高考化学模拟试卷（二）（含解析）

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:;Ḅ>?@5CI+I+6HO712H+10CI+2IO,2223ᦑC┯D(n(CI)+n(O)=lmol,n(CI)x71g/mol+n(O)x32g/mol=!2222Än(CI)=0.4mol,n(O)=0.6mol,22ᦑn(CI):n(O)=2:3,,>?@Ḅz+ᦪᐵ/ÙᦑD┯(22ᦑ⌱:B(Z[⚪ὃ½ᓄÈÉ:;:;ḄzÎஹÔDஹᭆÛ|
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ᦪa,æᐸᐰèᢗᐭ50mLbmol-LḄê⏚ëì
s<íᐸᐙᑖ:;âᎷðNO8ñ¥ḄÈÉfᱥàâ2ᑡ¹º67Ḅ8âàA!áòᨵᒕô
ᙠëìÑõᐭö⏚F
FeÖ÷øë
Cuë3.B!áòᐰèë
ᑣë쥼*ᨵFe3,2*D&ëìáòùÀúᨵFeஹCu
ᑣa,bḄᐵ/:b?80yl,a/3
ὃZ[ᨵᐵÅᔠᱥ:;ḄzÎâg⚪[zÎ⚪âᑖ᪆[Aâëìᨵê⏚᪷
Ñsᐭ⏚
ëìᐹᨵ¦½ᓄឋ
áòåஹäüÃë"Bâáòᐰèë
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ᜫᵯḄᐗᐗᵯḄ⏚Ḅᐗ⏚ᓄᑺஹ⏚ឋᵨ᪷NᐗឤᓄᑺᵨḄ⏚Ḅ!"ᑨ$%D&ᜫᵯḄᐗᐗᵯḄ⏚Ḅᐗᜫᵯᦪ)*+&,-.,:A&012ᨵᒕ56789ᨵ⏚᪷ᙠ89;<ᐭ>⏚?*@ABCᙠD⏚12ᙳF8,ᦑA┯I%“B&@ḄJKLMNOPQᡂḄST;UVWX89YZ[\ᨵFe,ᦑB┯I%C&⏚NᐗḄᓄᔠTᵫ+5Tᑮ+2T@bQ336mL&᪗defgᓽ0.015molNOMijᓄឋḄ⏚WO.OlSmol,ᡠOᓄᑺḄ⏚Ḅ!c==0.3mol/L,UᨵZl0.015inol0.05L,0.3,ᦑC┯I%ᑖ⏚ijD⏚ឋᑣbD&᪷o⏚Ḅ⏚ឋḄ⏚ᙠFeNO
CuNO
W3yl,a
mol+2yamol=3332

