江西省抚州市2022-2023学年高三化学第一学期期中检测试题（含解析）

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2022-2023
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1925ஹᵯ⛳hi᳛Ca(ClO)2+2KCl=CaC12+2KClO1ᨔᵨᒕ;!33ឤKLKClChᑖᐰজᙠᘤ@ᓾᒕ;ᔾঝ6¡⏚£ᐰᑖ(¥ᑏ)ூᑖ᪆௃(1)§¨ᵨᵯ⛳Ḅ©ª«¬¡$(2)®¯ᓣ±ᨵᑭ³hi᳛$(3)Ḅ¡⏚┛µ¡ᓄ£hi«ᡂ¶¯·¸Ḅ¡⏚£ᵨᨔḄ©ª¹º¡⏚£ᨔ;$(4)প»¼;ᙠ«½@{|$(ii)¾¿¾¿Ḅ;!ឤKLᑖᐰ$(iii)À¿ÁÂÃḄz7ÄÅ298%,KLᡠÇᦪBȸ
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◤⌕ᐹᜓḄẠ஺26ஹ⛳FeCLᕈ⋎⁐ঝটঢঝঢঞঠডঢFeCk+SlWl)AFe(0H)3()+3HClS0!Ḅ"#$%&ᦔ(2Fe3t+Cu=2Fe"+)*+,-ᴻ/2Fe3t+3C10-+10OIT=2FeO0+3C1+5H2O(ᡈ2Fe(OH)3+3Cl(r+401r=2FeO0+3Cr+5H2Oᑏ678ᓽ:)ூ<ᫀ>᪆௃Iஹᵯ>BḄCDEᙠGᡈᰚIJ᝱LMNOᵯḄᓄᔠᱥS⌕ᒹU⏚ஹWஹXஹYZ[\]ᓄᱥஹ
஺ᡃ_ᙠᑨabcd⚪Ḅf᎛ᨬijḄklEᢥ᯿ᱥBḄᑖcpqᑨa஺জstEu᝱v]ᓄwx\yz{ᱥBGḄ|7}ᙠᰚIJ᝱LᙳxOᵯᡠxEᵯ>BঝNaHCChᨔ\yXᙠG:ᵯ

20z{[]|ᵯᡠS~ᵯ/6ঞ~ᔠᱥ]9ᓄᔠᱥᡠS9ᵯ/6ট⏚~⏚ᙠ!gRSᵯ{z{[]|ᵯᡠS~ᵯ/6ঠFeCb!9ᔠᱥ]9ᓄᔠᱥᡠS9ᵯ/6ড9ᓫ6]9ᓄᔠᱥᡠS9ᵯ/6ঢᰚḄKOH~ᙠᰚ᝱C!gᙳRSᵯ{z{[]|ᵯᡠS9ᵯ/6ণⅅ~ᱥ6gḄᙠ!Cᰚ᝱ᙳ|ᵯᡠS9ᵯ/6ᡠS~ᵯ/6Ḅ9G(2)@©»ᵯ/6Ḅ9ᙠ!gᡈᰚ᝱ᐰᵯ{Ḅᵯ/6ᵯ/6✌ᐜ¢£9ᵯ/6¤eঝ©ঢ§☢©ᐸgNaHCChᨔ2ᙠ!gRSᐰᵯ{z{[ᡠS~ᵯ/6⏚~ᐳ¬ᓄᔠᱥᙠᰚ᝱ᵯ{z{[ᙠ!gᐰᵯ{ᡠS~ᵯ/6ᰚḄKOH9{[ᓄᔠᱥᙠᰚ᝱C!gᐰᵯ{z{[ᡠS~ᵯ/6~ᵯ/6Ḅ9ঝঢ஺ᙠஹFeCh!ஹᰚḄKOHg®ᨵ¯°ᵫ²³Ḅ{[ᡠSRS|ᵯ´Jµ~ᓫ6®ᨵ¯°ᵫ²³Ḅᵯ[ᡠScRS|ᵯ¯|ᵯḄ9ঞঠডঢ஺IIஹজ.Fe(OH)312Ḅᑴᜓ¹º9Gᔣ¼Ḅ½¾g⌲Ànᐭ⛳CḄFeCb!ÂüÄ!ᕈÆ⋎⁐ÉÊAnËᓽRᑴÌFe(OH)312஺ᦑ'ᫀ9G⛳CFeCh!ᕈÆ⋎⁐FeCb+3H2஺()=Fe(OH)3(12)+3HCl஺ঝ.ᔣFe(OH)312gnᐭNa2s04⛳C!ᵫÐ⏚᪷{[gCÒᓄÓ1=Ḅᵯ₹|Ô12ÕqÒÖsᦑ'ᫀ9GSO42';12ḄÖsঞ.ᑭᵨ12ᐹᨵNOPᦔ#]!ØᨵNOPᦔ#ÙÚEᑖ12C!ᡠS'ᫀ9GNOPᦔ#IDஹজ.FeCh!