华东理工高化题库

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ஹ⚪1.ᑖᓄᔠᱥᑖᓄᔠᱥᨵᱯᑖᓄᔠᱥᑖᓄᔠᱥᨵ⌕ᱯ(1)ᑖᓄᔠᱥᑖᜧᑖ""ᵫ$%&Ḅ(ᓫḄ*᪀ᓫᐗ-.ᐳ0123456ᡂ;(2)ᓽ:;
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66nHN
CHNH+nHOOC¾CHÉ4COOH^-^^fNH
CHÉNHOC
CHCQ^H+
2n-1HO2262226242Ö▭~ᾮÃS;Ùᐸ@ᓫgᐳGḄÚᱥ¬4┝Gᔠ஺
3ᔠᡂ´µ⌕§<ᨵÛº´µÜÛ´µE஺Ûº´µHC=CHCH=CH+HC=CHCH------»^CH2cH=CHCH2cH2cHe6H5…222654┝GᔠÜÛ´µnCH2=CHCH=CH24┝GᔠA«H2cH=CHC¥±o6.ᔲᵨßàḄáâ>ᑖᓄᔠᱥ?z¢£D஺ᵫᑖᓄᔠᱥᑖãÒᵨä""å.ᑖ`ᑁḄ1ᔠäᡠçᓣéᑮëᓄçìíÔî`Ḅïðᡈᑖñ6ẚóôᑖᓄᔠᱥḄᓄB*᪀õDᵨö÷Ḅáᩭâ>ᑖᓄᔠᱥ஺7.¢£øùᛛឋ?¢£øùúឋûüýþÿ஺
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ᔠᱥᑖZᐰ[Iᡈ\ᜧ[ᑖN^_K᪀⁚
1-᪀ᡈd-᪀NὶaᡂḄᔠᱥbc*HIᡈbᐰKL᪀Nᔠᱥ஺ᔠᱥᑖZᵫd-᪀P1-᪀⁚,eὶaᡂḄᔠᱥbOHᡈbOKL᪀ᔠᱥ஺ᔠᱥᑖZᵫd-᪀P1-᪀⁚QHᑣᙢὶaᡂḄᔠᱥbQHᔠᱥ஺h'"cU

2CH3CHCH3QH33,AAA/*CH2—C-CH2-C—C&—c—CHjfiww*H'"HHHHHH—.c——CKH'"CH3HHF——J—c——QH'"CH3CH39.rsᔠᱥḄtᑡa᪀Rᑏw$!"2Ḅtᑡa᪀஺
ᔠᱥtᑡa᪀ᢣᔠᱥᜧᑖZa᪀ᓫᐗḄz{|}஺$!"2Ḅtᑡa~ᨵ3cH2—CH—CH2—CH…ᜮz{ClC1MVCH?—CH—CH—CH2,/VWVᜮᜮz{ClC1■AA^CH—CH—CH—CH…z{22ClC110.ᑖZa᪀ᨵRḄᱥᳮஹᓄឋᨵEFᱯR
ᑖZḄ⌕ᨵஹP0ᐸ.ᨵஹஹ*IcᡈḄᱯUN஺PᑖZ☠ᙠ0ᑖZO¡஺¢£ᱥᳮ⊤¥c¦§¨ஹ©§ª0ᡂḄᔠᱥᐹᨵᛛឋ0ᰚᓄ0ᙠ«ᑺ«
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஺11.rsᑖZÎḄÏᑖᦣឋ?᝞r⊤ÒᔠᱥᑖZÎḄÏᑖᦣឋ?Sᑖ᪆ᔠᱥᑖZÎÏᑖᦣឋ¯ᙠḄÔÕ஺
ᔠᱥᑖZÎ1*ḄKÖᱥḄ×ᔠᱥ0ᐸᑖZÎᡈᔠ§ØᙳÙ஺ÚᑖZÎḄ1ᙳឋbcᑖZÎḄÏᑖᦣឋ஺ᑖZÎÏᑖᦣឋhᵨ3ᙳᑖZÎPᦪᙳᑖZÎḄ¹Ùᩭ⊤Ò஺ÚH]Þ¹ÙbcÏᑖᦣᢣᦪ0ᐸßàcHI,ᓽâjᑖZÎᙳḄᔠᱥᐸHIc1஺HIãᜧᑣᔠᱥᑖZÎḄÏᑖᦣȧãᜧ஺ᑖZÎÏᑖᦣឋºäᑗḄ⊤Ò|æᵨᑖZÎᑖçè⊤Ò஺hᑖZÎcéᙶ᪗0hᡠìᔜᑖZḄ3ÎᡈᦪÎíᑖᦪcîᙶ᪗0ᓽïᑖZÎḄ3ÎᡈᦪÎᑖçè஺ᑖZÎᑖçḄðñò{¾¿ᔠᱥḄóPᱥᳮឋ2஺ᔠᱥᑖZÎÏᑖᦣឋ;ôḄÔÕ⌕^

3ᔠᱥᡂõÈḄö÷ᱯឋᡠøù஺12.ᔠᱥḄØᙳᑖZÎᨵ⊤Ò|æ0ᑏwᐸᦪ⊤ü}஺
I1NᦪᙳᑖZΗZNiMi^WiMn=--------=----------=ENiMiENiXWi/MiI2N3ᙳᑖZÎýþýÿJEᔊ
XWiXNiMiN,W,ᑖ⊤iḄᑖᦪஹᑖ஺XW,EMiᑖ⊤ᑖḄᡠᨵᑖ"i#1ᑮ&'()jy,w,ᑖ⊤iḄᑖᑖ᳛ᑖ᳛஺.301ᙳᑖ(ZNiM
Mr=3ZNiMi)a56ᑖ789ᱯឋ1<-ᑖᐵḄᦪ?@A0.5-0.9஺13.ᦪᙳᑖM“ᙳᑖMḄᱥᳮJK5LM?OPQRM.-M„STᦪᙳᑖḄᱥᳮJK5ᔜVWᑖḄᑖᡠᓰḄᑖᦪYᐸ[\Ḅᑖ]^Ḅ)஺ᙳᑖḄᱥᳮJK5ᔜVWᑖḄᑖᡠᓰḄᑖᦪYᐸ[\Ḅᑖ]^Ḅ)஺_஻AiḄᑖᑣ—᪗jR/OᓽEM
ἌME஺hᓽiji“?k஻•mn°ᦑqMrm“sM^M'qMtᔊ"sM>M,rnw14.ᔠ<ᑖxyᨵLMᐵz{|Wᔠ}}\~Ḅᔠᱥ\JLMzOQ஺ST_”“AᔠᱥḄᑖ"oAᓫᐗḄᑖAᔠ<.ᓫᐗᦪ⊤Ḅ0ᑣ“="஺஺“Aᔠ<.᪀ᓫᐗᦪ⊤Ḅ0A/஺A᪀ᓫᐗḄᑖᑣ

4M,=M.X^{|s\JT(1)ᓫᐗ⊤Ḅᔠ<ᵨ#┝ᔠᱥᐸᓫᐗ5᪀ᓫᐗx஺᝞ᐳᱥᨵ᪀ᓫᐗ—CHCH—CHCH—2|||CCC6H5஻'¤Oc0Mi=98%=10஺Mo=98+104=202M.=M஺=(Mi+M(2)᪀ᓫᐗᦪ᪗⊤Ḅ©ᙳᔠ<“ᵨ#ªᱥ«ªᱥ“=2ᐸ᪀ᓫᐗḄ©ᙳᑖ?஺=”|"2,᝞¬NH(CH)6NHOC(CH)CO^224.᪀ᓫᐗ,—᪀ᓫᐗeM,=114M=1122?ᓫᐗTM஺=226"jᑍ•²ᘞ=113ᐗᡈjµ஺=226ᡠ15.᝞¶ᵨ·¸¹º?»¼ᓫḄᔠ}\5⌲¾ᔠ¿5┝ᔠÀᳮÁÂḄ஺ST?@ÃÄŹºᔠᱥᑖᡈᓫÆᓄ᳛Y}\syḄᐵᩭ␺஺Ê}\syḄËÌᑖ⌲ÍÎᜧḄᔠ}\Ð⌲¾ᔠ஺ᔠÑÒsyÓᑖÔÊ}\syËÌÎᜧḄᔠ}\Õ┝ᔠ஺[}ᓫÆᓄ᳛ÊᔠsyḄËÌ⌲ÍÎᜧḄᔠ}\Ð┝ᔠ஺ᓫÖ×ÆᓄÆᓄ᳛ØÙYᔠsy&ᐵḄᔠ}\Ð⌲¾ᔠ஺16.ᑏÛᑡᓫÝᡂᔠᱥḄ}\஺ᢣÛÝᡂᔠᱥḄᓫᐗஹ᪀ᓫᐗஹᓫᓫᐗᓫ,àᔠᱥáâQÐ#¶~ᔠ}\஺]CH=CHC1CH=CHCOOHOH(CH)COOH22225

5CH2cH2cH2஺IIHN(CH)NH+HOOC(CH)COOH(4)(5)226228OCN(CH)NCO+HO(CH)4OH(6)262nCH2=CHC1-------ᔤCH2cHeä——CHCHC1—2ᓫåᵫØᔠçèé”ᓫᐗ᪀ᓫᐗST(1)ᓫᓫᐗnCH=CHCOOH------►-ECH2cH±?CH2cH?2ᓫåᵫØᔠCOOHCOOHêé⏚ᓫᐗ᪀ᓫᐗᓫᓫᐗ(2)nHO(CH)COOH------►-Ep(CH)CC)3-+nHO25252ᓫª}\ì(ᑁ)în(3)—O(CH)CO—Aᓫᐗ᪀ᓫᐗ&ᓫᓫᐗ஺25nCH2cH2cH27——►-ECHCHCHQ^222nI-------1?τïðᔠñᩖðóô)ᓫ(4?CH2cH2cH2஺?Aᓫᐗஹ᪀ᓫᐗஹᓫᓫᐗ஺(5)nHN(CH2)NH+nHOOC(CH)COOH—►H-[NH(CH)ioNHCO(CH)C(g-OH+(2n-1)H02102282282ª}\᷾ö⏒᷾öø11H2N(CH2)IONH2HOOC(CH2)8COOHAᓫ஺—NH(CH)NHCO(CH)CO-Aᓫᐗ2l028?NH(CH2)K)NH-?CO(CH2)8CO?ᑖA᪀ᓫᐗ&ᓫᓫᐗ஺(6)জnOCN(CH)6NCO+nHO(CH)4OH--------►-Ep(CH)4OCONH(CH)6NHC(H2222iiúî,ঝAᡂ}\&ᓫᓫᐗ஺—O(CH2)4OCONH(CH2)6NHCO—Aᓫᐗ

6HO(CH2)4OHOCN(CH2)6NCOAᓫ஺17.OᑏÛᑡᓫüᑮýþ6ᑖḄᓫᐗḄᓄÿ᪀஺(1)a-ᵬ(2)(3)a-⏚ᵬ(4)A+(5)ᵬ⏚+⏣(6)+⏚CH3nCH=C(CH)aBH2"n23C6H5C6H5(1)CNnCH2=C(CN)2aECH2(3-nCNফCNLJnCH2=C(CN)-------►H2c3!COOCHCOOCH33(n+l)HO0H+(n+2)CH,CHCHCl,\7oভ+(n+2)NaCl+(n+2)HO2nHOOCCOOH+nHO(CH)OH--------►22(5)+(2n-l)HO2(6)

7nHN(CH)NH+nHOOC(CH)4COOH------►fNH(CH2)4NHCO(CH)Cqj+(2n-l)H02262224218.ᑏ'(ᑡᔜ+ᔠᱥḄ+ᔠ/012345678Ḅ9:(1)+⏚ᵬ;+<⏚(2)+⏒;+ᑁ⏒(3)+ᾦ;+ᵬBnCH=CH(COOCH)23COOCH(1)3nHN(CH2)6NH+nHOOC(CH2)4COOH——(2)22£NH(CH)NHCO(CH)4CC)}+(2n-1)HO2622nNH(CH)CO---►£NH(CH)CO3-2525nnHN(CH)COOH------►£NH(CH)CCg-+(n-1)H0225252nCH2=CH(CN)a-ECH2CH3-nCNবCH3nCH=C(CH)(CN)------►/EF23CH319.ᑏ'Hᑡ+ᔠᱥḄIJஹᓫM;ᔠᡂ/03஺CH3-ECH—c3-£CH—CH^2n2nCOOHCH3OHপফ-£NH(CH2)6NHOC(CH)8C(g-£cH—C(CH)=CHCH^223বn(4)nᵞH(CH2)5Cᔙ(5)-n(6)(1)+ᵬ⏚ᵬḄᓫMUᵬ⏚ᵬ஺

8CH3nCH=C(CH)(COOCH)-------►2c2331-nCOOCH3(2)+⏣ḄᓫMU<⏚H02nCH=CH(OCOCH)■>ARH2cHm23nCH30HnOCOCH3OHW3X+᷾⏒WZ[-610XḄᓫMU;᷾⏚nH2N(CH)6NH2+nHOOC(CH)8COOH—►HH(CH2)6NHCO(CH2)8CᔙOH+(2n-l)H2஺22W4X+^_ḄᓫMU^_஺I4ab“d….fg”iᡝ…kW5X+WᑁX⏒ḄᓫMUᑁ⏒ᡈm⏚஺nNH
CHCO------►£NH
CHCO3-2525nᡈnHN(CH)COOH—►H-ENH(CH)Cd^-pH+(n-l)H0225252W6X+n⏚ḄᓫMUA;ᐝq஺Ao11~OC—Cl+(2n-l)HCln20.rᑏ's(+ᔠᱥᢥIUPACxyzI{ḄIJ஺{NHNHCOYO>-CFCH2cH2(1)\-----/\-----'n(2)nCH3CH2-1COOC2H5-ECH2—CH(OH(3)(4)11

9-^CH2c(Cl)=CHCH--2|nমপ+}~~ফ+}ᓄব+-WX-1-ᵬভ+-ম+-1-21.ᨵ(ᑡᡠᡂᑖᡂḄᔠMx஺ᡂᑖ1ᑖᦪ=0.5,ᑖ=1x1W/ᡂᑖ2ᑖᦪ=0.4,ᑖ=”1WX5ᡂᑖ3ᑖᦪ=0.1,ᑖ=1X1WX6gᔠMxḄᦪᙳᑖ“;ᙳᑖ0“ᑖᑖᢣᦪ஺ᑖᑖᑖᛛᧇBio4¤¥WX104X¦§4WX10X¨©+6-30ª«1.8-2.3ᜩᯠ¦§20-40+5-10Z[f661.2-1.3¦§15-20+10-30¥Z[6-7.5¯¦§25-30+n⏚2-8¤¥°50-100¦§10-12⊤1f1ᵨ+ᔠᱥᑖ¡M“=ZN,ஹ±Mii='=1.85xl04o3~04~oT-rTr101010"=ZW,M=0.5xl()4+0.4x105+0.1X106=14.5xl0422.᪷³⊤1-1ᡠᑡḄᦪ³4´µ¶+ஹ+ஹª«ஹZ[-66ஹ+ᜩᯠ¦§Ḅ+ᔠ஺᪷³g·¸+ᔠᱥḄᑖ;+ᔠ¹ᛛᧇஹ¤¥;¦§ᨵº»¼:½ᓫMᑖᡈ+ᔠᱥDPᑖWxIOு¾ᓫᐗᑖ+62.5806-24195-10+104962-288510-30ª«19294-1201.8-2.3Z[f6622653-57.51.2—1.3

