高考化学模拟试卷（三）（含解析）

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ᑣc(Ag)CDæᜧᑮèéê᣸ᑡ.H???û"ᦑ⌱C(FGHI⚪ὃLM¸¹23ð⊝üýð⊝Ḅþ"ÅCDḄüý"CD÷ᜧ"üý÷ᜧ(6((2ᑖ)ᨵᐵÿḄᑨᡈ⊤Ḅ()-,A(ᵫ:H+OH=HO?H=,57.3kJ/mol,:0.5molHSOḄImolNaOH(aq)(aq)2(l)24Ḅᔠᜧ57.3kJB(C?C?H=+119kJ/moI,:!"#$#%&'((#)“!"#)C(+,Ḅ-./0-12ᑖ45ᐰ789ὅ&;D(2gH5ᐰ78<ᡂ᝱?285.8kJᑣA/78ḄᓄCDEF:2H+O=2H2222ὃHIJK0ᯚM;78;O0(P⚪IᓄCJKOḄRMᓄ(

13ᑖ᪆IAஹ⏚VO0JKḄO0W⏚WVḄXJK<ᡂImol?Ḅ-⏚YZDO[\ᓣ^_Bஹ`aRbឤᑖ᪆ᑨRd^def_Cஹ12-MF./◤⌕ᔾᦈ_DஹᓄCDEkl᪗nᱥ,Ḅpqr᝱JKklsᔠᓄCDEtᦪᐵt_YwIY:Aஹ0.5molHSOḄImolNaOHḄᔠ-⏚?24ᜧ57.3kJ,ᦑA_Bஹ#%MᓄF!"#ZDᔾJK!"#R^#%$!"#'(ᦑB┯z_Cஹ+,Ḅ-./0-12ᑖ45ᐰ7812-MF./◤⌕ᔾᦈ{ὅ&;ᦑC┯z_12Dஹ2gHᱥ,ḄFlmol,A/78ḄᓄCDEF:H+O=HOপH=,285.8kJ/mol/22(g)2(g)2ᦑD┯z_ᦑ⌱A(H}I~⚪ὃO0ḄᭆKᵨᱥ,ḄRd^defᓄCDEḄᑏᑣ(ḄKᵨ(ஹ⌱⚪(~⚪ᐳ6⚪⚪4ᑖᐳ24ᑖ(⚪ᨵᡈ⌱⚗sᔠ⚪(wᫀᒹ⌱⚗;⌱⚪0ᑖ;wᫀᒹ⌱⚗
⌱2ᑖ
⌱Ḅ4ᑖ
⌕⌱┯¡0ᑖ)7((4ᑖ)ᙠpH=lḄ£⁐ORᜧᐳ¥Ḅ¦§¨()+2+2“2++,,A(NHஹMgஹSOஹClB(BaஹKஹOHஹNO3+2+,+2+,2,2,C(AlஹCuஹSOஹClD(NaஹCaஹClஹCO43ὃHI¦§ᐳ¥©⚪(

14ᑖ᪆IpH=lḄª⏚ឋ᪷a¦§®¯R°ᔠ<ᡂ±²ஹ/2ஹ?+¯R³<´ᓄµJKᑣ¦§ᜧᐳ¥¶°ᔠ¦§Ḅ·⁐ᩭYw(YwIY:A(⏚ឋO¨¦§®¯JKᜧᐳ¥¦§ᙳF£⁐ᦑA_“B(HஹOH°ᔠ<ᡂ?¯Rᜧᐳ¥ᦑB┯z_2,C(CuFº⁐£⁐¯sᦑC┯z_.2.22D(HஹCO°ᔠ<ᡂ?0/2CaஹCO¯Rᐳ¥ᦑD┯z(33ᦑ⌱A(H}I~⚪ὃ¦§Ḅᐳ¥F^⚣ὃH½¾¿⚪OḄÀÁÂÃĦ§®ḄJKFYwḄᐵÅÆÇÈᑖYJKḄ¦§ᐳ¥ὃn¦§Ḅ·⁐⚪ÉÊ\¯ᜧ(8((4ᑖ)ËJKA(g)+2B(g)?2AB(g)(JKFJK)ÌᑡᔜÏᡠ⊤Ḅ222MᓄsᔠÑÒᱯᑡᳮḄA(B(C(D(ὃHIᓄCÕ⊝×Øᳮ(ᑖ᪆IÑÒᱯᑡᳮF:᝞ÚᦋMÜÝÕ⊝ḄᩩßÕ⊝àᔣḼRãäåæçᦋMḄᔣ×Ø(èᵨÑÒᱯᑡᳮJKkl⌮JKᔲᑣÑÒᱯᑡᳮ¯〉ᵨ(YwIY:Aஹᓣ^[\Õ⊝K⌮ᔣ×Ø⌮JKì᳛KᜧJKì᳛¯sᔠÑÒᱯᑡᳮᦑA┯z_Bஹᓣ^[\Õ⊝K⌮ᔣ×Ø[\d^ABḄd¯sᔠÑÒᱯᑡᳮᦑB┯z_2ஹîᜧïWÕ⊝ᔣ×ØᡠðïWdᜧABCḄdᜧ¯sᔠÑÒᱯᑡᳮᦑC┯2

