皖豫联盟体2022-2023学年高三化学第一学期期中综合测试模拟试题（含解析）

《皖豫联盟体2022-2023学年高三化学第一学期期中综合测试模拟试题（含解析）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2022-2023
ᓄᔁ⚗1.ὃᔁ⚪ᓱ.2.⚪!"#$%Ḅ'(ஹ*ὃ+,ᵨ0.5./0⁐23Ḅ4567ᑏᙠᔁ:⚪ᓱḄ;<=>.3.?@᪶BCὃᕒᙠ⚪ᓱᡠFGḄᩩIṹḄ'(ஹ*ὃ+,KLMᔲOP.4.Q⌱S⚪#Tᵨ2BU6⚪ᓱBV⌱⚗ḄW᪾YZஹY0[᝞◤ᦋ_ᵨ`abcde⌱Yᐸgᫀ.Qi⌱S⚪#Tᵨ05./0⁐23Ḅ456ᙠ⚪ᓱḄᢣ<=>Qᙠᐸg=>Qklᦔ.5.᝞◤QnTᵨ2BU6oஹᑏpqrᩩஹP,sTt0ஹtu.ஹ⌱S⚪(ᐳᒹy22z{⚪஺}{⚪ᙳᨵzPᔠ⚪Ḅ⌱⚗)1ஹH2O2M⏚ᙠ⌕H(h-Iᙠ஺Al—H2O2ᵯᵯCO(NH2)2ḄឋᑴᜓH2,ᑡ¡ḄM()A.ᵯ£¤ᵯ¥Ḅ¦ᔣᵫa-d—>c—>bB.ᵯḄ᩽ªV«¬HO2-+2e-+HO=3OH-2C.ᵯ®ὑ5.4gALᑣ±²᪗´2.24LN2D.ᵯ᩽cM□᩽¶ªV·ᵯ᩽¸pH¹{2ஹº{»ᑭᵨ☢Ḅ¾>¿ÀÁÂঝஹঞᙳÅÆÇQÈ᝞⊤஺Êᧇ¬CaS⍗3Íᐰ3ᵫÏÁÂÐÑḄÒ¡ḄMA.ঞÓ⁐ÔÕMCaCChB.ঝpHÖ×ḄØÙM¬HS+CU2+=CuS
+2H+2

1C.ÁÂIজCCh£ÆÛ²ḄªVM¬CO2+H2O+s2==CO2+HS32D.ᵫÁÂInÜÝÞ112co3H2s⏚ឋḄ3ஹᓄKßàஹáஹᢈãஹä᛻æᑗOᐵ஺ᑡ¡ḄMA.é!êÑḄ“×ìíî”ᓽ¹ñᔣä᛻᣸óCO2,ᢓᑴ⏚õḄIᡂB.÷øùᵨúᧇᵯûüý¹ñ⚩ÿᱥஹCOᨵᱥḄ᣸C.Ḅấᵨᑴᐝᐝ⍗“”D.!ஹ"ᴻஹ☘%&ஹᨔஹ(ᴣஹᑖ+,-.ấ⏚012344ஹ5ᑡᐵᨵ8ᓄ:;<Ḅ=>?@ḄABCA.◀EFGḄᵬFIJᵨ⏚ឋKMn4LNaOH,ᯠNᑖOB.◀EP⏣GRᨵḄSTP⏚UNaOHVOᯠNᑖOC.W┯uḄAA.vwkxyz{ᩖḄ}8ᑖ+A~⌕Ḅ◚ᩞᧇᡃvwkḄẆᜐ⚞ᐜᙢB.sᙠGbᡂḄᓄnᨵᔾ▬ឋᵨsC.2017ᡃᓅ¢ᙢ£¤¥¦§¨“᯼ᦋm”L“᯼ᦋᵯ”Ḅ¬®Aᦋᗐ°mTḄ~⌕±²D.³ᢈ32GḄµᵯ◌&·bᱥ◌&.¸¹}8º».ᩞᧇ6ஹ5ᑡᨵᐵ;<=>?@ḄAA.¼T½L¾¿ÀÁ-᪗ᨵJᵨÃJᵨl¾¿ÀÄNÅ◤ÇÄȼT½ÄNÉᵨÇÄB.ÊVOpH:ᵨËÌÍÎḄ"ᴻÏ↾ÑNaClOVO¾ᑮᙠ⊤☢ÕÁḄpHÖG×Ø⁐NÙ᪗ÚÛ⁐ᓱÛC.ÝÞßàGÄághlâᐵãäᜮUÄáᑺçèghᵨ"ᴻÏᙠßÞᘤÁᤅëìJghíÄáᑺᐙᑖ^ïìðÄñòËÎD.;<ßàGḄᨵó4Éñᐭôᑁᡈὅ^ïøôᒕúḄûOÉñüýᦈJᵨâ᎔ᐭ
⍝7ஹ
ᑡᨵᐵḄḄA.◀NazCOsᨵḄNaHCOs,ᐭNaOH!"#$%&'(B.)*ᓄ,-ᨵ.ᓄ/-"01ᨵ⛳3NaHCOs!Ḅ4-5674-"ᯠ%9(:C.;<=Ớ?@;

2B.ᨔ᝱ᵯᰚ᝱ᵯ!ᐙᑖ$%&ᨔ'()ᨔC.*ᑖᨔ+,ᨔᨬ☠Ḅ0123'456X—7897:;D.<᝱SO3+SO2=>?)Ḅ@ᵯ)4ᦪBCD9ஹ=FGHḄI%J⌼LMNᦻ%5PQRSTᜧVWXᑡZᨵ\]ᓄ1_`Ḅ'A.AB.BC.CD.D10ஹXfLN2ᑖ)ᙠhᓄᑺjᵨXIlmnᑡoᓄḄpqfXᑡrstuḄ'()N1NOOH*OONhᓄᑺahᓄᑺbA.xNyNz'akJmol^H—Hz'bkJmol^H—Nz'ckJmoH,{||~lᡂ2molNH3,R(6c-a-3b)kJNH3ᑖ)+H2Oᑖ)Ḅ=>?)ᩖᓄNC.hᓄᑺaஹb⊤☢ᙳIlS᩽ឋᐳzḄᙠhᓄᑺbjᵨXIloᓄᑮḄlᡂᱥᙳL8ᑖ)11ஹ
2016•᪗ᔁIXᑡᐵᨵᓄᔠᱥḄ$3tuḄ'A.2-ᵬ¡¢£¤¥L¦¢£B.ᵫ¨©lᡂ¨⏣«¬ᡂ_`C.C4H9aᨵ3ᑖ¦᪀D.®ᾦ+°±²³«´ᑖ)ᓄᔠᱥ12ஹᡃ¶·¸=¹1℉j»¼½₝¿=ᐵ“☘Ẇ”ḄÄsLÅ“½ᩭÇ⁐RÉÊËÌὅt᝞ᳱᴻÑÒÓ⁐஺”%Õ1ὅ2Öᡠ℉»ᱥᳮÙÚ¿=$Å“☘Ẇᔆ<ÜM⊟ÞßÒ᧕áâã஺”XᑡᨵᐵrstuḄ'A.Ó⁐'Fe2(hB.“☘Ẇᔆ<å'CO+CO2C.☘æ'NH4Al(Sth)rl2H2OD.☘çèéêëì■îï?ð²

