高考化学模拟试卷1（含解析）

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16ᑖ%N&'()*+,ᦪḄᦪ/0ᑡ23!"Ḅ4%AA,5028g67ᡠ9᩽ឋ<Ḅᦪ=&4NA3.1LFeAC᪗?@A0ᵬ⏣ḄᑖDᦪᡠ9EFᦪ&NA•D10LpH=lḄG⏚IJ9ᨵḄHKDᦪ&2NA26ᑖ%ᙠ0ᑡMNᩩPḄIJNQᜧSᐳTḄUDV4
AQWpHXᕈZ⁐ḄIJ:NaஹNHஹIஹNO«KwcH+
cB,50,ḄIJ:NaஹKஹ=0.001mol-LSiO.NO”T32C,50ᵫ_ᵯKaᩭḄcH
=1.0xl0molLIJ:Al஺ஹKஹSOஹBr2….DdefghiᜧSjkḄIJ:NaஹKஹNHஹNO«I-CH-36ᑖ%lmnopᑖDqS&86,᝞sᑖD9ᨵ3,CHஹ2,CH,t132ᑣvw᪀ḄnḄyz{ᱥᨬ~Qᨵ%ὃ⇋᪀%A9B6C5D446ᑖ%lᨵᱥ4ᱥihḄᐸw᪀᝞0ᑡᨵᐵ!"Ḅ4%Avᨵᱥd_iz{fgB1molvᨵᱥdSNaOHIJfgᨬ~ὑ4molNaOHCvᨵᱥdG⏚ᔠᐳifgDvᨵᱥᓄᓄdᑴjᓄ¡¢JᐳiᡂẈZ⁐¥¦56ᑖ%0ᑡ§¨©d⚜«§¨=Ḅᡈᡠ§¨w®¯Ḅ4%

1⌱⚗§¨©§¨=Ḅᡈw®AᔣCuSOIJ²ᐭHSka´µ⁐¥¦HSḄ⏚ឋ¶HSO·42224Bᔣ9ᨵ¸SFeCIḄMgCIIJ)ᐭSMg(OH)¹ºᤅ¼½¾¿À◀322MgCIIJ¸SFeCI23CⅅÃIJ)ᐭÄÅÆG⏚_Ç)ÄᑖÈÉ)ᐭᑴjᓄ¡¢J_Ç)Êa´Z⁐¥¦ⅅÃÊ_ËDCHOHdG⏚170?ᐳᑴḄk²ᐭ⏚ឋKMnOIJ̨ᑴk4ᔲ&67A(AB(BC(CD(D6((6ᑖ),500ᑡ23!"Ḅ4()A(ÐÑஹÐᱥqḄSÒḄNaCI(aq)KDÓᦪᜧÔNaCIO(aq)KDÓᦪB(pH=3ḄG⏚IJ_ḄᵯKÕÒÐÔpH=llḄÖ_IJ_ḄᵯKÕÒ.*zC(0.1mol/LḄNaHAIJpH=5,ᑣIJ:c(HA),c(H),c(A),c(HA)2*+z.D(ᔣNHHSOIJÅ×ØNaOHIJÙឋᡠᔠJ:c(Na),c(NH),c(SO)”,>,c(OH)=c(H)7((6ᑖ)ᙠឤÛÜḄÝÞÛᘤi⌮fg:M(,)+2N(g)?P(g)+Q(g)?H,0,áâMḄ@᝱Êâᑣ0ᑡäNåᑮç⊝Ḅ᪗é4()?ëᱥqMஹNஹPḄÑᑖᦪ¶&1:1:1¾?ᔠkḄÝÒì¾?íḄ5Òì¾?fgî᳛2v(N)=v(Q)¾!⌮?íḄð·ì¾?kḄçᙳopᑖDqSì¾(