15z_DஹîᜧïWÕ⊝ᔣ×ØᡠðïWdᜧABḄdᜧ[\d^ABḄdisᔠ22ÑÒᱯᑡᳮ
ᦑDñᦑ⌱DH}I~⚪ὃÑÒᱯᑡᳮḄèᵨᩩßÆÇᓄCÕ⊝×ØḄòᔠKᵨḄὃÊ\¯ᜧnèᵨÑÒᱯᑡᳮḄ{ókl⌮JKñ94ᑖ
2010ôõö÷ᓄCᝄᣴúûüýCþ
ÿᵫẆ"ᨵᱥᔠᡂᓄᏔὶ"ᝄḄᓄᔠᱥᓄᵨᩭᨵ!"#CO,$%&'Ḅᓄ()*+:CO+Pda+HO?CO+Pd?+2HCl-.!01234Ḅ50A⚪7&'ᩩ9-:;ឋ:CO,PdB⚪7&'PdCI=>ᓄ2Cᙠ᪗A-%ᡂ11.2LCOBCDEḄᵯG+2mol2D⚪7&'CO+>ᓄHᱥ2ὃJK>ᓄ:;&'ᑖ᪆KCO+PdCI+HO=CO+Pd?+2HCI
CᐗOḄᓄᔠPᵫ+2PᓣT++4PCPbᐗOḄᓄ222ᔠPᵫ+2UV+0,WᔠᐗOᓄᔠPḄXᓄYZ[⚪YZKWCO+PdCI+HO=CO+Pd?+2HCICCᐗOḄᓄᔠPᵫ+2PᓣT++4PCPbᐗO222ḄᓄᔠPᵫ+2UV+0,A&'PdCI+>ᓄᑺCCO+:;ᑺCᑣ:;ឋ:CO,Pd,ᦑA34_2BPbᐗOḄᓄᔠPᵫ+2UV+0,&'PbCI=:;
ᦑB┯a_2Cᙠ᪗A-%ᡂ11.2LCO,DEḄᵯG+1mol,ᦑC┯a_22

16D(CᐗOḄᓄᔠPᵫ+2PᓣT++4PCCᐗOḄᓄᔠPᓣT=>ᓄCᡠdC஺+>ᓄHᱥC2ᦑD34(ᦑ⌱AD(JhKi⚪ὃj>ᓄ:;&'Ckl(%Ḅᑖ᪆mnḄὃjCo4&'ᐗOḄᓄᔠPXᓄpqiᭆsᓽYZC⚪uvwxᜧ(10((4ᑖ)aஹbஹcஹdஹe|}ᱥ~ᙳᨵ}ḄᐗOCᙠᩩ9-$%᝞ᡠDᓄCᐸa5ᓫ~CbᙠA-5"#Ccஹd5>ᓄᱥCe5[ᐗOḄᨬTP>ᓄᱥ'ᓄᱥC5}ᵯY~Cᑣam5()A(ClB(NC(SD(C22ὃJKᱥḄ(ᑖ᪆Kᑭᵨ2ᑖ᪆YZCa5ᓫ~CbᙠA-5"#Ccஹd5>ᓄᱥCe5[ᐗOḄᨬTP>ᓄᱥ'ᓄᱥ
u5}ᵯY~CᵫDᓄᐵC(ᐗOஹᐗOᓫ~pᓄᔠᱥᔠDᓄᐵ(YZKY:5ᓫ~CbᙠA-5"#Ccஹd5>ᓄᱥCe5[ᐗOḄᨬTP>ᓄᱥ'ᓄᱥC5}ᵯY~CWᔠDᓄᐵC(ᐗOஹᐗOᓫ~pᓄᔠᱥᔠ(A("¡>"v¢£ᓄᔠ¤ᑮᐗO>ᓄᱥCᦑA┯a_B(a5N,b5NH,c5NO,d5NO,e5HNO,ᔠ⚪¦CᦑB34_232C(a5S,b5HS,c5§>ᓄCd5¨>ᓄCe5HSO,ᔠ⚪¦,ᦑC34_224D(§>ᓄªḄ'Ḅ⏚+ª⏚
¬ᵯY~CᦑD┯aCᦑ⌱BC(JhKi⚪ὃj®ᱥC¬¯°ឋ⚪u
±¦᪷³c´d+>ᓄᱥ[ᐗOᨵµ}3ᓄᔠPC±¦ᑭᵨ2YZCvw¶(