313ஹñò1gó<ôᐰöÑlᡂ÷᝱øùR143k.I,18gøú<ðᡂ÷᝱øR44kJḄ஺ᐸüCᐵᦪý᝞X⊤Åᑣ⊤=xL()0=0H-HH-O(g)Imolᓄ1zù◤496436X⌕ᔾᦈḄ/kJA.920B.557C.463D.18814ஹᓄஹᑗᐵᑡḄ()A.ᨵ!"ᑺḄᱥ%&'Ꮙ)ᙳᨵ+,-ᵨB.“12”456ᵨḄ789:;<=Ḅᨵ>?ᑖAᩞᧇC.FezChDEFGHIG⁐KLMNᧇD.OPQRHᵨᵯTNaஹMgஹAl%UḄVᓄᱥᑴXY4;Z[ᓫ]15ஹᑡᓄᵨ^_ᵨᩭ⊤b:;cdḄ()A.C3H8B•᳘gC.hVijD.|J]|J]|/16ஹᑡᑖAk[lᨵ᩽ឋoḄp᩽ឋᑖAḄA.HOB.NHC.CHD.HC123417ஹᑡ,ḄA.-ᑭᵨrᨵP2O5Ḅstu◀wNH3kḄxyzB.ᡃ|}~ᕚᕚᑭᵨi⏚☘kḄ☘⃓XᩭC.Ẇ-ᑺᐸxTᡂḄ'ᑖᦣ]ᐹᨵᜧḄ⊤☢D.-ᵨ⃓XỚᓫ]ỚḄVᓄ7kXᩭ18ஹ¡¢kᑡIḄA.ᵨ᯼K¤¥Z[┞B.ᵨstᘤst¨©Ḅª⏚«C.ᵨF¬"®ᰚ°NaOH±'D.ᵨpH²³´FeCbḄpHµ19.:¶·¸2moiSO2M1molO¹ᐭ10Lឤ·¼½ᘤk,¿U:2SO(g)+O(g)^2SO(g)AH=-196kJ/mol,22235minÁÂᑮÄ⊝´ÆUÇ®166.6kJ஺ᑡ┯ÊḄ()A.0~5minᑁᵨCh⊤bḄÄᙳUÌ᳛i)(C)2>=0.(H7moÎ(L,min)"B.ᩩÐ,ÑÒÓÁᔣ½ᘤk¹ᐭ4moiSO2M2moiCh,Ä⊝ÁUÇ®Õl333.2kJC.Ö×ᜧO2ḄظᑣSO2ḄÚᓄ᳛×ᜧ

4n(O)2D.ḄeWdf,g#$hᑮj⊝l᝱n(SO)320ஹ
ᑡᢣo#$ḄpYP\qḄA.ᔣFeBn!0ᐭC2Br-+Ch=Br+2CF2B.ᔣNH4Al(SO,2!ᐭKOH!?Al3++4OH-=A1O+2HO22C.ᵨ/*ᓄs!ᔾᦈvwx-ḄNO2NO+2OH=NO3+NO2+H2O22D.ᵨyឋᵯ᩽ᵯ}AlCb!?2C1-+2H200ᵯCLT+H2T+2OH21ஹ~!Xᕈ⁐"ᨵBa2+ஹNa+ஹNH\CஹஹSO2\SC^-pYḄ(Wὃ⇋Ḅ43ᵯp)"!ᔜpYᙳ0.1molூr,ᔣg!ᑴ."ᡠ!⁐஺
ᑡᐵ!XḄᑖ᪆WḄ()A.oWCB.oWH+C.oWNH4+D.oᨵSCh"22ஹ
ᑡᨵᐵᓄP\qḄUVḄ()A.¡2¢9)+O(g)="=="2HO(g)AH=-483.6kJ/mol,ᑣ/-Ḅ¤¥&241.8k.J/mol22A.¡C(¦§,s)="=="C(¨©¦"s)AH>0,ᑣ¨©¦ª¦§«oB.ZO.OgNaOHḄH!ZH¬⏚ᐰ3"¯¢28.7kJḄ&,ᑣ⊤±g#$3&Ḅ&ᓄP\q:NaOH(aq)+HCl(aq)="=="NaCl(aq)+HO(1)AH="-57.4kJ/mol"2C.¡2c(s)+2(h(g)===2CO(g)AHi2C(s)+O(g)===2CO(g)H2ᑣ³HI>A¢22)ஹ´⌱¶⚪(ᐳ84ᑖ)23ஹ(14ᑖ)ᨵ¹ᱥM»¼½✏ᧇ"CJiio]ᧇ0᝞
ÁÂᔠᡂ?C4H10¡:জR—CH-CH2ߟ""""►R—CHCHOH22(I)H,O,/OH-(2)RCHCHO+RCH2CHOJ^21L2RCHCHCHCHORCHCH-CCHOAOHR*-*R'ঞFᑖYḄ,ÅÆÇᨵÈÅ;EÊ✏ËᓄᔠᱥEஹNÌMbÍÎ#$஺ÏÐÑ
ᑡÒ⚪?

5(1)AஹBᙳ».Ó¥"ᑏ¢ᐸ»ḄÖ×(ØÙÚÖ)»
MḄÛÜÖ×(2)ᑏ¢
ᑡ#$Ḅ#$_`:F-G,D+GfM(3)FZᑴCu(OH)2/NaOH(aq)#$ḄᓄP\q(4)MḄN᪀Þq
EḄ᪶àᐳá/âᨵ»ã஺(5)ZGᐹᨵåæÛÜḄGḄÊ✏_æᑖç᪀ᨵ»"Ïᑏ¢ᐸ»ḄN᪀Þq:(6)è᯿ÆVᔠᡂÁÂ"êëì()3ëí]ᧇ(¹îᑺð⌱)"ñòᑴᜓ^ycIhCH-CHCHOḄᔠᡂÁÂ?24ஹ(12ᑖ)¦ôõ}ᑮḄëì31,3-ö)ì]ᧇ"÷
ᑡ#$ᔠᡂøᑖYᓄᔠᱥH,gᱥTᵨᑴ⌼úᴻüýþᧇḄÿᛛᧇ(ᴻ)ত,HR+OOᢥ⌕(1)ᑏᑡḄজঠO(2)ঝḄᓄ!"#$஺(3)ঞஹট(ᨵ*$+HC1,ᡂ./$(01).234*5Ḅ6Ḅ$.ᱥ8CḄ9᪀;#$»(4)ᑏ+Gᐹᨵ=>?@ᦪ6ḄBCDḄ>ᑖF᪀G.(5)ᑏᵫᵬKᔠᡂKᵬMḄᔠᡂNO஺25ஹ(12ᑖ)ᙠRSTUᑴWXYZ.[\]^_`abcd.eᑖX⏣ghH2s04cᡂSO2,CO2,ijk@lm஺

6IM!+iqrsMiᨔursv50ߟ'-p1জঝঞট(1)ᵨ01yজ*টḄRSz{23*|RS.}S~ᔠkG(CO2,SO2@ijk஺ᵨz{Ḅ(ᢥᱥkᑮḄᔣ)_T_T_T_஺*(2)RSḄz{(1)(AḄ$*9y_B(Ḅ$*Brsᵨy*஺C(urs⁐.ᑮ9y*O(3)z{ঞ(,ḄG$*,}S~ᔠkG(ᨵ*஺z{ঝ(Ḅrs$*,}S~ᔠkG(ᨵ*஺26ஹ(10ᑖ)ᓄ᜜¢£y¤¥k(CO2Ḅ¦.§¨©᝞RSজ«ᑴ0.1000mol/L@0.01000mol/LḄ᪗®⏚஺ঝ°2
3±²Ᏺ,ᐭµ¶h^ḄBa(OH”rs10.00mL(.·ᵨ0.1000mol/LḄ᪗®⏚§¨±¥.9¸ᵨ¹®⏚19.60mL஺ঞᵨ¤¥ḄBa(OH)2rsᔾᦈ¥¦k(ḄCOoWBa(OH)2rs10.00mL,¼ᐭ100mL½¦U,i¾¿^O.2WÀÁÂḄrs¼ᐭÃĽᘤᑁ.·Çᐭ10L᪗ÈÉḄk.Ê₩.4ZcᡂÌÍ஺ট_ÎᡠÐs஺ঠWÎs20.00mL,ᵨ0.01000mol/LḄ®⏚±¥.ᵨ¹®⏚34.80mL஺ÑÒᑡÓ⚪প«ᑴ᪗®⏚Z.◤ᵨᑡ×ØÙᘤ?஺A.ᡲÜᜩÞB.½¦C.⏚#±¥ßD.¦àE.áâF.ãᜮ±ßG.ᴻåফঝç(ᑮè±¥éêZḄ$஺(3)Ba(OH)2rsḄᱥ8Ḅ¦h^$o(4)ëRS(.ì*í±¥ZîᵨḄ⏚#±¥ßµïᜐᳮ.ᓽóᐭìô?᪗®⏚.·§¨ìôí±¥.9¸(“öᜧ”“ö¢”ᡈ“úûü.ý(5)ëRS(.ᙠì*í±¥ḄZ᎛µÿ
(“ᜧ”“”ᡈ“27ஹ(12ᑖ)⏚(NaNO᧕!"⏣$%&ᾙ()*Ḅ,⁐ᑺ/$0■2ᾙ3ᩚ5ᙠᾙ()*789:ᢝᾙᑴ*Ḅ᪀>⃩@ABCDEFG᤬ᐭJK73஺MᓄOᐶQRS⏚TUVWXYZ[I.⏚Ḅᑴᜓ