ᵨ´⇨ÜÝᑴ⌼ᵯßàḄáâᑭᵨḄ9Fe3+ḄᓄឋäᓄᡂCM+,ᡠSᐸ"#Ḅ{[åºæ9G2Fe3++Cu=2Fe2++Cu2+»ঝ.ᑭᵨFeCb!ᑴiFeCb6H2Oᨔ2◤⌕ᙠHC1çègnËஹ½Õéêᐸë⌕ì´ᒹîGÀᐭ¹ït⏚,½Õéêஹñᓾóᨔஹ¹ô¹ôì´ë⌕◤⌕ᵨᑮö÷ஹøᧅஹúᴻüᡠS'ᫀ9G½ÕéêúᴻüঞஹᵨFeCbKC1Oᙠឋᩩþ"#RᑴiKzFeO4,ᐸ"#Ḅ{[åºæJG3Fe3++3ClO+10OH=2FeO2+3C1+5HOᡈὅ2Fe(OH)3+3ClO+40H=2FeO42+3C1+5H2஺஺4227ஹᑖᧅ■C12KOHᡂKCKhHC1ᔾᦈCI2,■3C1O+2Fe3++10OH=2FeO2+3Cl+5HO⛳KOH94.3%42ூᑖ᪆௃(DᘤaᑖᧅC⚠!"#$%Ḅ'Ḅ()ᑴ+,■-./Ḅ01(2)B(◀34Ḅ4ᓄ6DḄ7ᵨ(9ᔾᦈ:1(3)CḄKC1O,;ᐭKOHஹFe(N(h)3)ᑴ$%+,25,C,ᤅ>1.5h,ᡂKzFeChஹKC1HO2(4)⚪@ABC“KFeCh᧕"$ஹE"FKOH”ᡠIᔣᐸ;ᐭFKOH1(5)LM./ḄᐵOPQ2FeO42———2CrO?-——CrO72——6Fe2+,RᐭᦪTUVWXRFeChYZḄ[,஺2

21ூ⚪>௃(1)ᘤaᑖᧅCG⚠ytGḄḄEᑴ,■C12KOHᡂKC103.<ᫀᑖᧅ■CbKOHᡂKCKh;(2)BE◀GḄᓄDḄᵨE¡ᔾᦈ¤஺<ᫀHC11ᔾᦈCL,■¥¦§(3)CGḄKC1O,¨ᐭKOHஹFe(NO3)3ᑴ25'C,ᤅ«1.5h,ᡂKzFeO¬ஹKC1H2O,(Ḅ®k¯°3C1O+2Fe3++10OH=2FeO42+3Cr+5HO0<ᫀ23C1O+2Fe3++10OH=2FeOr+3C1+5HO2(4)⚪G±²³´“RFeCh᧕yஹ¶y+KOH”ᡠᔣᐸG¨ᐭ⛳KOH஺<ᫀ⛳KOH(5)º»(Ḅᐵ½°2Fe(V———2CrO2'——CrO2——6Fe2+427,,250mLn(FeO2)0.01000mol-L^xO.OSLx-------425mL0.00Imolx198g/mol¾:¿6”(FeO4*)=0.()()lmol,RFeOa!ÀḄÁ-----ஹ…,-----x100%=94.3%,<ᫀ94.3%஺0.2100g28ஹa+bAI4C3+I2HCIMAICI3+3CH4t■MgஹAlç]ᓄ52molAl2Al+3AgO+2NaOH=2NaAIO2+3Ag+HO2ூ⚪>௃(1)জ᪷ÅÆÇCÈÉ⚪GᡠÊËk¯°Ì¨ÍALO3(s)+3C(s)=2A1(I)+3CO(g),Î(ḄÏ!!=(a+b)ᦑ<ᫀa+b1ঝÓÔᨬÕḄ±CH4,᪷ÅwÖ®×ឤ38w◤⌕Ùᔠ128HÖ®Úᡂ38CE,ÛᵫÝÖ®×ឤ48Ý◤⌕Ùᔠ128C1Úᡂ48AlCb,ᡠAl4c3HC1Þß1Q12à¨(ᦑá(k¯°AI4C3+I2HCIMAICI3+3CH4t1(2)জ╅ஹÝãEYZḄ[\ᓫBå᧕çGḄ]]ᓄæᐭ]çè■vὅÃ]ᓄᦑ<ᫀ■MgஹAlç]ᓄঝImolMg17Ali2êᐰᔾ17mo1,ᙠX⏚Gìᐰíîï6ᩭ╅Ýᔠ[GḄ╅ÝãMX⏚(ᡂlh,ᡂḄᱥBḄÔᑖñ17mo1ஹ18mol,ᑣᡂ7ᐳ(17+17+18)mol=52mol,ᦑ<ᫀ52mo11ঞ╅NaOHx(Û᪷Åõö÷ø:ùᙠNaOHG!ḄS⌕ᱥBEÝᦑ<ᫀA11(3)Ýúû᩽ᜫᵯ®Ã]ᓄᙠWឋGᡂNaAKh,]ᓄÿ