10+544630-555625-30ᜩᯠ¦§682921-588220-40᪷³sÃᦪ³4¤¥(ª«ஹZ[-66)ᑖᨬÅ4ÆU10000-200000¦§(+4ᜩᯠ¦§)ᨬᜧ4•Éᙠ20000sÃ஺ᛛᧇ(+Ëஹ+)ÌÍ஺¦§ÎÏ+ËÐÑᓄᔠᱥ4ᑖḄÒឋᜧ4ᑖÔÕᵨÖÅ4¤¥Uᨵ×ØÕᵨᡈᨔឋ+ᔠᱥ4ᛛᧇḄÕᵨÖÌὅÛÔ஺ÜÝ⌲ß+ᔠfஹà⚪1.ᑏ'ᵫHᑡᓫMãä+/0åᡂḄ+Ḅ᪀஺HORCOOH)HOOCRCOOH+HOR'OH(1)(2!ஹHOOCRCOOH+R"(OH)ভHOOCRCOOH+HOR'OH+R"(OH)33(2)(3)(4)¡Í+ᔠᱥḄ᪀æ/0ᱥçᨵèᐵx4᝞ᨵᐵxrëìÛ—[ߟORCO,=I-(1)ís|,U¾ᓫᐗḄîïᑖ஺ᓟOCRCOORO+_(2)ð᥅òóís1-'U¾ᓫᐗḄîïᑖ஺ᐸᡠíöᱥᦪᙳ+ᔠX,,——1+ræøùúû᥅òᦪÛür(rý=1);/02PÛÔᨵX,=]+,.2þᐵx஺(3)ÿ
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[°P0.500ஹ0.800,0.900ஹ0.950ஹ0.970>0.980,0.990ஹ0.995Ḅᦪᙳᔠ°È“~DP¼ïᐸᦪᙳᑖ=×஺P0.5000.8000.9000.9500.9700.9800.9900.995—1Xn=-----25102033.3501002001-PÉ=312.551016.6525501002ð=113ñ+18244583114822783781566811318226187.ᡃÚ᥅Ḅᐗ⏣ᐗ⏚óᧇÂõö°÷øᙳᔠ஺qr£0ùḄᨬûḄÈ“1üýâþp£ö°
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13CCCH3IH3正II.SSSL小-3IIICH3CCH310000-(2x73.1+16)ᡠdX,1=13374.1ᡠ◤5)=2x0.01x108.5=2.17(g)W°)s©=133x0.01x129.5=171.7(g)10.᝞9ᣚklᦪᙳᑖFnᜧ#1.5xl()4Ḅ+ᵬᵬ⏚9-᝞᪷*+,-ᳮᑴᐸ⌕klᦪ஺./ᐸ5⊝ᦪ14zL9ᣚ*+ḄRᓄ,-1nHOCH2cH2OOCCOOCH2cH2OH*HOCH2cH2O£OCCOOCHCHq3-H+(n-1)HOCHCHOH2222ᡠdr=l,aK=4,"()=96,1.5xl04ᦑy=¢£ு156.25AnMoKᵫ§8⚪~Dª1.65x10"nᓽ-ᑴ?@ABC⏣ᑖFᑖᦪᙠ0.165%஺d'஺11.ᙠᔠᡂ+9Ḅ,-A¯ᑮa"1100Ḅ*+ᱥ⌕±²ᑖBCn᩽´஺µᔠᡂ¶·ឋ¹º᪛ᾦ⚜+?ᑣ¶dᙠ²·¿A()஺ᐸÀᙠ஺zLÀ1+Ál¹º᪛ᾦÂÃ,-Ḅ5⊝ᦪÄÅ᩽ᜧ஺ÆὅÈ10.1-10,Éὅ¶4IO?Ì#,ÀÍ⌕ᔠᡂa“=100Ḅ+ÎP=0.99஺Ï7Ð◤110Ñ-10-3஺µᔠᡂ¶·ឋ¹ºa“È110ÌÒP=0.9,KaÓᜧᡠd᯿¶410£dÕÀÍ,-¶ᙠ²·¿A()஺12.*+,-5⊝ᦪ⌕ᵫÀÖ×<ØÙᙠÚÛ5⊝ᦪÝᑁßà*+ᱥᑖFnḄ⌕ÀÖ஺zL*+5⊝ᦪ⌕ᵫ*+,-áâ,-ãä×஺*+5⊝ᦪᢥᐸᜧD¶ᑖeáL(1)5⊝ᦪDᙠ10d'Ḅ´ᑖFᱥᙠ?@ABCnæßàᑖFnḄ⌕ÀÖ஺(2)5⊝ᦪᜧDçA᝞110-103ᦪnèḄ,-஺´ᑖFᱥBCnᨵßà஺êßàᑖFnḄ⌕ÀÖëᨵᧇíᱥînï1ᙢ,-äᑴᙠñÝ஺(3)5⊝ᦪᙠIO?dÕḄ*+,-஺ßàᑖFnḄ⌕ÀÖæᧇḄíᱥînï1ᙢᑴḄ,-ä13.᥅ᐗ⏣ᐗ⏚᜜⏚ôᓄ*+஺<õöP÷0.98ø0.99ᡠ◤7ùú÷ûPøP=0.98ᡠ◤7ùüý஺

14zLᙠ᜜⏚ôᓄḄ+9ᔠᡂ,-ACᙠX=K'Ct+inoP=0.987,X=50ᡠ◤,-7ùti=49/K'Co.nP=0.99£=100,ᡠ◤t2=99/KCo஺ᡠt~2tpᦑP0.98ᑮ0.99ᡠ◤!P=0.98ᡠ◤Ḅ#$஺214.&'()*+,-᜜ᐝ0+12321.35678⏒78:;᪵=>ᨵ2.50x1BC3moiFG஺᪷IJᦪILM3ᑮᦪᙳᑖPQR8520஺;SLM◤TUᎷ*W᝞U&'YZᩭ\*ᐸ^☠ឋW᝞aᎷ*b^☠᝞UᵫYZᩭ\*ᐸd\Ḅe“gWhijRMlmZW.=2L3g"“=8520ᡠZN,=2.5xio3,jtLMᎷuvwᜧᑖPyzᙳ{>|wFG஺^ᵨ~#+\2QᦪᙳᑖPQḄ+2QᐸᦪᙳᑖPQ஺2tᎷuḄ^☠ឋ஺15.ᵫ78:,78⏚ᔠᡂ6⏒:ᑖPQR15000,R0.995஺;LMᓫᧇ஺ᱥḄGW᝞◤ᔠᡂᑖPQR19000Ḅ6ᔠᱥT1᪵ḄLM஺hiᑖPQR15000Ḅ6⏒:=”=132.74£"113¤¥P=0.995஺᪷IP¦᥅¨©ᑴX,,ᨵ—1+rV=---------£஻1+r-2rp±3²0.995஺u78⏚'Qᑣ78⏚78:᥅¨ᢗᧇR1:0.995ᵫP=0.995r=0.995BM>MC:Gᦪ=N“BI-PC=N/BI-PCFGᦪ=N1N"P=Nb-N—Ngrp-ᦑ:GஹFGᦪ=¹B1|¹C/B1|ºC=1/2᝞u78:'Qᑣ1ᳮ^3:Gᦪ/FGᦪ=2/1ᑖPQR19000Ḅ6⏒:=¼½=168ᐭ“113ᢥ1+±3ÁP=0.995r=0.998஺Á78⏚78:᥅¨ᢗᧇR1i0.998ᑣᱥḄ:Gᦪ/FGᦪ=0998
1-0.995=$.1-0.998x0.995Á78:78⏚᥅¨ᢗᧇR1i0.998ᑣᱥḄ:Gᦪ/FGᦪ=7/516.LMÂÃᱥÄQḄ78⏚78:ᙠR0.99,0.9956ᔠᑖÆÇÈÉὅᑖPQᑖÆḄË஺hi*¤¥r=l,P=0.99ᡈ0.995

15᪷IFloryᑖÆÑᦪ6ᔠRxḄ6ᔠᱥḄᦪᙳᑖÆÑᦪNx-iÒ=p''(1-P)N16ᔠRxḄ6ᔠᱥḄÖᙳᑖÆÑᦪWஹ=XP'T(1—A7P=0.99X210305080100150300”X1089.99.147.476.114.523.702.240.495NWxxlO80.1980.9142.243.063.623.702.481.49P=0.995X210305080100150300500Ý|()ஹ4.964.784.323.913.373.042.371.120.410NWxxlO80.04980.2390.6490.9781.3461.5221.7771.6761.025ØḄᐸᑖPQᑖÆ⌕ËÚÛÜ2—1,Ü2—217.ßà1010᪷I1010á='QḄ᷾8⏚ᩭ©ᑴᑖPQḄ஺᝞ã⌕±ᔠᡂßà1010ḄᑖPQR2x10**,SßàI஺ä஺áḄ⏚g(mgKOH/glOlOáL)aRæºWhi1010áç᪀RNH+(CH)1NHOOC(CH)COO-320328ᑖPQ374஺ßà1010ç᪀ᓫᐗzᙳᑖPQM=169o2xl04ᐔ==118.34169—1+rᎷu᷾8:P=l᪷IY=83²0.983஺ë"1-ruN”(᷾8:)=1^,=1.0/0.983=1.0173,ᑣ⏚g=(N8"í¥&%"2=§18(mgKOH/g1010á)N.XM3஺18.ñò⚪=ḄᦪILM᷾8⏚'QᱥḄ6ᔠÖQᑖÆÇÈ஺|õhi*ᙠò⚪¤±ÃL0.983,ᑣ6ᔠḄÖᙳᑖÆÑᦪôஹ=xrT^-----÷ÛÜ2—3'1+rX111214161101VKrxlO41.4614.7125.7842.4653.1562.46X121201301401501WxxlO463.0352.7433.5118.9410.0419.ᙠßàߟ6,ßà|66ú=R⌕ûᐭü⏚ᡈ78⏚TRᑖPQ©ᑴᑺWᙠþÿᦪ᪛ᾦ

16ᵨᑴᑖḄߟ666!⊝#ᦪ$ᜧ஺'()*1஺,-▭/66012663Ḅ456ߟ6ߟ66Ḅᙠ-▭89ᙠ:;ᱥ=Ḅ>⚪஺@ABᙳ)ᵨDᐭF⏚ᡈIJ⏚ḄKLM┝OPᑴᑖ஺ᵨ@QOPᑴᑖḄRS0ᑖKL8TᨵVWXYḄZ[4ᱥᙠ\]D^2'ᑖ8_VW`ᜧ஺abᔠᡂ!⊝#ᦪ$e4fgeᑖᑖᦪ0hiᑖḄj⌕5l456mZ12ᑴnJ⏥fpᩭᑴP\*ᑮᑴᑖḄtḄ஺u*ᑮ⚜wᑖ4xy*ᑮ•w{(456)12ᤅ}~*ᵯᓄᑨS஺20.᝞ᦪᙳᑖᑖ=”1()4=3x1(/ḄPET/᪵ᔜ1kgᐸᔠ4ᙠD¡¢V£¤¥ᣚ஺Ꮇ᝞¨©/᪵ᐹᨵᳮ¬Ḅᑖᑖ4/®¯¤¥ᣚ°]Ḅ“²“ᔜ³´:¶·²“¸஺4,²“2=3º6»¸¼2=1½4M°=96¤¥ᣚ°=1-5X1O4__Æ,Zᡠ”=2x104¤¥ᣚ]²&=஻“=L5X1()4᪷ÊË=25=ÌÍp=o.9936AnM¨¸o²ÐM/(1+P)=299x10421.ᎷÒÓL⏚ÔᓫxḄᱥᐸᑖᑖÖ×Floryᑖ஺/>uᱥḄ!ᙳᔠ(^=154xyᑁᓫxfgḄᑖᦪᓰßàᓫxḄḄáᑖâã——1¶·r=14X஻=15,᪷ÊX஻=----ÌÍP=0.93஻n\—P5%=pஹe¸ç4ᦑuX=1Ḅ=(0.07é=0.49%/Voᡠ\uX,r15,xyᑁfgᑖᦪᓰßàᓫxᑖᦪḄ049%஺22.\HO(CH2)6COOHîᧇᔠᡂ¤᪛ᾦ4ð2'ñLḄò(w4óàxôḄpH2஺õö÷]pHø4஺>6'(P0³´ᱥḄù“0³´*5ò(a=[H+]/[-C00H],ᡠ\t=0,pH=2,[”+]=10-2,~co஺"[o=["+]/a=10-2/a஺

17t=t,pH=4,ᵪ+],=10[஺஺஺"],=[H+]Ja=10^/a஺t=tp[-CO஺"]஺-஺஺஺ᑗ!=o99'[-COOH]KT?023.()ᙠ+,ᔠᩩ/0ᵫ234⏚67,8ᡂḄ,234⏚;Ḅ<ᙳᑖ?@A18400g/moLFGHI(1)(;ᓄḄ23Mᑖᦪ(2)O,ᔠᱥḄᦪᙳᑖ?@(3)O,ᔠᱥḄ“(4)RSᡂ,ᔠATU“VWḄ,ᔠᱥḄSᡂX᳛஺ZI(1)()M.=18400,^0=100᪷\X=]^_V=\+PA,vMoA,vi-pdeP=0.989஺ᦑh;ᓄi3Mᑖᦪjk98.9%(2)᪷\Mm=1+Pe”—“=9251(3)᪷\V=pTeX=92.51A,A„Mq(4)᪷\t=pi(1-P)vwx=2ᐘ“=185,,ᔠA185Ḅ,ᔠᱥeSᡂX᳛=N24.\z⍝|}Ḅ~3⏚ᙠᵬR67,Sᡂ,⏒ḄA஺᳛ᦪ᝞0IT(࠷)150187K(kg/(molemin))1.0x10-82.74x1O-2(1)ᑏᓫ7,ᡂᑖ?@A127I8g/molḄ,⏒Ḅᓄ⊝(2)GHOḄᓄ(3)eᦪᙳᑖ?@A4.24xl03g/molḄ,⏒ᐸ◤⌕¢ᜧ¤e<ᙳᑖ?@A2.22x104g/molḄ,⏒¥◤⌕¢ᜧ¤IOOHN(CH)COOH-H-^NH(CH)CC)JOH+99H2O2224ZIপ(2)()7©=273+150=423K1=LOxlO-3ᔆ=273+187=460,¬=2.74x10-3᪷\