2A(???B(???C(??D(???òஹËó⚪(ᐳ3⚪ôᑖ43ᑖ)8((14ᑖ)e⏚õ4ö÷iht§¨øḄ⌕ᓄᑺö÷û,ᵨeýþ(ÿ⌕ᡂᑖFeO-CrO,ᩖSiOஹAIO)ᧇᵨᑴKCrOḄ⌕23223227᝞(!Ḅ⌕"#$%6FeO«CrO+24NaOH+7KCIO12NaCrO+3FeO+7KCI+12HO(23324232(1)&'()*+,Ḅ-ᵨ((2)"#ᘤ/0◀2⚪0ᡠ5"#᜜7ᑏ9ᐸ;<=ᓄ?@AB(⌕C<="#0"#ᱥᙳFGH);(/0K⁚pH=7,8ᡠMNOஹ((3)PQ⊝STᑖ᪆/0⏚ᓄḄᳮX(4)ᵨY⌕Ḅᦻ[\]^-/_ᐭKCIaMᑮKCrOᨔdḄe$(f(5)ghi*⏚jk᪵mᡂ250mLnoh925.00mLpỚrs0ᔣᐸ0_ᐭ3*2210mL2mol/LHSOuvrỚᓄj(*ḄwᱥCrSO᪗ynoz{(I+2SO=2I+SO422322346,)2?ᑨ~ᑮz{Ḅ$X?0ᐳᵨNaSO᪗yno40.00mL,ᑣᡠM0i⏚jḄT(᦮=A0223ᐸ;ᩖF_"#)(ᶇ2ᨵᦔᦪ[)(9((14ᑖ)⏚ᔆஹ0Ḅᓄᱥᜧ¡ᨵ¢£¤◀ᓄᱥḄ@᝞¥:§(¤◀ᓄᱥᨵ¨£@((1)@©:CHªᓄw(«¬“j?CH(g)+4NO(g)=4NO(g)+CO(g)+2HO(g)?H=,574kJmol-?CH(g)+4NO(g)=2N(g)+CO(g)+2HO(g)?H42222,i?HO(g)=HO(l)?H=,44kJ«mol223

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4Na2sosûnoC1OZj^n'"#I,4
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⁐!᧕ᑖ#ஹ᧕%#,'ᵨ)*ᧇஹ,-24ᑺஹ01ᑺ23ᓄᐶ56789ᑴᜓᵬ⏚,Ḅᓄ᝞2NHg
+COg
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6z:((5)@¦ᐗ±ᜐ]Ï|yÐḄÑᐗ±ᐹᨵÓᵯ«ឋᐸᓄᔠᱥÔÔᐹᨵᔠឋzÕÑ⏚.(HBO)ᙠÖ×Ø@Ö2*ᡂÕ/Ê|ᐗÙ⏚ḄឋᑣBḄE«ᩖᓄÛÀÜ33(6)ÝÞCuᓫß@àÖᡈᓫß@ᓄáâT2ãL@àÖ-ᓄáḄäᔠ×Ø22Ḅ¶«>,Ü(7)|µ¤ÝᔠÝᨔ/ᐹᨵ☢å¿>ᨬçᚮ0Ḅ᪀(ᙠᨔéAuE«ê]⚔KCuE«ê]☢åᑣ<ᔠÝAuE«@CuE«ìᦪ{1,í<ᨔéḄîïapm,ᑣᔠÝḄ*çñgcm(ò⌕óᑡôTõô7ᦪö÷øùúû[ᦪN)(Aüஹூᓄ-⌱þ5:ᨵÿᓄ
Ạ௃(15ᑖ)13(0,(0,lapachone)ᢙ,ᔠᡂ᝞:(1)XḄᑖCHCI,ᑣXḄ᪀"#59(2)ᨵ'ᱥBḄ)*+:(-./)(3)0123456ᑭᵨ᳛:100%Ḅ(⌱-#"A?B"ஹ"B?C"ஹ"D?E"ஹ"E?F")((4)D?E=>Ḅ?@235AᨵBCᱥDEEFᑖG᪀H5IJKLM5NᱥOḄ᪀"#((5)ᓄᔠᱥBḄFᑖG᪀HPQ5RSᑡᩩVḄFᑖG᪀HᦪXᨵ(Yᒹ[\HG᪀)(]^_0ᨵ`a?@b]ᑖ4ᨵaLcad;]ᑖ4fgᨵahឋj6(6):klᔠᡂ23#ᵫ2,ᵬ,1,3,oplcql6ᧇ(s'tᑺvwᓄᑺxᵨ)ᔠᡂyᑖ0H-EO^H(CH2)C^OH4CH3zᑏ|☢`a23~2,ᵬ,1,3,oplDql:(

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-“AÒ*ÎpHtÙᕈÛ⁐Ḅ°±:NaஹNHஹIஹNO“KwcH+
Ò¤5=0.001molLḄ°±:NaஹKஹSiOஹNO33HCÒ¤ᵫ·ᵯ²|ᩭḄc
=1.0xl0molL°±4:Al஺ஹKஹSOஹBe”ÒDß23C>ᜧ¾àáḄ°±:NaஹKஹNHஹNO«ὃ#²ᐳÖâ⚪Òᑖ᪆#AÒ*ÎpHtÙᕈÛ⁐Ḅ°±5ã⏚ឋbKwcH+
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=1.0xl0molL°±5⏚ᡈ´ឋ°±bDÒDß23C>ᜧ¾ÃáḄ°±5æçᓄឋ⏚ᡈè´°±Ò.“#:AÒ*ÎpHtÙᕈÛ⁐Ḅ°±ã⏚ឋHஹIஹNO=>çᓄA623Y*3ᜧ¾ᐳÖ5ᦑA┯ÂbKwcH+
äBÒ¤5Ḅ°±5ã´ឋ5NزëìY235íᜧ¾ᐳÖ5=0.001mol-LᦑB;