7(1)_`7ᵨឤc
deᧅghijᑖdeᧅᐸl℉noE.(2)D7pqrᮞtuvᑣC7ᑴᜓNaNChḄxyz{|&II.YZ⏚}~⏚8ᡂḄᱥ[জNO+NO2+2OH-=2NO2+H2OঝdᓄḄX[NOs2PC,NO-152࠷2(3)ᡭᜳᐜjᐭᐸḄE.(4)&`A78ᡂḄᱥḄ()[AஹCஹ(5)ᐵ¢ᜳᡭᑖdeᧅ£¤
ᐭ70%~⏚¥A78¦§⁐஺জ©ªA78Ḅ«ᨵNO,®Ḅ¯°EoঝEḄ%ᵨE.ঞjF³´_`YZF{$µ¶A7ḄᓄOz{|&oHL·¸_`¹º⏚ឋᩩ½¾NaNOzᐹᨵÀᓄឋ(6)Á⌱ᵨḄÃᑺ[NaNChdஹKMnChdஹFeSChdஹKIdஹÄ~⏚ஹÅÆdஹKSCNd஺᪷®ÈÁḄÃᑺ·¸⏚ឋᩩ½¾NaNChᐹᨵÀᓄឋḄ_`zᫀ[o28ஹ(14ᑖ)C1O2EÊËᵨḄÌ3ᑺ,ᡃÏ2000ÐÑ⌲ÓᵨC1O2ÔÕÖS×ᵨTUÌ3.পÌ3,COÙ$Ú7ḄFe2+ஹMi?+ÜÝᓄᡂFe(OH)3>MnChÜÞᱥ◀àᙠáâF{7Fe2\Mn2+ḄᓄᔠAᓣåæºCKhᐹᨵឋ.ফèé³$0jF¾ᑡzëᑴìC1O2,íîᡂïᓄOz{|2KCK)3+SO2==2CKh+.বCh>HO(g)jFñòḄóô8ᡂHC1>COᑏ¶ᓄOz{|:22(4)÷ᩭᔆᵨCKhᜐᳮ¥Ḅ7⌕ýCKhḄþXᙠ0.1~0.8mg/Lÿ஺ỚCl(hḄ᝞

8åIX:¶'Ḅx᪵"ᐭ:¶ḄỚᓄçèᵨéêᓄëìíkឋî"ᐭïðÑñ஺II"ᐭ:¶ḄNa2s2O3஺(òóå2S2O2+l2==SO62+2r)34HI"ª⏚ì⁚x᪵pHí1
3஺õÁ,öpH÷᛻kdA;ù᝞ûᡠbå-1+3+4ᓄᔠýþÿজIḄ஺ঝᙠmᕈ⁐Ḅ»ঞ᪵Ḅ1.0L,ᙠII!"ὑ$1.0xl0-5mol/LḄNa2s2O310ml,ᑣ᪵CIO2Ḅ'(mg/L.29ஹ(10ᑖ)“-☘/01/2/”45Ẇ7NOxஹSO28ᜧ:;<ᱥḄ>ᗐᜐᳮᐹᨵD⌕FG஺(1)SO2Ḅ᣸IJ⌕ᩭLM᯼ḄOPQRSTᵨVᔾᦈYᜐᳮZ:ḄSO«2[\ᔾᦈ]ᐵḄ_ᓄa᝞cজSO2(g)+NHyH2O(aq)=NHHSO(aq)AHi=akJmol'43ঝNH3H2O(aq)+NH4HSO3(aq)=(NH4)2SO3(aq)+HO(l)AH=bkJ-mol122@2(NH)SO3(aq)+O(g)=2(NH)SO4(aq)AH=ckJkJmol422423ᑣ2SO(g)+4NH-HO(aq)+O(g)=2(NH)2SO(aq)+2HO(1)ḄAH=kJ-mol-12322442(2)O᯼dᵯᔆTᑭᵨ2CaCO3(s)+2SO(g)+O(g)=2CaSO(s)+2CO(g)AH=-68L8kJmol”h᯼ijῃ2242lᜐᳮᩭmnSO2Ḅ᣸I஺hMoᙠT࠷!pqrsᘤuvᙠwx!yzSᔜᱥ|Ḅ'(᝞c01020304050021.000.790.600.600.640.64CO200.420.800.800.880.88জ0
lOminᑁ~ᙳ᳛v((h)=mollfminrᓣ(oḄ~⊝TᦪK(“ᜧ”“mᡈ“w”)஺ঝ30minᦋᩩDᑮ~⊝஺᪷S⊤ḄᦪᑨᦋḄᩩ(¡)஺

9A.¢ᐭ¤¥Ḅ¦§¨⏚┛B.«ᐭ¤¥Ḅ஺2C.〉®ᘤḄD.¢ᐭᔠ〉Ḅ°ᓄᑺ(3)NOxḄ᣸IJ⌕ᩭLM²³Z:ᨵ´ᑭᵨC(s)+2NO(g)=N2(g)+C(h(g)AH=-34.0kJ-mol1,ᵨµឋ·hNOijᔾ▬஺[\ᙠ¹º®ᘤ¢ᐭ»¥ḄC¼¤¥ḄNO:½ᢝឤÀuvNOḄÁᓄ᳛Â(Ḅᓄ᝞ÃᡠÅᵫÃ\1050KÇNOḄÁᓄ᳛Â(ᓣÈᜧᐸÊ4ᙠU00K!CChḄᑖᦪ(4)ᵨᱥ|Ḅ~⊝ᑖÀËÌᐸᱥ|Ḅ¥'(ÍÎ⊤Åᓄa~⊝Tᦪ(ÏKp)஺ᙠ1050Kஹl.lxl()6pa!oḄᓄa~⊝TᦪKp=Ð[\:ᑖÀ(Pᑖ)=:ÒÀ(P/xᑖᦪÓ஺মQRSTᵨ'(ḄK2cᔾᦈCCh,vX,ÕᑭᵨᵯÖY×K2c03ÕØᐸÙÚÅFÃ᝞Ãe©HCO,O222——------,----------X'ß/KHC03জᙠ□᩽ãdØḄᒹå¼H++HCO=CO2T+HO32ঝæçCO3?•ᙠ▢᩽ãÕØḄÊᳮ஺2022-2023ᔁὃᫀ(!"#$᪆)ஹ⌱ë⚪(ᐳᒹå22î⚪஺ï⚪ᙳᨵîðᔠ⚪FḄ⌱⚗)1ஹAூᑖ᪆௃᪷ÙÚõöᵯ÷øöᵯÖ÷dᵯ᩽SùØH2,᪷ᵯÖÊᳮdᵯ᩽▢᩽ᑣCᵯ᩽□᩽,

