江苏省连云港市2022-2023学年化学高三第一学期期中综合测试试题（含解析）

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2022-2023
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SO2+NaClO+HO=HClO+NaHSO3215ஹᑡ““opᐵyzḄc⌱⚗ᔣᨵFe(NCh)2Ḅg~ᐭH2sCh,ᙠgAHNO3ᑖ5£ᡂNO2ᑮ⁐¢-ᔣ¥~ᐭH2s04,~¦ᑖ§¨ᓾª«B¥®ᨵ#5ᡂℍ⃔±~ᐭ¬ᑴCu(OH)2~¦®ᨵ⁐£ᡂᔣ²#⏣~ᐭ´H2so4,~¦µ170C,¶£ḄCE¸⁐Ḅ¢-c¹¢-ᐭ⏚ឋKMnO4¸⁐Dᔣ⛳Na2cChᐭ»(CO2,¼½᪆iNaHCOaA.AB.BC.CD.D16ஹ¿ᑁÀÁᢈẆÄÅÆ✌AÈij¬ÉḄLi+ᵯË-Ì-y᩽_ᵨÎᨵrஹLi+Ḅ#Ï᩽_ᵨ,-ᨵÐÑᔠᱥᵯ5ÔLiNO3ÑᔠᱥtuÕᣚ×◞×Ù᝱y᩽,᝱Ï᩽ᑖ◞Û(ÜᳮnÞß᝞ßᡠn)஺ãäIᙠ#å⁐ᑣᑡᨵᐵᑨèYyzḄc

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ᨵH+ஹNOAF+ஹSO42\crᑖ᪆஺ூ⚪௃A.᪷ᑖ᪆ᙠO.lmol/LḄ"ஹO.lmol/LḄ#O.lmol/LNO6□%ᨵḄᵯ₹()(O.lmol/Lxl)+(0.1mol/Lx3)=0.4moI/L*◀,ᙠO.lmol/LḄ-⏚᪷᜜᪷ᵯ₹0ឤ234ᨵSOF5cr,ᡠ478ᨵNOyஹA13\SO4*ஹcr9ᦑA;<=144"B.᪷>3?@A3CU+8HNOKC)=3Cu(NO3)2+2NOT+4H2஺DEὑ14.4gGn(Cu)=.,,=0225mol,64g/mol᪷>3?@ACuHNOḄᱥJḄKᐵMNᡂ7PᓄRSTḄᱥJḄK(22n(NO)=—n(Cu)=yx0.225mol=0.15molᵫVWᨵXYᩩ[\ᔲ\᪗_`abᡠ0.15mol7PᓄRḄTcd78(3.36L,ᦑB┯f=c.᪷gᑖ᪆ᙠh⏚ឋᨵNO஻ᐹᨵhPᓄឋᑣ78dᙠᐹᨵ2
ឋḄr,ᦑc┯f=D.᪷gᑖ᪆ᨵl⏚᪷ᡠmno78ᨵBaCO3ஹBaSO,ᦑD┯f=4ᦑᫀ)A஺3ஹA38gூ⚪௃Aஹ38g3H2O2ᱥJḄK()~r=lmol,7qᑖᨵ2qH-Or51q0-0r஺ᐳᨵ3NA38g/molᐳtrᦑA;<=BஹF2Pᓄឋuhvᐭ⛳5yz{|ᐜH{>3~ᣚ{ḄPᦑB┯f=Cஹbᙠ-⏚ᓄd>3ᐰᑣ5.6gᓽO.lmol>3ḄᵯᦪV0.3NAqᦑC┯f=D,lL0.5mol»L'pH=7ḄCHhCOONH4ᙠᱥᧇ0ឤc(NH3)+c(NH3«HO)=0.5mol/L,ᑣc(NH+)<0.5moVL,24NH4+ᦪV0.5NA,ᦑD┯f=ᦑ⌱Aoூᫀ௃⚪Ḅ᧕┯(B,⌕F2vᐭ{|ᐜH{>3Ḅ2ᨵᢗᐭz\ᐜH{>3஺4ஹB