9“i3“C(¤ᵫ·ᵯ²|ᩭḄc(H)=l.OxlOmolL°±5⏚ᡈ´ឋ°±5⏚ឋ°±4Y*ᜧ¾ÖᙠAIO,ᦑC┯Âb2Q(Dß23C>ᜧ¾ÃáḄ°±æçᓄឋ⏚ᡈè´°±´ឋ°±4Y*ᜧ¾ÖᙠNH,4..⏚ឋ°±4KஹALNO=>çᓄA623Y>ᡂïá5ᦑD┯Âb3ᦑ⌱B(Ä#⚪ὃŲḄᐳÖ5y⚣ὃ5òÌó²Ḅ23vô⚪4ḄõöḄᐵ§5÷øᑖ23ஹçᓄA623Ḅ²ᐳÖὃÅ5⚪XÏÐYᜧ(I-CH-3((6ᑖ)ùúûüýᑖO¾86,᝞þᑖ4gᨵ3a,CHஹ2a,CH,c1a532ᑣN᪀ḄûḄà?@ᱥᨬ
ᨵ0(ὃ⇋᪀)A(9B(6C(5D(4ὃᨵᓄᔠᱥḄ᪀;ᑖ᪀ᑖ᪀(86-214ᑖ᪆!"ᑖ#$%&86,ᑣ()*ᨵḄ+,#ᦪ.&:=6,(&12ᑖ#3*ᨵ34,CHஹ24,CH,14789():*ᨵ14;<7ᐸ;<
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10STS:Uṑ!"ᑖ#$%&86,ᑣ(3*ᨵ+,#ᦪ.&:N==6,&1;ᑖ#3*ᨵ34,CHஹ24,CH,147ᑣ(1ᑖ#3:*ᨵ14;<ᵬ?,32I-CH—W*ᨵ>?7ᐸX<*ᨵ54C,YZᩩ\Ḅ1Ḅ᪀BC&:]ZHCHCH
CHCHCH,32?CHCHCHCH
CHCH,ᐸ3]ᑖ#3*ᨵ5J323KḄH,ᓽ*ᨵNOPᱥḄᦪ.&5'32323?ᑖ#3*ᨵ4JKḄH,ᑣᐸNOPᱥᨵ47ᡠa(᪀ḄbḄNOcPᱥᨬ
ᨵ5+4=97ᦑ⌱Agh⚪ὃjkᑖ᪀Ḅlm7⚪.no3p7qrstᑖ᪀Ḅ᪷Gulmvwxᢈz7{|ᳮS⚪~&STh⚪Ḅᐵ46ᑖUᨵᱥ@ᱥḄ37ᐸ᪀BC᝞ᑡᨵᐵ{|Ḅ@
A(ᨵᱥx
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¡ᓄ¢ᓄᡂ,CHO7ᑣ¡ᓄ¢ᓄEx£ᑴ¥¢ᓄ¦§¨ᐳᡂẈ«⁐®7ᦑD{|2ᦑ⌱C(gh⚪ὃjᨵᱥḄ᪀ឋ$&2015ÁÂὃ⚪ÃÄÅÆÇḄᑖ᪆ÈḄὃj7qrÉtᨵᱥḄ᪀ÊËḄឋ$7&ST(Q⚪.Ḅᐵ7noᜧ(5((6ᑖ)ᑡÍÎÏÐx⚜ÒÍÎ.ḄᡈᡠÔÍÎÕNÖḄ@()⌱⚗ÍÎÏÐÍÎ.ḄᡈÕAᔣCuSO3ÙᐭHSÛ7ÜÝ⁐®HSḄ⏚ឋÞHSOß42224Bᔣ*ᨵà%FeCIḄMgCI3áᐭZ%Mg(OH)âã7ᤅåNæçEèé◀322MgCI3à%FeCI23Cⅅì3áᐭíîï⏚7ðáíᑖñ7òáᐭ£ᑴ¥¢ᓄ¦§¨7ðá7óÜ«⁐®ⅅìóSDCHOHx⏚170?ᐳ7ᑴÔḄÛÙᐭ⏚ឋKMnOôÎᑴÔÛ@ᔲ&>254öA(AB(BC(CD(DὃᓄÇÍÎvᫀḄgø(ᑖ᪆A(ᔣCuSO3ÙᐭHSÛ7ÜÝ⁐®®&CuS;,2B(áᐭZ%Mg(OH)âã7ùúûü#S22C(ôÎSᱥℍ⃔ì7ᙠឋD(⏣ᢵ═⏚ᓄ(:A(ᔣCuSOᐭHS⁐"#"#$CuS,$%ᑖ'(
42)*+ᔠᳮ.⏚⏚ឋ/ᦑA┯2B(3ᐭ45Mg(OH)6789:;<=>?@◀ᩖCDE)*ᙳᔠᳮᦑBGH2

