盟校联考高考化学模拟试卷（含解析）

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2016
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XஹYஹZᐗZḄᨬ᜜ᵯᦪ᜜ᵯ32432ᦪXஹZYஹZஹRஹTᕜRᨬ᜜ᵯᦪ!᜜Ḅ3"T#$%XR&'ᦪ()!WḄ2"*+ᑡ-.┯0Ḅ!*1A*&23:Y,Z,R,TB*5᝱7ᓄᱥḄ9:ឋ:W,R,TC*ᨬ<%=ᓄᱥ>?Ḅ@ᓄᱥḄAឋ:X,ZDXRஹWRBᓄᔠᱥ
RḄᓄᔠ%zzூὃF௃&H᪀ᐗᕜJḄᐵL*ூᑖ᪆௃✏PQᓄXYZWR
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R&ᨬ᜜32432ᵯᦪᐸ᜜ᵯᦪḄ3"R&UVᨵ2Xᵯᨬ᜜ᵯᦪ6,ᑣR஺ᐗ;YஹZஹRஹTᕜ,ᓽᜐ_`ᕜTᐗ#$%ᑣTFᐗ;ZḄᨬ᜜ᵯᦪ᜜ᵯᦪᑣZBeᐗ;Yᐗ

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R&32432ᨬ᜜ᵯᦪᐸ᜜ᵯᦪḄ3"R&UVᨵ2Xᵯᨬ᜜ᵯᦪ6,ᑣR஺ᐗ;YஹZஹRஹTᕜᓽᜐ_`ᕜTᐗ#$%ᑣTFᐗ;ZḄᨬ᜜ᵯᦪ᜜ᵯᦪᑣZBeᐗ;YᐗᑣYLi;XஹZaᑣXMgᐗᡈCaᐗcX╅ᐗᑣᵫXR&'ᦪ()!WḄ2"ᑣ=10,efWᐗhiᔠ⚪k
cXCaᐗᑣᵫXR&'ᦪ()!WḄ2"ᑣ=14,efWSiᐗ
iᔠ⚪k*12+820+8~2~2~AY┞ᐗஹZ╄ᐗஹR=ᐗஹTᐗᕜᐗḄ&23mnᔣp23ᙠrs,ᓽ&23:Y,Z,R,T,ᦑA$tBWấᐗஹR=ᐗ'TᐗuឋF,஺,Si,ᑣ5᝱7ᓄᱥḄ9:ឋW,R,T,ᦑB$tCX┛ᐗஹZ╄ᐗឋCa,Be,ᑣᨬ<%=ᓄᱥ>?Ḅ@ᓄᱥAឋ:7=ᓄ┛7=ᓄᦑC$t

14DXRஹWRBᓄᔠᱥCaOஹSiO,Ca஺
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*6ᨵᱥᵬḄᑖCHO,ᐸ
=Ḅᑖᦪ20.25%,Ḅᑖᦪ68.35%*ᙠ“2⏚ឋᩩ¢+ᵬ@~£ᡂ¤)¥Bᨵᱥ;ᙠ¦)§w+Ḅ¤)¥Ḅ¨5ᡠᓰḄ«¬ᑣᵬḄH᪀Vᨵ*1A8B14C16D18ூὃF௃ᨵᓄᔠᱥḄ®᪀¯°*ூᑖ᪆௃ᨵᱥᵬḄᑖCHO,ᐸ
=Ḅᑖᦪ20.25%,ᨵ3212X+Y+32xl00%=20.25%?12X12X+Y+32Ḅᑖᦪ68.35%,ᨵ3xl00%=68.35%?ὶ²³³
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=Ḅᑖᦪ20.25%,ᨵÄ,

