高考化学5月模拟试卷（含解析）

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2015
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2015•wᵨ᝞yz{|}~gz{9:iᑮḄ;
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2013•[jᨵ2ᑡᕜᐗឋ`Ḅᦪ¢£????????ᐗ¥¦ᐗឋ`§¨©ªᨬᡈᨬᓄᔠ®+2+1+5+7+1+5+3,2,3,1,32ᑡ789:Ḅ;
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ᑨ;1D(<⏚=Ḅ!">ᜧ?@A⏚=("B:"CA(NaSO᧕EFGFᓄA⏚=ICa(CIO)!"JᡂḄHCIOL./IFeCI!2323"JᡂḄHCI᧕ᢵNIᡠOPCa(CIO)ஹNaSOஹFeCIQRLSᑮ5,I2233ᦑA┯W1B(45ឋXḄSY45ឋZḄ[ᣚ]ᩭIIḄ45ឋᜧ?CI,ᑣ22I+2NaCIO?2NaIO+CISNJ,ᦑB┯W12332C(7!8ᙠClஹCl\CIOHCIO,7Gaᨵᐰde!NJ2#IᑣLSf/72GeClCl஺-ஹHCIOḄᐵIᦑC┯W1D(<⏚=Ḅ!">ᜧ?@A⏚=I!">iᜧIᒕkḄiI222..ᑣC(SO),C(CO),COḄ!">ᜧIᑣJᡂḄHCOmIᡠO⏚᪷3333

1522.ᜧᐵ:c(SO),c(CO),c(HCO),c(HSO),ᦑDnf(3333ᦑ⌱D(q:r⚪ὃtḄ!"OuᐗwᓄᔠᱥyzI⚪{|}I~A⏚⏚ḄᢵNឋḄLI?Ạyz#ᵨḄὃt(.17((5ᑖM2015•)l.Omol-LKIᐭI,NJ2#:I(aq)+I(aq)zz...?I(aq)?H;IḄᱥ,ḄcপTḄᓄ᝞ᡠ(y2#3ᑮ⊝ᵨ10s,ᑣᑡ¢£nfḄ()A(¤2#Ḅ¥H,0B(aஹc¦#ḄI2#§᳛©}C(b0,10sIḄᙳ2#§᳛0.04molLsD(d¤2#ᙠ¦#ᜐ?⊝¬᝱ὃ:ᓄ®⊝Ḅ¯°±w;ᓄ®⊝²³Ḅ´>(ᑖ᪆:⊝¬᝱2#µ¶Ḅᨬᜧ▲IᡠOb⊝¬᝱Ic(I)¹1,0.4⊝Ḅ²³Iºb»Ḅᦋ⊝Ḅ½¾IᵫÀᑖ᪆"B("B:"CAஹb»ᓣÂIº⊝⌮ᔣ½¾IᡠOn2#ÅÆ2#Iᑣ¥H,0,ᦑA┯W1Bஹi§᳛iÇIcḄÂ?aIᡠOcḄ§᳛ᜧ?aḄ§᳛IᦑB┯W1Cஹb⊝¬᝱Ib0,10sIḄᙳ2#§᳛v(I)

161-0.410,i,i==0.060.04mol»L«s,ᦑC┯W1Dஹb»ḄÈḄɦ#Ḅ⊝¬᝱IᡠOdᙠ¦#Ḅᜐ?⊝¬᝱ᦑDnf1ᦑ⌱Dq:r⚪ὃtᓄ®⊝½¾ÊË⚪I⚪{|}I~᪷*Êᓄᑖ᪆ᓄ®Ì>ÍḄᱯÏOuஹஹÐX¦⊝½¾Ḅ¯°IÑ⚪ÒÓÔ®JḄᑖ᪆ஹᳮ"SÖuᮣØ#ᵨᡠ®yzḄSÖÙஹ"B⚪Ùᐳ3⚪IÛᑖ53ᑖÜ818ᑖ
2015•ÜÝᵨᓄ®2#5ᳮᑖ᪆"BOË⚪Ù▲Q
Z⏚ᙠ!8ᙠᵯ⊝Idᑖ0ßmolLZ⏚Ḅᵯ⊝àᦪ᝞⊤CZ⏚ᵯ⊝àᦪ25?
sHClOK=2.98x107HCOK=4.3xl0,nK=5.6xlO22HSOK=l.54X102317K=1.02x102?äZ⏚Ḅ/IᓣÂIKåᜧÙæ"ᜧ"ஹ""ᡈ"L"ÜÙ¥ᑡÌ>Íᨵᐵ¢£┯WḄad2aÙéḄCOêᐭ7⏚=:2CIO+HO+CO=2HCIO+CO2223