1711((4ᑖ)-ᑡ¸¹CºᱥḄᑖ»᪀#}ᦪᨬµḄ5()A(»¾¸B(2,ᵬq¾¸C(À¸D(3,Áq¸ὃJKᑖ»᪀ÃÄ´ᑖ»᪀#(ᑖ᪆Kᐜ4¸¹ḄÆÇCᓽÈɶᦔḄË;GCÌ᪷³ᐜÇÍ᜜ÏḄ;ᑣCÐ;G⌲ÒºÓË;GCᨵÔ}Ë;GÕᨵÔ}ºÖ(YZKY:A(»¾¸ᨵ2}Ë;G,ᡠdºÖᨵ2}CᦑA┯a_B(2,ᵬq¾¸CHCH(CH)CHCHᨵ×}Ë;GCᡠdº¹ᨵ4}CᦑB34_»33(À¸CHCCHCHÙÚᵬqCᐳᨵÙ}Ë;GCᡠdºÜᨵ2}CᦑC┯a_323D(3,Áq¸ᨵ3}Ë;GCᡠdº¹ᨵ3}CᦑD┯a(ᦑ⌱B(JhKi⚪ὃj(%ᑖ»᪀#Ḅᭆs´'ᵨÝC⌕ß(%ᐹᨵ᦮ᔠÝḄmnCvw¶(12((4ᑖ)â-Cãwᙳ+O.lmol/LḄ¨}äå:æCHCOOHäåஹ?NaOHäåஹCHCOONa33äå(-ᑡ12x34Ḅ5()A(äåḄpH:?,?,?B(ᵯçÉḄ+..C(?´?¶#éêᔠÍḄäå:c(Na)+c(H)=c(OH)+c(CHCOO)3D(?´æ¶#éêᔠÍḄäå:c(CHCOOH)+c(CH33ὃJKᵯY~ᙠäåḄᵯçë⊝;îïYḄ'ᵨ;ᵯY;ᳮ(ñ⚪Kᵯçë⊝¡äåḄpHñ⚪;îïḄYñ⚪(ᑖ᪆KA(¶ãwḄ⏚òîäåḄ⏚òឋᑨᐸpHᜧô_B(ᨵ᪷çGḄîõᵯçC⏚ᡈòᢓᑴᵯç_C(᪷³ᵯ₹úឤᑨ;

18D(᪷³ᱥᧇúឤᑨ(YZKY:A(â-Cý⏚5⏚pH,7ஹË>ᓄþ5òCᐸäåḄpH,7,ý⏚þ5ò⏚îäåᕈឋ,pH,7,ᜧḄ⏚ḄpH,ᡠᱥḄḄᐸpHᜧ:,,
ᦑAB(⏚!"#$%&'#ᵯ)*⏚+,-ᓄ!ᢓᑴ#ᵯ)*⏚1ᵯ$*,-ᓄ!2ᵯ$*ᡠ⏚ᢓᑴ#ᵯ)Ḅ3,-ᓄ!*ᡠ4#ᵯ)5Ḅc(OH.):?,?,?,ᦑB.C(ᕈᵯ4ឋ*▢□)9ᡠ:ᵯ₹<*ᡠ᪷>ᵯ₹?ឤAc(Na)+c(H)=c(OH.)+c(CHCOO),ᦑC3D(DEḄ⏚+,-ᓄ!FᔠH*ḄDEIᜧJK*ᡠᐸLᩭḄJN*O᪷>ᱥᧇ?ឤAc(CHCOOH)+c(CHCOO)=0.05mol/L,ᦑD┯R33(ᦑ⌱DTUVW⚪ὃZ[1ᵯ$Ḅᵯ)
\]ᜧ
᧕┯⌱⚗D,`aDEFᔠH*LᱥḄbcdLᩭḄJN*d᧕┯T(eஹWᔁᒹijὃ⚪+⌱ὃ⚪klᑖ(n13⚪*n17⚪djὃ⚪*opq⚪ὃrbjstu(n18⚪*n20⚪d⌱ὃ⚪*ὃr᪷>⌕wtu(ஹjὃ⚪13((9ᑖ)AஹBஹCஹDஹEyzᕜ|ᐗ~*ḄL9ᦪIᜧ(BL9Ḅᨬ᜜ᵯ9ᦪᐸ᜜ᵯ9ᦪḄ2K;CḄᨬ-ᓄᱥḄ#ᓄᱥᐸ,ᓄᱥrᡂJX;EA;AஹBஹCᐗ~4*oJDb"ᡂL9pᦪ<Ḅᓄᔠᱥ(uᑡ⚪V(1)ᑏ5BḄᐗ~:C((2)Dᙠᕜ|⊤4£neᕜ|
n16¤¥(Na"ᔁ:-Na-(3)CE¦ᡂ)9ᓄᔠᱥEC,qᑏ5Ḅᵯ9§:(3