10a'(᩽b'*᩽+,ᑖ᪆.ூ⚪1"$௃Aஹ᪷+5678'ᵯ:;8'ᵯ$:dᵯ᩽<=>H2,᪷+ᵯ$?ᳮdᵯ᩽'▢᩽ᑣcᵯ᩽'□᩽a'(᩽b'*᩽ᵯ$DᑁFGᨵᵯIJKᵯILᔣᵫa-d,c-b,ᦑAP┯R.Bஹ᪷+A⌱⚗ᑖ᪆bᵯ᩽'*᩽ᵯ᩽UVWXY'HO2-+2e-+H2O=3OFF,ᦑBP*Z.Cஹ᪷+[ᜫᵯIᦪ1^ឤ`,ᨵù3=x2x3,$[V(N2)=2.24L,ᦑCP*Z.27g/mol22.4L/molDஹ᪷+A⌱⚗ᑖ᪆ᵯ᩽c'□᩽ᵯ᩽UVY'CO(NH2)2+8OIT—6e-=CCh2-+N2t+6H2஺aὑOHT,UVcdᵯ᩽epHfgᦑDP*Z.ᫀ'A஺ூᫀhi௃ᵯ᩽UVYḄjᑏlm⚪Ḅnholphqrjᑏsᐜᑏuvᓄᑺ+ne--x?=ᱥx?ᑺqne-fvᓄ=ᱥᯠc᪷+ᵯ$DḄ{᛻ᑨ~ulH+ஹOH-UVᡈ>ᡂᨬc᪷+ᵯ₹^ឤᐸ஺2ஹCூᑖ᪆௃I.ᔣজḄNa2sᢝJᐭCO2Kঝ=>⁐ḄpHP>ᡂᓄs>ᡂ⏚.ঞ=>¡⁐¢£d¢£⍗⏚ᑈ¦P§vᓄ¨K©vᓄ┛ᔾᦈ>ᡂ¨⏚┛.U.ᔣᨵNaHCChḄজᢝJᐭH2sKঝ=>⁐ḄpHl`'KḄᓄ⏚®UV>ᡂCuS⁐s>ᡂ⏚.ঞ=>¡⁐¢£d¢£⍗⏚ᑈ¦PUV>ᡂ§vᓄ¨©vᓄ┛ᔾᦈ>ᡂ¨⏚┛.+,ᑖ᪆$஺ூ⚪1"$௃A.᪷+<¯ᑖ᪆ঞ¡⁐¢£lCaCO3,°±lCaS,`'CaS⍗²ᐰ$ᦑA*Z.B.ঝUV>ᡂḄᓄ⏚®UV´HS+CU2+=CUS
+2H+,µ[ḄpHᦑB*Z.2C.CChKUV>ᡂHCCV,¶>ḄUVl´2co2+2H2O+S2-=2HCO3-+H2S,ᦑC┯R.D.᪷+IஹII¸¹´IJ§vᓄ¨ᨵH2s>ᡂIIJH2sᨵ§vᓄ¨>ᡂ°±º»H2cCh¼H2s⏚ឋḄ¾¿ᦑD*Z.ᫀ⌱C஺3ஹBூᫀ$᪆௃A.1ÀÁuḄ“¨ÃÄ”ᓽfÇᔣ{᛻᣸ÉCO2,ÊËᦔVÍvᓄᱥÎÏ⏚ÐḄÑᡂᦑA┯R.B.ẆᑴÔ¶Õᧇᵯ:×ØÙfÇÚÛØᓄÜÕᧇḄÕÝÞßfÇ×ØàḄ᣸É`,fÇá⚩ãᱥḄ᣸ÉᡠᙠæçX<fÇèPM2.5!ᦑB*Z.C.éêḄ§vᓄấìíᵨïᑴðᐝòóô§vᓄấ¾õUVᐝòóô⍗¾õö“~÷”ᦑC┯R.

11D.øஹùᴻஹ☘üýþïÿḄấ⏚ᨔஹᴣḄ⌕ᡂᑖᓄấấ⏚ᩞᧇᦑD┯ᫀ⌱B஺ூᫀ%&௃ᐝ)*+Ḅᩞᧇᓄấấ,ᵨᑴ/0□2ᵯ456ᱥ8ᐹᨵḄ6ᱯឋ஺4ஹAூᫀ=᪆௃A.ᵬ@2AB⏚ឋKMnO4CDᓄE@ᵬ⏚FGHᓄIJKLᡂ᧕CḄN@C,OᵨᑖDḄPQᑖRᦑASTB.U⏣GWC2ᑖDᑖRᦑB┯C.XYZU[\]ᐗ_◤⌕ᐜbᐭd⏚⏚ᓄᦑC┯D.eYfᑴᜓḄUh\iijᨵᓄklmnᩖ8ᓄkp2qZr⁐ᦑD┯ᦑ⌱A஺5ஹBூ⚪uv=௃A.wxh/Eyz{ᩖḄ|}~ᑖ⌕Ḅ◚ᩞᧇᡃwxhḄẆᜐ⚞ᐜᙢASTB.Hᓄnᐹᨵᔾ▬ឋ,2ᔾ▬\ḄᱥN,ᨵᓄឋ,ᡠO2ᩔ,ᦑB┯C.“᯼ᦋm”¥“᯼ᦋᵯ”Ḅ¦§¨©ᓄkmnḄ᣸«¬ᦋᗐ¯m8°Ḅ⌕±²CSTD.³ᵯ◌µ¶Lᱥ◌µ·¸¹|}º»ᩞᧇDST¼½ᡠ¾¿⚪⌱B஺6ஹAூ⚪uv=௃A.À°Á᪗ᨵÃÄஹÅÆஹÇÄÈÉÊË᪗ᨵÃÄஹÅÆஹÇÄÈqᵨÌÉÊËÍÎÏ◤ÐÍ,ÑÀ°ÁÍÎᵨÐÍᦑASTB.NaClOCDᐹᨵᓄឋ,qÒÓpH§Ô|QÕTÖÊᐸCDḄpHØᦑB┯C.ᵨÙᴻÛᙠÝÞᘤ½ᤅáOâ)ãÞÔẚåÝÞᜫç2ᤅáᦑC┯D.eYÝè\ḄᨵéêëᐭìᑁᡈὅðñòìᒕôḄõDK᎔ᐭeYf÷ᵨḄᢣÊùᦈÀᘤ\2᎔ᐭû⍝â⌼ᡂnþÿᦑD┯ᫀ⌱A஺ூᫀ௃◤⌕᝞Ḅ!"#$%&┵(%◤஺7ஹBூᫀ*᪆௃A.,ᐭ.$NaOHᐭ/ᩖ12⏚4567ᵨ,9Ḅ:;◀ᩖᦑA┯B.=>ᓄ2@⛳&2⏚45Bᓄ47C2⏚45DEFᡂ=>ᓄ2HI7ᵨ@◀ᩖᦑBJKC.LMNḄỚ@PQỚRESᐜULMVWᡂLMᮞᦑC┯D.YZRỚ᧕ᓣ]^_ᜫEᵨ⃓bஹᑖḄ:

12;ᑖeᦑD┯ᦑ⌱B஺8ஹDூᑖ᪆௃NH3ᑖfCH+gᔠFᡂNFV
efᨔIjᵯ*1ᨔIlᵯmPᡈᰚpq᝱slᵯ᪀ᡂᨔIḄufᙠwxyz{ᕈ}ᕜឋḄᨵ᣸ᑡᨔIḄg᪀ᱯ7.X-D᧜ᩭNfḄᵯfᦪ-NfᵯfᦪNfgᔠḄfᦪxNfgᔠḄfQḄᓫᵯfᦪ¡஺2ூ⚪£*௃A.NH3ᑖfCH+gᔠFᡂNW+,DE¤¥NfḄᩖᓄ¦§ᙳ©sp3,ªᔠ⚪«¬ᦑAJKB.efᨔIjᵯ*1ᨔIlᵯmPᡈᰚpq᝱slᵯ®¯ᨔI°᝱ᵯᰚpq᝱lᵯ,7²ᐙᑖ´µSᨔIjefᨔIᦑBJKC.᪀ᡂᨔIḄufᙠwxyz{ᕈ}ᕜឋḄᨵ᣸ᑡᨔIḄg᪀ᱯ7.X-D᧜ᩭ஺®¶ᑖᨔI&·ᨔIḄᨬ7☠Ḅº»:;j°I¼½X-¾¿ᦑcJKD..ÀÁNfḄᵯfᦪSO
ஹ2X3=0ஹso*ú6-2x2û=],ᡠ=ὅḄᵯfᦪ322ÆÇᦑD┯ᫀ⌱D஺9ஹDூᫀ*᪆௃AஹÈZʬËᧇḄËWᨵᓄ»DEᦑAJKBஹ◌ᘤWᑴ.ÐNᨵ/Ḅấ⏚ÒFᡂÓ@ᓄ»ÔᓄᦑBJKCஹÕ;Ö×jᢣÙCÚ⏚×DEFᡂ×ᓫ1ᦑCJKDஹᡭÜÝÞᑴᢣᓭ┐áᦋÔᱥ1Ḅ᜜(åᨵ/ᱥ1FᡂÓ@ᱥᳮÔᓄᦑD┯஺ᦑ⌱D஺10ஹAூ⚪£*௃A.DE9çjèéᔾᦈḄl$&(ᡂᓄ»éᡠìḄl$Ḅ"íᑣ᪷ðélᦪð7ñSDEḄDE9AH=akJ/mol+3bkJ/mol-2x3ckJ/mol,ᑣòFᡂ2moiNH3,ì6c-a-3bkJ9$⌱⚗AJKB.PᑖfNᵯfᦪ=2+
6-2x1=4,PᑖfNôᨵ2õᵯfᡠ>föbsp3ᩖᓄ÷HNøᵯfõᦪ=3+
5-3x1=4ùôᨵ1õᵯfᡠNföᵨsp3ᩖᓄᩖᓄ:ÁÆú⌱⚗B┯C.ûᓄᑺa⊤☢j4Hÿ
ᡂᓄᑺa⊤☢᩽ឋḄᓄᑺb⊤☢᩽ឋᐳḄ⌱⚗C┯!"D.ᙠᓄᑺb$ᵨ&'ᓄ(ᑮḄ*+ᡂᱥH2ONO,NO-./0ᑖ230-V0ᑖ2⌱⚗D┯!"4ᫀ⌱A஺11ஹBூ⚪:;<௃A.2-ᵬ@ABC5DCE2ᑣ2-ᵬ@ABGHIJBᦑA┯!"B.ᵫMNᡂM⏣PP'ᓄ-ᓫRSTᡂ
ᦑBUV"

