`᪀*©,ᑣm<®¢%NO^ᑏHOHOUPLᐸ`᪀bCIb,ᦑᫀ^c—CII3;110onnoon[<=^CH=CHCHO✌ᐜ⌕´µ¦¶|ὃ⇋(6)¯20HஹCH3CHOᧇᑴ²HO-n_ᩩplMmk⌕h>RRiᡂᑣᐜ⌕³HOY^VCHOHNO¸ᓄ<ᓄROteCH3CHO2iᡂ¹tuvº%⌕EFᐜ³NOef<ᓄ»■½NO¾<ᓄ,ᨬ¹teÀ⏚#ᑮG᪗sÂᦑᫀHO-^>CHzOH..ó-NaO^>CHzOH&ᨌ>Na(Y/ACH஺3ô„ö)ுNaO-^CH=CIICHO—CII=CIICI10»ூᫀ56௃ᨵÃÄÅ⚪ᐵÇ%Äᱥ1Ḅ`᪀b¢⚪È⌕%ᐜ⌕#AḄ`᪀bt᪷ÉAÊ˹Ḅ`᪀ÌÍᑖ᪆ᳮzᑖ᪆ᑖª᪀ÎÏÐᵨÌÍÒᐜᑖ᪆;ᨵÓÔ`᪀ᡈ`᪀tὃ⇋ÕÖᐵ×஺