19(4)ᑏ5JpE+DᡂḄᓄᔠᱥ#Ḅᓄ¨©3§:NaO+HO?2NaOHஹ222NaO+2HO?4NaOH+O?(2222(5)XḄ#ª⏚(«"⏚"""ᡈ"4")ឋ*ᐸL®ᵨ)9©3⊤°V♦*NH+HO?NH-HO+H(4232ὃTV£±²᪀ឋḄ<´ᐵ¶ᵨ(ᑖ᪆VAஹBஹCஹDஹEyzᕜ|ᐗ~*ḄL9ᦪIᜧ*BL9Ḅᨬ᜜ᵯ9ᦪᐸ᜜ᵯ9ᦪḄeK*ᨬ᜜"¸¹8pᵯ9*ᑣ᜜nJᵯ9*ᑣBCᐗ~;CḄᨬ-ᓄᱥḄ#ᓄᱥᐸ,ᓄᱥrᡂJX,ᑣCNᐗ~*XNHNO;EA*AஹBஹCᐗ~*oJDb"ᡂL9pᦪ<Ḅ43ᓄᔠᱥ*»DḄL9ᦪᜧ7,Dd஺ᐗ~*AdHᐗ~*A+E
»EḄL9ᦪᜧ8,ᡠENaᐗ~*½$u¾⚪($uV$:AஹBஹCஹDஹEyzᕜ|ᐗ~*ḄL9ᦪIᜧ*BL9Ḅᨬ᜜ᵯ9ᦪᐸ᜜ᵯ9ᦪḄeKᨬ᜜"¸¹8pᵯ9*ᑣ᜜nJᵯ9*ᑣBCᐗ~CḄᨬ-ᓄᱥḄ#ᓄᱥᐸ,ᓄᱥrᡂJX,ᑣCNᐗ~*XNHNO;4SEA*AஹBஹCᐗ~*oJDb"ᡂL9pᦪ<Ḅᓄᔠᱥ
»DḄL9ᦪᜧ7,Dd஺ᐗ~*AdHᐗ~*A+E*»EḄL9ᦪᜧ8,ᡠENaᐗ~*(1)ᵫÀᑖ᪆¦ÁBdCᐗ~*ᦑuᫀd:C;(2)Dd஺ᐗ~*L9᪶᜜ᨵ2pᵯ9*ᨬ᜜ᨵ6pᵯ9*0ᙠᕜ|⊤4£neᕜ|*n16¤¥*ᦑuᫀd:e;16;Na-(3)CNᐗ~*ENaᐗ~*ᡂᓄᔠᱥdNaN,d)9ᓄᔠᱥ*ᵯ9§d,3

20Na-Na-Na-ᦑuᫀd:(4)E+DᡂḄᓄᔠᱥd-ᓄ!+¹-ᓄ!*-ᓄ!+¹-ᓄ!ᑖÅ#Ḅᓄ¨©3§dNaO+HO?2NaOHஹ2NaO+2HO?4NaOH+O?,222222ᦑuᫀdVNaO+HO?2NaOHஹ2NaO+2HO?4NaOH+0?;222222(5)XdNHNO,Æ⏚╆2⏚1*È᪷)9᧕#$%Éᐸ#ª⏚ឋ*ᐸL®ᵨ)43♦,9©3§⊤°VNH+HO?NHHO+H,4232JᦑuᫀdV⏚NH+HO?NHHO+H(4232TUVW⚪ὃZ[ᐗ~£±²᪀+ឋḄᐵ¶*ÊËᐗ~$W⚪ᐵÌ*᪷>Í#$ஹᱥÎḄᩭᑖ᪆$uᓽ¦*`a(2)4Dᙠᕜ|⊤4Ḅ¤¥%
d᧕┯T(14((8ᑖ)ᡃÑ4Ò4ÓÔÕᐗ~+ᨵÖᐗ~Ḅ×ᔜ⚗ᢣ᪗ÛZÜÝÞßḄ(☢ᑖ᪆áâã4₝Ò4¦"ḄåæᨵÖᐗ~AsḄÛâ©ç+èé(Asᙠ4₝Ò4⌕ASOḄ§êᙠ)V23?ì1000g4₝Ò᪵î'¥ï|ᜐᳮᑴAòó*½ô᪵î4¦"×ᨵḄAsᐗ~õöᓄdHAs஺33?õòóö÷ᑮ250mL┵ú4*ûüᐭ2,3þ0.2%Ḅÿ

Ḅ:HAsO+I+HO?HAsO+I+H()2332234ᑡ⚪(1)᝞₝!᪵#$%&'ᜐᳮᑴ+,-
,/01᪵#2ᵨ┡ᑁ67ᡂᮞ:ᮞ;<=7>?@ᐭBCDEFGHIJ/JឮL=MNO+,-
((2)PQRST:1HASO+1I+1HO,1HASO+2I+2H332234(3)᝞ᑨVWXᑮZ[\,
ᵫ^⁐`a⁐bᢝdᑖfg`⁐(