153212X+Y+32xl00%=20.25%?12X12X+Y+32Ḅᑖᦪ68.35%,ᨵ3xlOO%=68.35%?ὶ²³³~ÅÆX=9,Y=18,ᓽÇᓃᨵᱥCHO(“azᨵᱥᵬḄᑖCHO,ᙠ⏚ឋᩩ¢+ᵬ@~¤)¥Bᨵᱥᑣᨵᱥᵬ¶(ᵫ9182Ḅ¤)¥Ḅ¨5ᡠᓰ«¬-·¤)¥Ḅ>ᑖ¸¹⏚º⏣¼½Xc&,-·@~¾´ᑮḄÀ⏚Áᨵ4XC&´ᑮḄ⏣Áᨵ5XC&(Áᨵ4XC&ḄÀ⏚ᨵ2ᑖ®᪀«:CHCHCHCOOH,CHCH(CH)COOH(32233Áᨵ5XC&Ḅ⏣Ḅᨵ8ᑖ®᪀«:CHCHCHCHCHOH,CHCHCHCH(OH)CH,CHCHCH32222322332(0H)CHCH923CHCHCH(CH)CHOH,CHCHC(OH)(CH)CH,CHCH(OH)CH(CH)CH,CH(OH)CHCHB232323333322(CH)CH
33CHC(CH)CHOH(3322ᡠÊᨵᱥᵬḄᑖ®᪀«ᦪᨵ2X8=16(ᦑ⌱:C(ூF௃ὃᑖ®᪀«ᦪḄᑨ
ËÌ⛳)½ᐗ⏣¼½XC&Ḅ⛳)½ᐗÀ⏚Ḅ>ᑖ!~⚪ᐵ(E+3..227(Î#⁐ÐÑᵫNaஹAgஹBaஹAlஹAIOஹMnOஹCOஹSO
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18ᜧV(⌮)(À"ᜧ"ஹ"m"ᡈ"")(dYHÅ£·WḄÆ¢£Ḅ³⊝OᦪK=1.6((ÈÉÊËÌᶇÎÏᨵᦔᦪÑ)(3)C0?ᔠᡂjᵬjᵬ?Ò0ÓᧇᵯÔḄ5ᧇᓄ_¢£5ᳮ0:CO(g)+4Hz(g)?CHOCH(g)+HO(g)?H,0332?ᙠឤÖD×ÖᘤÙᢥ#ÛÜ01:4ᐙᐭ2ᓄ9Ý1"ᩩ¢£Þᑮ³⊝à᝱(âᦋ䢣Ḅå¯ᩩæᑡäᓄ<èé³⊝ᔣâ£SᔣëìḄrBD;A(⌮¢£í᳛ᐜïᜧæðmC(¢£ᱥḄ#Ûòᑖ8ðmB(â£í᳛ᐜïᜧæðmD(ᓄ_³⊝OᦪKóïᜧ.2?ᑏ)jᵬõឋÓᧇᵯÔḄö᩽ᵯ᩽¢£øCHOCH,12e+16OH?2CO+llHO;3332?ùúᵯ᩽¢£Ḅᵯ᩽ᩞᧇᓫÏýþ)ᵯ<Ḅᜧm0ÆᵯÔḄÜ<(ᐵjᵬÿឋᧇᵯ⏣ឋᧇᵯᑡḄC()A(ᧇᑖ᪀ᑖ!"᥅$%&'()&'B(ᧇᡠ+ᐳ-.ᦪ0'1.2ᡠ◤)&'()&'C(ᧇᡠ+ᐳ-.4561.2ᡠ◤)&6()&6(4)78Ig9ᵬ;<=ᐰ?@ᡂBCḄDᓄᱥGHḄI&31.63kJ,JᑏH⊤M9ᵬ;?IḄIᓄNOP!CHOCH(g)+3O(g)?2CO(g)+3HO(l)?H=I332221454.98kJ/mol(ூὃS௃UVI"WX;ᵯ᩽UV"ᵯUVOP!;ᓄN[⊝Ḅ]^(ூ_⚪௃ᓄNUVaḄ)&Xᓄ;ᓄN[⊝_⚪(ூᑖ᪆௃(1)᪷dUV[Cu(NH)]AC(aq)+CO(g)+NH(g)?[Cu(NH)]ACCO(aq)32333?H,0GIUVefghᓄN[⊝Ḅijklmno(2)pUVᔣrsᜧḄOᔣuvwᜧ
CHḄxᓄ᳛wz;uvP2ᙠYSU42