12C(JK=Lᱥℍ⃔P(ᙠឋᑣ=Sᐜ3NaOHUឋV3ᐭWᑴYᓄZ[\ᩭJKᦑC┯2D(⏣ᢵ^⏚ᓄ(◀_⏣SVJK`ᔲbᡂdᦑD┯2;ᦑ⌱B(ghi⚪ὃlᓄmnKoᫀḄhr$⚣ὃgtE'(uᳮஹᨵxᱥḄឋyஹᱥyJKEnKziCD{|nKziCD}'(uᳮ$ḄᐵnKḄhrឋᑖ᪆⚪+ᜧ(6((6ᑖ)ᑡ+GHḄ`()A({ஹ{ᱥyḄ5ḄNaCI(aq);<ᦪᜧNaCIO(aq);<ᦪB(pH=3Ḅ.⏚=Ḅᵯ;{pH=llḄ==Ḅᵯ;>2,C(0.1mol/LḄNaHApH=5,ᑣ:c(HA),c(H),c(A),c(HA)2p.D(ᔣNHHSO3NaOHUឋᡠᔠ:c(Na),c(NH),c(SO)….+,c(OH)=c(H)ὃg;<ᜧḄ(⚪Ḅ=⚪(.ᑖ᪆A(NaCIOb='(:QO+HO?HCIO+OH,NaCI+=2B(⏚ᡈᢓᑴ=ᵯ;⏚Y;<ᡈY᪷;<¥ᜧᐸᢓᑴ=ᵯ;¥ᜧC.0.1mol/LḄNaHApH=5,ᑣHAᵯ;ᜧ=D(ᔠᕈឋḄy`.⏚¨ஹ.⏚╄}ª=ᔠ(:A(HCIO`«⏚ᡠ¬NaCIOb='(:CIO+HO?HQO+OH,2.7..ᕈឋ,Y;<10mol/L,ᡠ¬NaCIC(Na)+C(H)ᜧNaCIO

13+….C(Na)+C(H)᪷¯ᵯ₹±ឤ:C(Na)+C(H)=C(OH)+c(Q)@;<ᦪ$2xxV;³ᳮ@NaCIOᦪ$2xxV,ᡠ¬NaCI;<ᦪᜧNaCIOᦑAGHB(⏚ᡈᢓᑴ=ᵯ;⏚Y;<ᡈY᪷;<¥ᜧᐸᢓᑴ=ᵯ;¥ᜧ.⏚Y;<{=Y᪷;<ᑣ´ὅᢓᑴ=ᵯ;¶{ᦑBGH2coimol/LḄNaHApH=5,ᑣHAᵯ;ᜧ=,ᑣc(A),c(HA),=}2..2.HA·ᵯ;Y;<ᑣc(H),c(A),HAḄᵯ;}=·ᑣ;<ᜧ¸¹`c(HA),c(H),c(A),c(HA),ᦑCGH;2.DºNHHSO3NaOHUឋ»1:1'(¼ឋNaOH>5ᑣc(Na)«,2.*2,C(SO),¼ឋ½Ḅy$.⏚¨.⏚╄ஹª=ᔠc(Na)+c(NH)=2c(S0-2.),c(Na),c(SO),ᑣc(NH),(SO),ᦑD┯2”ᦑ⌱D(ghi⚪ὃl¿;<ᜧtE«ᵯyḄᵯ;ஹ={ÀÁg᪷¯ᱥyḄឋyV}ᱥᧇ±ឤ{ÀÁgᩭᑖ᪆⚪{(7((6ᑖ)ᙠªÃឤÄÅÆḄÇÈÄᘤb@⌮'(:M(,)+2N(g)?P(g)+Q(g)?H,0,ËÀMḄÌ᝱ÎÀᑣᑡÏЪÑÒᑮÔ⊝Ḅ᪗×`0?ÙᱥyMஹNஹPḄᑖᦪ$1:1:1½?ᔠḄÇ+Ú½?ÛḄ+Ú½?'(Ü᳛2v(N)=v(Q)½G⌮?ÛḄÞ/+Ú½?ḄÔᙳ¶ßᑖ