14(3y,ya)mol,ᓄឋḄ⏚ᑮḄᵯpAFeஹCuᜫḄᵯᵫANOqZḄUVbᱥᡠOᓄឋḄ⏚W:mol=mol,⏚sᱥtḄJW.(3v,v2)11101+17101=01஺1,⏚Ḅ!W:C(HNO)34y(1-a)mol3y(1~a)+2ya(3y-ya)(3y-ya)4y(1-a)3aa~33330.05L33==80y(l,),W⏚UNFᒕ5ᡠOb?80y(l,),ᦑD%ᦑ⌱D(.⚪ὃᓄUVḄ⚪)!ptJឤ[ஹᵯឤᙠᓄḄᵨ7ᨵᐵᓄUVḄ⚪DQḄᑖ᪆FᓄF(ஹ,-⚪(ᐳ4⚪ᑖ58ᑖ)8((14ᑖ)AஹBஹCஹDஹEஹFᕜ¡¢£ᐗ¤¥ḄV¦ᦪ§¨©ᜧᐸCஹFᑖ¬+Z¢£ᐗAஹFᐗḄV᪶tᦪ¯°CஹDᐗV᪶tᦪ¯±2,FᐗḄᨬ᜜´ᵯᦪ¨᜜´ᵯᦪḄ0.75µ(B¶BᐗḄᨬ᜜´ᵯᦪᑁ´ᵯᦪḄ2µEᐗḄᨬ᜜´ᵯᦪpAᐸᵯ´ᦪ(¸¹-.(l)lmolᵫEஹFᐗºᡂḄᓄᔠᱥ»ᵫAஹCஹDSᐗºᡂḄᓄᔠᱥQᡂ¼½¾ᐰ?Àὑ?ὅḄᱥtḄJW8mol((2)AஹCஹFÃNOÄᡂᵬஹÆÇZTÈV▢Êᵬᨵ18ËᵯÆᨵ10Ëᵯ,2ᑣᵬoÆḄÊÌÍWHS+OH=S+HO;2(3)ÎẆÐÑ7:ᓄÒÓoÔÕ᝱ᨵᐵo×ÌØᐵ(ᓫtBḄÚÛÒWakJ/mol(ᵫBஹCᐗºᡂḄᓄᔠᱥBC14g¾ᐰÚÛÜÝÒJbkJ,ᑏÝᓫtBᓫtCQᡂBCḄÒᓄÌÍ:C(s)+O(g)=CO(g)?H=,(a,2b)kJ/mol;212(4)ßàáᙠâãḄᩩåæNOᵨACoBCᑴèᓫtA(ᙠpéêḄIஹIIËëì22

15íᘤᑖ¬ᐙᐭImolAClmolBCஹ2molAC2molBC&Z[ᩩåæᐙᑖ?ᑖ¬ð22ᑮñ⊝&íᘤã!*pg&æᑡ6ḄAB,11A&ðᑮñ⊝ᡠ◤⌕ḄMÃ:1B&ðᑮñ⊝?ACḄöᓄ᳛:1=112C&ðᑮñ⊝?BCḄᱥtḄJ:I,HD&ðᑮñ⊝?AḄéêᑖᦪ:I,II25
ᵨBᐗḄᓫtoEᐗḄᓫtNOᑴᡂᵯ᩽ùᐭᵫAஹCஹDSᐗºᡂᓄᔠᱥḄ8.9᪀ᡂᵯüᑣᵯüÇ᩽ÍW2Al,6e+8OH=2AIO+4HO22ὃ.ýþÿ᪀ឋḄᐵᵨ⚪ᐗᕜᐗᕜ⊤⚪ᑖ᪆AஹBஹCஹDஹEஹFᕜᐗḄ!"#ᦪ%&'ᜧFᐗḄᨬ᜜+ᵯ"ᦪ&᜜+ᵯ"ᦪḄ0.75-ᑣ&᜜+ᵯ"/8,ᨬ᜜+ᵯ"ᦪ/6,0CஹF12ᐗ!"#ᦪ:C,FᑣF/SᐗஹC/஺ᐗ;BᐗḄᨬ᜜+ᵯ"ᦪᑁ+ᵯ"ᦪḄ2-ᨬ᜜+ᵯ"ᦪᨬ6/8,ᑁ+ᵯ"ᦪ78/2,ᑣBḄᨬ᜜+ᵯ"ᦪ/4᪷:!"#ᦪB,C;ᐸᵯ"+ᦪ᪷:!"#ᦪᜧ@;FḄ"ᦪICḄ"ᦪᜧ2,ᑣDḄ"ᦪIAᜧ10,Lᔠ!"#ᦪᜧ@;ᐸᵯ"+ᦪ᪷:!"#ᦪᜧ@;

16Alᐗ;AஹFDᐗḄ!"᪶F"ᦪGHICஹDDᐗ!"᪶F"ᦪGHJ2,ᵫ>FḄ"ᦪICḄ"ᦪᜧ2,ᑣDḄ"ᦪIAᜧ10,Lᔠ!"#ᦪᜧ@;