180-EIRTK=AAeK\RঢTJe£=82.65V/mol—1—1+±——————ব᪷\X“=77X³´0'M,=X„M^M.=X.Mv0wMo=99,GHeᑮᔠᡂ᪗“=424°Ḅ,⏒P=097;ᔠᡂ¹,=2220°Ḅ,⏒P=0.988625.12—23ºᾦ⏚ᙠ433.5K0¼½ᰚ¿,ᔠ)ᐸÀᔠᱥᙠÁÂ0Ḅi3}ᦪ\᝞0IT(h)00.51.01.52.02.53.0[COOH](mol/dm3)3.11.30.830.610.480.400.34FÅI(1)TUᩩ/0Ḅ᳛ᦪKAÆÇ?(2)OÈᔲÊᐭÌÍᓄᑺ(3)1Ï_5ÏḄᔜA¢Ñ¤ZIXn=[COOH]/[COOH],()0{COOH]=3.\mol-dm-3M0t(h)00.51.01.52.02.53.0[COOH](mol/dmJ)3.11.30.830.610.480.400.34Xn12.383.735.086.467.759.12Xn215.6913.925.841.760.183.0Ò¥“/■ᕈÕឋᐵØÙÚ24ᵫÛÕÜ᳛eK=2.44xl()4dm3.s".mori஺OÊᐭÌÍᓄᑺ஺1Ï¥“A3.723,PA0.731©5ÏᐘA14.615,PA0.932»26.àáâḄGHãᨵåXæ¤ᔜᨵÆᱯâ?ZIàáâeGHãᨵv0VæI(DᵫCarothersGHᦋ3kêàáêëḄì,⌳Jᑖ?@îïᜧᙠðRᢥᜩ“»8ᩭᜐᳮö÷ePo=2/f஺÷ù▭Têàáê륓ûüýkþÿᦑḄPo஺(2)FloryḄᙠឋᳮ!"#$ᙠᑖ&ᑁᡂ)*+Ḅ,-.,012ᓄ4ᦪaḄᭆ8ᵨ:;<=>.*+?@ᵫPR[r+3/-2)/A▭*+CDEᎷG,-ᨵI#JKᦑLLMN஺27.TUVᵬ⏚YZᱥ\]Ḅᵞ_ᡈabc⏥efgh(1)jᙳfᔠ@m(2)ᢥCarothershtu=m

19(3)ᢥhtu=஺wx(1)ᵞ_y4f==2.4J5k4r᧽n72x2+4xl_mac⏣y4==-----------=2.672(2)ᵞ_y4=*=0.8332abc⏛:y4P=——=0.749'2.67(3)ᵞ_y4p=f---------------=p7=0.703/=1,p=1,/=3;[r+rp(7-2)]abc⏣y4P=---------------YTJ=0.577,r=l,p=l,/=4;T[r+rp(7-2)J28..ᑡᔠᱥḄtu=஺(1)TUVᵬ⏚ᵞ_Ḅ᥅1.50:0.98(2)TUVᵬ⏚ஹᵞ_V⏣Ḅ᥅1.50:0.99:0.002wxᧇTUVᵬ⏚:ᵞ_TUVᵬ⏚:ᵞ_:V⏣150:0.981.50:0.99:0.002r0.980.9913P10.998772.3712.387f33Pc*(Carothers)0.8430.838Pc**(Flory)0.7140.710?_2R/+N/)2JNA+NB+NCᓃ7p**=__________!____________[r+rp(f-2)]229.Z£¤ef*+¥¦y¤ef*+ᨵ§¨ᱯ=ªwxy¤ef*+ᨵ>.ᱯ=x(1)«¬*+Ḅᓫy¯y¤ef*+C°±ᨵ²ᓫy³ᐹᨵµEᡈµE>¶@Ḅ·£¤ef*+Ḅᓫy³D@Ḅ஺(2)«y¤ef*+1?¯y¤ef*+¸Ḽ*+?@º*+ᑖᵬ»µE▤½஺ᵬDE▤½ᙳᙠtu=P஺¾,஺ᙠy¤ef*+Ctu=Ḅ⚜À³ᓝᑖÂ⌕ÄᓄÅᔠᡂÆÇÈᑴᙠP஺¾,>ÊḄ*+◤ᙠÌCÍÎ஺·£¤ef*+᝞ᡠ◤ÑÒ³fᱥ*+ÆÇ

20ÍÎᑮÔḄ*+?@஺Õ3«ᡠ:ÑᱥÖ᪀¯——,ὅÚᡂÛÜឋ£¤ᑖ&ÊὅÚᡂ#Ü#ᰚy¤ᑖ&஺30.Þß1000g)à᪛ᾦÕ)à0.2ᵨᱥ\]ḄVãäᓄgäᓄᑺᵨ]஺æhçäᓄ*+Ḅtu=஺᝞èé*+Ḅ*+?@ZIêḄᐵ4Ûᔲh:äᓄᔠᱥḄ〉ᵨî஺wxèé)à᪛ᾦ@ï2,VãḄ@f=4oᵨᱥ\]IDὅᑖ&2x1,ᦑ7_2x2+4x1_8/_3-3ᵨCarothersp=2=0.75஺fᵨFloryP=——=0.587
1+3-1᪛ᾦḄ〉ᵨîðᯠ⌕ᙠòóôᑮtu=Po¾,Ḅõ½Iêᑁ஺᝞öé⍝*+?@Iê:ᐵ4ᑣÛ>ùúûᨬý〉ᵨîþA▭〉ᵨî⌕ÿ஺31.⛳᪛ᾦḄ⌕ᧇ⏣ஹᩭ⏚ᵬ⏚஺ᧇᔜ!"#ᵨ%&'()*+,᦮Ḅᳮ/!"?ᵨ12ᓄḄᳮ/!"?᝞ὃ⇋782ᓄ9:⌱<2ᓄ=>%?@⏣Aᩭ⏚Bᵬ⏚⏥9ᔠᡂḄᧇ஺ᐸGᩭ⏚BḄ#ᵨ9ᙠ⛳GIᐭKLAᵬ⏚ᩭ⏚Ḅ*+/Mᑴ⛳Ḅ⛳OPQᩞᧇḄSὶUOḄ஺12ᓄ9ᑭᵨWᵫYIZ1ᔠ[\⛳]^ᑖ`GKLᐳᨬcdᡂ=^e᪀A᝞ὃ⇋782ᓄ:⌱ᵨghឋḄjkᓄᵬ⏒mᵬYnkᓄo=>஺32.ᵨ2.5᥅qᵬ⏚B\1᥅q⏣1᥅qr⏣stuAvw⌲yᓣ8A[{j|}᪛ᾦᰚஹ⏚h?ឋᩭMᑴvwᡠ⏚/ᢣG1g᪛ᾦG⏚ᡠ◤ḄKOHᦪ஺ᳮvw<⏚9஺Ix2+lx3+2.5x2N/?:==2.22,/=3,r=1,஺==0.61+1+2.5N/+N/2ᢥCarothers]_________ᢥFloryp==0.7906[r+rp(7-2)J2P,=0.9Avw¡Y᥅qᦪ2.5*2x0.9=45,ᒕ£¡Y᥅qᦪ0.5,=>¤¥524g,¦᪛ᾦ§¡Y᥅qᦪ0.5/524=9.5xl0"mo|/g,⏚g.SxlO^xio^SS.SZ^gKOHP°A=0.7906:#¨©Ḅ஺ª▭9⏚ᙠ¬ὅ()஺33.ᵨᐝ°±ᔠᡂḄ²⏚ᑖ`³:P´ᜧ஺¶·ᱥ¹º»¼ᓄ½jQAᙠ⌼¿jGᨵ9ZÁᑖ`³Â℉ÄÅḄÆÇ஺Èᑖ᪆⌼ᡂÊÆÇḄ⌕ËwÌÍḄ■ÏÐÑ஺?@ᵨᐝ°±ᔠᡂ²⏚ÌᵨÒ☢u±AvwYÔ:⌮AᡠP·ᱥᑖ`³´Ö஺᝞º»¼ᓄQḄ²⏚×ØÙÚÛA⌼¿9AᙠᰚÜ8Oݲ⏚ᐸGÞßḄàᑖZÁà?½vw

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36ឋ">?ᜧ஺ᙠᙳᔠWᔠᵫឋ"¡"no]>ᜧᜧQ¢tu^_Ḅnold]uv஺ᙠ£¤ᔠnoᵫ¥¦ᦔoᡈ¨©ªᵨ¬kp?ᜧ®Ztunold]஺noḄld]ᜧ6ᵫᓫ¯V°ᑁ²³Ḅ"W!Ḅ"ḄᦪµHJ⌼ᡂឋ">H¶?ᜧᡠ஺·¸⁚²³ᑺḄqºWᵨ²³{|Ḅ»"Ḅ]>®*ᓄ᳛?d¼⌴¾ᑣ'ᢓᑴnold]஺b᜜⌱ᵨÂIᑺdᜧIᑺᵨÃ9ᔠÄ>ᡈ〉ÆQ\ᔠᱥḄᑖCJYZ¾Çnold]È>஺nÉᑣ'ld]uvÃ$³|஺20.wxylᵫmᔠnoÄ>Êᔠno]᳛ḄËÌ஺GkY/2ᙠlᵫmᔠnoÄ>Êᔠno]᳛ḄËÌÍÎÊḄËÌᩭuḄ஺᪷Ñk=Ae-E,3L᝞ᓃ,kᑖÒÓ4,ÔḄᦇ2ᑣ2Öe"72%]Ù᝱lᵫmᔠḄ]᳛ÈÓÛ=4ÜÝÞc]᳛ßᦪ%=Û[℉ã⊤åᓄ£—è+Êêᑖë²³ᑺ%Ó120-150KJ/mol,M20-40KJ/mol,E,M8-20KJ/mol,ᦑE,Ó80-90KJ/moloᙠUqíîÄ>ᓣ910,ᔠ]᳛,?d2—37஺ÊðᓄñK²³ᑺᵫ4Ó40-60KJ/moIᦑE,Ó40KJ/mol,Ä>Êno]᳛ḄËÌò`஺ÊᐝᔠᡈôõᔠLÓὡ,=÷ã,ᡠ0E,Ó20KJ/mol஺noÄ>Êno]᳛ḄËÌø`஺Êùᙠld]Ḅᔠnoᐸld]È>WÄ>ᨵᐵ஺UVÄ>Êno]>ḄËÌøÓúᩖ஺21.wxyᙠlᵫmᔠnoÄ>ʲ³ᑺ²³ðᓄñK²³ᑺ²³Wᐝü²³ᔠýþoᡠÿᱥᑖḄ஺ᙠᵫᔠ⌕ᜐ!᝱#$%vᡈ'_kᙳᔠ)X“+)Ḅᐵ-./ᙠ——f3+)Ḅ4ᓄ6஺#$782
9:;

37<=ᓄ>?"2ᑣ£=BCD஽/2-6/2JKᑖLMNᑺEQ8D40KJ/mol,+)ᓣ[%vᡈ'ᙳᔠ)]“ᙳ4^J_ᓄ`aMN.-E8D5-5KJ/moLde0,ᡠg+)Jvᡈ]0h^஺JᐝᔠᵫEd80,Ek8lmnᐸmpᜧᡠg+)ᓣ[vᡈrsᶍᨵᓣ[஺vwḄ⌕xyᑣ+)JG”Ḅ⌕|E"~EpḄmᨵᐵ~MNᑺḄᐵ-^஺#ḄᢣᡂᜧᑖḄpᢣ?஺22.ᙠᵫᔠ⁚ᑖḄᨵCgᔠ.ᔠ⏚ᔠ~¡¢ᔠᑖ⁚x£8¤ᩭ▊§~¨©஺ᵫᔠᔠᱥḄᦪᙳ«)¬ᙠgᐵ-X+c±L+c²1p´Ḅᔠ.-µ¶ᨵᡠp´஺=Xnk2[M]2[M][M]p1?ᔠᔠᔣᓫ.vw¹ᦪQᙠ1X108ᦪ»ᓫ.vw¼᳛¾¿Àl¹Ḅ¼᳛஺ᔠÁᨵᑺMNᑺvwÂÃᶍpÄ7ÅḄ'ᙳᔠ)ᵫCM#D⚗ᡠÉÊ஺CMḄᜧ^ËÉÊ«+)7Åᙠᔠ☠ᦋ4ᔠ+)ᩭ⁚ᑖ஺2?.ᔠᙠ100CgÎÏ.ᔠÐÑᵨMNᑺMN஺gᏔᔠ8ᓫ.vw~MNᑺvwËᓰÕ⌕ᙢ×஺Ḅᑖ⌕ᵫ+)~MNᑺᵨᩭÉÊ஺+)Ø[ᡈMNᑺÙ)ØᜧᡠÚᑖØÛ஺ᙠ100࠷g6ÎÏ.ᔠÝÂgKᔠ஺+)[$Þᓄ~ᓫ.vwᡠᓰߤàsáᜧÅ$⁚ᑖḄ⌕âãäᔠ+)஺3?⏚ᔠ⏚ᵫæçÂgNÐvwgAIBNᙠ60CḄMN8¤Gw=3xl0-4Cᵬ⏣?=6xl?YC,ᵬ?=208X10-3g?=2.96X10“g⏣?=2.5x10-37ÅÂgóÀ⁚ᑺ~ᵨᩭ⁚ᔠᱥḄᑖ஺ᙠ⏚ᔠ◀õᦋ4ᔠᱥ+)~MNᑺÙ)ᩭ⁚ᑖ᜜ᑺḄ⌱ø~ᑺḄᵨÝ⁚ᑖḄù⌕âã4?¡¢ᔠᙠᳮû¢ᔠᱥḄ'ᙳᔠ)ᵫgᐵ-ü28[M][]ÿ/5]᮱3/5ᦋᓫᓄᑺᑺ⁚ᑖ஺!"ᑮᓄ$Ḅ▲ᑴ஺()ᔠ+ᱥᑖ•./ᜧ᝞◤ᜧ!34ᐸᑖ,ᑣ89ᐭ;⏣=>?@ᑺ஺ᙠ50cDEFG>HᵫJKLM;⏣Ḅ?@NᦪC,QR16஺9ᐭU;⏣ᓽW℉ᙢ34)EFGḄᑖ஺

3823.]^_ᵨHᵫJ)ᔠ+aḄᜧbcᨵefghijkNᵨḄ)ᔠlm)ᔠᩩopqrHstuὃwᧇ9ᑖ᪆z{ᩭ}~⚪஺24.ᙠᵨᏔFE.ᑺḄG)ᔠ᝞ᵨcḄ)ᔠᩩoq1$ᓣ80࠷,ᢝᙠ)ᔠ2$ᓣ75࠷,ᯠ¡¢£D4.5࠷Ḅᓣᓣ95࠷஺ᙠc¥¦§?ᓄ᳛Ḅ©ᜧ+ᱥªᙳᑖᓄ᝞q?ᓄ᳛ᑖX10%³8ᩩo1ᑖ*10»³8ᩩoফ201111301413402016502419602621702823802924g¬ᔠᑖ᪆⌼ᡂc¯°Ḅ±஺pq²)ᔠ³8´ᨵᓫᔠᑺuµᙠ¶᝱12
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39(Xn)=w^-ߟa,᝞ᨵᓫJtuᑣX=-J—+Ckw2(X.(X);ᙠ-abUᕴMH174'ᙳᨵᐵ஺Hᨵ⌱ᵨ!ឋ#$ᑺᵫvEd9y,¡0Ḅᔠ]£ᓫJtuop¤|ᶍ.~;¥¦§¨ᡠVᡂᔠᱥ)Xᙳᔠ'©Z#$ᑺ&'7ᓫJ&'Ḅ[\]4'L^_ᐵḄab஺1-(2)᪷«(1)MḄᐵ¬ᙠᨵᓫJtuabUwᵫ⚗¯°஺ᐸM(X“)³´ᯠZ#$ᑺ&X'[\஺z{Hᨵc⌕ᵫCM¯°;¶¦§¨ᔠᱥḄXᙳᔠ'Z4'[\]#$ᑺX"&'L^_ᐵḄab஺27.¸¹ᙠº»¼ᓫJMᐭ¾¿»⏣ᔠ;ᡠ)º»¼ḄᑖÁ¿Âwx^Jᔠ⌕+஺»⏣¿Ãᑮw°Å'ᡠ)ᑮḄº»¼ḄᑖÁ¿⌕ÂᩩTU^Jᔠᡠ)Ḅ⌕ÆfÇÈ஺fg¾¿»⏣;ᔠrÉᙳḄ»⏣ḄntuÊᵨ¦ᑖÁ¿U(஺»⏣¿Ãᑮw°ÂËᔠÉᙠ.ÌÍᑺᡈÎÍᑺM§¨Ï´Ḅ¨ÐÑ]⌼ᡂᱥḄᑖÁ¿Â^JᔠḄ஺28.᝞ÓÔwᵫLᔠḄnop>ᐰᏔᔠop×~ᙠ+tᓄ᳛Uᡠ)ᔠᱥḄᑖÁ¿ḄᑖÙᢣᦪÉܾÝᙠUᑡabUᔠᱥḄᑖÁ¿ᑖÙab¦᝞ßàᓄÝ(1)ᐭ,áLâ⏣Êntuᑺ(2)ᑮtᓄ᳛(3)ᔠᱥᑖÁ$Vntu(4)åᙠᦔfg᪷«ᭆ᳛èéêᙠᏔᔠopḄᔠMᦪᙳᔠ'ᵨ=*x=I(1w¡¡îᙳᔠ'31-Pᙠ+tᓄ᳛U⚜~ᔠᱥḄᑖÁ¿ᑖÙᢣᦪ1.5஺(1)ᐭ,áLâ⏣ÊntuᑺXᙳᑖÁ¿U(×~ᑖÁ¿ᑖÙᢣᦪ2ᑮtᓄ᳛ᵫv§¨ᦔñòᔠMIḄày¬ᑖ(2)Á¿ᑖÙᢣᦪ´℉ᜧ஺(3)7ᔠᱥᑖÁ$Vntu¦õᑖÁ¿ᑖÙ(4)¦ᑖÁ¿ᑖÙàõ