21(4)ᡃjk!ᵨlᱥnᑴᑺ$pqr⁐%s᪗uvwX:r⁐!Ḅxy1gz{I(2.000mg/kg,|}~₝!᪵#ồy1mg/kg,ᑣ~₝!᪵#ᔠ("ᔠ"ᡈ"gᔠ")(ὃ\ᱥḄᡂᡈ-1ᱥḄy1;ᓄRSTḄ;WX(ᑖ᪆(1)2ỚḄ/:/01᪵#2┡ᑁ67ᡂᮞ:ᮞ;<=7>?@ᐭBDEFGHIJ/JឮL=MNO+,-
.(2)HAsO?HAsO,Asᐗᓄᔠᵫ+3ᓣ¢+5
ᐳᓣ¢2(1?1,ᐗḄᓄᔠᵫ0¤¥,1
ᐳ¤¥2ᓄᔠᓣ¤ᨬ§¨©ᦪ2,ᦑHAsOḄ33¬ᦪ1,IḄ¬ᦪ1,®ᔠQ¯ឤஹᵯ₹¯ឤᐸµᱥ¬ᦪ2(3)¶ᙠỚᨵᐵḄᓄWXºᵨ»ᢣ½ᑺᵨ0.001mol/L᪗uỚ
WX,-
=[\ᦑ¾⁐`ᓄᵫ^⁐`a⁐¿⌕dᑖfg`⁐(4)ᵫÁÂ+:As,I,ÃÄ|}1kg!#AsᐗḄ1ÃÄ|}ᑨV(2ÅÅ(1)2ỚḄ/:᪵#67OᙠBD
ÅÆᨵᦔᡂᑖ
Å(ᑭᵨIJ+ᑮᡠ◤,-
Ë»ÂÌ:/01᪵#2┡ᑁ67ᡂᮞ:ᮞ;<=7>?@ᐭBDEFGHIJ/JឮL=MNO+,-
ᦑᫀ:/01᪵#2ᵨ┡ᑁ67ᡂᮞ:ᮞ;<=7>?@ᐭBDEFGHIJ/JឮL=MNO+,-
(2)HAsO?HAsO,Asᐗᓄᔠᵫ+3ᓣ¢+5,ᐳᓣ¢2(1?1,ÎঢᐗḄᓄᔠᵫ0¤¥,1ᐳ¤¥2ᓄᔠᓣ¤ᨬ§¨©ᦪ2,ᦑHAsOḄ”¬ᦪ1,IḄ¬ᦪ1,®ᔠQ¯ឤஹᵯ₹¯ឤᐸµᱥ¬ᦪORST2,.HAsO+I+HO=HAsO+2I+2H,332234ᦑᫀ11112;2;(3)¶ᙠỚᨵᐵḄᓄWXºᵨ»ᢣ½ᑺᵨ0.001mol/L᪗uỚ
WX,-
=[\ᦑ¾⁐`ᓄᵫ^⁐`a⁐¿⌕dᑖfg`⁐ᦑᫀ:
ᵫ^⁐`a⁐bᢝdᑖfg`⁐;

22(4)ᵫÁÂ+:As,I,2751mO.OOlmol/LxÅ+m(As)=,lOOOmg1kgÑ!Iy10.0015x=1.5mg/kg,2.000mg/kg,ᦑᔠ,ᦑᫀL5;ᔠ(\ÓÔ⚪ὃÕᱥy1Ḅ-X¢⚣ὃ\×nᓄஹWXnPQஹᐵ¬TḄ|}ØÙÚᑖ᪆|}zÛḄὃÕ⚪ÜÝÞØ(15((8ᑖ)᝞ßᔜᱥáâᓄâºãḄᱥᵬஹåᙳáPQᓄᔠᱥ¿▢ஹ□PQéᦪê1:1(ᵬë»⏗åáíîºᵨḄᓄï(BஹDºNáðñ(òᑡ⚪(1)ᵬḄóôá§õᡭ((2)DḄD
Wᐭ÷⏍O
ùú⁐ûüD
ùýឋឋòᵨÎ⌕Ḅᦻ
ᑏᐵḄ:DNH,ᡂḄNH-HOᵯ332..NH«HO=NH+OH(432A