13C.C4H10ᨵCH3cH2cH2cH3ஹCH3cH(CH3)CH3*+Y᪀ᙳC2+H,C4H9clᨵ4+\ᑖI᪀]ᦑC┯!"D.^_`aRSbᑖ2ᓄᔠᱥdeᾦghᦑD┯!"ᦑ⌱B஺12ஹAூ4ᫀ<᪆௃“☘Ẇ”Ḅno-p“qᩭs⁐u3vwxyὅU᝞ᳱᴻ~⁐஺”“☘᪻”Ḅ⁐-s⁐ᡠ-FeSOr7H2O,“~⁐”~ᑖ<ᡂ⚩dឋḄFezCh,FeSO4-7HO2ᑖ<Ḅᓄhp2FeSO4-7H2O=^^=Fe2O3+SOt+SO3T+14HOO22A.᪷oᑖ᪆⁐]hFe2O3,ᦑAUV"B.“☘¡”hFeSO#7H2O,RS¢⏚¤ᑖ<ᡂḄhSO2S(h,gᑖ<ᡂCOCO2,ᦑB┯!"C.NH4AI(SO4)2T2H2Oh¥¡᪷oᑖ᪆☘¦hFeSOr7H2஺ᦑC┯!"D.FeSO47H2O§CᨵFe2+,ᙠ¨§©ªᓄ«`ᡠ¬®¯°■²ᓄ«`dgh■²³E«`ᦑD┯!"ᦑ4ᫀ⌱Ao13ஹCூ⚪:;<௃´⚪ᑖ᪆p1gµᐰ~ᡂ·᝱¹º»3¼143kJ,ᦑ2moi~ᡂ2moi·᝱¹º»3¼------½——xl43kJ=572kJ,18g¹¿«ᡂ·᝱¹»344kJḄ¼2moi·᝱¹«-᝱¹ᔾᦈḄ¼-1g2molx]8g/mol---------2——x44kJ=88kJ,ᦑ2moi~ᡂ2moi᝱¹º»3¼-572kJ-88k,I=484kJ,ᦑᓄ18g-2H2(g)+O2(g)=2HO(g)AH=-484kJ/mol,ᡠ2x436kJ/mol+496kJ/mol-4xkJ/moI=-484kJ/moL<(x=463,2ᦑ⌱C஺14ஹCூ⚪:;<௃A.-ÂᢝÄÅuÆÄÅÇTᑺᢥÉÊ▲¼Ìᵨ᝞ÍÎϧTÐÑ⏚ÒÓ■ῖᑺA⚗┯!"B.PÕÖRS×ØᩞᧇgRSᨵØbᑖ2ᩞᧇB⚗┯!"C.FezCh-ÛÜ⁐ÝHÞÛßÛ⁐eàáᧇC⚗UV"D.ãᓄä-ᐳᓄᔠᱥᐸᙠᰚçè᝱&géᵯᵯ<ᰚçᓄäëìALdíîïᵨᵯ

14ᵯ<öp〉ᵨSKஹCaஹNaஹMgஹAl
³Eöp〉ᵨSZn^FeஹSnஹPbஹCu
ᑖ<öp〉ᵨSHgஹAgo15ஹAூ⚪:;<௃A.C3H8×\ᑖI᪀]øᵨᩭ⊤ùúBᦑAUV"••B.Q1hMBGhMấBᦑB┯!"C.üãMBýᙠ1,1üãMB1,2üãMB*+Y᪀ᦑC┯!"D.Is22s22P6ᵨᩭ⊤ùᮞE2ᡈஹ╅ஹᦑD┯ᦑ⌱Ao16ஹCூ⚪௃A⚗ஹ0V᪀ᨵ᩽ឋᵯ₹Ḅ$%&$ᔠ᩽ឋᑖᦑA┯B⚗ஹNH3)*┵᪀ᨵ᩽ឋᵯ₹Ḅ$%&$ᔠ᩽ឋᑖᦑB┯C⚗ஹCH4,☢.᪀ᨵ᩽ឋᵯ₹Ḅ$%$ᔠ/᩽ឋᑖᦑC0D⚗ஹHC112᪀ᨵ᩽ឋᵯ₹Ḅ$%&$ᔠ᩽ឋᑖᦑD┯ᦑ⌱C஺ூ4ᫀ67௃89ᐗ;<=ᡂ/᩽ឋᐳ@&8ᐗ;<=ᡂ᩽ឋᐳ@ᑖAᵯ₹A%&$ᔠB᦮DᑖᩭFᵯ₹ḄᑖGH&ᙳᒴḄ&KLḄM᪵Ḅᑖ᩽ឋᑖO᩽ឋᔠḄPQRS᩽ឋᑖO᩽ឋᔠḄTQᑖ᝞᪀KLᵯ₹Ḅ$%$ᔠᵯ₹ᑖGᙳᒴᑣ/᩽ឋᑖ஺17ஹAூ⚪௃A.P2O5WXYZ[ᡂ\⏚\⏚^W_`a[YZᡠO&cᑭᵨfᨵP2O5Ḅghi◀kNH3AḄXl`ᦑA┯B.m⏚HRDnoḄᨵpqᑺs☘uvwᙠmyA☘u;^qzmyqᑺA☘u;Ḅᑖ᪀Aᨵ{|{}~ᑖm⏚Ḅnoᢵaឋ6◀kmy☘u;&zᑖᦑᡃᕚᕚᑭᵨm⏚s☘uAḄ☘u;⃓ᩭᦑB0C.ᙠXqAX[ᡂ|ᓄ.|ᓄ.ᐹᨵᜧḄ⊤☢ᨵᔾ▬ឋᦑc¡¢ᑺᦑC0D.ᙠỚḄ,¤ᓄ¥qA¦ᐭ|ᓄqỚᓫ©W|ᓄa[YZ3L+6NaOH=5Nal+NaIO3+3HO,[ᡂ᧕qzXḄỚᓄỚ⏚«₩ஹ☟®ஹᑖ¯ᑮỚᓄỚ⏚Ḅ±ᔠq2

15
⏚⏚ᓄỚᓄỚ⏚ᙠ⏚ឋ᛻5Nal+NaI(h+3H2so4=3Na2so4+3L+3H2O,ᡂỚḄᑮỚᦑᵨ⃓"#$Ớᓫ&'ỚḄ()ᓄ*+,-".ᩭᦑD012ᦑ⌱A஺18ஹCூ⚪:;<௃A.>?┞ABC᯼EFᑣᵨH∑JK>?┞ᦑA┯M2B.⏚N᧕PQRᡂ⏚NᨔᑣTUḄ⏚NVWXḄY#XZᦑB┯M2C.ᰚ\NaOH]P^ᴻ,ḄSiO2ᑣ`ᵨaᵨb
cᰚ\NaOHᦑC012D.FeCb+def+ᵨpHghiFeCh+ḄpHjklmpHḄn⁐pᓄq]r1᪷tghḄp⁐u.+ḄpH,ᦑD┯M2ᦑvᫀxCo19ஹBூ⚪:;<௃A.ᱥ&Ḅ{Pc{ᡂ0C5mink|ᑮ}⊝ic166.6kJ,ᑣ
Ḅx196kJ?nolI=0.85mol,0
5minᑁᵨCh⊤Ḅ}ᙳ᳛u(O2)=——=—'—=0.017mol-L'-min1,ᦑA012WLx5minB.2moiSO2ImolChᐙᐭ10LឤAᘤ,|ᑮ}⊝kὑx().85mol,.c{x166.6kJ,ᩩqp,ᔣᘤ,ᐙᐭ4moiSO22moi02,ᱥ&Ḅ{xᩭḄ2ᜧ}⊝0ᔣ¡|ᑮ}⊝kὑᜧ¢0.85molx2=1.7mol,ᑣ}⊝kcᜧ¢166.6kJx2=333.2kJ,ᦑB┯M2C.£ᜧChḄ¤B}⊝0ᔣ¡ᑣSO2Ḅ¥ᓄ᳛ᜧᦑC012D.|ᑮ}⊝¦᝱ᔜ©ᑖ¤Bqp0⌮᳛¬Ḅjqpk,®ᔜᱥ&Ḅᱥ&Ḅ{qpᑣn(SOj|ᑮ}⊝ᦑD012ᦑ⌱B஺20ஹCூ⚪:;<௃A.±ឋ:Fe2+>Br-ᡠ`ᔣFeB஺+,µᐭ¶{CL,·a¸¹ºᓄ,¸¹Y»¼x½2Fe2++Cl=2Fe3++22Cl-,ᦑA┯M2B.¾ᓄ¿+¢À+2ᔣNH4AKSO62+,
ᐭ{NaOH+Ḅ¸¹Y»¼x½Al3++NHZ+5OH=A1O+2H2O+NH3*H2O,⌱⚗B┯M22C.ᵨ¾ᓄ+ᔾᦈÄÅÆ,ḄNO2,Ḅ¸¹Y»¼x½2NO2+2OH-=NO3-+NO2-+H2O,⌱⚗C012D.ᵨÇឋᵯ᩽ᵯÊ3H2T+2A1(OH)3],⌱⚗D┯M;ᦑvᫀ⌱CoூvᫀÌÍ௃