4029.ᐺ÷øùᔠḄᱯûÉᢝý'þᱥᑖÁ¿஺ᙠᜧÜᦪ^JᔠM¤-¦§¨'àþᑖÁ¿ÃᜧḄ¨Ð஺Æᑖ᪆⌼ᡂḄᐸ஺ᐺᔠᔠᙠ!஺"ᙳ$%&ᨵ(%)ឋ+,-./᡽ᦣᐭ(%3ᵫ5ᓽ789஺ᵫ:+3ᵫ5;ᓄᑺḄ>?@A589ḄB᳛D+3ᵫ5ḄEF-+3ᵫ5GH(I3ᵫ5ᔠ⌕KLMNOHPQᱥᑖTUK஺ᙠVWᔠX(YZᓄ᳛[ᵫ:W\]H,ᜧᡈᔠᱥ`abcd+89;e@+fgᑭ+,-ij`;klNmn᝱pẚr)ឋ+GH,ᜧ)ឋ+EFs-tuvwOHxPQᱥᑖTU,ᜧ஺ᙠyz{|}~ᔠW\)ឋ+GH(I3ᵫ5ᔠ⌕ᜧ)ឋ+EF(I3ᵫ5ᔠm⌕-஺yᜐ.ᙠᔠᦋᓄᑺᵨUfgᑺᵨUᑴW\+3ᵫ5ḄGHEF஺y{ḄKOHQᱥḄKᑖTUᢝnYḄ஺@ᙠVWᔠ3xOᵫ:W\ᱥᳮ᝱`ᓄ⌼ᡂḄᙠឋb☢ᙳ`:ᔠ஺30.5DPPH,FeCbḄeᦪeᦔu஺keᦪ஺(=jCḄᜧDᵨᩭ⊝Ueᦔ᳛஺PS/StW\PMMA/MMAW\¥kp¦᪷¨ᐸC©ᩭᑨ~eᑺḄeᦔu஺W\eᑺCT(࠷)z50.3265064.2050PS/StDPPHFeCl(DMF)53660o146005025.544PMMA/MMADPPH266044eᦔ᳛Ḅ¬¥O,DPPH>FeC13>ு5231.¯°±²³´Hᑖ᪆ᜧ¶ᑖxᙠᔠm¥·¸`⌮஺xºᑖTᓫWZᓄ¥ᜧᑖT¼©½DḄ¾AS¥¿©mÀ±N¥¿©஺@°±²³ÁÂÃ&ᨵAG¥¿©mÄÅ!஺ᦑ◀ÈᦪᓫW᜜ᙳÊ62.8KJ/mol,|A5|Ë¥104.6KJ/mol.k஺(IxᔠÌHÊ80࠷Ḅ`M@ᜧMᦪᓫWḄᔠ▲ÌHToK஺NᙠÎÏÌHÐ("⊝ᓫWGHÑÒº஺ᡠMᦪᓫWᙠᐸÎᔠÌH~ÔÕ¥ᔠm`⌮Ḅ஺32.6(ᵬ5×Øᵬ5ÙØ⏚ᵬÛḄᔠ±(IᓫWº஺ᐸ஺(ᵬ5×ØḄᔠ±Üº,᝞Ïßà×ØḄᔠ±áÔ:ØâḄᐔäḄäÅåæçḄ6äḄäÅèéê×ØḄëp

41ᐸ5ìíî[ᵫ:íî5Ḅïeᦔåᐳ᪻ᦔᙳdᔠ±òº@ᵯ¿ឋôḄíî5òdᔠ±ᓣK஺ᵬ5ÙØ⏚ᵬÛᨵCOOCH3Ḅᐳ᡾ᦔC%ḄÊᐳ÷ᦔøzὅḄïeᦔᙳdᔠ±òº஺a—ᵬ5×Ø5ḄôᐳΊᦔᵬ5ḄÊᐳΊᦔzὅḄïeᦔûÑüdᔠ±òº஺.ᔜíî5Ḅkl(wþὅÿ
ᔠᜧᜧ஺33.ᵨỚ60࠷ᓄ⏚DCPDḄᑖ᳛ᦪ!᝞#DCPD$%&'(஺)0.0754mol/lo+0.2,0.7,1.2,1.7,-./DCPDḄ&'ᑖ0)0.0660,0.0484,0.0334,0.0288mol/L1234ᑺᙠ60࠷7Ḅᑖ᳛8ᦪ9:⊦<=,?#*34ᑺᑖABCDEFᦑHᑖ/=JKtLMFᡠ/OPḄQ᳛)Ḅ[/][7]0=0.0754mo///RT(h)[I](mol/L)[/]00.075400.20.06600.1330.70.04800.4431.20.03340.8141.70.02881.196k=1.76X10-4S-1d0.693,1/21.08/734.ᢥWXYZ[F\]^ᙠ\_ᵨᓄ\ᵬ⏒ᙠ60࠷34bᵫdᔠ
1[BPO]=2xlO-4mol/L;[St]=418g/L
2[BPO]=6xl04mol/L;[St]=83,2g/Lef=l,f1gWXYZ[Ḅhᓄ᳛ᙳj10%kᡠ◤⌕Ḅkno#Z[p1?ᓫr/ᢗᧇouZ[p2/5vFᡠJjᑮxBhᓄ᳛k;zὅ|ᡂḄᔠᱥḄ).ὅḄ5v஺hᓄ᳛)10%A᝱FZ[p1ᡠ◤Ḅkn),Z[p2ᡠ◤kn)t2,ᑣ

425Rp2_]_5x0.832x7^x10-2_1/R~t~4.16x7^x10-2Pi235.ᵨC14ឋxᑴᜓḄAIBN34ᑺᔠᡂḄ\]^Ḅᙳᔠ')1.52x104./iABNᙠ¡ᘤ_Ḅឋ£ᦪ)9.81x107/(mol.min)„¬3.22\]^Ḅឋ£ᦪ)203/min஺f᪷!£¯°±BᔠDEḄ²=³´µ¶[·஺#¸¹ᐘF=1.52x104,AIBN»ឋ£ᦪ)9.81*l()7/(mo[.min),¼½¾¿ÀAIBNᑖÁḄ£ᦪ981x1072102)B-----Â=1.63x1()76/min,ᑣ203Ä£ᦪ¼½¾B--------=1.205x1()18ÀAIBNᑖÁ஺6.02X10231.63x10.39?,3.22\]^¼½¾....———=2.04x10-6"?஺/\]^஺ᐸ_ᨵ\]^ᜧᑖÁ104X1.52X1042.04xl0«x6.02xl()23À=123x1018À஺Ì)¿ÀᜧᑖÁ_ÍᨵXÀ(CH3)2CCNÏdFᡠJ´µ¶[·)Ꮤᔠµ¶஺36.100ÑᓣÓÔᱥÕᙠḄᵬdÖ^⏚ᵬ_Fᐭ0.0242ᓄ\ᵬ⏒FØᙠ60࠷ᔠ஺DE1.5,k./ᑮᔠᱥ3FᵨÙÚÛ/ᐸᑖÁ)831500(¸¹60࠷BPOḄ:⊦<)48,kF34ᦔ᳛)0.81,Q)0.02,CM)Six©,ᵬdÖ^⏚ᵬâḄã')0.930g//ml)of1(1)ᵬdÖ^⏚ᵬᙠ60࠷Ḅkp2/k,çè(2)ᙠ2é'êᓄµ¶9Ꮤᔠµ¶ᡠᓰḄoì஺#(1)R,,=—=—x-10-=5.56x105mo//(/•s)(îïðñ)QdtN10090x60ò[M]=9.3mol/l,[I]=0.001mol/l,fH).81JõJ=6^=4.01x10-65-10k,2öᐭg·Fᑣq=0.011//(mol-s)k,(2)ᨵ´høkᦪᙳᔠ'ᨵJFᐵû:g=ᯅ+஺"+஺ÿ=8315,஺“=O.lxlOG=0.02,[“=1x10-3[]=9.3ᐭ(£,)஻=9250(%„),"#$%&'()ᦪᙳ,ᔠ.Ḅ01஺

43k/2#$%&2v=•5■•7L='xO.OUx9.32=85562k,R25.56X105p=Ꮤᔠ'(ᑖ᳛"x,ᑣBᓄ'(ᑖ᳛"l-x஺V2vDEFGXHஹ2-x-+(l-x)ᦑx=0.15=15%]—x=0.85=85%ᓽ60࠷,ᔠNᏔᔠ'(ḄOPQ15%,Bᓄ'(ḄOPQ85%஺37.STUᙠ60࠷WXᓄYᱯ[\"]^ᑺS"`ᑺab,ᔠ஺cSTUḄd."Imo"1,]^ᑺd."O.Ohnol/LN]^ᑺl,ᔠᱥḄno᳛ᑖp"4*10”ll.SxlO,mo]/E.G஺u᪷wxyᑨ{ᙠ|}ᓄ᳛~ᙠ,ᔠ&'(Ḅ⌕ᵫWXᓄᱥ]^Ḅ&ᵫ\ᙳ}ᜫឋEᙠ.~CM=8.0xwtC,=3.2x10",.c=23x1O-6,STUḄ."0.887g/ml,SḄ."0.839g/mlG஺¡STU¢£"ᳮ¥`¦஺§¨᪷w⚪ª~ᦪw[M]=l.Omol//,[/]=0.0\mol/1R,=4.0x\Q-ilmol/Gls-.R=1.5xl0-7mo//E/-5Gp]_104x839887,-----=9.50mol//"58R.V=2=3750STUᙠ60cN#$%&'(ᐰNᏔᔠ'(஺᝞°}ᑣEG“G*=2v=7500±Q²ᨵᓫ¢]^ᑺl`ᑺ}ᡠ0.019S——=—+Cu+C
-—--FC——=-----F8.5x105+3.2x104+2.3x10-62X(X,)k[P[s[M]7500To-n1.0=0.000138+0.000085+0.0000032+0.000022=0.000243ᐗ=4115Ꮤᔠ'(ºᡂḄᜧᑖ½ᓰ54.7%,}'(ºᡂḄᜧᑖ½ᓰ45.3%,ᨵ2x54.7&ᵫ\^ºᏔᔠ'(¿ᨵ45.8&}'(DÀ&ᙠÁÂÃᜫឋÄᙳ}0.4138.ᙠ50࠷~Åᨵ0.26%ÆÇÈᑖᦪWXᓄᱥḄᵬ\ÊU⏚ᵬÌᙠ|}ᓄ᳛EÍ5%G~Ḅ,ᔠᱥḄᙳ,ᔠ."6600»uᑨ{&'(Ḅ⌕ÏᢣÑᑨ{ḄÒwÓc}ᓄ᳛"30%NÔÕºᡂḄ,ᔠᱥḄᙳ,ᔠ."27500஺uÖ×N&'(Ḅ⌕QØÙÚEᙠ30%}ᓄ᳛~,ᔠo᳛Q,ᔠno᳛ḄÛÜ஺50࠷~G=2xl0",C=0.15XW4,M

44MMAᙠ50࠷~Ḅ."0.930g/ml)§¨᪷w⚪ª[M]=9.3mol/l,[BPO]=0.01mol/l,ᙠ|}ᓄ᳛~50c~MMAá¢,ᔠឋ&'(ᡈὅäåᑗᙢè,ᵬ\ÊU⏚ᵬÌᑖ½Ḅºᡂ◀êᓄ'(lᏔᔠ'(᜜ìᨵᓫ¢l]^ᑺ&}'(஺=(í“)î"êᓄ'(lᏔᔠ#$%'()ᦪᙳ,ᔠᱥḄ01ᑣA-+c.+Gïx“(XJM'[M]=ñὃ⇋ᓫ¢]^ᑺ}'(ᑣX=C+C,=0.15x10-4+0.02X-=0.0000365MX,[M]9.3nX=27397n²ᡠôᱥᙳ,ᔠ."6600,èÑឋ&Ḅ'(⌕Q#$%&'(õöQ&}஺ᙠ30%}ᓄ᳛~ᨵÑ÷Ḅ#oᦔ×NùÑ÷~úõkpkr.M,kgᓾÿᨵ
ᜧᓄ[M]ᓄᜧᙠᙳᔠḄᐵ⚗(ᓄ!ᜧ"#$⚗ᓄ%&஺ᙠ()ᓄ᳛+,-.ᡂḄᔠᱥḄᙳᔠ1275000᪷78☢Ḅ:;<=>1ᙠ30%)ᓄ᳛+AឋCḄDEFᡈὅIJᑗḄLᵬNOP⏚ᵬRᑖTḄ.ᡂFU=ᓫW)XYZᑺ)X1\஺39._⏚`Pᙠ60࠷=Ꮤdefgh1YZᑺijkWᔠᐸmnoᦪ7᝞+rkd=1.16xioVk=37001/(mol.s)pk=7.4xl07l/(mol.s),[M]=10.86mol/l[I]=0.206xio'ol/I,CM=1.91x10“ᏔᔠDEᓰmnoDEḄ90%,ᡠ_⏚`PḄX,,஺rmnoCv=———!஺fᢥ1:;ᐭᐸᦪ72//)“2I”஺v=47777o(X„)*1mnoDEX,,Ḅ¡-v47777(X=-——=--------------=86867C0.9/2+0.1+D2J=-J—+C”=—^—+1.91x10-4=0.0002025)(X,)96967X=4938nᓽ§`PḄᙳᔠ14938,\⌕©ᓫW)Xᑴ«஺40.¬®¯ᓄe°ᵬ⏒ᙠ60࠷Ḅ²⊦´148&µஹᵬNOP⏚ᵬRᙠ60cḄkp2/k¸”10஽1(mol.s)஺᝞º»¼ᢗᧇ¿1À100mlÁÂ(Áᑺ1Ãឋ)Ä20ÅᵬNOP⏚ᵬR0.1Å®¯ᓄ°ᵬ⏒