23(3)!ḄKOHᐳ#$ᑏ%&Ḅ:NH+HCO+2OHCO433,+NH?+2HO(32ὃ()*+ᱥḄ-.(ᑖ᪆)ᵬஹᙳ4ᓄᔠᱥ7▢ஹ□:ᦪ<1:1,ᵬ=>⏗@ᑣᵬNaHCO,3ANaCO,4BCDᵨḄᓄFᵫHIJᓄᐵK=LNHHCOM(JBC஺D23432NH,CH0,OPQ⚪(32P):ᵬஹᙳ4ᓄᔠᱥ7▢ஹ□:ᦪ<1:1,ᵬ=>⏗@ᑣᵬNaHCO,ANaCO,4BCDᵨḄᓄFᵫHIJᓄᐵK=LNHHCOᑣB32343CO,DNH,CH0(232(1)ᵫSᑖ᪆=LᵬNaHCOTUVWᡭᦑPᫀ:VWᡭ[3
.(2)DNH,ᡂḄNH-HOᵯNHHO=NH+OH,\]ឋ,
332324ᐭa⏍c\d⁐,..ᦑPᫀ:]ឋ;DNH,ᡂḄNH-HOᵯNH«HO=NH+OH;332324./3)NHHCO,!ḄKOHᐳ#%&Ḅ:NH+HCO+2OHCO43433,,+,2.+NH7+2HO,ᦑPᫀ:NH+HCO+2OHCO+NH?+2HO(3243332(h)i⚪ὃj*+ᱥḄ-.kl᪷nᱥoḄᵨ⌶ஹqᡂrᑖ%&stu-.◤⌕xyz{|ᐗ~ᓄᔠᱥLIs(16((8ᑖ)ᵫAᐸ*+ᧇᔠᡂᓄᔠᱥE,ᐸᔠᡂ᝞:(rᐸ*+ᱥᙳḕᶍ)A(CH,O|34!"E(QH.OJᐗ6B

24HaOH/HO2A*L:RCHCIRCHOH,AḄᑖIᵬ,7⁐($Pᑡ⚪)”(1)ᑏ᪀:ACH=CHCHOH,DCHCH(OH)COOH;223(2)HIḄ%&¡¢4
ᡂ%&[(3)ᑏ%&Ḅᓄx:2CHCH(OH)COOH+2Ho(3zὃ()ᨵ+ᱥḄ-.(ᑖ᪆)D¤ᡂ6ᐗ¥E,¦§DIᨵ¨©n⚪ª«¬C?D4ᓴ~Jᓄ©Ḅ;AḄᑖIᵬ7⁐ὶKAḄᑖrA?B?CḄJᓄ=LACH=CHCHOH,©¯ᓄ○±²²³´µ¤¶¯ᓄ
ᡠ✌ᐜº²²22³´CI
ᡂᡂCHCHCICHOH,BCHCHCICHOH,B»¯ᓄ©ᡂ¨ᡂC,C23232CHCHCICOOH,CᙠNaOHI%&ᡂḄDCHCH(OH)COOH,2molD½¥ᓄ%&33oOᡂᐗE,EnOᑖ᪆(P)(1)D¤ᡂ6ᐗ¥E,¦§DIᨵ¨©n⚪ª«¬C?D4ᓴ

25~Jᓄ©Ḅ;AḄᑖIᵬ7¾⁐ὶKAḄᑖrA?B?CḄJᓄ=LACH=CHCHOH,©¯ᓄ¨±²²³´µ¤¶¯ᓄᡠ22✌ᐜº²²³´CI
ᡂᡂCHCHCICHOH,BCHCHCICHOH,B»¯ᓄ©ᡂ¨ᡂ23232C,CCHCHCICOOH,CᙠNaOHI%&ᡂḄDCHCH(OH)COOH,ᦑPᫀ33CH=CHCHOH;CHCH(OH)COOH;223(2)ACH=CHCHOH,©¯ᓄ¨±²²³´µ¤¶¯ᓄᡠ✌ᐜº²²³´22CI
ᡂᡂCHCHCICHOH,ᦑPᫀ:
ᡂ%&[\4(3)DCHCH(OH)COOH,2molD½¥ᓄ%&ᡂᐗE,Eᓄx3\ÀÁ⏚$2cHeH(OH)COOH+2H஺
32\ÀÁ⏚$ᦑPᫀ2CHCH(OH)COOH+2H0(32