16ᵨ³ឋᵯ᩽ᵯNaClqYZ´µ¶2Cr+2H2஺·ᵯCLT+H2T+2OH,|ᓄ¸z¹qºᨵ»¼ᵨ³ឋᵯ᩽ᵯMgCLqYZ´µ¶Mg2++2Cr+2HOjlS'UC12T+Ht+Mg(OH)1,222|ᓄ╅&qzXḄ»¼ᵨ³ឋᵯ᩽ᵯA1CLqYZḄ´µ¶2AF++6CT+6H20½23CLT+3H2T+2A1(OHR,|ᓄ&qzXḄ»¼ᡠOᙠ¾⚪¿RS⌕Á%Â⚪ÃÄ┯஺21ஹCூ4ᫀ᪆௃ÆqXᕈÈ⁐ÊËcÌᨵBa2+ஹNa\NH\H\Cl.SO2\S(V-Î9AḄÏ9(&ὃ⇋X43Ḅᵯ)᪷ÕᐳÖ,Ba?+WSO3*ஹSOÙ?”&Ì8¿Öᙠ,H+WSO3?•&Ì8¿Öᙠ஺ᔣÝqAÞ¦ßàáᑴ¤X,ᡠ¯qãÈ⁐ä¤XAḄ¤`a[åYZäXARSᨵSO3%ᑣ&ÖᙠBa?+H+
qAᔜçèᙳO.lmol/L,åéêᵯ₹ëឤíîᨵNa+ஹNH4+,ᵫzºᨵᐸñ□ÖᙠᑣRSºᨵCóSCh*஺A.᪷Õôõᑖ᪆qAöS&CLᦑA0B.᪷Õôõᑖ᪆öS&H+,ᦑB0C.᪷Õôõᑖ᪆öSNIV,ᦑC┯D.᪷Õôõᑖ᪆öSᨵSCVஹᦑD0ᦑ⌱C஺22ஹCூ4ᫀ᪆௃Aஹ`Ḅ÷ø}HImol`ùᐰ÷ø[ᡂ᝱XᡠüḄ}àᦑA┯Bஹ᪷ÕC(ýþs)=C(ÿ
s)AH>0,ᑣ
Ḅ
ḄᱥᐹᨵḄᡠ
᝞
ᦑB┯Cஹ⏚!ᭆ#$%⏚%&'()*+ᡂImol-./Ḅ!01ᑖ᪆420.0gNaOHḄ&'(5&6⏚7ᐰ./28.7kJḄ!40g9:ᓄ<7ᐰ)*.!57.4kJ,ᑣ=)*Ḅ!ᓄ>?@ABCNaOH(aq)+HC1(aq)=NaCl(aq)+H2O(1)AH=-57.4kJ/mol,ᦑCEFDஹᱥC7ᐰGH./ḄIJ$)*$.!ḄKL$MᨵNOḄᡠAHJAH2,ᦑD┯Pᫀ⌱C஺TஹU⌱V⚪(ᐳ84ᑖ)23ஹ2-ᵬ]-1-^_`aabcd]:ᓄ)*dᓄ)*/^S-CII-CH-CIIO+2Cu(OH)2+NaOH,f/-\y-CH—CH—COONa+CgU2OI+3…H2cO/rLV-JC;H-CH-COOCH,—CH—€H>CHaCH-ClCH-CH>CH-€H,ஹ(jᑏlm)COOH446'COOH'6-COOH'஺COOHqH4.CH,CH,OHCu/O»1NaOH.U(DH.O./OH*kJ-Z-*CH,CHOCHCH-CHCHOt

17ூPᫀo᪆௃᪷ᨵrᱥstḄu᪀ឋஹ)*ᩩyஹᨵrᱥᑖzA{ᓄᐵ}~ᑭᵨEᡈ⌮⌲lᑖ᪆ᑨ/mᨵrᱥḄu᪀Aᨬuᔠ⚪oP஺QHio5^ᐝ᯿ᑮmᨵrᱥAB,ABᙳ+)*+ᡂC,ᑣA$`C$2lᵬ]_¡᪷জ£C{ᓄBD,ᑣDḄu᪀AB(ClUCHCHzOH஺FᑖzḄa¤¥¦ᨵ§¤EB¨✏ªᓄᔠᱥ«EஹN¬+®)*¯°ᙳ4ᨵ±]஺᪷ᑖzAঝ£E$³ᵬ±N$´±FḄu᪀AB11=(11l(H(>,GḄu᪀ABOLCH=CHCOOH,DG+dᓄ)*+ᡂM,ᑣMḄu᪀ABM0(1)AஹBᙳBl^µHᐸ·¸B2-ᵬ]-1-^_`ᡈ2-ᵬ]-2-^_`᪷MḄu᪀A£Ḅst·¸Baabcd](2)᪷¥ᑖ᪆£F-G$±]Ḅ:ᓄ)*D+G-M$dᓄ)*(3)F4ᨵ±]5¹ᑴCu(OH)/NaOH(aq))*Ḅᓄ>?@AB21=(11-(11()+2(CII(()11),+\,1()11—¼஺100½+(C1()1+31(0(4)᪷¥ᑖ᪆£MḄu᪀EḄu᪀ABQ-CHO,¿À᪶ÂᐳÃ9Äᨵ4mÅÆ(5)GḄsABt$aabc±]ᑣ5GᐹᨵÇÈstḄGḄ¨✏ÉÈᑖ᪀ʳ˥£4ᨵlÌ͵]ᑣ*=$lC(CH0)=CH,᝞Î4ᨵÌ͵]*=$±]´¡]ᨵÏÐÑÒmᐳ0ᨵ4mᐸu᪀AB2;(6)᪷জÓ᪾~C{ᓄBDḄ£ÕÖ~BÏÐO'"*"CHUCHO—1^CrÑ()||CH-CH.BrÒCH-CFLOH24ஹ×ᡂ)*)*II+2NaOHᐁÔII+2NaBrঞØÙAᑖzC=CCH—CHBr
cCH—CH0H22Ú:ᓄHOOCCH2CHCICOOHCH=C(COOH)22ூᑖ᪆௃1,3-T¡5Û+1,4-×ᡂ)*+ᡂ1,4-TÜ-2-¡Ý+ᓴµHḄ-o)*+ᡂAB