19V}~ᑮ[⊝ᑣUVᔣ;]^H~ᑮ[⊝2ᔜᑖḄᱥ%Ḅ&egᨬ|<=]^HpfgpUVḄ[⊝ᦪoc2(CO)-C2(H)2c(C0)-c(CH)24(3)?᪷dijᓄN[⊝Ḅklᑨ1"[⊝CᔣUVOᔣ"Ḅ⌱⚗o?ᵯ᩽@DᓄUV9ᵬ;ᙠឋᩩᜫᵯ@ᡂ⏚᪷¡"¢d£ᑏHᵯ᩽UVo?᪷d⏣"9ᵬ;a¤᪀¥!6@UV21¦ḄᓄN.6UVGHḄ)&6§'d£klᑨ1o(4)᪷d1g9ᵬ¨<=ᐰ?@ᡂBCḄDᓄᱥGHḄI&31.63kJ]^HImol9ᵬ;=ᐰ?GHḄI&ᯠ᪷dIᓄNOP!ḄªᑏOᑏH9ᵬ;?IḄIᓄNOP!(ூmn௃!?:(l)[Cu(NH)]AC(aq)+CO(g)+NH(g)?[Cu(NH)]ACCO(aq)?H32333,0,pUVGIUVᓣ¬fg[⊝ᔣḼ⌮ᔣ¯°±ᔾᦈDᓄḄ´µᜐᳮ¸¹º»[Cu(NH)]AC,32ᦑnᫀ:¿Io(2)pUVᔣrsᜧḄOᔣuvwᜧCHḄxᓄ᳛wz
78'fgP”ᩩḄxᓄ᳛ᜧÀP,ᑣPzÀP9uvP2ᙠYSUV}~ᑮ[⊝
ᑣUVᔣ2122ᡠ°V()ᜧÀV(⌮);78CO(g)+CH(g)?2CO(g)+2H(g)2§ÁÂ&(molÃ)0.10.100Xᓄ&(mol/L)0.080.080.160.16[⊝&(mol/L)0.020.020.160.16,c2(CO),c2(H)20.162XQ.l6sc(C0)-c(CH)240.02X0.02==1.6;ᐸ[⊝ᦪ⊤~!K=

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ᦑDoᦑnᫀ:BD;.?9ᵬ;ᙠឋᧇᵯḄ᩽ᜫᵯ@ᡂ⏚᪷¡"¢ᵯ᩽UVCHOCH,12e33,2.+16OH72CO+11HO,32.2ᦑnᫀ:CHOCH,12e+16OH?2co+11H0;2333?ᓄNUVØ%Ù.Ḅ1¦"¹.Ḅ@ᡂGHḄ)&Ù.1¦ᔾᦈḄ)&"¹.Ḅ@ᡂGHḄ)&ᨵᐵÜ9ᵬ;"⏣ᑖaᓄN.456ᡠ°UVÝPaGHḄ)&6ᡠ°Cᦑnᫀ:C;(4)lmol9ᵬ;Ḅ%&46g,46g9ᵬ;=ᐰ?@ᡂBCDᓄᱥGHḄI&:31.631z469=1454.98kJ,ᡠ°9ᵬÞ?IḄIᓄNOP!ßCHOCH(g)+3O(g)332?2CO(g)+3HO(l)?H=,1454.98kJ/mol,22ᦑnᫀ:CH0CH(g)+30(g)?2co(g)+3H0প8H=,1454.98kJ/mol(33222ூSà௃á⚪ὃâÉᓄN[⊝ḄãäåᵨஹᓄN[⊝Ḅijஹᵯèåᳮeᵯ᩽UVḄªᑏஹᓄN[⊝ᦪḄ]^ஹᓄN[⊝é᝱Ḅᑨ1ë8ì⚪0ígîᜧὃâḄ8ìSîᜧᐙᑖὃâÉN@hᓄN[⊝ஹᵯèåᳮë8ìḄðñòóô⚪õöÉN@Ḅᑖ᪆ஹᳮm)÷eᓄN]^)÷(