12ூ⚪௃A.“o7”¢£Pᓄᡂ,¤£¥N,Pᓄ>3ᦑA┯f=B.✏¨©©ªrḄ«7q©¬,qᵬ£dᙠ¯>°᪀²³ᦑB;<=C.ᵬᑖ´V⏣d´V¶⍗¸{d¹Nº⁐mnᦑC┯f=D.✏¨ᨵ¨£5©©ªr¼5"S½ᡂH2moi"S¥N½ᡂ>3ᦑD┯f=ᦑᫀ⌱)Bo5ஹDூᫀ᪆௃¾⚪ᑖ᪆)A.¿(À´ឋK>Na,ᡠÁឋKOH>NaOH,ᦑA;<=B.¿(ÂÀ´ឋC1>S,ᡠPᓄឋC12>S,ᦑB;<=C.¿(ÂÀ´ឋBr>I,ᡠÃ8ឋHBr>HI,ᦑC;<=D.¿(ÂÀ´ឋN>P,ᡠ⏚ឋH3Po4VHNO3,ᦑD┯f=ᦑ⌱D஺ὃ)ὃÅ,ᐗÇᕜÉÊḄËᵨḄÍᐵÎ஺6ஹCூ⚪௃জSiO2(⏚ឋPᓄᱥÏHNaOH>3dHCl⏚>3d;<=ঝA1ÐHCl⏚>3ÑHNaOH>3;<=ঞNaHCQ,(Ò⏚Ḅ⏚AzÐHCl⏚>3ÑHNaOH>3;<=টALO3(ឋPᓄᱥÐHCl⏚>3ÑHNaOH>3;<=ঠ(NHQ2CO3(Ò⏚ÒÁzÐHCl⏚>3ÑHNaOH>3;<஺ᡠঝঞটঠ¼;<஺ᫀ(C஺ூᫀ௃#×ᯠÐH⏚>3ÑHÁ>3ÙdÚឋÀ´஺¿(ÛdÜH⏚>32\HÁ>3¼⊤²Þ2
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ᦪ(3NA,B;<=CஹâTã\äqᑖåᡂḄæᔠT1.ImolAlCbᐰᓄ("Pᓄ#âTNᡂèV1.1NAqâTãC┯f=DஹNazSiCh{2ᨵ{ᑖᨵḄP
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140.4mol“&°&±…³----------x22.4L/mol=2.24L,D┯d4ᦑᫀWbC«13ஹAூᫀE᪆௃জµᑴ100mLlmol/LḄNaOH&/⌱2100mL·¸&¹W·¸º·»◤⌕C¼½¾&ᡠ1¿ᵨÀÁ◤⌕ÂÃ&TUঝNaOHk¾si&ᡠ1ÁnÄᓽÆᑮ·¸.&┯dঞᵨ¼✂¾ÊËÌÍᑁÏ2Ð&ÊËÑᙳᐭ·¸.&WÓÔ%ᐰÖᑮ·¸.&TUটº·WÓ■ÙC¾ÚÛÜÝ,ÞC¾ß☢áÛÜÝ1!2cm&ᦋᵨãᜮåæåC&¿Ḅç☢ḄᨬéoÛÝêë&┯dঠᵫkÁí,☢ÚÓ·¸ḄÛÜÝ&ᔾtîïÓ%Ḅ%&ðñòé&;<ᜫô&◤⌕!õµᑴ&┯d&ᫀ⌱A஺b⚪⌕ὃÓµᑴ°ºᱥ%ḄḄḄµᑴ}öK78÷⚗&øUµᑴHᳮ·¸¿ᵨ}öᓽPE&⌱⚗ঠEḄ᧕┯஺14ஹCூ⚪BhE௃AஹúeᓄVã.CᐭHIb2Fe(OH)3+6H++2r=2Fe2++L+6H2O,A┯dBஹᵨû¾EúeᓄüýþbCu(OH)2+4NHyH2O=[Cu(NH)4]2++4H2O+2OH,B┯d3Cஹᵨÿ⏚◀ᑁḄ3Ag+4H++NO3=3Ag++NOT+2H2஺CDஹNaCK)ᐹᨵᓄឋSO2ᓄᡂ⏚ᡂHSO-D┯ᦑ⌱C஺15ஹDூ$ᫀ&᪆௃AஹᔣFe(NO?)2*+ᐭH2sCh,ᑣ./01233Fe2++NO+4H+=3Fe3++NOt+2HO,432ḄNOᙠ6ᡂN(hᕈ89⁐;?