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᝱ᜧ274ᜐᳮ᣸(.22?ᙠᙠ⊝:2CrO(⁐)+2H?CrO($⁐)+H0%ᦋ'ᩩ)*+,⊝ᔣ./0ᔣ12ᑣ4ᑡ67.8Ḅ:aca(⊝;ᦪK=>?ᦋ'22b(@ᑮB⊝CrOḄCὑE᳛GHCrOḄCὑE᳛c(I@⊝J./0E᳛KLᜧH⌮/0E᳛d(⊝12@ᑮB⊝NOpHKLPᜧ.2.?CrOQCrOᨬSᡂḄCr(OH)ᙠNOᙠ>4UVNW⊝(X(஺ᡂZ[[23+3*3.32?Cr(aq)+3OH-(aq);\4,Cr(OH)ḄN^_Ksp=c(Cr).c(OH)=10,`c33e(Cr)ab10mol-L,NOḄpHcb4deᨵ(g"ᨵ"ᡈ"eᨵ")UV((3)jk:mCO(g)+2H(g)?CHOH(g)25?2CHOH(g)?CHOCH(g)+HO(g)3332?CO(g)+HO(g)?CO(g)+H(g)222

18n\^4op/0Ḅ⊝;ᦪḄ=qrsaஹaஹa,ᑣu\^4/03co(g)+3H(g)123224.4?CHOCH(g)+CO(g)Ḅᓄw⊝;ᦪK=aaaLmol(ᵨyaஹaஹaḄzᦪ{332123123⊤})(ᔣn~L_Ḅᘤᐭ3moic0Q3molH,ᐙᑖ/0ឮbᩭ\^Lᘤ223Ḅs/0JḄᑣC0Ḅᓄ᳛50%(ὃ:ᓄw⊝;ᦪḄy;ᓄw⊝Ḅ;ᓄw⊝Ḅ;ᵯWᙠNOḄᵯ⊝(⚪:¡ᭆ£¤¡ᳮ¥(ᑖ᪆(1)?᪷¨ᵯsᔾª«¬ᑨ®¯.mᵫ⊤ᦪ¨k⏚ឋHSO,HCO,HSO,HCIO,HCO,´HCIOᐹᨵ¶ᓄឋHSO23233323ᐹᨵ·ឋ¸ᔠ⏚ឋḄ>
ºḄWW»¯?½¾Ậ⏚NO?®ÀᐭSOÁÂ⋎⁐ᓫ0ᡂSe,6žẬ⏚¤Æ¶ᓄ2Çȶᓄ·/0ᡂÇ⏚QSe;(2)?*⊝ᔣ./0ᔣ12Pᜧ/0ᱥÊ^ᡈË[ᡂᱥÊ^᝞\^?'ᑣ⊝;ᦪ?'¯3+3?`c(Cr)ab10mol«L,NOḄpHcb4d,c(OH)=10mol/L,¸ᔠKspÍᑨ®¯(3)⊝;ᦪ:ᑭᵨᡂᱥ⊝Ê^ÏrÐ_◀>/0ᱥ⊝Ê^ÏrÐ_Òᑮ;¬{ÓdÔ⊝;ᦪGHᑖ¬Ḅ⊝;ᦪÕ_;¸ᔠoÖ{7ᑡ{(