45(1)10%ᓫW)ᓄ1ᔠᱥ◤
ǵ-È(2)ÉÊË´.ᡂḄᔠᱥḄᦪᙳᔠ(60࠷+85%ÌᓄDE15%ᏔᔠDEfᢥ1:;)஺(1)□=”Ï=4.0*10%-1:*1/2k2/k,=1x10-2//(m஺/.s)pk/kW=0Al'i2/(mol-s)[M]=2mol/l,[I]=0.0042zno//ZÓ[=2.6xl0-5஻?o//(/s)10%ᓫW)ᓄ!ÖÀᓣ»¼ÉÊḄᓫW10.02moloᡠ◤µ-0.2mol/I=7.69x10%=2.14஻2.6x10-5஻zR/(/.s)(2)v=ÙÚߟᧅ!=769᝞ὃ⇋)XDEᦪᙳᔠḄ¡ᑣ2(ᓻ&âãg2769=8310.15/2+0.8541.äᵨÉÊFæ⊤è_⏚`Pᙠ=Ꮤdefgh1YZᑺᵬ⏣1ÁᑺµÖ600cᔠḄÉÊêᳮ(ᒹí<îïᙠḄᔜñÉÊ)஺¬60࠷,Cs=6x10-4,C,=0,055,C,=1.91xIO-4,᝞ᡠᵨôF1VAclOO,CH30H,AIBNw400.3(ù¿ᑖᦪ)஺ᵬ⏣Ḅú10.792g/cn?,VAcḄú10.936g/cn?஺¬ᙠü)ᓄ᳛+ᡠᔠᱥḄᦪᙳᔠ11000஺JýᙠþᔠÉÊCDE.ᡂ_⏚`PḄ\⌕F஺᝞º⌕ÿᱥḄᦪᙳᔠᑮ1500,ᱥḄᑖᑖᡈᓄᜧ!"#$%&'஺)*(CH)CCNN=NCNC(CH3)2*2(CH)CCN+N32322R.+CH=CH(OCOCH)——►RCHCH(OCOCH)R-=(CH)2CCN23233-./♦…CHCH(OCOCH3)+CH=CH(OCOCH3)S^^*CH2cH(0C0CH3)CH2cH(OCOCH3)22.ᓫ234…CHCH(OCOCH)+CH=CH(OCOCH)------►23233CH=CH(OCOCH)+CHCH(OCOCH)333…CH2dH(OCOCH3)+CH3OH^^M►…CH2cH2(OCOCH3)+CH20H

46…CHCH(OCOCH)+…CHCH(OCOCH)>2323…CHCH(OCOCH)CH(OCOCH)CH2…233=ᨵᐸ@Ḅᓫ234AB!CDEFᑺ34Hᜧᑖ34I஺᪷KᡠMN&O103"Q+40=7320..9360.792.xU♦=V4஺=7%X஺஻/+0..9360.792”X10!ᵪ=1.40=00116஻?஺///----------1---------0..9360.792C+C,•—C--^-=1.91X10-4+0.055X^1^+6X10-4X^=9.22X10-4Mv[M][M]7.367.39᝞`ᐭbcdc⚗(X)-i-=C+Gᦋ+Cs0!ᐘ“=1085wX"M'[M]S[M]nopHqrstuv!wx34yz{|ᡂ~⏚ᑖḄ⌕yz&B!ᐸCᑺ34ᨬ⌕஺!ᑮ1500,〉ᵬ⏣ᵨ஺d᪵Xᑖᑖ!᳛ᓄᜧ஺42.ᵨᓄᵬ⏒EFᑺᔠ!ᐸ-EFஹ-./!-yz¢ᓄ£ᑖ¤E,=125.6,Ep=32.7,Es=10kJ/mol஺¬`ᔠ®ᵫ50࠷ᓣ²60࠷!ᔠ᳛³ᱥᑖḄᓄ஺᝞ᦋᐝEFᔠ!ᐸop᝞µ¶)*᪷K%,=3(·■)[M][I]'12E=E-E,/2+E/2=21.6kJ/molpdTi=323K,T=333K2

47JI|Zl.O11_ER(f\~T2>—e1.987Mo-3(323333,=[75ek1ᡠC60࠷Ḅᔠ᳛»500CḄ2.75¼஺[M]᪷K-34X„=2v=2--------^ߟ2
ᡃ”2[/ᐘ2=A=E/R([-±)E=E-E,/2-E/2=-SAKJImolpdY-8.41___i_*=01.987X1
7323333=
675x,“ᡠC60࠷Ḅᑖ»50CḄ0.675¼஺E᝞ᦋᐝEF!ᵫ½Ed=0,᳛Rp³ÀᙳᔠḄᐵÂB⊤Ä¢ᓄ£EᙳMEp—⁚,ᑖᓄÅÆHᔠ᳛ᓄÅÆÇÈ஺ᵫ50࠷ᑮ60࠷k5-s??J__L2_1.987x10-3323333=]36Éᔠ®Ê50Cᑮ60࠷,ᔠ᳛³ÀᙳᑖḆ50࠷Ḅ1.36¼஺43.ÌAᓫ2ᙠ60CᵨÏᵫÐEFᑺIÒÓÔEFÕ2ᔠ!ÊqÖr×CØᦪK:[A]=8.3mol/1Rxl03(mol/(l-s))PXn0.005083500.01055500.02033300.05013170.105920.15358EFᑺḄ-34{ᔲ⌕¶᝞p⌕!¬MßcàrCtḄ&'஺)**ã=k2,R,P+c”+G''পX.k2[M]2M'[M]pCãäå!᝞pBæ1çèé⚗Cêᶍ!ᑣᡠ×íîḄïðC“!ᵫñ᳛ò×X”

48k_%᪷K⚪ô×CØᦪK:Rxl05mol/(l-s))XxlO4PXn0.51.21.01.82.03.05.07.610.016.915.027.93õå3-2×ö!æ÷0.02x10-3஻“"/æ/.Sç!1HR.ᕈíîᐵÂ!ñ᳛X”-k,--=12,ᦑH=0.0348.ïðk2m2kU2ppC=0.6x1O~4Mw=4.0X10T[/]"2(2)1/2kᵫæ1çB×ü[M]=4.0X10Y஺f=0.0348[஻]=8.3ᐭfk=1.9X10-65-1dᑺ0.0025mol/lᑺ!"ᶍ$%&I()!ᑏᡂ,-.)1kjR»kR
==,+C,,+C,°——X.k_[M]2'k_fk[M^tdᦋᑏD_]1_8τCAR஺c[X.M\Rk2[M]2k2fk[M]3Pppd,X-C,ஹ:;<=>?@ḄB᳛DG
ᐭᳫQ2ᙽcd[3஺FGw/H”,ᓻK[L,ᑣ!>Na஺44.PQᵨSTᑺUVW᳛RiKᦔ᳛fḄ\]஺^_ᙠTᔠbcdeᐭSTᑺTᔠfNghij஺hij&t(ḄlmKnᵫpqᡂW᳛KS

49Tᑺrsᙠ,-ᐵc__஻uSTᑺvT—w:)dnyK1zSTᑺᑖ|}<ᵨḄnᵫpḄᦪ஺ᵨhij\]UVW᳛ᡠᵨḄSTᑺynᵫpᣓᣍᑺnyFGḄ᝞DPPH(ppj)Ḅn=LDPPHD⁐nᵫpᡂK⁐!ᵨ⁐]UV஺UV¡¢£¤ḄSTᑺeᑮTᔠbcdUNTo,T;uSTᑺv<=ᵫᡠ?@ḄB᳛ᓽ!>◀஺©᪷«ᑺᑖ^W᳛ᦪᵫ-)>Nf.RJ2kdiI=f45.¬(M)ᙠᵬ(S)d±Tᔠ(100࠷),¢³-´µᓄ᳛-U᝞-ᦪ«:[S]/[M]XnxlO-303.351.62101.14150.80200.65(1)»>¼-½ᑺᵬḄC3(2)⌕ᑴÀᙳTᔠDḄT¬DÂÃÄ^_*ᵫ´±Tᔠ1k2[M]2'CM'CS[M]P1kRÆ)ÇÈ==_P,+C”Ê⚗ÌK!,Íᡂy½ᑺḄÀᙳTᔠḄ᎔ᦪ:ÏᵨX"k~
MP-=—⊤Ò஺,:=—";<=!>NCஹ=6.18x10'(X")o(X“)o[S]/[M]Q/×030.3560.71087.7ᓃফ2Ú153.8⌕ÛᑴTᔠD2.1X10'ḄT¬ᐸÝ!ᢥ-)$ß:

5011+6.18x10-5[S]21003100[M][S]/[M]=2.80àáâã|Tᔠ-ä⚪1.»æᓫbᑺTᔠ\]èḄᱯêÆ\☢;nᵫp▢ã|K□ã|Tᔠîïð஺^_ñòónᵫpTᔠ□ã|Tᔠ▢ã|Tᔠð⚗ᓫbôᨵᔾᵯ|¡pḄ¬ôᨵýᵯ|¡pḄ¬ᨵᔾᵯ
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ᓫᐳᓫKùúqᐳüḄᓫbþÿ
ᩖᓄᔠᱥ
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01⊤6(ᓄ78ᜧ8:8:;<ᑺ7!"#ᵫ
ᡈ>(ឋ&᪶%ᑺ&ᵯ%ᑺ/?ᡂABC᪀Ḅ%ᑺ<ᔠEF2GHIJKLᡈML,-.HKL,-.HKL<ᔠNOPQ8R8S8S<ᔠᱥᑖT><ᔠUᑖT><ᔠUVYᐵᑖT><ᔠUVYᐵᑖTZ<ᔠUV[\VᐵX]^ᜧKᑺ_`ḄababNOcQdabe<ᔠNOcQ<ᔠᱥC᪀ᙳᨵgᜧab<ᔠᱥC᪀2.hiᑡᓫᑺklᓛn஺pq<ᔠNO_`rᑏtNO3஺ᓫuCH2=CHC6H5CH=C(CN)22ফ

51CH=C(CH)232(4)CH?=CHO(n-C4H9)CH=CHC12CH=C(CH)COOCH(6)233ᑺuপ(C6H5co2)2(CH)COOH+Fe2+33ফNa-ⅉব(4)JBF3+H2O:CH2—CHC6H5{|ᑺ(if)<ᔠ(1)(2)C(CN)2{|ᑺবম<ᔠCH—C(CN)2{|ᑺ(4)<ᔠ(3)2CH2=CH0(n-C4H9){|ᑺ(4)<ᔠ(4)CH—CHC1{|ᑺপফ<ᔠ(5)2CH2=C(CH3)8࠷H3{|ᑺপஹQ)ஹবஹম<ᔠ஺(6)ᨵᐵNO3᝞i:CH=CHCH(1)265জCH2=CHC6H5+(C6H5co2)2u#ᵫ
<ᔠC6H5co2)2——►2CHCO-652C6H5c+CH2=CHC6H5——►C6H5cO2CH2dHe6H5ঝCHᡝCHC+NTu▢<ᔠ

522Na+UHCH2——►Na+CHCH2CH2UHNa+C6H5C6H5C6H5ঞCH2=CHC6H5+BF3+H2஺u□<ᔠBF3+H2O-AH+(BF3OH)-CH2=CHC6H5+H+(BF3OH)-——►CH3C+H(BF3OH)'C6H5টCH2=CHC°6H5+n-C஺6H9Liu0▢᝞7<,ᔠCH2=CHC6H5+n-C6H9Li——►n-C4H9CH2CHLi+C6H5CH2=C(CN)2ফজCH2=C(CN)2+n-Na—᜼u▢<ᔠ•+Na+C(CN)2dH2CH2=C(CN)2+ঝCH2=C(CN)2+n0H9Liu▢<ᔠCH2=C(CN)2+n-C4H9Li——►11-C4H9—CH2—C(CN)2Li+CH2=C(CH3)2CH2=C(CH3)2+(BF3H2O)u□<ᔠBF3+H2O—►^(BFsOH)-CH2=C(CH3)2+H+(BF3OH):——►CH3C+(CH3)2(BF3OH)-ভCH2=CH0(n-C4H9)CH2=CHO(n-C4H9)+(BF3+H2O)u□<ᔠ

53BF+HO-►H+(BFOH)-323CH2=CHO—n-CH9+H+(BFOH)u——►CHC+H(BFOH)'4333O(nC4H9)CH)=CHC1মজCH2=CHCI+GH5CO2)2u#ᵫ
<ᔠ(C6H5co2)2—►2CHCO.652oII.CH=CHC1+C6H5co-------►C6H5co2cH2cHe12cCH=CHC1+[(CH)COOH+Fe2+]{&/ᵪ╃33ঝ~u#ᵫ
<ᔠ(CH)COOH+Fe2+——►(CH)CO.+OH-+Fe3+3333CH=CHC1+(CH)CO-------►(CH)COCHCHC1233332CH=C(CH)COOCH233(6)CH=C(CH)COOCH3(CHCO)#ᵫ
<ᔠ(D23+6522u(C6H5co2)2ߟ►2c6H5c஺2.(CH)CO-+CH=C(CH)COOCH------►(CH)COCHCCH33233332COOCH3ঞCH2=C(CH3)COOCH3+Na-ⅉu▢<ᔠNa++CH2=C(CH3)C00CH3ANa+C(CH)CH+32COOCH32Na+C(CH3)CH2»Na+C(CH3)CH2cH2c@3)¦IIICOOCHCOOCH3COOCH33CH=C(CH)COOCHn-CHLi▢<ᔠ@233+49uCH2=C(CH)COOCH+n-CH9Li——►n-C4H9cH2c(CH3)Li+334COOCH3