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>ᧇTUVWXAYKMnO'ᓽᙠ\ឋᩩ_`ᵨ24bbᓄMnOdᑮKMnO,ᑖfgdᑮḄKMnO,hᵨiឋᩞᧇᵯ᩽ᵯ=KMnOmVdᑮ224242“KMnO,ᐸAYJoᶍ᝞`r41
stᘤvstḄᓄFwxy4KOH+2MnO+O=2KMnO+2HO222422
AYUxvᨬE{ᵨ|MnO80%MLḄ}P~MnO|ᨬḄPvALSiḄb22ᓄᱥ|DKOHὑ'""ᡈ""'ᵯ=2.3
ᵯ=vḄfstwxy2MnO+2HO2MnO+2OH+H?4
ᙠJovdᑮKMnOgᔣᐸvTᐭ〉COstAᡂ⁐5ஹKMnO&st2424ḄᓄFstwxy3KMnO+2CO?2KMnO+MnO+2KCO242*23Lstvbᓄᑺ>ᑺḄ1:2'JoWᵯ=XḄ;Y᳛ஹKOH¡¢ᑭᵨ'JḄ⏚ឋKMnOmV'ᩖ#st¦mVᕈ¨©ª⁐«¬ᑖᑁ#¯°ὑKMnO”,mV14.80mL,ᑣ₝⏚ᨔ5Ḅµ¶93.2%''·¸¹ᶇ3»ᨵᦔᦪ¾'¿À₝⏚·ᨔÁᔠᱥHCO2HOḄWÃᑖ126
2242ூὃ)௃ᱥᑖfÄŵḄwXÄÆ,ÇÈÉᔠtᵨ'ூÊ⚪௃ᱥḄᑖfŵÄ␺Ì'ூᑖ᪆௃1
\ឋᩩ_`ᵨbbᓄMnOdᑮKMnO,᪷ÎdᜫᵯÐឤÄ>ÐឤᑏÓ224

24WtḄwxyÔ(2)bᓄÕ;ÖឋbᓄᱥbᓄÕÄ×\stAᡂÕ⏚ØÄÁᡠMKOHὑ((3)ᙠᵯ=vᵨÛÜÈᵨ□᩽ÞÈ▢᩽ᵯ=KMnOmVdᑮKMnO▢᩽LÁdᵯà2áA>stAᡂCÄCb᪷f□᩽L═⏚᪷fᜫᵯstbᓄstAᡂ═⏚᪷f((4)᪷Î⚪âãäåÀstᱥKMnOஹC0Aᡂ⁐5MnOஹKMnO,᪷Îx>Ðឤæ24224ᑏᓄFstwxy᪷ÎwxyåÀ3molKMnOçèstAᡂ2molKMnO.ImolMnO,Îéᑘëᑨíbᓄᑺ>ᑺḄî;ᵯ=X□᩽ïAᡂKMnO,Y᳛Ô4,*2*(5)àAst:5HCO+2MnO+6H=10CO?+2Mn+8Ho,᪷Îwxy?@᪵ñv₝⏚Ḅ,224422òó?@₝⏚Ḅᑖᦪ(ூ=௃=Q)ôbᓄ═ÄCbᓄõஹbàAstAᡂ═⏚õÄÁMn(+4?+6),0(0?,2),stḄᓄFwxy4KOH+2MnO+O=2KMnO+2HO,22242ᦑᫀ34KOH+2MnO+O=2KMnO+2Ho,22242(2)bᓄÕ;Öឋbᓄᱥö×⏚st÷×\stbᓄÕÄ×\stAᡂÕ⏚ØÄÁstḄᓄFwxy2KOH+AIO=2KAIO+H஺,ᡠMKOHὑ2322ᦑᫀ:Ô6)ᵯ=═⏚õmVù▢᩽LÁdᵯAᡂCÄCb᪷f,ᵯ᩽st2H0+2e?,,=H?+2OH,□᩽L═⏚᪷fᜫᵯAᡂ═⏚᪷fᵯ᩽sty22MnO,2e=2MnO244...2..2„,ᓽMnO,e=MnO,ᑣᵯ᩽st:2MnO+2HO2MnO+2OH+H?,4…