19W»:W:(1)?⏚Ḅᵯsᔾª«¬ª×ᵯ⊝;ᦪPᜧᦑ»ᫀs:'ᜧ¯..?ᵫ⊤ᦪ¨k⏚ឋHSO,HCO,HSO,HCIO,HCO,232333a(ÚÛḄCOÀᐭrÜ⏚ÝNO0ᡂHCO,/0ḄÞ¬{sCIO23+HO+CO=HCIO+HCO,ᦑa┯à¯223"b(ÚÛḄSOÀᐭã⏚ÝNOᡂHCOQSO,Þ¬{sSO+HO+2co=2HCO23322332+SO,ᦑb.8¯3c(ºä0Ḅ⏚Ḅ⏚ឋåᑣW¬^åᜧÓæ\^dGpHdºNOÊ^å[ᑣoçºNOḄᱥḄÛÊ^ᐵéc(NaCO),c(NaCIO),c(NaSO),ᦑc.23238¯d(Óæ\^dGᱥḄÛoç⏚¤êÛNaOHNOëᐰQã⏚ஹ¾Ç⏚ísÆᐗ⏚ᑣCὑNaOHḄ_s:V(HCO)=V(HSO),V(HCIO)ᦑd┯à2323ᦑ»ᫀs:ad;?½¾Ậ⏚NO?®ÀᐭSOÁÂ⋎⁐ᓫ0ᡂSe,6žẬ⏚¤Æ¶ᓄ2Çȶᓄ·/0ᡂÇ⏚QSe,¬{sHSeO+2SO+HO=Se?+2HSO,/0232224Sᐗᓄᔠïᓣñ¶ᓄᱥsHSO,24ᦑ»ᫀs:HSeO+2SO+HO=Se?+2HSO;HSO;23222424(2)?a(᝞\^?'ᑣ⊝;ᦪK=>?ᦋ'ᦑa.8¯22b(ᵫE᳛ᐵ>
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20d(᝞PᜧNOôÞÊ^ᑣ⊝.ᔣ12⊝12@ᑮB⊝NOpHKLË[ᦑ┯à(ᦑ»ᫀs:ac;3+.3.1..103+?`c(Cr)ab10mol«L,NOḄpHcb4dc(OH)=10mol/L,c(Cr)3„33..c(OH)=10,10,eᨵUVᡂ,32ᦑ»ᫀs:eᨵ¯(3)ᵫõöL÷kø/0mx2+/0m+/0mÓÒÔ¬ᑣÔ¬Ḅ⊝;2ᦪGHᑖ¬Ḅ⊝;ᦪÕ_ᓽK=aaa,,3CO(g)+3H(g)?CHOCH(g)+CO(g)2332úû(mol)33xx11^3ᓄ(mol)xxxx11^3⊝(mol)3,x3,xxx6-322633ᘤḄs/0JḄᑣ=,x=1.5,1R^XIOO%ᑣCOḄᓄ᳛s=50%,ᦑ»ᫀs:aaa;50%(ঢ

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2,m2Fe+HO+2H=2Fe+2Ho(2223.(2)q⁚pHj⌕8slmAḄFeᡂuvwx◀zlmpH{◀Feᦔ᳛~᝞^2ᡠ3+(ᑣ◀Fe4ᑴlmḄpH
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:Zn(OH)CO2ZnO+HO+CO?;22322ᔡ*ᔡ*çiojioniojinnᦑcᫀ
gCuஹZn;Zn(OH)CO2ZnO+HO+CO?;2232222.(4)ᵯ$4ᙠ▢᩽ÀᵯpᡂZn,ᐸ▢᩽Ḅᵯ᩽/01
:+2e=Zn+4OH;□᩽ÃK᪷&pᜫᵯpᡂK¤□᩽Ḅᵯ᩽/01
4OH,4e?HO+O?,HI2212Àᑮᐵé1:Zn,2eQ,ᡂlmolM4ᡂḄO
0.5mol,ᓽ;Þ+ᵯ¬522o
Zn+2MnO+HO=ZnO+2MnO(OH),ëZnᙠ¸᩽ᜫᵯpᡂZnO,ᐸ¸᩽Ḅᵯ᩽/22,01
:Zn+HO,2e=ZnO+2H;22..“+ᦑcᫀ
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