543.ᙠ<ᔠNO©ª*7ᔲt¬#®cᦔO°.±²°uᙠ<ᔠNO©ª*d³t¬#®c¬´஺#ᵫ
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55ẚº6ᑺ»ឋᜫ஺P½ᡠᵨᑺᓫ#¾p±=ᔠ¢ᘤ¿ÀEFÁ¤ᓄ!¦§஺=ᔠ$¿Àᙠ®ᩩ°)EF஺ᔲᑣÅÆ=ᔠᜫÇ஺8.ᑏÊpËᵬÌ9ᑺpSnC)96ᑺḄÐÑÒ=ᔠ$Óᳮ஺+Ẇ,CH3Cl+SnCl4—►CH3(SnCl5)-O:YÖI6:CH+I3CH(SnCl)-+CH=C(CH)2——►CHCHC+(SnCl)-3523325CH3CHCHCH333CHCHC+(SnCl)-+nCH=C(CH)——►CH-ECHCH-CHC+(SnCl)-3252323225…CHCHCHYÚ333333Y(1)ᔣᓫ#Z[(ÜÝY)CHI_►^CHC(CH)=CH3232…CH—C+(SnCl)'+nCH=C(CH)—+(CH)C+(SnCly25232335CHI-----------CHCH(CH)+3232CHZ=C(CH)C+H(SnCl)-325(2)6Y(ÜÝY)CH3…CH—C+(SnCl):-----►…CH2c(CH3)=CH+H+(SnCl)-2525CH3(3)
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YZ[ᑺᡈᑺ$*CH3“CH—C+(SnCl)'+AB------►…CHC(CH)B+A+(SnC15)'25232CH3
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56□=ᔠ᧕6VW᣸$஺W᣸$]ᵯ0ᡈýḄZ[EF஺W᣸$ḄþÜᜫ*ឋÿ
ᔣᡂ᪀஺□ឋᜫ□ீ□ீ□஺᝞ᙠ3ᵬ1!"Ḅ$ᔠ&'((*ᓄᑺ-AlCh,.ᑺ-/01)34ᨵ□6᪀ᓄ-□Ḅ789ᡠᨵ$ᔠ;ᱥ=ᨵ>?᪀ᓫᐗᓽCH3—CH2cH——CH2cH2c—CH(CH3)2FCH310.ᑏI4-ᵬ1—J"F3—01—J"ᙠLMNOP$ᔠQᡠR$ᔠᱥḄ᪀ᓫᐗ஺S4ᵬ1J"Ḅ$ᔠᱥᨵTPU?᪀ᓫᐗCH3I—CH2cH——CH2cH2cH——CH2cH2cH2dH—CHCH(CH)2CH(CH)CH3323301—J"Ḅ$ᔠᱥᨵTP>?᪀ᓫᐗCH2cH3—CHCH——CH2cH2c—2CH(CH2cH3)CH2cH3$ᔠᱥNOWM96᪀ᓄ᪀ᓫᐗḄ=XWY஺Z-NOWM9[\]ᓫ^Ḅ_OW`,Zbcde[6᪀ᓄḄfgឋ஺11.Th⏚-jkᑺ9lm0"ᙠnឋ.ᑺ($ᔠ஺᝞opcq78_᳛sᦪ஽0=7.6//(஻?஻s),wkpxy_᳛sᦪz=4.9x1CT?/$,ᔣᓫ^p|}Ḅ_᳛sᦪk,=1.2x1s),rM78^~(Ḅᓫ^O-200g/l஺$ᔠᡂ$m0"ḄᑖX஺Skp=7.61/(mol•s),[M]=200g/l=1.92mol/IZr=4.9x102/s,k=1,2x101//(mol•5)(lrMZᵨḄnឋ.ᑺ9ᦑᔣ.ᑺḄp|}஺$ᔠᱥᡂḄ$m0"ḄᑖX9f᪷14.9x10-2/S1.2xl0-l//(mo/-5)X7.6//(mol•.V)X1.92mol/17.61(mol-s)X=52.22M='Xm=52.22x104.14=5438=5.44x103R$ᔠᡂḄ$m0"ḄᑖX-5.44xlO3o12.ᙠᩩP6!"$ᔠTᔣᓫ^|}-⌕xy9ᡠR$ᔠᱥ-⛳F஺ᨵ

574g$6!"9fាl6mlO-O.Olmol/IḄ/ᓄ.⁐஺$6!"ḄᑖX஺CHCH3.,A/vv,CH?—C=CH?+Br?-------►CH2c
BrCH,BrS᪷T¢789£¤$6!"ᑖp¥ὑᑖ§஺$6!"-4g¨¥ὑḄX-0.01©஺/,,,,-5,n------------x6ml=6x10'mol1000mlᡠT$ᔠᱥḄᦪᙳᑖX¬-4Mn—=6.7xl046x10-513.ᙠᩩPl6!"\□$ᔠ9᝞opxyTᔣᓫ^F|}ᑺ|}-9ᓫ^O-2moi/I,p|}ᑺOᑖ®0.2mol/L04moi/I,0.6mol/l,0.8mol/loᡠR$ᔠᱥḄ$ᔠO¯°25.34,16.01,11.70,9.20஺±ᵨ²³´ᓫ^Fp|}Ḅ|}sᦪC”F஺S*ᓫ^ḄO[M]=2mol/1¨p|}ᑺḄO³=0.2ஹ0.4ஹ0.6ஹ0.8mol/l¨$ᔠᱥḄ$ᔠO·i=25.34ஹ16.01ஹll.70920¨᪷1/3=C,“+C.s[S]/[M],T1/9¸²³¹³4-1஺ᡠRº»Ḅ¼½-¾9¿᳛-C஺sC”-¼½9=1.6x10-2¨C5-¿᳛9=a/b=2.3X10T஺À[M](mol/1)[S](mol/1)S/MXÁ120.20.125.340.0395220.40.216.010.0625320.60.311.700.0855420.80.49.200.108714.Â᪵ᔠᡂḄ$ᵬÄÅᑏI$ᔠ78&'஺SÆÇ¢ÈlU$ᵬÄᙠBF3FÉXÊḄ²ᵨË\ÌÍ$ᔠᩭᔠᡂ$ᵬÄ஺ᵬÄḄT¹$ᔠ¢▲NOÐLM9$ᵬÄ᧕kS$78஺Ò᪵Ḅ$ᵬÄÓᵨÔÕ஺Ösᵨ⏚×ØÙឋÚÛÄ|ᓄÉÙÜḄÝ9T■yS$஺ß&à┝ᢈãᜐᳮ&Ḅ$ᵬÄឋ9ᓽlᙠTNOT¢9æçS$஺P☢-ᔠᡂ$ᵬÄÓḄ78&'pjk

58HO+BF——AH+(BFOH)-233O—\ீO+H+(BFOH)-3AHOCHOCHOCH2(BFOH)'223O-IpcqOHCHOCHOCH(BF3OH)-n(°2¨O^HO^CHO^CH^BFOH)-222+23pxyOH^CH,0?2H2(BF3OH)-+H2஺OH-pH2Cg-CHOH+H+(BFOH)"23é3n+2à┝+OHFCH2ëCH2OH+2(CH3co)2஺^CH3coOfCH2▕CH2OOCOCH3+2CH3coOH1-é3n+2Lé3n+215.ðñ▢$ᔠḄjkᑺ¸ᓫ^Ḅjkᨵ⌱ôឋ9õᑨ÷Fᑡjkᑺgjkùúᓫ^$ᔠ?jkᑺপn-C4H90KফLi-ⅉ9বs-C4H9Li,ভHOমEtN23Li-pH2cH=CHCHLi(6)RMgX,(7)ᓫপCH2=CHCN,ফCH2=CHCH2cH3বCH2=CHCH=CH2,ভCH2=CHC6H5মCH=CHNOCH=C
CHCH=CH226232CH=CHCHCOOCH233▢ᔠᑺᓫḄᨵ⌱ឋ!ឋᜧḄᑺ#$%&'!ឋᜧᡈ)Ḅᓫᙳ+!ឋ)Ḅᑺ#$,-#./ᓫᓽ!ឋ)Ḅᓫ஺n-C4HQK#C%=CHCN2CH=CHNO22Li-FCHCH=CHCH^Li2Li-ⅉஹs-C4H9Li54#67Ḅᡠᨵᓫ%஺2Et3N#CH2=CHNO2஺RMgX#CH2=CHCNஹCH=CHNO2CH2=CH(CH3)COOCH322

5916.=RK@ᑺᔠᡂ=BCDᐳᱥGᧇIJ᝞LMmN%Pm(1)QRᔢFAN,(2)᧼UH2cH2Y(3)Z[Edᜧ"-mSqpᙠᔠᡂCDᐳᱥde✌ᐜᔠᡂpkdijᜧḄᓫḄ“.Ḅ”ᔠᱥᯠnGᐭp%ij)Ḅᓫpqᔠ஺ᔲᑣtuvᑮCDᐳᱥ஺ᔠᡂᔠᱥ1de✌ᐜᔠᡂxyz.ឋᔠᱥᯠnGᐭMMApqᔠ஺ᔠᡂᔠᱥ2✌ᐜᔠᡂ.ឋ}~zᯠnGᐭxyz஺xyzᔠnGᐭzᨴ☘pqᔠ஺ᔠᡂᔠᱥ3✌ᐜᔠᡂ.ឋ}~zᯠnGᐭ~pqᔠ஺17.L@.ឋᔠᱥMM@▢ᔠ+@.ឋᔠM.ឋᔠᱥᢣᙠ.ឋᑮᓫᐰὑᢝ.ឋḄᔠᱥGᐭᓫ+=ᔠᔠᱥḄᑖG஺ᙠ▢ᔠ¡¢£ᵯ₹Ḅ.ឋv#¦§¨©ª.ឋ«¬Ḅ@®¯°v±²³´µv#¶·Ḅ¸¹±ᡈ4°©ª.ឋ»¼ῃ¾H+¦©ªÀÁÂÃᡠ=ÄÅ&ÆÇÈᡈ©ªḄᩖÊË▭Í&©ªᔠᓽ.ឋᔠ஺18.ᑏ7ᵨ▢ᔠÑÒᔠᡂÓÔv£Õ¨´OH,—COOH,-SH2´NH2Ḅxyz⍩ÛᔠᱥḄ¼Ü஺ᐜᔠᡂxyz¨§┞ᯠnpqÞv£Ḅßᑺà+uᑮ¢Õ¨Ḅ⍩Ûᔠᱥá᝞

60nCHCH=CHCH22Li+CH2cH=CHCH2cH2cH=CHCHLi.2Li+CH2cH=CHCH2BH2cH=CHCHafH2cH=CHCH2U+Li+CH25cH2U++2cH2—CH2——►Li+OCHCHCH2^CHCHCHOLi+22222পoHOCH2cH2cH23CH2cH2cH2OH+2Li+2-Li+CH^CHLi++2CO—►Li+OOCCH^CH2coOLiᓱ22222HaHOOCCH2/CH2co0H+2Li+Li+CH^CHLi++2CH—CH—►Li+SCHCHCH^CHCHCHSLi+2222222222s
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62ᡠ`ᔠᱥḄᑖ/¨ᑖ©ᢣᦪ~“./Ã:0.1(MQI2+0.1(M7)2M=0.~*+0.1ÎwM0.1MÏ+OAMm-n0.223.`e⏣ᵬgᑺ`BuLiabᑺjeᔠabᑺEᑖi*4.00x10^01/1,l.OOxlO^mol/l,4.45x10^01/1,2.60^10'5mol/l.à´Ḅᔠ⊤â᳛äᦪ2.22x103V(mol.s),4.24x103V(mol.s),6.25xl03l/(mol.s),8.12xl03l/(mol.s)»᝞éᵯ9¹⊝äᦪKd=2.4xl0-7mol/Lᵨqîïð=+,᳛äᦪ஺)**µ¶abᑺḄE
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þ)஺Kp*103(l/(mos*s))!ᑺ#(mol/1)1/!ᑺ#஽i/(mol/l&12.224*i(r*5024.241*10"10036.254.45*10+15048.122.6*10-5196ᵫî´k(ÿ
=2.10102l/(mos)᳛=a/b=K?'2k()k(0)=a/bKd"2=8.22*104l/(mol*s)24.2BuLi6!ᑺ789:6;ᑺ7ᔠᡂ>?@ABᐳDᱥSBS஺ᓫIJKL150g஺BuLi89:;NḄPQ60.4mol/l஺ᓫIḄRᓄ᳛6100%஺UVᐳDᱥḄWᡂ(X7YZ)6S/B=40/60([KZ)7ᑖ]K6”1()5஺_`a◤YcdeXfdᔜhij7◤BuLi;NhikᓣmnopqoBuLi(89:);NḄPQ=0.4mol/LᓫIJK=150gᐳDᱥḄYஹXZ=60/40ᐳDᱥḄᑖ]K=1஺5ᡠ2◤⌕ḄBdK=150gx60/100=90g◤⌕ḄStK=150gx40/100=60g◤⌕ḄBuLi;NK=3.75ml25.ᢣyzᑡᓄᔠᱥj|}~?ḄDᔠ஺(1)ᔬᗏ(2)20ᵬᔬᗏ(3)1,40c8(4)@8(5)0Yᑁ(6)8f:no(1)ᔬᗏo|}□]?Dᔠ(2)2-ᵬᔬᗏoDᔠ(3)1,4-c8oDᔠ

634@8o|}□]Dᔠ5V-YᑁoDᔠ68f:o|}▢ஹ□]DᔠDᔠ0ஹ⚪1.⌕n¡0zᭆ£e¤¥o1Dᔠe¦ᐭDᔠ2ᨵ©ª᪀Dᔠeª᪀⌱Dᔠ3®ᔣDᔠeZiegler-NattaDᔠ4ᐝ´µ᪀ஹ¶·µ᪀e᪀¸µ᪀5¹᪗»¼6ᐰ¾Dᔠᢣᦪnozᑡᭆ£e¤¥ḄÀÁLo1DᔠLᢣᓫIᑖ]✌ᐜᙠÅឋÇḄÈᜐ7ÊᡂËÌÊÍo-ᐔḄÏᔠᱥ஺ÐÑᓫIᑖ]¦ᐭÒÓÔÕMt-×CÙÚÛÜÊᡂᜧᑖ]ḄÒÞ஺ßÇDᔠàáâLᓫIãäÛÜMt-RÙḄ¦ᐭ7ᡠ2æçè¦ᐭDᔠInsertionPolymerization,2ᨵ©ª᪀Dᔠ஺ᢥ᯿IUPACò▭ôõöᵨᓄ´ὶᔠùḄ©®7ᨵ©ª᪀DᔠLᢣÊᡂᨵ©ª᪀Dᔠᱥ6úḄDᔠÒÞ஺ûüý·DᔠÒÞᒹÿᵫஹ▢ஹ□ᡈᔠᡈᔠ᝞ஹஹᔠḄ⌕!"#$ᡂᨵ'(᪀ᔠᱥ+,-"ᨵ'(᪀ᔠ஺/01ᑺ34ᐜ⌱789:᧜<ᐭᔠᱥ>Ḅᔠ?@ᑣB+(᪀⌱7ᔠStereo-SelectivePolymerization3Uᔣᔠᨵ'(᪀ᔠ"WXYZὅ-"ᢣ$ᡂᨵ'(᪀ᔠᱥ+,Ḅᔠ]^஺Ziegler-Nattaᔠbc"ᢣdᵨZiegler-Nattaf01ᑺḄᓫḄᔠᡈhᐹᡠkᔠᱥl#mᨵ'(᪀ᔠnol#"p'ᔠᱥ஺!qc"ᔠrs8U-"Uᔣᔠ஺4ᑖvwWr"xywὶ{Ḅv|}sWᡈxᙠḄ᣸vsWḄᓄᔠᱥ᪀஺᪀ᨵ8"{᪀sW/⌼ᡂḄ᪀{᪀᪀ᡈBWᑖ᪀Z"xᡈxḄ(᣸sW/Ḅ᪀B+(᪀஺᪷(᪀ḄsW(᪀ᑖ+ᐝ᪀ᓽᑖᨵឋxmᱥᐸ¡s3¢ᔠ£/m¤ᨵsWḄ¥ᐝឋ¦9᣸sWḄ:᧜ᡂ+ᐝ᪀§¨᪀ᡈB|ஹ?᪀"ᢣᑖ©ᙠª«ᡈ¬m®xᙠḄ¯sW£/({᪀sW§ᐝ᪀¨᪀ᙳ+᪀f᪀஺◀²ᓄ«³´¦9᪀f"s3wyµᓄḄ஺᪀¡᪀¶·ᓫ«¥µ/¸¹ḄᑖᙠsWḄ᣸ᑡ$v᪀஺ᵫᓫ«ᑁ¥µ⌼ᡂḄ(᪀᪀¼᪀஺᪀f8᪵᪀¼o"⊤¿ᑖxᙠḄ᣸$vsWḄ"᪀¼l#b]ᓫ«ᑁḄ¥µ/ywµÀ஺ᔜ9᪀8Âs3ᑖÃᩭrŶ·ᓫ«Ḅ¥µÆÇÈol#ᑖ஺5᪷IUPACÎÏḄÐÑᐝ᪀Ḅ:᧜᪀fᵨRÓᡈSÔ⊤¿஺ᓽÕឋÖ᝞ឋ×ᕜ¶ḄÙÚxᡈxaஹbஹcஹd,ᢥ᯿à}'ᑣḄ|}ᓽᵫaib—cid᣸ᑡᎷUãäὅdḄ:☢æa-b-c"|È┐ᔣ᣸ᑡᡈèឋ×xéêëìᔣídᙠᔣíḄîᩚðᐸñòÚxaஹbஹcᙠᔣíðᕈa-b-c|È┐᣸ᑡ¦8᪀fôᵨR⊤¿§æa-b-c"?È┐᣸ᑡᑣ᪀fô+S஺ឋ×Ḅðõ⊤¿B+}¥᪗÷஺6ᐰWᔠᢣᦪû89(᪀'᦮ýḄ⊤¿!"ᢣᐰW(᪀ᔠᱥᓰÿᔠᐰ᪀+Ḅᑖᦪ஺*2.ᑡᓫᔲᔠ᝞ᑏ"#$%ᑺ'(᪀᦮ᔠᱥḄ+᪀஺