&@ḄABC⁚ᡂ>ឋEFG49⁐HAB┯CஹI⏣KL⏚23ᑴNIOḄPQ*.ᨵRSḄSO24TFGU⏚ឋKMnC>4V⁐C┯Dஹ⛳KNa2c03*XᐭCO2/23NaCO3+CO2+HO=2NaHCO3,ᵫZ4Ḅ22[⏚\]&^_Z[⏚]ᦑ.`P⛳K*᪆aD$ᫀ⌱D஺16ஹCூᑖ᪆௃ᵫ⚪cdefghijᨵkஹLi+Ḅ?`lᜮḄᢣᔣoᵬef*kqᓄiI,Ief*IqᓄiI-.ூ⚪rs&௃A.tᵬ*3r-2e=I,u□᩽3<ᵯyᐙᵯ{u|ᳮttI*I+2e-=3I-u᩽3<|ᵯ(y|ᳮtAB.~ᵯIy*ghᵯ᩽i᩽□01ᔣ᩽ᑣLi+`ᔣgXPᔠᱥ01ᣚBC.~ᵯ᩽3iᨵᱥᜫᵯ1ᵯ᩽23i

15VfyY0Li-WWNs~C,H—2ne'i1~/-C?H,+“+2஻Lu,C@:;%4D.ᐙᵯy□᩽3r-2e=I,Iᙠ'()}~⁐ᡠB)᝱ᵯ()Ḅ⁐D:;%ᦑ⌱C஺17ஹBூcᫀ᪆௃Aஹ⏚@⏚@ᐰḄᵯᦪO0.3NA,A┯$%Bஹ}ᙳ¡ᐗ£ᨵ2¤812gᓽImol(ᓫ¨)}£ᨵ0.5mol¡ᐗ£ᨵ¡ᐗḄᦪ0.5NA,B:;%CஹᙠDªᓄ«'Ḅ}O2~2e-,ᡂO.lmolªᵯḄᦪ¬0.2N1,C┯$%Dஹ᪗®¯°±²ᕈa᝱1L2L²}£ᨵᑖḄᦪ¬ᜧO0.5NA,D┯$%ᦑ⌱B஺ூcᫀµ¶௃·B⏚¸ªᓄ═ºP»¼ᵯᦪ¬y⌕ᑖ½¾y⏚D¿À.¸ªᓄ═D¿⏚D¿y¸ªᓄ═ᨵÁÂÃÁ·¸ªᓄ═D¿y@»¼ÄᐹÁÂ஺᝞A⌱⚗5()mLl2moiூrḄ⏚Ç¿MnO2⏚@⏚@ᐰḄᵯᦪO0.3NA஺18>Cூcᫀ᪆௃ÈᕜÊᐗË}MᐗËḄᨬÍΪᓄᱥ=Ḅ'ᓄᱥᐸ᝱ÑᓄᱥᡂᑣMNᐗË%NᐗË8ḄMᵯ¨Mᨵ3ᵯᑣNA1ᐗË%ᙠÈᕜÊᐗË}WᐗË8ÓÔᨬᜧᑣWNaᐗË%XᐗË8ᨬ᜜¨ᵯᦪ.ᵯ¨ᦪḄ2Ö×ØΪᓄᱥᐸ᝱ÑᓄᱥᡂXḄᓫH£,ᑣXSᐗË%YᐗËᨬÍÎ:ÎᨬØÙÎḄÚᦪ6,ᑣYC1ᐗË஺A.Ûᑖ}NᐗËᜐOᨬØÎᐹᨵÀ8ឋᐸ'()ÞឋA⚗:;%B.«ᙠª}àáḄâᱥDªᓄ«▢□ᦪäå1
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42CH=CH2uáâ«ᨵ4ö$z÷,uáâ«ᨵ2ö$z÷
ᦑZ2H2ᑖì᪀íᐳᨵ2+3+4+4+2=15?᪶þᐳÿ
ᨵḄ᪀OHCOOH
6ᵬ⏣/V᪀᪷⚪◤ᵬ⏣ᓄᡂᵬ!"#$AᡂBḄ%X/0HCH=CHCOOHOH&ᡂ6COOH44…,,"᪷(()*+ᓴ-ᓫ/0ᡂ"12ᔠᡂ/2,ᦑᔠᡂ78:\zOHBrBrICH—CH—C(X)Hᓄ/,⏚ᓄ.ூ;ᫀ=>௃@⚪A⌕ὃDᨵEᱥḄGH+ᔠᡂIᵨKG⌮GMᔠḄ%N⌲Pᑖ᪆ᨵEᔠᡂ78SGTᔜᨵEᱥḄ᪀ᯠWᑖ᪆XYZGHᔜP[\][\^_஺XYZabcᨵEᱥᓄdឋ/ḄfgᡈfgZᨵE[\iᜧkᦪmanoXYZpqrstᦟᩞtḄ[\fᳮxyaᨵE[\Ḅ4zᑖᡠ|ᨵE}ᔠ⚪t~TᩭGHzᑖᨵdḄᨵE[\fᳮ[\fᳮS|ᨬᓫḄH*]ᣚḄ%Nrk஺25ஹDḄឋY᝞ᵨ⏚ᑣᡂḄ¢ᓄ£¤ᙠ£¦tr§|⍎T©dூ;ᫀ¤᪆௃10ªᑺ¬⌕Ḅ®aDḄឋ஺