14A(???B(???C(??D(???ὃgᓄmÔ⊝Ì᝱Ḅᑨá(ᑖ᪆ᓄm'(ÒᑮᓄmÔ⊝Ì᝱½G⌮'(Ü᳛¶{â+{0,ᔜᱥyḄ+VbÚᓄᵫåæbḄªçᱥᳮ5+bÚᓄ¬å9èᑨáGH)*(:M(,)+2N(g)?P(g)+Q(g)?H,0,?Ô⊝½ᔜᱥyḄᱥyḄ5éêëᱥyḄìíᱥyḄ5}îᓄ᳛ᦑMஹNஹPḄᑖᦪ$111½+D$ᑨá`ᔲÒᑮÔ⊝Ì᝱Ḅï¯ᦑð┯2?MḄÌ᝱ÎÀᦑḄy5`ᔲÚᓄÎÀ+ÚᦑᔠḄÇ+Ú½+ªÑD$ᑨá`ᔲÒᑮÔ⊝Ì᝱Ḅï¯ᦑð┯2?ñ'($òÆ'(ÛḄ+ÚóÒᑮÔ⊝Ì᝱ᦑðGH?'(Ü᳛2v(N)=v(Q)½ᓄm'(Ü᳛éôᓄmõ5ᦪé+{ᦑ+óG⌮ÒᑮÔ⊝Ì᝱,ᦑð┯2?Äᘤ$ÅÆÄᘤÞ/+ÚóÛḄ+ÚóÒᑮÔ⊝Ì᝱ᦑðGHðÔᙳᑖ<5=,»M$ᑣy5+ÚᱥyḄ5÷Ú;»M+$ᑣy5÷ÚᱥyḄ5+ÚᦑḄÔᙳ¶ßᑖ

156FeO«CrO+24NaOH+7KCIO12NaCrO+3FeO+7KCI+12HO(23324232(1)234567Ḅ8ᵨ9ᜧ;<☢>ஹ?@/0A᳛((2)/0ᘤDE◀G⚪EᡠJ/0᜜LᑏNᐸPQRᓄSTUV(⌕WQR/0E/0ᱥᙳZ[\)AI0+NaC஺2NaAI0+C0?(ᡈSiO+NaCONaSiO+CO?),232322223232SiO+2NaOH=NaSiO+HO(ᡈAIO+2NaOH=2NaAIO+HO)(?E^⁚pH=7,8ᡠ`abHSiOஹ2232232223Al(0H)(3ᔡ*eᔡ*fiojinniojinn.22(3)gh⊝jkᑖ᪆DE⏚ᓄḄ"ᳮ+2H?2CrOCrO+HOE9ᜧopqrkh⊝ᔣtu4272vw(4)ᵨx⌕Ḅᦻz{|}8D?ᐭKCI`ᑮKCrOᨔḄ"KCrOk227227kᜧ((5)⏚᪵ᡂ250mLN25.00mLỚEᔣᐸE?ᐭ3*2.210mL2mol/LHSOỚᓄ('Ḅ"ᱥCrSO᪗(1+2S0-21+SO2422322346,)?ᑨᑮ¡¢Ḅ£¤?ᨬ¦§¨©¨⏚ª«⁐⁐®₩¦°ᑖ±ᑁZឮ´w?µEᐳᵨ·NaSO᪗40.00mL,ᑣᡠ`¹E'⏚Ḅºk(»᦮R½UE223ᐸPᩖZ¾?/0)94%(¿ᶇ2Áᨵᦔᦪz)(ὃ¢ÆᑴᜓTᫀḄ»É(ᑖ᪆Æ5'⏚67ÊḄ9ᜧ/0ᱥ;<☢>?@/0A᳛ᯠ¦ᔣ/0ᘤE?ᐭº2ஹNaOHஹKCIO,G/0

166FeO?@/0A᳛ᯠ¦ᔣ/0ᘤE?ᐭº2ஹNaOHஹKCIO,G/0316FeO«CrO+24NaOH+7KCIO12NaCrO+3FeO+7KCI+12HOஹ23324232ᔡêᔡêio]inniojinnSiO+NaCONaSiO+CO?,AIO+NaCO2NaAIO+CO?223232232322x1