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40%஺ᐳᵫn2ᜧ⌕ᢝᐳᱥᡂᙠ"#$%Ḅ(ᑁ*+,-./0ᑴ2ᓄ᳛(640%)஺8᪵:ᨵᜧ<Ḅ"=>?⌕@ᦈBᵨDEFGᢗᐭḄ

77(2)-fᐳghi2.5j0.5(),2=0.4j0.1(f)lm52=1Ḅᳮoᐳgh஺⌕ᑮF]=0.98Ḅᐳᱥf,=0.952ᓽr஺ᢥt☢Ḅvw
᝞yᐕ{F1ᙠ0.98-0.96|}~ᓄRḄ6rᙠ0.95-0.90|}~ᓄ8QRḄ2ᓄ᳛r70%,᝞yᙠQR〉⊡ᐙ"2ᓄ᳛r0ᑴ஺8"ᐳQR@ᦈᓫg1,r>>ᦑᑮḄᐳᱥMiÂìM2Âìí,ᙠ{KM1îïḄíÂtᨵ1-2#M2ᓫgᓫᐗᓽM(M]M)M]M2M)M]M[M]M|M).......MiMiM2M௃M|(2)n=0.9r=0,ñòᓫgM2»óᐳóôᡠᐳᱥᡂ(1)ḄËõöᓽᙠ÷2ø#M]ÂìPᐭ"#MᓫgÂ⁚...M]M]M௃M|M2MlM1MiMiMi........212.ᓫgḄû᳛é20,9=0.5஺᝞ᓄ=0.5,2ᓄ᳛C=50%,üᐳᱥḄýᙳᡂ஺º§2ᓄ᳛>10%,»óᵨþᑖÿ
஺Ao—c=l-(4°(/°)'(4^7)‘fl-Oὡ=[°(1-஺)/஺(1)01=T2/(1H2)=1,Of/(1)=-2y=(l-rir)/(l-ri)(l-r)=0,8=(1-r2)/(2-rr2)=-l22ry=0ᡠ(-3)/(ᳫয=1ᦑ(1)ᓄC=l-(f/f°)/(f2/f2())-21l!"#$ᐭ(3)&'(F)=0.62

7813.,-⌕/0ᐳ2ᱥᑖ56&7ᑡஹ7ᑡ:;<7ᑡᑖ=Ḅ?@஺AB7ᑡCᢣᐳ2ᱥᜧᑖ5&ᔜᓫHᓫᐗḄ᣸ᑡK7஺7ᑡ:;Lᵫ•OᓫHᓫᐗPᡂḄ6RḄ:;஺ST:;ḄᔜO7ᑡUVḄWXYZᡂᐳ2ᱥḄ7ᑡᑖ=஺᪷\ᭆ᳛Ḅ_`ab7ᑡᑖ=cᦪ஺᝞&fᡂ?ᨵniMlᓫHᓫᐗḄ7ᑡḄl᳛(PMI)n=Pu"l(l-Pu)ᐸPu=Ru/(Ru+Ri2)LM|.fᡂMM2.Ḅl᳛(l-Pu)=P12=R12/(Rll+R|2)LM|.fᡂM1M2.Ḅl᳛R11

79Ni=l/(l-Pn),N=l/(l-P22)MM2
¨©᝞«fl0.8290.7430.5510.49NMI2.261.721.321.25NM21.211.371.832.0615.᪷\«ᔜᐳ2HCḄᓫH³2᳛&´µᐳ2HCḄ¶ᓫHᙳ᥅¸Yᢗᧇ&º»¼ᙠ¾¿ᓄ᳛«ᡠ(ᐳ2ᱥPᡂ<ᐳ2ᱥ¶ᓫHᓫᐗḄ7ᑡᑖ=ÀÁ஺7ÂMiM2hÄ21Å4.50.22Æ⏚1.071.083ᵬÉÊJW0.250.254Æ⏚Íᩭ⏚Ï0.0550.0035Ð9.02.0AB(1)Å-ᐳ2HCḄᐳ2ᱥPᡂÑÒᕈÔÕḄÖf஺f10.5ᜐÑÒØXÙÒÅÚᨬÜ஺ÅÝឋᓫH&ᦑᐳ2ᱥÅ?ßà℉ᜧâ&F=0.821tᐳ2ᱥ¶ᓫHᓫᐗᕈåæᑖ=&çM)Ḅ¡ᙳ7ᑡ:;¼àᜧâM,Ḅ¡ᙳ7ᑡ:;஺(2)-Æ⏚è2HCḄᐳ2ᱥPᡂÑÒléêLXÙÒ஺ᐳ2ᱥPᡂØᢗᧇPᡂW&Fi=0.5஺ᐳ2ᱥ¶ᓫHᓫᐗᕈåëᑖ=&çᨵìíḄîïឋ&¶ᓫHḄ¡ᙳ7ᑡ:;ðWñ஺(3)ᵫâ-ᵬÉÊòᐳ2HCḄó<_ᙳôâ1,ᐸឤYöPᡂ(f|)A=(l-r2)/(2-rE),ùúLû⚪ᢗᧇPᡂ&ᡠᐳ2ᱥPᡂðØᢗᧇPᡂWT&F1=0.5,ᐳ2ᱥ¶ᓫHᓫᐗᕈåëᑖ=&çᨵìíḄîïឋ஺¶ᓫHḄ¡ᙳ7ᑡ:;ðWñ஺(4)Æ⏚-Íᩭ⏚⏥ᐳ2HCḄᐳ2ᱥPᡂÑÒléLþÿB=0.5xḄ஺ᐳᱥᡂᓫᡂK=0.5,ᐳᱥᓫᓫᐗᕈᑖ!஺(5)ᵫ%&'(-*+(ᐳ,ᓫᔜ.Ḅᙳ0123ᐳ01456ᔠᡂ89Ḅᐳᱥ஺:0;ᑮ=>ᐳᱥᡈ@AᙳᱥḄBᔠᱥ஺᝞D0;ᑮᐳᱥᑣF0@MiIM2ᙳKᑡM2NMḄ=>ᐳᱥ஺16.ᑖQRS72ஹ53ḄAᓫWᐳXYᦪ[᝞\]ᓫ[M]](wt%)ᐳᔠd[M]](wt%)2025.52530.55059.56069.57078.68086.4hᵨj᧕l(FinemanandRossl),urlxr2«z]*✌ᐜ~Rᑖᦪᣚᡂ᥅ᑖᦪ[M)]=Mi(wt%)/72,[M]=1-M,(wt%)/532ᡠ;ᦪ[᝞\[MJ0.2770.3470.6940.8330.9721.11[M]1.511.4150.9430.7550.5660.372

80d[M]]0.3540.4240.8260.9651.0921.2d[M]1.4061.3110.7640.5750.4040.2572p=d[M|]/[M2],R=[M]]/[M2],Iᐳd[M]/[M]=[M]/[M]*(r[M]+[M])/(r[M]+[M])l21211222lF;R(1-p)/p=r2-rτR2/pR(l-p)pR2/pFu;ḄnI᳛r”ᱏ1.74r=0.84,2ᡠ;ᦪ[᝞\R(l-p)p-'0.5460.514-0.055-0.446-1.081-2.313R2/p0.1330.1880.5010.7281.0921.85617.*+((MJIᵬ(⏚ᵬ(M2)W.ᵫᐳ30%Ḅᦈ᳛ᐳᱥ¡R¢RS£¤ᓫ¥hᵨ¦ᑖlu§I஺z]*᪷[¦ᑖ©ª1gW«):s1-¬◍]஺/®]஺2«"]஺°1-PM"]ª[M±ஹ[M2]o²³ᐭᓫ¥[MI]ஹ[MRSµ£¤Ḅᓫ¥P=(l-r,)/(l-r)2¶·ḄP¸¹ᐭ(1)ªuº»¹ᐭ(2)ªun¼½;ᑮ«ri0¾¶3-4¿P¸u3-4nn¸;«஺ᵫÀᓫ¥F;ÀᩩᙠᐸÄÅᑁ«ᨬÈÉᓽ;¤Ḅ1ஹr»2ᡠ;ᦪ[Ë[M,]O/[M2]O[M)]/[M2][MJg/tM1][M2]O/[M2]14.1024.83641.51131.781820.9920.98511.50911.498530.25470.20071.95191.5386\জঝঞr\Ër2r\r2r\r2A0.4-0.46290.41480.94460.97780.53620.81450.60.20450.52270.91980.95190.52120.71280.80.45360.56290.84900.84900.50540.59570.90.52730.57460.73170.75850.49700.54731.00.58370.58370.48830.4883hSÐᙶ᪗2SÓᙶ᪗;Àᩩ1ஹ2I3,ÔÕḄÉÖᡂ«¿À×Ø஺¼À×Ø×ᑖḄÉ(ᑁᑗᙊḄᙊÛ)ᓽ;¤Ḅnஹr2ri=0.55,r=0.522

8118.ᓫM|IM2Wᐳ,50࠷n=4.4,º=0.12,Þßà:(1)᝞Dᓫ᩽ឋä·ᜧæçᦔ¤Ḅéê®·ë℉íî¹Ḅᐳïᦔ¤ð¿ᜧñÞzòó஺(2)ôõöᡂḄᐳᱥ᥅ᡂMiIM2ᔜᓰ50%,øùõᓫᡂ@úûñz:পᵫr¬QiQ*eT@v2)r=Q/Qi*e-e2(e2-el)22C|-e2)*'i=4-4,r2=:0.12QI>Q2ᓽM,Ḅᐳ᪋ᦔᜧফᵫd[M]/d[M]=[M]/[M]*(r[M]+[M])/(r[M]+[Mi])121211222[MI]/[M2]=0.165ᓽf,=0.14219.*+ஹ-ᑺ/0ᵫ1ᐳ2Ḅ32᳛ᨵ6789:ᑘᙠᐳ2=>?ᨵ@Aᓄ9/CDᐳ2Ḅ32᳛Eᨵ6789F32᳛G*+ḄᐵIJKdlnr/dT=(E-Ei)/RT21u2EuQE12ᑖSK0TUQᐳ2TUḄVᓄWXᙳZ[:X\]^ᑣ`:஺ᐸcde*+Aᓄ/32᳛Ḅ78fᜧXg*+TᜧXr^hi1஺-ᑺ᩽ឋ/32᳛lᨵ78X◤⌕opqrsturvXᐸAᓄḄᦪsxyK3*10{2—5*10-2஺ᙠCDᐳ2?X*+/32᳛Ḅ78[ᜧXAᓄh~gQI\f஺-ᑺḄ-ᑺᓄWQ᩽ឋ78Vឋ?Ḅ᝱XᐸᑖSᜐiᐳ᝱ஹqCD/ஹCD/ᡈ0ᵫCD᝱஺\fḄVឋ/2ᔠ᳛ஹᱥᑖDs᪀᦮ឋᨵᜧḄ78஺20.32᳛Ḅᜧ:¡¢iᐳ2ᓫ/Ḅc᪀Xᐹu¥¦cᡂ¥¨©ª«☢(1)G¡®1Ḅᐳ¯°ᵨ²(2)¡®1Ḅ᩽ឋᦔ;(3)¡®1Ḅ´µ¶·஺F¸ᑨº¥»©«☢ᑖS¼½¾°ᵨ¿Xᓫ/Ḅc᪀XÀᔜÂ{ÃÄÅ¥Æ஺(1)ᙠ•ÈÉʨXG¡®1ḄᐳË°ᵨe78ᓫ32᳛Ḅ½⌕ÌÍ஺Îᓫ?ÏᨵW¼ᐳË°ᵨḄ¡®1¿Xu¥ᓫVÐ\Ñ0ᵫ1ÒÓ஺Ä᝞ᓫḄVឋÕÖQ×0ᵫ1ḄVឋÕÖ½⌕eᵫ¡®1Ḅᐳᦔ¢ÓḄ஺ᓽÙᓫḄ¡®1Ḅᐳ¯°ᵨÚÛ¿Z[Ü᧕ᐳ2²ÞßXàÙᓫḄ¡®1Ḅᐳᵐ°ᵨÚ]ᜧXᑣâᐳ2஺Ä᝞ãäåᵫiãæḄᐳç°ᵨÚÎVÐXÎèGᐳ°ᵨ:Ḅᓫé⏚äåᐳ2¿XᵫiÙVឋ]SᜧXr=55,r=0.01,ìWÑᡂt2ãäåᙳ2×?ᩖᨵ᩽îsé⏚äåᓫᐗḄᐳ2ᱥஹᡈðäåᐰòᙳ2ᔠXé⏚äåóôõᙳ2XcdᑮÙᙳ2ᱥḄ÷ᔠᱥ஺(2)᝞d¡®1ᨵ᩽øḄᔾᵯDᡈûᵯD°ᵨXᑣᨵᑭiGᐹÚÞ°ᵨ¡®1Ḅᓫôõᐳ2஺ýeÌKþÿ᩽
ᔾᡂḄ᝱஺᝞Ḅᵯ⏚ᨵᔾᵯḄ!ᦑ#$ᑮ&'ᐳ)ᱥ஺(3)./0!ᐹᨵ2ᜧḄ456ᑣᨵ89:;ᦔ=஺>?1,2:/089:;ᜧDEFGᙳ)IGJ89:;KḄᓫ4ᐳ)஺MஹOᐗ/0ḄQᓫ4ᐸ89:;ᜧS#ᙳ)TFGᐳ)஺