18HOCHCH=CHCH2OH
´¡5ß+×ᡂ)*+ᡂEBBrCH2cH2Br,E+ᓴµᓻḄ-o)*+ᡂFB2HOCH2CH2OH,uᔠ)*ত+ᡂḄâãᱥHḄu᪀£GBHOOCCH=CHCOOH,=)*Bäã)*åUDBNaOOCCH=CHCOONa,A}ᑡ{ᓄᑮG,)*ঞஹটᨵl)*$5HC1×ᡂ*$ØÙaabc■êÚ:ᓄᑣ)*ঞBA5HC1+Ḅ×ᡂ)*ᑣBBHOCH2cH2cHeICH2OH,B+:ᓄ)*+ᡂCBHOOCCH2CHCICOOH,C+ᓴµGḄ)*ஹ)*ᑮD,D⏚ᓄ+ᡂG஺ூ⚪ëìo௃(1)ᵫ¥îᑖ᪆£)*জï×ᡂ)*)*ঠï)*CH-CKBrCH-CKOHu(2))*ঝBᓴµGḄ-o?@AB||+2NaOHÕÌÔ||+2NaBr
CH-CHBr
cCH-CH0H22(3)HOCH2cH=CHCH20H}ᑡ{ᓄᑮHOOCCH=CHCOOH,ò@◤⌕Ú:ᓄõaabcö÷᧕Ú:ᓄᡠ)*ঞஹটᨵl)*$5HC1×ᡂ*$ØÙaabc■êÚ:ᓄᡠ⌕ᐜ×ᡂÝ:ᓄᓽ)*ঞBA5HC1+Ḅûüᡂ)*å!|BBHOCH2cH2cHeICH2OH,B+:ᓄ)*+ᡂCBHOOCCH2cHe1COOH
(4)GBHOOCCH=CHCOOH,5GᐹᨵÇÈmÉᦪëḄstḄÈᑖ᪀ÊBCCH=C(COOH)2;2(5)ᵬ³Ḅᵬ]£ᙠᐝ᯿ᩩᓴᰦᓴḄᑮ⏣⏣ᓄᓄᑮ,ூᫀ!"௃$%᪷'ᨵ)ᱥḄ+᪀ᩩ-.ஹ⌮123+ᔠḄ5216஺25ஹটঞজঝ=>?⁐AᔠBCDᨵEᓄFGH?⁐IEᓄFᔾᦈLᐰAᔠBCNOEᓄFOHF⏚QHRBSTUᮞHCO2ூᑖ᪆௃(1)YZ[ᱥ◤]^_ὃ⇋ᐜcde(2)EᓄFfg=>?⁐hfᔾᦈEᓄFe(3)]^HRBiᵨOHF⏚Qஹ]^EᓄkiᵨSTUᮞH஺ூ⚪mno௃(1)]^EᓄFᵨ=>pq]^EᓄkᵨSTḄUᮞH]^HRBᵨOHF⏚QrpqDᨵH,ᡠtᐜ]^HRBᯠ]^EᓄFvᙠ]^Eᓄkxᵨy◀{|}~=>pq?⁐SO2N◀ᡠtcdটঞজঝe(2)^ḄজDAḄ=>pqAᔠBC}~A_=>?⁐[ᱥDᨵEᓄFeyHfEᓄFᡠtEᓄFfGHᔾᦈAᔠBC|}~=>_?⁐=>Nᐰᔾᦈe(3)ঞḄᵨ]^HRBḄᙠOHF⏚QC⁐OHF⏚Qᡂ⁐ᨔCᨵHRBᙠঝḄᵨ]^EᓄkḄᙠSTUᮞHSTUᮞHᨵEᓄkᙠ஺

1926ஹBஹD(ᡈC)ஹEஹFஹG+ᵫÚ⁐ាÜpxÝ⁐Þßᑖàᑁn⁐Ýpᓄ0.09800moI/Láᜧáᜧூvᫀ<᪆௃(1)᪷tãᑴåæᱥ&Ḅ{¤BḄ+Ḅãᑴçè⌱éêᘤ2(2)᪷t01ḄëæìíîïY#ᑨñëæòÌḄóô2(3)᪷tY»¼õëæᦪt÷øùú2(4)(5)᪷t⏚À,ëækḄMûᑖ᪆஺ூ⚪:;<௃(1)ãᑴåæᱥ&Ḅ{¤BḄü⏚kçèᨵùúஹ{"ஹþÿஹ
ஹஹஹ᤯ᒴ◤⌕ᘤᨵஹ(ᡈὅ⏚)ஹஹᜮ!"ᴻ$ᓽBஹD(ᡈC)ஹEஹFஹG,ᦑ'ᫀ)BஹD(ᡈC)ஹEஹFஹG»(2)+2-3,-.ᐭ0123ḄBa(OH)25656)7⁐ᵨ0.1000mol/LḄ᪗;<⏚=>56ᵫ7⁐ាAB)C⁐DEᑖGᑁI⁐CBᓄᦑ'ᫀ)56ᵫ7⁐ាAB)C⁐DEᑖGᑁI⁐CBᓄ஺(3)᪷MNOPQBa(OH)2+2HCl=BaCl2+2HO,ᑣc[Ba(OH)]x10.0()mL=22l/2x0.1mol/Lx19.60mL,STc[Ba(OH)]=0.09800mol/L,2ᦑ'ᫀ)0.09800mol/L
(4)UVWXYᵨḄ⏚0Zᜐᳮᓽ]ᐭU^_᪗;<⏚`aU^W<⏚23bᜧdὑḄ᪗;6<⏚fgbhijkḄlmᓄ⚞ᱥpḄbhᑣq^mᓄrNOḄlmᓄ⚞ᱥpḄbᜧijstbᜧᦑ'ᫀ)bᜧ஺(5)ᵫu⏚vᨵw`aUVW<⏚23bhdὑḄ᪗;6<⏚fgbᜧijkḄlmᓄ⚞ᱥpḄbᜧᑣq^mᓄrNOḄlmᓄxᱥpḄbᜧijstbᜧᦑ'ᫀ)bᜧ஺ூ'ᫀz{௃⏚}~ᑖ᪆জb⏚vwᓽ⏚┵ᵨ6wX⏚6k⏚ᑁᨵdᜫᘂᜐᨵ6ᦪᦪzᑨ6X+ᘂ6ᔿᐭᑁঝb¢6ᓽ}6X}6k⏚Cᨵᦪᦪzᑨ£X}6k┵ᑁ¤¥¦v§஺27ஹ¨⊝6ªᧅqᑁ¬®u¯°⏚56±§4NO+O+2CO^=4NO+2CO᣸³᦮µ¶~Ḅ·222■¹º»ḄNO¼mᓄ»ᡂNthEDBD~¾ᐭmfᵫC⁐B)7¿⁐Àᓾ^mᓄÂᵨᩭÄÅNO2NaNO+HSO=NaSO+NOT+NOT+HOÆỚᓄÈ56É.¯Ê⏚⏚ᓄ.2242422ËÌ56CÍÎÏÐ.ÑÒNaNCh5656BÓÔÍNaNO?ᐹᨵmᓄឋᡈὅÆÊ⏚×x56É.¯Ê⏚⏚ᓄ.ØKSCN5656Ù)ÚÛ⁐.ÑÒNaNCh56ÜX56ᵫÚÛ⁐B)⊈7⁐ÔÍNaNO2