172KCIO2KCI+3஺DஹFeO+NaCO2NaFeO+CO?.SiO+2NaOH=NaSiO+HOஹ32232322223AIO+2NaOH=2NaAIO+HO,ᯠ¦32NaCr஺ஹNaSi஺ஹNaAIOஹKCIÌ᧕ÎFeOÏ23222423223ÎNaFeOᙠÎEGÎᡂFe(OH),ᯠ¦½a`ᑮaEÑᨵNaCrO.NaSiOஹ232423NaAIOஹKCI,^⁚pH7,8,ᵫấ⏚ªÔ'⏚ªᙠEGÎpqTUV22,,…SiO+HO?HSiO+OHஹHSiO+HO?HSiO+OHxAIO+2HO?AI(OH)+OH,ÕÖpHᨵᑭ3233223223Îh⊝ᔣØ/0TᔣuvÙpH^ᑮ7,8ÚÛPÜÝᐰÎᡂßàHSiOஹAI(OH)232”ᔣaE?ᐭ⏚âã⏚ᓄpqTUV2CrO+2H?CrO+HO,ᯠ¦ᔣE?ᐭKCI,34272âãräஹ½aஹåæ`ᑮKCrO,{|EKCrOkNaCrO,227227227(1)ë/0Ú;<☢>ìᜧ/0A᳛ì@ᡠí234567Ḅ8ᵨ9ᜧ;<☢>ஹ?@/0A᳛ᦑèᫀ:9ᜧ;<☢>ஹ?@/0A᳛w(2)/0ᘤDE◀G⚪EᡠJ/0᜜LᑏNᐸPQRᓄSTUV(⌕WQR/0E/0ᱥᙳZ[\)SiO+NaCONaSiO+CO?.AIO+2NaOH=2NaAIO+HOᡈ2232322322ïðïêla]inn[a]innAIO+NaCO2NaAIO+CO?SiO+2NaOH=NaSiO+HO'2323222232xñ½íᑖ᪆òDE^⁚pH=7,8ᡠ`abHSiOஹAI(OH),233τajinnᦑèᫀ:SiO+NaCONaSiO+CO?(ᡈAIO+2NaOH=2NaAIO+HO)'2232322322

18AI0+NaC02NaAI0+C0?(ᡈSiO+2NaOH=NaSiO+HO);HSiO;AI(OH);2323222232233.22(3)?EpqTUV2CrO+2H?CrO+HO,⏚ᓄÚh⊝ᔣØ/0Tᔣuvᨵᑭᡂ4272*2.2,NaCrO,ᦑèᫀ:2CrO+2H?CrO+HOE9ᜧopqrkh⊝ᔣtuvw2274272(4)??ᐭKCI`ᑮKCrOᨔ{|KCrOkkᜧᦑèᫀ:KCrO227227227kkᜧw(5)?ᑨᑮ¡¢Ḅ£¤?ᨬ¦§¨©¨⏚ª«⁐⁐®₩¦°ᑖ±ᑁZឮ´ᦑèᫀ:?ᨬ¦§¨©¨⏚ª«⁐⁐®₩¦°ᑖ±ᑁZឮ´w“+3+222,2,=2I+S0ó`/0ḄᐵõVCrO,?/0CrO+6I+14H=2Cr+3I+7HO;I+2SO,6272,222232.31,6S0,»ᑴḄ25.00mLö⏚E⏚ḄᱥḄnmol,223..CrO,3I,6SO272232216n0.1200mol/Lxl:6=n:(0.1200mol/Lx)01200mol/LXO.04LX1~~6~n==0.0008mol,ᑣ250mL⏚E'⏚ḄᱥḄ0.008mol,0.OO81110IX294g/molஹ<øøù§ú—xl00%
⏚Ḅ==94%,ᦑᫀ94%(

19⚪ὃᱥᑴᜓᫀᱥᑖ!"#ஹᱥḄ%&'()*ᔠឋ-./ὃ01ᑖ᪆ஹ34546᦮89:;ᑖ᪆<1Ḅ=>ஹ?@ABC⚪ᐵE(⍝GHI<1Ḅ=>ᱥḄឋ⚪JKL'(9((14ᑖ)O⏚ᔆQRஹSTURLḄVWᓄᱥYZ[ᜧR]ᨵ_`a◀VWᓄᱥḄA᝞d:Jfa◀VWᓄᱥZ[ᨵg`A((1)AH:CHhᓄijA(k(4,i?CH(g)+4NO(g)=4NO(g)+CO(g)+2HO(g)?H=,574kJ.mol-?CH(g)+4NO(g)=2N(g)+CO(g)+2HO(g)?H"2222,i?HO(g)=HO(l)?H=,44kJ*mol223]ᨵHlᔠR8LNOmNOḄ8no3:1,ᵨ(᪗rstd)ᵬvR8hᓄijwlᔠR28ាyzᐰ=>(k(1ᡂᱥᐰ}R᝱)1042.8KJḄ!!?H,1160kJ/mol;2ᑏCH(g)mNO(g)=>1ᡂN(g)ஹCO(g)"HOপḄᓄ0CH(g)+2NO4222242,(g)=N(g)+CO(g)+2HO(l)?H=,955kJ»mol(2221(2)A:ឋijA(ẆᔣឤᘤᐭH&Ḅឋ"NOឤ(T?)ᩩd=>1ᡂᵬ!"ᵬ"ᙳmᜧR¡¢ḄR8J=>£¤ᑮ¦§¨©ª«ᔜᱥḄ᝞dNOᵬ00.20000ᵫ¯9°±Y(:

20s)+2N0(g)?N?wjᳮḄᓄ0C((g)+CO(g)(22?wdḄ´⊝¶ᦪK=((¸ᶇᦪº»¼ᨵᦔᦪ¾)?¿2001ºᓣÁÂT?,Ãᑮ´⊝º¿ᘤLNOஹᵬஹḄÄo1:1:1,2ᑣw=>ḄÆH,0((Ç""ஹ""ஹ"=")(3)AÉ:NHhᓄijVWᓄᱥ(SCRᢈË)(wᢈËBJf>ᵨᨬÍÎḄÏRVWᓄᱥ3ῃ◀ᢈË(=>jᳮ2NH(g)+NO(g)+NO(g)?2N(g)+3HO(g)G1ᡂImolNÑÒḄᵯÔᦪ322223N(ANa2sosÕÖ×C102'=>I,(4)AÙ:CIOWᓄVWᓄᱥ(ᐸÑᓄÛ᝞d:NONON222k(=>ÆḄᓄ02NO+CIO+HO=NO+HNO+HCI,ᑣ=>ÆḄᓄ0B22232NO+4NaSO?N+4NaSO(223224ὃᓄ0´⊝Ḅ3;ᓄ0ḄÝᑏ;ᵨÞß&ࣤᨵᐵ=>Ḅ3;Wᓄij=>Ḅ3(ᑖ᪆(1)á§ᩩdR8Ḅ8nÄo'âᱥḄÄoᡠ¯HlᔠR8LNOmNO?Ḅ8no3:1,ᑣᱥḄÄo3:1,NOஹNOḄᱥḄᑖäB3xmoLxmol,n(CH)4==Imol,222.4L122.4L/mol4NOzᐰ=>◤⌕n(CH)=xxmol=0.25xmol,§¨1ᡂn(NO)=n(NO)=xmol,ᑣçḄn?42(NO)=4xmol,NOzᐰ=>◤⌕n(CH)=xmol,4

21xmol+0.25xmol=lmolx=0.8,ᑣNOஹNOḄᱥḄᑖäB2.4molஹz0.8mol2,´X0.8NOzᐰ=>Ḅ()kJ,23.2AH24-NOzᐰ=>Ḅ=,éê3ÆH'2᪷éÞß&àÝᑏwᓄ0ì(2)?ᔣឤᘤᐭH&Ḅឋ"NO,ឤ(T?)ᩩd=>1ᡂᵬ",íᵬ"ᙳmᜧR¡¢ḄR8ὅN"CO,w=>C(s)+2NO(g)?N(g)+CO(g)222Jc(N).c(C0)22c2(NO)?ᓄ0´⊝¶ᦪK=;?ᓣÁ´⊝ᔣᔾ=>ᔣÒðì(3)᪷éVR"ÑÒᵯÔÄ©Ḅᐵñ3ì(4)WᓄVᐹᨵWᓄឋóô⏚õᐹᨵijឋὅ<1Wᓄij=>(CC(1)á§ᩩdR8Ḅ8nÄo'âᱥḄÄoᡠ¯HlᔠR8LNOmNOḄ8no3:1,ᑣᱥḄÄo3:1,NOஹNOḄᱥḄᑖäB3xmoLxmol,ö222.4L22.4L/mol(CH)==lmol,4

2214NOzᐰ=>◤⌕n(CH)=xxmol=0.25xmol,§¨1ᡂn(NO)=n(NO)=xmol,ᑣçḄn«22(NO)=4xmol,NOzᐰ=>◤⌕n(CH)=xmol,“xmol+0.25xmol=Imol,x=0.8,ᑣNOஹNOḄᱥḄᑖäB2.4molஹ0.8mol,2010.8NOzᐰ=>Ḅ()kJ,23.2AH24"NOzᐰ=>Ḅ=kJ,3.2AH2574X0.844Ḅç=()kJ+kJ=1042.8kJ,(]?H=1160,2.!?CH(g)+4NO(g)=4NO(g)+CO(g)+2HO(g)?H=,574kJ«mol,i?CH(g)+4NO(g)=2N(g)+CO(g)+2HO(g)?H=,1160kJ.mol÷?HO(g)=HO(l)?H=,44.0kJ»mol221øéÞß&à(2+?+?x4)?2«Â!lCH(g)+2NO(g)=N(g)+CO(g)+2HO(l)?H=,2222,1,955kJ*mol;ᦑᫀ,1160kJ/mol;CH(g)+2NO(g)=N(g)+CO(g)+2HOপ2H=,955kj»mol42222.1'