8221.ᙠVᵫ!ᐳ)ᔠY=ZḄ
[\ឋ^ᜧ_`⏚஺.`⏚ᙳ)6᝞abᐭdeᑣ`⏚FG)ᔠ஺fghijkDlmḄno஺gp*`⏚rḄᐳ)Y=ZsᙠGtOuvwxY᧜ᐸvwxz{|ᦪ᝞tTwwS+S1~]]—amwSS•k"=176l/(mol*s)vS+VAc——>,SVAc»ki2=3.2l/(mol*s)VAc.+VAc"2»TVWVAcVAc.k2=3700l/(mol*s)2k2i'/vwVAc*+S---A-AAA?VAcS*ki=370000l/(mol*s)2…VAc.᧕ᡂ-VAcS-᝞aVAcᓫ4Zbᐭde_k21»k22,ᡠGiVAcSᙠᡂiSVAc.ᑣ
.F஺4Zᜧᑖᓫ4?VAcᡠGdeḄsᙠᜧᜧ`⏚Ḅ)ᔠz{஺22.fQஹeᭆ᝞᪷Qஹeᩭᑨᓫ49Ḅᐳ)ឋ஺gpQஹeᭆ?ᢣᓫ4Ḅᐳᦔ=oQr᩽ឋᦔ=oeJᓫ4Ḅ)᳛
ᐵὶḄeᐵὶ¢஺£k¤PiQVeiej)(i,j=l,2)ᑣr¥ku/k|2=Qi/Q2*eT®8¦2=1<22&21=Q2/Ql*e"~"~""Q§ᜧ⊤©ᐳªᦔ=§ᜧT«?ᓫ4Vᵫ!§᧕஺e0⊤᩽ឋ¬ᔾᵯ/0!e஺Q,eJᓫ49Ḅᐳ)ឋᐵ᝞tA.Q
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±Ḅᓫ4[᧕ijᳮ³ᐳ)°C.e
®¯ᜧḄᓫ4[᧕ij&'ᐳ)஺23.ᵬ!µ⏚ᵬ¶ஹµ⏚ᵬ¶ஹஹ·ᩭ⏚ஹ`⏚ஹµ¸¹ᓫ4Jᐳ)fG&'ºᔣḄ¼½᣸ᑡÀᓫ4ÁÂÃno஺gp᪷rmÄ5ḄᜧKGᑨÅuᓫ4&'ᐳ)Ḅºᔣᓽr,r->0,Åᓫ4ij&'ᐳ2)r2rl§Ò±_0,&'ºᔣ§ᜧᔜᓫ4ÓÔÕஹrÖ×᝞tᓫ4hQ232ᵬ!µ⏚ᵬᾦ0.250.750.1875µ⏚ᵬᾦ0.050.760.0380.581.350.783·ᩭ⏚5.74*10-50.3251.86*1()J`⏚0.01338.450.499µÙ0.020.30.006À⊤Z·ᩭ⏚Çr`⏚ḄKÈᵫQஹeÉÊËÌ$ᓫ42஺Àᔜᓫ4J¥j&'ᐳ)Ḅ¼½p·ᩭ⏚⏊ுµᨴ☘ுµ⏚ᵬ¶ுᵬ!µ⏚ᵬ¶ு`⏚ு஺

83*24.ᑖÛᵨVᵫ!Ýஹ□ßÝஹ▢ßÝi4á(M1)rᵬ!µ⏚ᵬ¶(M2)ᐳ)ãäᓫ4åæ(fi)o=O.5,ᐳ)ᱥZF1Ḅîïᑡ_t⊤
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89ᓽᑁᐕ¢Ḅ£T⏥ᨬᜧ§¨©/86.66Pa10.ᑴ⌼ÅÆ66/1ÇᢝÉT⏚2ÉTḄ᥅ËÌcdᐜETὅᡂᯠÐ254cah34஺Ñ#$ᙠÒÓÔᘤahÖ#$aht×ÐØÙḄ-Na=2.510-1஺ᑏÛᡂÜݾÞßàᡠḄ34ᱥḄᙳ4ᔠO஺²wÅÆ66ḄáᡂHN(CH2)NH2+HO2C(CH2)4COH^^HN(CH)NH.HOC(CH)4COH2622262222i+HN+(CH)NH3263■OOC(CH)COO-24Z/34ᱥḄᙳ4ᔠOXnᙠÒÓÔᘤᑁn=n,zaXn=-1ߟ-V300=69.3=692.5x10-111.ᵬãäåæ#$ᑴ⌼çã᪛ᾦᡠᵨèéᩩëìíᧇïÌ᝞gwᵬã-ð(37%)2480g,åæ1133g,²O20-25C,ñ£⏣(80%)2g஺òópH=7.2-7.4஺34O98-102࠷஺ßàô34#$Ḅõö÷Þøùᔠᡂ#$Ḅø=ú⚗஺²w᪷ý⚪=ᡠᵨCH2஺Ḅ᥅Ëᦪ/35moiåæḄ᥅Ëᦪ/18.88molᢥCarothers
(Pc)Pc=2/f=0.77ᢥFlory
Pc=l/[r+rp(«)]l/2ᵫp=l,f=4,r=0.927ᡠPc=0.6Pc(Flory)

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94ROOR——►ZRO-CHCH33RO•CH2CHVWCH2CH2'/VWV'------►ROH+wCH2cMeH2cCHCH33I2'AA/'CH2—CwCH?—CH'/vvv'*A/W'CH2cH'/wvv'••CH2—CJWCH2—CHCH3(5)â?ãËᓄᑺCH—CHiCH—CH+HN-R-NHAiCH(OH)CH2CHCH(OH)>22222'(/ON-R-N…CH(OH)CHCHCH(OH)…22(6)ᵨÀÙᓄᱥὶᑺCHCH33I.RO,«/VWQ——S1O

958.èµ3ᑡᔠᱥḄᔠᡂ(l)ABS᪛ᾦ(2)HIPS᪛ᾦ(ᢙê)(3)SBSëᛛíឋ©(4)îï$/îð$(1)ᔠᡂABS᪛ᾦḄñ⌕ᨵA.zòᐳ஺ᐜóôõ>ᐳTᑮôØõN?ᐸ:öD÷óஹÖø!õ>zòTzòᐳᱥ:᜜úḄØõ஺ᨬஹÖᨴ☘ᐳØõþᔠஹÿஹABS᪛ᾦ஺B.ᙠᐭḄᐳ஺C.-ᐳᱥᐳ஺(2)ᔠᡂ"ᢙ$Ḅ%⌕'()*+ᓫ-.ᐭ/ᵫ1234ᑺ.647ᔠ89.;<ᙳ>ᙠ?@ABᐳC<47஺DᡂᑖᦣᨵHI.IJKᨵLᔠ,NᨵOPQឋḄᦋឋ஺(3)ᔠᡂSBS6ᛛUឋ-Ḅ%⌕'ᨵA.ᵨWXYZᓄᑺ\]ᔠᡂ

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97@y_ᱥz{|}~89CH—CH?2\/OH02জ---------►O^vw1ঝஹHz஺vx19.PMMAஹPANஹPEஹPVCᔠᱥ{|689.ᑖᑮ_ᱥ)PMMA{|689<47.%⌕_ᱥᓫ-PE{|689<47.%⌕_ᱥCᔠḄᱥPVC{|689✌ᐜῃHC1,7ᡂᑖ%1᪀Ḅᔠᱥ6ᑣ{O]47ὶ¡¢£ᓄ89஺PAN{|689<✌ᐜ47%ᓄ.ᯠῃ¥7ᡂ¦Dᔠᱥ஺{O]6ῃ¥7ᡂ£§¨஺10.ᑭᵨ6©ᦈᨵ«ᴻ®ᧇ<.᝞±®ᧇᨵPVCᩖ³.ᑣ´MMAḄ_᳛u.³¶u·.¸ᵨᓄ¹89º»¼ᐸ¾¿஺)¿PVCᩖ³ᙠ6<ÀῃÁHCLHC1ᵬ1⏚ᢥ}º{|ᡂ89.¿ÅÆᵬ1⏚ᵬÇḄ_᳛.NÈÉ_ʳ¶஺CH3CH2=C(CH)COOCH+HCl-»-CH3CC02cH333CH311.ᵨᓄ¹89º⊤Ì}ᑡᔜ89পḄᓄ(2)1,4-ÐÑḄᓄবḄÓᓄ(4)SBS¥(5)HBrÔᵨ}1,4-ÐÑḄᓄ*yx/v\ACH,'/WW+C[-------A*A/w'+HC1)প“+C1?-------►CHCl'zww+C1CHH3Cl112CH---»…CH2c(C1)C(C1)CH2…3ywvCH2---C—CH—CH2,/WW…CHC=CHCHC122CHফ3TVWCH2'A/V.CH2,/WW02,SO2»CH(C1)'A/VCH(SO2C1)'ZVWV'-HC1ব

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99(1)}⏚~PḄ'(ᑖXᑺ®C6H5஺03H9ᵨᩭt(Sᓄ஺ঢP⊤ᔠᱥL@ᐹLᢣḄj'(L஺®C6H4cH2—P(C6H5)2-Rh[P(CH)]2653ci(2)ᑖq[ᓄᑺ9ᵨ;Sᓝ(Ḅᓄ[ᓄᑺ஺(3)ᵬ]'(;LḄ]⏚~Pᱥ6c6H4cH2-OCO—CH2RNH29;6ᔠᡂ¡¢Ḅᑖ]^஺18.!¤ᑡ¥¦:(1)'(¨ᓄ"◀©ª‘03H᜜@¬©ªE®Ḅᾪឋ©ᱥ;(2)ᵬ]±(⏚ᵬ²ᙠ³ឋ®´µ!¶᳛⌲¹º»;(3)±(⏒½ᙠ³ឋ®´µ!¶᳛⌲¹¾¿À(4)Á}ÂÃ⏒ᓄᔠᡂᙳÅÆ⏚ÇÈÉÊËÌÍ஺!2(1)J6Ϊ᝞Ïὶyz'/vwCH2cH(2)J6ᑖqrÕṑ×ḄØÙ.C00.Ú]9;Û᪶XᑺÝyz஺CHCHCHCH3333CH2CCH2clz—W—A,A,WCH2CCH2C7WWJ0=C0࠷Vo=Cc=o(3)J6ᑖqrÕ!ḄØÙ-COO-]᣸ãÛ᪶XᑺOH-Ḅä

100CHCHCH333CH2c—CH2c—CH2C,/WWAèé!coo-CONHcoo2ஹ0H/(4)J6ÂÃ⏒ᓄ"ÇÈÉᙠyzêhᱥµE®!@᪵ìíîªᡂdïÇÈÉqjðᐰ⏒ᓄḄ@uòdïjðᐰóᨵ⏒ᓄḄÊᙳÅ©ᱥ@ᦑËᵨ9®ឋḄaÆ⏚ÇÈÉḄöᑴ!øùÃᑴᜓᙳÅḄÆ⏚ÇÈÉ஺19.XᵨMerrifieldúÎḄûÅᔠᡂüᔠᡂᑡᱥ^OooIIIIIIH-CH-C-NH-CH-C-NH-CH-C-OHN22CH(CH)2CH32c6H5!:NH—CH—COOH—►BOC-NH—CH—COOH2CH(CH)3CH(CH)233(CH3)3COCO-N3+NH2cH2coOH—►BOC-NH—CH2COOH(BOC-Na)NHCHCOOHaBOC-NH—CH—COOH2CHCH22c6H5C6H5CH-CH265BOC-NH—CH—C00"6H4—CH2cl----------------A(ᵬ]ᓄ'()(P>CHCH2OOCCHNHBOC^^^i

101CF3COOH,HF_-----------------------►(P/-CH4CHF4-HOOCCHNHCOCH—NHCOCHNH62222CHCH(CH)223c6H520.ᔠᡂᑡᱥ^(1)ᐹᨵ-CON(COCF3)-lmþnḄ⏒½L(2)ᐹᨵ-P(C6H5)2PtCbᓄḄ*AAWCONH'W/W+CF3COCI—A'AAA/'CONCOCF3(1)C1CH20cH3ZnCl*CH2P(C6H5)22()CHC12(2)PtClCHP(CH)PtCl2652221.ᡂᑡiCH2cH(0H)CH(0H)CH2…+3NaIO-------►3(1)-nCH2=CHC6H5hnCH=CHCNCellOH+Ce4+-A-------2---------------A(6)

102-^CH—C(CH)=CH-CH3^—232ENH(CH)6NHCO(CH)4CO^-+HN(CH2)6NH------►2222(8)n@O(CH2)2OCOC6H5coA+2nNaOH------►(9)11'A/w'CH,—CH'aaa/'C(CH)32O-ECHCHCnm2(10)῁(D…CH2cH(OH)CH(OH)CH2…+3NaK)3------►96H5&CTCH?=C(C6H5)2_DC^TTEnMMAF'A/wCH2—CH--------------------►'AAAACH2—CH-Crl2—C---------------->!c6H5C6H5C6H5(4)CH65ICC仅MIH-I比C6C6Hম

103£HJ-CH65niCell—OH+Ce4+-CellO-+H++Ce3+(6)(7)-^-CH2—C(CH3)==CH—CH——^^'a-n/vv,CH2—COCH3+O—CH—CH2,/WW=NH(CH)6NHCO(CH)CO^+HN(CH)NH---->■22472621n^NH(CH2)NH2+HN(CH2)6NHCO(CH2)4CO…62G-^O(CH2)2OCOC6H5CC3^+2nNaOH-*■nNaOOCCOONa+nHO(CH2)2OHOH2

104O-ECHCHCnn222.ᵨ345⊤78ᙠ:ᯠ<=ᵫ?@ḄAᵨBC஺9H3CH3I᡻Iywv*CH2—CH—CH2'ZWW—~—A'/wv'CH2—C—CH2'/WW'+H•প8ᐝCHCH33'A/WCH2—C-CH2'AZVW+஺2-------'/VVV'CH2—C-CH2o—o-(2)FCHCHCH333TVWCH2—C—CH2,/WWHA'A/W'CH2—C——CH2yww+WCH2—C—CH2'/WWIO—0--<—OOHCHCH33CH2—C—CH)'/vvw—►'a/wCH2—C—CH2'/WW+*0HOOH0-CH3■AWCH2—C—CH2'/VVW------►CH3—C—CH?,/ww'+•CH2,ZWWV'o-o8ᑖJᙠᐝᡈLḄAᵨᐜNOPQRJSTRJῃVWᡂᜧᑖJ:ᵫHY(1)5஺Z:ᵫ[@AᵨOᡂᜧᑖJ\@:ᵫH]^_`'8ᜧᑖJHabO`'ᜧᑖJ:ᵫcᜧᑖJ\@ᓄTᱥH᝞5(2)஺f'gah@ᓄiḄj⌴஺ᡠmᜧᑖJ\@ᓄTᱥnobOHO,pqNOᑖJrinoH]Oᡂ`'ᜧᑖJ:ᵫHY5(3),f᪵tᩭtvḄ8ᑖJwᑮ^_HyBztᩭtvḄ8NOrino஺f{@ᓄCᐹᨵi5Ḅឋ஺23.2,6-ᱯ-ᵬḄᢙ@ᳮc2-ᵬḄᐝᳮ஺f{ᱥᨵᜐH᝞⊡2,6-ᱯ-ᵬḄᢙ@ᳮᵫ?ᐸᑖJ=ᨵḄTRJH᧕[\@:HyB¡\@:ᵫ[ᐸ¢ᜧᑖJ=ḄTRJHᨵᦔᙢ¥¦¡@ᓄiḄj⌴HzᔠᱥḄC¨⅁ª஺«᝞¬ᨵrᢙ@ᑺ2,6-ᱯ-ᵬHOᡂḄᜧᑖJ\@ᓄTᱥ®¯noH⌼ᡂᨵ±ᑖJḄC஺²ᐭ´µᢙ@ᑺ᝞¶·⏚¹Hº»¼ᜧᑖJ\@ᓄTᱥ½¾ᡂḄᓄᔠᱥ஺■¦¡inoḄNO஺

105O-OH(CH)C.Å/C(CH)3333ACH3P
O—C6H5À3+ROOHAP
OCHO+ROH653Á¶·⏚ᾦÀÁᜧᑖJ\ÀÁ·⏚¹ÀÁᜧᑖJÄÀ@ᓄTᱥᓄᔠᱥa-ᵬḄᐝᳮ᝞Zᓄᔠᱥwᐝ᯿ÇᔾᦈᐝÊHᵫ᝱¾ÌÍN᝱HᯠÇa¾Î᝱Ïᐝʽ¾ᡂLÊ஺rᢙ@ᑺcÐ᜜Òᔾᦈᑺ]ᵨHÓ²ᐭ´µᢙ@ᑺÔº»ÕÖᙢ■¦ᔠᱥḄLஹᐝ@ᓄὁᓄAᵨ஺

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