20(2)¢ᓄ᧕£°±᝞ᵨ⏚ᑣᡂḄ¢ᓄ£¤ᙠ£¦tr§|⍎Tᡠ|²⏚Yᵨ⏚2³஺(3)£¦t᪆TḄᨔµ◤⌕©¶ᑮ஺(4)¢ᓄaᜧ¸¹ᱥ◤⌕ºᜐᳮ4¼ᵨ½¦¾¿◤⌕■Á᎔ᔾ;ᫀ⌱d஺26ஹÅ◀Ǹᡈᑭᵨ(⏚ɱ¤WʽឋḄឋ/◀Å⊤☢ǸFe+H2s0)50࠷~80࠷FeS04+H1ÎÏ©2ÐÅᩖ/ÒÓÐÔ&tFeSO«•7Õ0ḄÖὑa56.7࠷?@:஺27ஹAgClAg++Cr=AgCUBaSOABCDE2F0ᔣᐸ.IJᓄLDEMᔲᨵPQRSᨵ4PQᑣU⏚᪷W◀YMg2++2OH=Mg(OH)0.52

21ூᑖ᪆௃[DE\ᨵBa2+ஹMg2+ஹAg+,]ᵨNaOHDEஹ_⏚`Na2sOaDEbcde$⌲gPQᑖeOIT`Mg2\Ag+hijSO!`Ba?+hiᡠkᐜᵨHCIbAg+mᓄAgClPQnopIᐭNa2sᡈNaOHsᡂBaSChPQᡈMg(OH)2PQᡠkBuvNa2sᡈNaOH஺RFᑺBNa2s஺4DEᑣPQ2BaSCh,DE2\ᨵMg2+,IᐭNaOHDEsᡂPQ3Mg(OH)2(RFᑺBNaOHDEPQ2Mg(OH),PQ3BaSCh,2kxyz{⚪஺ூ⚪%}y௃(1)ᔣ\ᨵBa2+ஹMg2+ஹAg+ḄDEIᐭHCL~shiAg++Cl=AgCU,sAgCl⁐PQᡠkPQ1AgCLsᡂ{PQḄe$Ag++Cl=AgClhফDE1\ᨵBa2\Mg2+,RFᑺBNa2sChDEᑣ~shiBa2++SO^=BaSOl.ᑣPQ2ᓄBaSCh;4᪷BaSChḄDឋSOfW◀ABCDE2F0ᔣᐸ.IBaCbDEMᔲᨵPQRSᨵPQᑣSO(W◀Yj(3)DE1\ᨵBa2+ஹMg2+,RFᑺBNaOHDEIᐭNaOHDE~shiMg2++2OH=Mg(OH)2(,ᑣsᡂPQ2Mg(OH)2((4)Ag+Ḅᙳ0.1mol/L,DE\ᨵḄ▢e$ᨵNO(,DEᕈᵯឋDEᙠc(NO()=2c(Ba?+)+2c(Mg2+)+c(Ag+),ᑣDENO(c(NO()=2x0/mol/L+2x0.1mol/L+0.1mol/L=0.5mol/Loூzᫀ௃⚪ὃᔠᱥᑖe¡Ḅ¢£¤஺¥e$¦§Ḅhiஹ⚪%Ḅ¨©yzḄᐵ«¬“⌲gPQᑖe”Ḅ▲ᑴᩩ²஺28ஹ³´µẆᡂ·¸ট2Fe2*+2H+K!10=2Fe3*+Cl'+H0ºᓾ?ᨔஹno5.3WpHV7.82.0X10-1222.0X10"0.9250(92.50%)ூᑖ᪆௃¼½¾⏚┛´µ(\ᨵB(SiWஹFe0>AIQஹFeC(hÁᩖ')ᵫÅuÆ´µ⏚D¦poÇÈÉᓄấo23E\ᨵFe"ஹFe"ஹAl3+,IË·bÌÍe$ÉᓄÍe$ᵨFᑺÎ⁚pHbÐÍ◀Yjk2ᑖ᪆yz஺ூ⚪%}y௃¼½¾⏚┛´µ(\ᨵB(SiOzஹFezChஹAU)3ஹFeC03Áᩖ')ᵫÅuÆ´µ⏚D¦poÇÈÉᓄấ,oE\ᨵFe/Fe*ஹAl஺IË·bÌÍe$ÉᓄÍe$ᵨFᑺÎ⁚pHbÐÍ◀Yj(1)³´µẆᡂ·¸ukÑÒ(1)ḄhiÓ᳛jÕ2ᡠÖ⚪zᫀ³´µẆᡂ·¸஺(2)vIᐭ_⏚Iᐭᐸ×⏚Øᐭᩖ'e$ᦑ⌱টjÕ2ᡠÖ⚪zᫀট஺(3)ÛJ⏚᪷e$ᙠ⏚ឋÜ᛻3³ÌÍe$ÉᓄÍe$e$2Fe2*+2H*+C10^2Fe3*+Cr+H0(Õ2ᡠÖ,2⚪zᫀ2Fe2t+2H++C10=2Fe3t+Cr+H0.2(4)1DEᑮᨔḄÞ~ßஹºᓾ?