23ᔣឤᘤᐭH&Ḅឋ"NOឤ(T(2)??)ᩩd=>1ᡂᵬ",1ᵬ"ᙳmᜧR¡¢ḄR8ὅN"CO,w=>C(s)+2NO(g)?N(g)222+CO(g),2ᦑᫀ:C(s)+2NO(g)?N(g)+CO(g);22?ᔜᱥ¦ù¨w=>Ãᑮ´⊝s᝱ᓄ0´⊝¶ᦪc(N).c(CO?)-----9J--------gߟ0.06QXQ.060c(NO)0.080X0.080K===0.56,ᦑᫀ:0.56;ஹᵬÄoᜧâ1:1,ᓣÁºᐸÄo1:1,úû´⊝ᔣüÆ20minºᘤLNO=>ᔣÒðᑣü=>Bᔾ=>ᯏùᜧâ0,ᦑᫀ:,ìব2NH(g)+NO(g)+NO(g)?2N(g)+3HO(g)LNᐗÿᓄᔠᵫ,3ஹ+2ஹ+432220ᵯᦪ6,ᡂḄᨵᓄᱥஹᱥᡠᡂImolNᨵ0.5molᓄᱥᵯᱥḄ=0.5molx2x=3mol,ᑣᵯᦪ3N,2Aᦑ%ᫀ3N;A(4)'ᓄᐹᨵᓄឋ*+⏚-ᐹᨵឋ'ὅ/ᓄ012342NO+4NaSO?N+4NaSO,ᦑ%ᫀ:2NO+4NaSO?N+4NaSO(2232242232245678⚪ὃ;ᓄ<=⊝?@ஹᓄ01Ḅ?@ஹABCDEFG5HIὃ;J8ᳮLஹ?@MNOP=⊝QᦪK?@R⌕ᵨUVWXᱥḄOP(1)'ᓄᡂḄNOYZ[01\]^<__`ᣵᡂḄNOWbc┯e᧕┯5(

2410((15ᑖ)jJᵬ⏚l(NHCOONH)mn⁐pq,᧕ᑖsஹ᧕tsuᵨvwᧇஹyz24ᑺஹ|}ᑺE(~ᓄ<ᐶᑴᜓjJᵬ⏚l,01Ḅᓄ<234᝞2NH(g)+CO(g)?NHCOONH(s)+Q(Q,0)4322(1)᝞ᵨ1ᑴjᡠ⌱ḄᑺUjtᮞᡈᓄ-pq(ᑴᜓjJᵬ⏚╆Ḅ᝞3ᡠj'ᓄᐭᓄXᤅ¡¢ᔠᡂḄjJᵬ⏚£ᨔq¥¦ᙠᓄ(¨¥¦ᱥ©]Rª«ᑴᜓ(O:ᓄq∑ᙳ°ឋ±((2)/ᘤᵨ³t´ᓾḄ¶·¸¹Vº»01ᱥᓄ᳛((3)q∑½¾¿ḄÀᵨÁÂþÄ⁚NHC஺ᐭÇÈ(32(4)É01ÊḄ¢ᔠᱥᑖËÌÍḄÎÏ2ÐÁÑ(ÒᑏÔÀÕÖ)(×ØᑮÚÛÍ1ÜḄ2Ðc(Òᑏ⌱⚗Þß)(a(Qà[áâÚb(»à[áâÚc(ãä40?âÚ(5)åᜐᳮ᝞2ᡠ(çèᴻêḄÀᵨ:■«᎔ᔾ;U+⏚ḄÀᵨ:ᔾᦈ]ðjஹ■«ätñòᐭ01ᘤójJᵬ⏚lts((6)¶ôᑖW¢ᨵ⏚╋ḄjJᵬ⏚l᪵Íᵨ÷ᮞtᐙᑖᜐᳮÊóᐗúûᐰᓄ⏚┛ÁÑஹ|}ஹÚÛþØ(ᑣ᪵ÍjJᵬ⏚lḄᱥḄᑖᦪ80%((ÿᑮ2ᦪ)ὃᑴᜓᫀḄ;Ḅᑴ;ᨵᱥḄᔠᡂ(⚪⚪(ᑖ᪆(1)!1"ᑭᵨᑖ%&ᧅ(ᐭ%*+,┵./0Ḅ1*2ᑭᵨ+,3456ᑖ,7ᡂ89(2):;"34:;<=>⊝@ᔣBC;

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