᩽ᵯAg,ᵯNaOHᡠᐸᵯ2Al+3AgO+2NaOH=2NaAlO2+3Ag+H2O஺29ஹ(S)CDVsp3᩽ឋᑖ!"ᙠ$(&ᫀᔠᳮᓽ+)஺-Jr44x64+4x56+8x32(0.5242xl.032)X102IXNA

22ூᑖ᪆௃(DCuFeSz1"ᙠCi?+ஹFe?+-S”CuFe%1345ᐗ78-945ᐗ7ᐗ7Ḅ345ឋ;<ᵯ=ឋ;ᜧ?8@ᵯ3d64s2,9@ᵯ3d»»4si,A᝱ᡈḄ@Dᵯ᣸FG1HIᡈᐰIKLM᪀?(2)ᙠOPQRSCuFeSzTU⏚WᵨYᨵ[\]^_`ᕡḄ`bXcdH2s`b?জ-fg$ᡂfgᐳ@᪷kH2s5AX2,@Dᵯl4lVSEPRmno☢bqSᨵ2lrᵯlᩭᑨuᑖḄvb᪀n1wᩖᓄzsp3ᩖᓄVឋM᪀ᑖᐹᨵ᩽ឋ?ঝH2sḄ|}~PḄ⌕ᑖ!ᡂ$?(3)ᓄᐳ@ᓄᔠᱥ-fg!ᑖᡂg0Y-!ᡂg4ᵯn?(4)জozᨔCuFeSzᨔM᪀᝞Gᡠᑖ᪆+9ᡂogᐳ@fg8-fg9?ঝᨔ18=8X+4X+1=4,9=6X+4X^=4,=8,ᨔᑁᐳ4gCuFeSz,a=b=0.524nm,8224c=1.032nm,ᑣᨔbḄR="஺ூ⚪௃(DCuFeSz1"ᙠCM+ஹFe2+-S%"ᙠḄᓄn?CuFeSz1345ᐗ78-945ᐗ7ᑣ¡¢ᐗ71ᵯ=ឋO<Ḅᐗ7?8@ᵯ3d64s2,9@ᵯ3di04sLA.@88ᜫ¤ᨬ᜜D2gᵯᡂḄ□3d¨⍝ᨵgᡂlᵯ4s¨⍝ª¨⍝ᦑA┯?B.9@ᵯ3d">4sL¨⍝⊤¯°ᔠᦑB┯?C.¡@88ᜫ¤4sfgᵯ-3dgᵯ3d¨⍝±ᔜᨵgᵯKLM᪀ᦑC
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³?ᦑ&ᫀCD(2)জH2sᑖ1@Dᵯl4lVSEPRmno☢b@Dᵯl´!Ḅᜳ¶ᙳ109஺28qSᨵ2lrᵯlᡠᑖḄ᪀nV1wᩖᓄnsp3ᩖᓄ5¸᩽ឋᑖ?ঝH2sḄ|}~PḄ⌕ᑖ!ᡂ$?(3)ᓄᐳ@ᓄᔠᱥ-fg!ᑖᡂg஺Y-!ᡂg4ᵯnSCh1wḄ@Dᵯlᦪ3lᐳ@Ḅnᨵ0-“?(4)জᨔM᪀ᑖ᪆+ᵫ☢w±CuT2gS¼ᨔ1½gCuT4gS¼Cu+Ḅ¾¿ᦪ4ঝᨔ18=8x+4x1+1=4,9=6x'+4x'=4,=8,ᨔᑁᐳ4gCuFeSz,a=b=0.524nm,8224mx(64+56+2x32)g/mol4x64+4x56+8x32c=1.032nm,ᑣᨔbḄR=—=N^mol______________________=(0.5242x1.032)x10-21xN,1V(0.524X0.524x1.032)x10-21cm3