26(h)i⚪ὃjᨵ+ᱥḄ-.◤⌕xêÄḄ«¬tuᑭᵨ
klEÆẚÈÉᔠᑖ᪆ᨵ+ᱥᑖtu-.◤⌕xyz{|ÊËḄឋo⚪ÌÍᜧÏ1711ᑖÐÑᐶÓVqᙠÔSᦈÖᑮ᝞«¬:Øஹ┛ஹÚஹ╅sÜÝÞßàᙠCOá2âIãäÏåÃÚᙠCOáâIãäcᡂḄæ⁐ᱥotuç᝞èé:2êãäḄÚëìíᐭᑮîᨵïðcoḄÖáñIÚᙠᐸIòóãäôõᐰ%&c÷ᓾ
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ᙠcoḄᱥḄᩩᨵᱥஹᨵᑺ2ᱥ!ᑮḼ#$2
%&'()*Ḽ#+ᑡ-#./01ḄDAᵨ3ᡫ-Bᵨ56-#ᘤᡫ-Cᵨ89-#ᘤᡫ-Dᵨ8:ḄṺ<ᡫ-Ꮇ>1⁐ᱥNaO2Ꮇ>2:⁐ᱥNaCO23Ꮇ>3:⁐ᱥNaO?NaCOḄ@ᔠᱥB'CDE*ᡂḄ⁐ᱥGH᝞+JKL.ᫀNOPQRS.ᫀ1TUV⁐ᱥWXYZᐭ〉V3]₩᪵`ᐰbcW3ᔣᐸZᐭf⁐ghXicijᡂk⁐⁐ᱥNaO2.ᫀ2?TUV⁐ᱥWXYZᐭ〉V3]₩᪵`ᐰbcW3ᔣᐸZᐭVḄBaCIcimP⁐no2?☟qᱏsTtuiWXYvZf⁐g⏚XifxyPQ3
ᵬ{|.ᫀ1}ᑮḄRS&01ᐸᳮᵫ⏚ci3yឋgᲩjk4
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27⁐noBaCO,ᡠEḄ⁐ᱥᨵNaCO,?vZf⁐ghXifxyPQ323xEḄ⁐fNaO(z(5)ᑏmᙠᓄḄᓄ|.4Na+3CO=2NaO+C(222(6){|⁐ᱥᨵᓄ(ᔲ{{|Ḅ$ᳮᵫ:&{ᱥfᐗ¢(ὃ$LḄ¤⌕ᓄᔠᱥ;ᱥḄ§?␺©Ḅ.ᫀ>ª(«⚪L®¤⌕Ḅ¯°±ᐸᓄᔠᱥ(ᑖ᪆L(1)´µPQ?Ḅᩩᑖ᪆¶·;ᙠ¸¹º+ᱥ◤⌕ᐹᜓḄᩩ:ᱥ;¾¿À;!ᑮḼ#$Á(2)´µÂï°?3ஹᓄÄᱥᑖ᪆Á(3)´µ⏚3ciyឋᑖ᪆ᑨÆÁ(4)´µnoᡂᑖᑖ᪆ᑨÆ⏚Çnog⏍&j⁐ÉxfᓄÁ(5)ᙠᓄ*ᡂ?ᓄÁ(6)´µᱥCᡂᐗ¢ஹஹᐗ¢ᑖ᪆ᓄ|ᐗ¢ÊឤÁ(1)ᙠ¸¹º+ᱥ◤⌕ᐹᜓḄᩩ(1·LL)ᱥ(2)¾¿Àᡈᨵᱥ(3)!ᑮᱥḄḼ#$;ÎÏᩩ{ÐᐹᜓÐÑ)*(ḄᒓÓÔÕÖ×ᱥ¾¿À☢ÙḄÚÛ(¾¿ÀÜᐙᑖÜᒓÓ(⌕Þᜧᱥ¾Ḅ¿À☢Ùàᱥ9áᡈᐸjâÞZḄãÔÁᦑ·ᫀ:ᨵᱥ;¾¿À;!ᑮḼ#$Á(2)A(ᵨ3ᡫ-¾3ᒓÓ,ᦑA&æᔠÁB(ᵨ56-#ᘤᡫ-ᓄ?ᙠ$ᩩ+ᒓÓᦑB&æᔠÁC(ᵨ89-#ᘤᡫ-ᓄ?ᙠ$ᩩ+ᒓÓᦑC&æᔠÁD(ᵨ8:ḄṺ<ᡫ-à¾ç◞é!&ᑮḄḼ#$ᡫ-ᦑDæᔠ;ᦑ⌱D(

28(3)TUV⁐ᱥWXYZᐭ〉V3]₩᪵`ᐰbcW3ᔣᐸZᐭf⁐g⏍Xijk&&Õëᓄ⏚3ci3yឋâg⏍jkÁᦑ·ᫀ:⏚ci3yឋg⏍jkÁ(4)TUV⁐ᱥWXY
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#$ᑮḄ&'()ᨵ()A(+ᡂ&'B(,ᓄ&'C(./&'D(+0&'E(10&'ὃ34ᨵ5ᓄ6&'Ḅ7ᔠ'ᵨ(ᑖ᪆4᝞::

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_`aᜧ(19((14ᑖ)╋deᱥC,ᓄᔠᱥNV$gᑖh᪛ᾦ()Ḅᔠᡂ!᝞4kl:RCHORCHCOOH0HজHCN/OH-........KUnJH.ঝ>0/H+ASOCln-----RCOOHRCOCIRCOOR'(1)AḄn,opqḄrsOtu((2)AᙠvᓄᑺᵨEUH&'xᡂB,y&'Ḅ&'()O+ᡂ&'ᡈ./&'(2CffHCOOCH-஺VOH(3)|(ᓄᔠᱥCḄᑖh}OCHO,ᐸ᪀}O(ম”(4)Ax&'Ḅᓄ6}O+2A(KH).OH——►^^-COO«H+2Ag+3+H0834