ᨔஹnoÁàájÕ2ᡠÖ⚪zᫀºᓾ?ᨔஹno஺

22(5)LᐭNᑺaḄQḄRS⁚ḄpH,UVWXYᓄWZ[\ᙠ.᪷_⊤aᦪ_cd.YᓄWᙠpH=5.5efghᐰஹᙠpH=7.8eklm.noS⁚pHḄqr5.3WpH<7.8(tuᡠw.x⚪zᫀR!5.3WpHV7.8஺(6)Fe(OH)3klfge.K[Fe(OH)]=8.0X10-38=c3(OH)c(Fe3*),c(Fe")=0.01mol•Le.c3(0H)=8.0X10-36,⌕sp3ᡂFe(OH)3fg.aḄc(OH-)ᨬrc(0IT)=2xl()T2mol•f1(fghᐰe.ᨬ10-5mol•L-1,K[Fe(OH)]=8.0X10-38=c3(OH)c(Fe3t),c(Fe3+)=10'5mol•L-1,c3(0H)=8.0X10-33,Fe"fghᐰe,ac(OIT)sp3ᨬr2X10".-i.molLtuᡠw.x⚪zᫀR!2.0X10-12(2.0X10”஺(7)᪵an(C)=0.05000x25.OOXl()Txio=o.(H25mol,᪷_n(AgCl)=2n(CaCb),ᑣn(CaCL)=0.006250mol,ᡠXm(CaCl)=0.006250X111=0.69375g,᪵aCaCbḄᑖᦪr0.69375/0.7500xl00%=92.5%(2tuᡠw.x⚪zᫀR!92.5%»ூzᫀ௃x⚪ὃᔠᱥa¡Ḅ¢£.¤¥¦§Ḅ¨x©ª.ᔠᱥᑖ¥¡¢£Ḅ«¬஺m⚪ᐵ¯!°±Ḅ²§³´µ¶·¸ᘤḄᵨ.᪵»Ḅᑖ᪆e⌕°±½Ḅ¾.°±ᨵᦔᦪÁÂ⚪஺29ஹÃᕜÅ.ÆVIAÇ0.5ÈÉSeḄÊ.ËÌSeÍÎÏaϽ¾CuO.AuÑ⏚Òᜧ.TeO?Ô⏚.ÕÖTeOzfg×hᐰTev+2S02-+2H0===2S0Z+TeI+4H+SO2Ḅ0ᔠ23ᵨ5ᔾᦈ8ᑮH2sO4ஹSe,>?Ḅᓄ@ABC2SeO+2SQ+2H=2HSO+SeJ஺ᵫᓄ@>?ABCJKL4molᵯNᡂImolḄSe,ᑣKL2molᵯ224Nᡂ0.5molḄSe஺SeḄQR685஺஺ឋ./S,SᵨTUVWḄAXYZẬ\]^_`SeḄQRa^bcSedU2ḄtheN>?஺!"⚪#ᫀ%0.5i_`SeḄQRbcSedU2+2eN>?஺(3)□᩽lḄCuSஹCtuSeஹCiuTeᙠmnᯏpqBrdO2>?KᓄCuOஹSO2ஹSeO>TeCh,Au\>?,2ᐭNaOH“vw”yCuOஹAu\dNaOH
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