20ᐹᨵᓄឋூᑖ᪆௃L⏚¡Ḅᑴᜓ¤᪷'^¥¦§^DᵨQ¨⏚ᡂNO,ᵨH◀©ªᢵ¬ᩭḄ⏚ᙠk⏚¡pqDBᡂ⏚¡^DḄ®BᵨDᔾᦈeII.¯°⏚¡F⏚BC[ᱥᡂᑖ¤xᡭ²³´ᜳᐜ}ᐭ·¸_¹ºB¦᣸◀ᑁḄ½BADᡂNO,ᯠᵨC¾E¿ᓾEᓄºD]^NO,ᨬÂÃB,■ÅÆǽBeIII.ÈÉ^Ê⏚ឋᩩNaNChᐹᨵᓄឋᵨËÌஹKIpq]^ᡈ¦ᙠ⏚ឋᩩᓄÎÏᵨKSCNpq]^஺ூ⚪mno௃1.(1)ឤÑÒqÓᧅ¦tÕ⊝ᑁ᜜ÑØ3ÙrÚ3ÛÜ}ᑖqÓᧅÝ℉Ḅß!Õ⊝ÒqÓᧅàᑁÑØáâ¨⏚pqãᦑᫀ¤Õ⊝ÒqÓᧅàᑁÑØáâ¨⏚pqãe(2)DDSTUᮞHᨵEᓄkᡂᱥNOஹBk⏚¡ᑣCDᑴᜓNaN(hḄÏ5æç4NO+O2+2CO3=4N0
+2CO2,ᦑᫀ¤4NO+O+2C0
=4N0
+2CO2
2n.(3)NOèé᧕BᓄDᨵ½BO2]^ᨵNOᡂᡠt}ºBḄmḄ᣸{᦮ìDḄ½B■Å[ḄNOᓄᡂNO2,ᦑᫀ¤᣸{᦮ìDḄ½B■Å[ḄNOᓄᡂNO2
(4)CᔾᦈHRBB®Bᜐᳮ■ÅÆǽBD]^NO,E¿ᓾEᓄºᵨᩭ]^NO,ᡠtḄÂÃATC—E—D—B,ᦑᫀ¤E
D
B
(5)জDDO⁐BCᡂ>⁐ïᨵNOBCrÚAD[ḄBCïᨵNOᡠð'ḄñòDD}ᐭBBCᵫO⁐>ô⁐ᦑᫀ¤DD}ᐭBBCᵫO⁐>ô⁐eঝ᪷'tõᑖ᪆¦§EḄᵨ¿ᓾEᓄºᵨᩭ]^NO,ᦑᫀ¤¿ᓾEᓄºᵨᩭ]^NO
ঞ}~õö^¯°~榬AD⏚¡F⏚ᡂ·ᓄºBCEᓄºBCᓄ÷5æç¤2NaNO2+H2SO_=Na2SO4+NOT+NO2T+H2O,ᦑᫀ¤2NaNO?+H2sC\=Na2sO&+NOT+NO?T+H?஺
)ni.(6)ᑭᵨ⏚¡ᓄỚᓄúᡂᓫüỚỚ⍗ËÌÝ⁐ᑣ^5ᫀ¤ỚᓄúpqþÒÿ
⏚⏚ᓄNaNChNaNChᐹᨵᓄឋᡈὅ
⏚
⏚⏚ᓄKSCN!"#$⁐NaNfh&'ᵫ#$⁐"⊈*⁐NaNO2ᐹᨵᓄឋᦑ,ᫀ".Ớᓄ0
⏚⏚ᓄNaNChNaNChᐹᨵᓄឋᡈὅ
⏚
⏚⏚ᓄKSCN!"#$⁐NaNCh&'ᵫ#$⁐"⊈*⁐NaNChᐹᨵᓄឋ஺28ஹᓄឋK2s042cl2+2H2O(g)+C=4HC1+CO2CIO2+2r=2Cl(h-+I2C1O+41+4H+=C1+22H2+2H2O0.675ூ⚪678௃(1)ᙠ;<=>?Fe2\Mi?+ḄᓄᔠCᓣEᑣCIChḄᓄᔠCGH"ᓄᑺᐹᨵᓄឋᦑ,

21ᫀ"ᓄឋ(2)JKLឤNO.2KCKh+SO2=2ClO2+K2sOsᦑ,ᫀ"K2so4(3)PCLQH2O(g)R=STḄUVWᡂHC1QCChYZT[\ᓄ]^>_"2cl2+2H2O(g)+C=4HC1+CO2,ᦑ,ᫀ"2cl2+2`0(g)+C=4HC1+CO2;(4)জᵨcᓄdef?ឋᵫgh&ᩩjklmno"C1O,C1O2pᐭḄỚᓄ0ᓄ"rstuvw2ᡂC1O2-,xm^>_".ᡂ102+21=2CKh-+"ᦑ,ᫀ"2ao2+21-=2C1OU+L;ঝᵫgz⊤pHf1
3'C1O2-prᓄᡂL,xm^>_".C1O2+41+4H+=Cl+2I+2HOᦑ,ᫀ"஺஺2}22+41+4H+=C1+2L+2H2O;ঞS2O32•
r
cio2111l.OxlO'3mol/Lx0.01L1.0xl0smolm(CIO2)=n(CIO2)xM(CIO2)=1.0xl0-5molx67.5xl03mg»mol-,=0.675mg,ᵫ~᪵"IL,ᡠC1OḄ"20.675g.ᵪ4AL------------=0.675mgL“ᦑ,ᫀ"0.675«IL29ஹ2a+2b+c0.021BC1050K[\ᑮ⊝᝱ḼᓣE[\᳛NOᓄ᳛ᜧ20%44OH-4e=2HO+O2T▢᩽ᵯ8WᡂcQc᪷xmOFTHCCH-[\WᡂCCh32ூᑖ᪆௃(1)ᑭᵨ£¤¥¦§¨஺(2)জ᪷©ª_§¨Chᙳ[\᳛¬ᓣE⊝ᔣᔾT[\¯°ᓽ⌮ᔣ¯°ঝA.ᐭ}¥KḄ³⏚┛,⊝¶¯°¶B.Rᐭ}¥KḄ02,⊝·ᔣ¯°¸ᓄ³¹ºwᩭC〉¬½¾ᘤḄÀÁÂὅÃᙠwᩭÄẠÆ⊝ᔣÀÁ^ᔣᓽ·ᔣ¯°D.ᐭᔠ〉ḄÇᓄᑺ⊝¶¯°¶஺(3)1050K[\¶ÈḄ·ᔣÉÊ⊝Ë&NOḄᓄ᳛ᓣEÌᜧÉÊÍÎ_ÏЧ¨஺(4)ÉÊÍÎ_§¨ÑÒ⊝Óᦪ஺(5)জᙠ□᩽Ö
᪷ᜫØᵯmÙWḄ[\ᒹÛ4Oir-4e-=2H2O+O2Tᒕ
mQ³⏚
᪷[\ঝ▢᩽ᵯ8WᡂcᒕÝc᪷xmᒕÝḄOH-Hah-[\WᡂCCVூ⚪678௃(1)᪷©6᪗[\pß}<^>_2à߸<^>_2àáßÍ<^>_Oᑮ.[\2s(h(g)+4NH3-H2O(aq)4-O(g)=2(NH4)2SO(aq)+2H2O(l)ḄAH=(2a+2b+c)kJ-moH24ফজ0
lOminᑁChᙳ[\᳛1)(0,)=ᒹ=0—S79)mol•L=஺02Imol•□•min,¬ᓣE⊝2At10minᔣᔾT[\¯°ᓽ⌮ᔣ¯°Ë&ä[\Ḅ⊝ÓᦪKᦑ,ᫀ".().021஺ঝA.ᐭ}¥KḄ³⏚┛⊝¶¯°¶ᦑA¶åᔠ⚪æB.Rᐭ}¥KḄ02,⊝·ᔣ¯°¸ᓄ³¹ºwᩭᦑBåᔠ⚪æC.〉¬½¾ᘤḄÀÁÂὅÃᙠwᩭÄẠÆ

22⊝ᔣÀÁ^ᔣᓽ·ᔣ¯°ᦑCåᔠ⚪æD.ᐭᔠ〉ḄÇᓄᑺ⊝¶¯°¶ᦑD¶åᔠ⚪æ;èÆᡠé,ᫀ"BC஺(3)ᵫgNh1050K[\¶ÈḄ·ᔣÉÊ⊝Ë&NOḄᓄ᳛ᓣEÌᜧᐸwË"1050K[\ᑮ⊝᝱ḼᓣE[\᳛NOᓄ᳛ᜧëìí'NOᨵImol,ᙠHOOK'ᓄ᳛"40%,C(s)+2NO(g)N(g)+CO(g)2ìí.2mol00ᓄ.0.8mol0.4mol0.4mol⊝.L2mol0.4inol0.4iiiolCO2ḄÀÁᑖᦪ3=-------?ð஺------x100%=20%ᦑ,ᫀ".1050K[\ᑮ⊝᝱Ḽ1.2mol+0.4mol+0.4molᓣE[\᳛NOᓄ᳛ᜧ20%஺(4)ëìí'NOᨵImol,ᙠ1050K',ᓄ᳛"80%C(s)+2NO(g)ஹ—N2(g)+CO2(g)ìí.2mol00ᓄ.1.6mol0.8mol0.8111O1⊝.0.4niol0.8mol0.8111O1nQn0l.lxlO6Pax—xl.lxlO6Pax—ä[\Ḅᓄ]⊝ÓᦪK,,=------------2---------------2-=4ᦑ,ᫀ".4஺pax")?2মজᙠ□᩽ÖYc᪷ᜫØᵯmÙWḄ[\ᒹÛ4OBT—4e-=2H2O+(MQH++HCO=CO2T+H2Oᦑ,ᫀ":4OH3_—4e-=2H2O+O2foঝ▢᩽ᵯ8WᡂcᒕÝc᪷xmᒕÝḄOIFHCO3-[\WᡂCO32-,Ë&▢᩽ÖáWCO32-;ᦑ,ᫀ":▢᩽ᵯ8WᡂcQc᪷xmOIFHCO3-[\WᡂCO2-«3