305
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35(2)ᙠᨔᙳᨵBa
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ᑴᜓÐÑ╅+»ÓᵯDᰚÕḄMgCl,ÖPᵨMgO,ᐸØ+MgOᰚÙ*ÚLὑᜧ2Iᵯ4
ÛÜÝ+¢Á⌕Ḅᓄ²ᧇ*Þß²àá+»ÓᵯD⛳SÛÜEᩭᑴᜓNaOHஹHS2C1E5AᑮḄäÜ5ååæᨵ¢çᩖa*éê±ᐭ¢çᓄ_ìᑺ*ᩖaíî*ᜐᳮ2z+2.ðḄÜEñ◤óᐭ□õö÷ᣚᛞ*ᐸØ+ᵨìᑺᜐᳮðḄÜE5ñæᨵ#IMgஹCa,ßឋᩩûZÚᡂíî*ü%õö÷ᣚýᵯDÛÜEᙠõö÷ᣚýᵯDþ5óÿ
ᣚḄᵨ■HC1ᔠᰦ■C1ᐭ▢᩽᪵!Ḅ22NaOH(

38(5)#ᨔấ&⌕(ᵨSiHCI)*+,-
ᐸ/-ᱥSiCI1ᓄ3SiHCI4567ᵨ(-343:ᩩ<=ᙠ20Lឤ@AB@ᘤDḄEF:3SiCI(g)+2H(g)+Si(g)?4SiHCI(g)(G423H⊝JHSiHCIᱥKḄLMNᑖP30.140mol/LQ0.020mol/L,RHᐰTᩭVWXY232+\,ᳮ_`◤bὑNaCIḄKL3kg(ὃefghiVjᐸkᔠᑭᵨ(ᑖ᪆f(1)nopᓄghḄqrᨵ#tuᵨqrᨵvwஹᵯz᪆j
ᣚr{|}~((2)MghDᐜ
ḄᓄᑮᓫKᑭᵨᓄᔾᦈᓫKᑮ
ᨬJᵨXᓄ(3)MgOḄᰚe32852?ஹᰚeᵯ}ὑ2+2.4)hDᨵᩖK
MgஹCa,(:ᩩ<=ᡂ¡¢£
ᣚ;᪷¦ᵯ}hḄ-ᱥ§¨EF(5)ᑭᵨ©ªᑖ᪆r᪷¦H⊝HSiHCIᱥKḄLMN«¬Ḅ®ᱥKḄL᪷23ᵯ}¦2NaCI+2HOCI?+H?+2NaOH,«¬ᳮ_`bὑNaCIḄKL(zzz}~f}(1)nopᓄghḄqrᨵ#tghpᓄ+ᔆ°u(ᵨḄᑴᜓphḄqrᨵ:vwrஹᵯz᪆rᦑ~ᫀ3:vwrஹᵯz᪆r(2)MghDᐜ
ḄᓄᑮᓫKᑭᵨᓄᔾᦈ¶ᓫKḄᑮ
ᨬJᵨXᓄᔾᦈᛞDḄᓄ¸EFq¹º3fSO+CI+2HO=HSO+2HCI22224ᦑ~ᫀ3:SO;CI;SO+CI+2HO=HSO+2HCI;2222224

39(3)MgOḄᰚe32852?ஹᰚeᵯ}ὑ
ᡠ+\`
ᵯ}ᰚ¼MgCI½¾¿2À╅ᦑ~ᫀ3:MgOᰚeÂÃbὑᜧLᵯ"2.(4)ᵨÅᑺᜐᳮJḄhD)ᨵÈLMgஹCa,Yឋᩩ<=Ãᡂ¡¢£
ᣚ2বᡠ⌕ᵨ□
ᣚᛞ◀ÍMgஹCa;ᵯ}hḄ-ᱥᨵXஹÎQÎᓄÏXÎᓄÏEFÎXÐEFᡠᵯ}hᙠ
ᣚᵯ}ÑD2+2.ᦑ~ᫀ3:ᵨÅᑺᜐᳮJḄhD)ᨵÈLMgஹCa,Yឋᩩ<=Ãᡂ¡¢£
.ᣚ;■HC1ᔠᰦ■C1ᐭ▢᩽᪵!ḄNaOH;22(5)EFq¹ºÓ:3SiCI(g)+2H(g)+Si(s)?4SiHCI(g),23®L(mol)n0ÔᓄL(mol)2xx4xH⊝L(mol)n,2x4xᑣ:4*=0.02€^஺1/1_*201_=0.4[71஺1,x=0.1mol,n,2x=0.140mol/Lx20L=2.8mol,n=3.0mol,ᵯ}ᵫ2NaCI+2Hoel?+H?+2NaOH,2222mollmolm(NaCl)2X58.5g3mollmol}:m(NaCI)=350g=,

40ᦑ~ᫀ30.35(eØfÙ⚪ὃÛÜghiVḄkᔠᑭᵨ⚪nÝND{⍝kᔠឋÅ⚪ßjÓàeáâ#ᐙᑖὃÛܸᮣåFᵨæẠÓàḄè⌕«¸ᨵé᦮ḄÓàë᪀Qᑖ᪆í⚪Ḅè(