25ᵯ=ᵯ=,2“ᦑᫀ:2MnO+2HO2MnO+2OH+H?;ú(4)stᱥKMnOஹCO,Aᡂ⁐5MnOஹKMnO,ᡠMḄᓄFwxy*242243KMnO+2CO?2KMnO+MnO+2KCO
2424223ᵫᓄFstwxy33KMnO+2cO?2KMnO+MnO+2KCOᑖ᪆dÓ3molKMnOçèstAᡂ2424223242molKMnOஹImolMnO,ᓽ3moi═⏚õçstᨵImolÈbᓄᑺஹ2molÈ>ᑺᑣsütvbᓄᑺ>ᑺḄ1:2;JoWᵯ=X□᩽ïAᡂKMnO,Y᳛ᡠM;Y᳛ஹKOH¡¢“ᑭᵨÔᦑᫀ33KMnO+2cO?2KMnO+MnO+2KCO;l:2;Y᳛ஹKOH¡¢ᑭᵨ;2424223(5)ᙠ0Uxv═⏚õbᓄᑺ₝⏚>ᑺstḄfwxy:5HCO+2MnO2244þ2++6H=10CO?+2Mn+8Ho᪷Îwxyådᐵÿ
225HCO2HO,2KMnO2242452100mL20mL,n0.02mol/Lxl4.8xl0Lx3,3:n(HCO2Ho)=3.7xl0mol2242,3ᑣm(HCO2Ho)=3.7xl0molxl26g/mol=0.4662g,2242

260.4662g0.500gᡠᡂḄ3xl00%=93.2%,ᦑᫀ393.2%ூ௃⚪ὃᑴᜓᫀḄ!ஹᱥ$ᑖ&'()Ḅ*ᔠ,ᵨ.⚪/012.34ᓄ6789ஹ:;<=ஹ>ᓄ?@A,BC!Dஹᱥ$EFḄGC2HI.᪷K⚪1LHᩩNOCPᡂᱥQᑏSA,=TO@ᳮV⚪ᐵX.VY6P*ᔠZ[Ḅὃ\ூᓄ6]ᓄ6'ᢈ_௃15ᑖ`11:abcde@ᧇᑴc⏚ᡠhPḄij◀lEᨵNஹ஺᜜.?EᨵSOஹpFḄSO2223q⏚r\lstu᛻.wx(yc⏚:aḄ*ᔠz{ᦔ}.,~Zij1ḄSOᓄ2ᨵᵨḄh\ᢥ⌕ᑡ⚪
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27ூὃ௃“Ýì"ᜐᳮ'u᛻st;ᵯ@ᳮ\ூí⚪௃ᓄ6,ᵨ\ூᑖ᪆௃1?¸>ᓄcïé>ᓄ┛A,Pᡂ¿c⏚┛.´ᐭc⏚.Pᡂc⏚┛q¸>ᓄcjñò?ó@ᧇ¢ô᧕ª.SOᦈᑭᵨõᑖ᪆ò2?´ᐭ〉FḄY·¸¹ᡈY·¸º2?@ឋᱥ$.■¾¿c⏚ÀÁ>ᓄò2?óCc⏚H.b▢&ÙÚᣚÔ\ᦑa□&ÙÚᣚÔ\ᙠ▢᩽ß,÷ᵯPᡂéjqé>᪷.ᦑAé>ᓄø.Eéjò?□᩽,¿c⏚᪷÷ᵯPᡂc⏚᪷\ூ௃31?S஺'FᮞA,.Pᡂ¿c⏚┛q.¿c⏚┛qc⏚A,Pᡂ2c⏚┛ஹq¸>ᓄc.ùPḄᓄ6A,ᑖçSO+Ca
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35.MLCIIOᐭCII-CNCHCCMHI•3/■^U♦y/N'”2ஹ/X“\HOHTᦑvᫀ]:

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