17?FnᜧpᜧA(?Fᜧ]᳛jJᑣᑮ⊝ᡠ◤⌕Ḅj:C,CᦑA¢£¤B(?HCFᱥḄeᡂ¢I/=ᦔ⊝ᑣ⊝ᑮ⊝¦ACḄ§ᓄ᳛:C=?,ᦑB¢2£¤C(?Fᜧ⊝¢ᔣª«ᑣᑮ⊝¦BCḄᱥḄe:,CᦑC┯¤D(?HCFᱥḄeᡂ¢I/=ᦔ⊝ᑮ⊝¦AḄᑖᦪ:C=?,ᦑD┯¤2ᦑRᫀ/:AB;(5)¯ᓫAIḄᓫᑴᡂᵯ᩽²ᐭᵫNaOH[\F᪀ᡂᵯ³b`]2AI+2NaOH+2HO?2NaAIO+3H?,Alᜫµᵯ"ᓄᔠpᓣ·ᑣAI/o᩽,ᵯ᩽]/2Al222...,6e+8OH=2AlO+4HO,22.ᦑRᫀ/2AI,6e+80H=2AI0+4Ho(22¹º»⚪ὃ½¾¿ஹL᪀ஹឋḄᐵÀᵨ⚪ÁÂÃÄᜧÅᔠឋÄὃ½<ƹÄ6ᐗḄÇÈQR»⚪ḄᐵÉÊËÌÍÎÏ!"L᪀ᐗᕜ⊤ஹᐗᕜḄᐵ(9((14ᑖ)ÒÓ¯⏚┛ᵨÖ×ØÙ(ÚÛÜFᑭᵨÞßᡠàá¿(âᑖᜳᢝá¿åᶍµ)ᔣ⛳HCaCI[\FèᐭNHHC஺;ᑴÒÓ¯⏚┛(232é⌱ëḄìí?îᮞî?ðᓄñ?yzᓄ┛

18?⛳Hðᓄ┛[\?òx⏚j?6moi•!,ó⏚?⛳Hôó_?⛳HNaHCO[\31
á¿AFöᘤaḄ÷øᑖ\ùᧅöᘤbFb`]Ḅs"{|}/+z.CaC0+2H=Ca+H0+C0?á¿DḄûüFb`]Ḅᓄý{|}/2NHCI+Ca0H"þCaCI+2NH?+2HOá¿BFÿḄ22232
ᓫḄᫀᑨᡠ⏚┛⚩ᔲ!"#$%&'⏚┛()ᐙᑖᤅ-.ᵨ012ᐝ᯿5.67ᔲ89:;<=>.?ᨵ:;<=>ᑣ!"#$.?Bᨵ:;<=>ᑣC"#$DḄEFஹ=>HIJ3
Kᐭ〉'NOP.CQRSᱥUាWXᐰZ[.\].ᡠ]^⏚"⏚"ஹ"`"ஹa-=NH."S"cឋ.ef+HONHHO+Hᵨghij⊤l4
mDQRnᙠᜐq◍.sq◍!tuNᔾᦈQRὃyz"#ᩞᧇ;ghijḄ~ᑏ⚪zghZ[⚪;HO⚪ᑖ᪆z1
᪷ᑨᘤ;ᘤbS!⏚┛⏚Z[;QRDSᑴN;QRBḄ◀ᣵᢵ8ᩭḄᓄ2
%&'⏚┛()ᐙᑖᤅ-.ᔲᨵ:;<ᦔ[3
ᓄᙠ)S89)4
uNᜐᳮ

19¢z(1)ᘤaḄᑖ£ᧅ;ᘤbS!⏚┛⏚Z[z*z+CaC0+2H=Ca+H0+C0?;QRDSᑴN.ᓄ¥ij!2NHCI+Ca(OH)4322CaCI+2NH?+2H஺;⛳HNaHCO1◀ᣵᢵ8ᩭḄᓄ.ᦑ¢ᫀ!:ᑖ£ᧅ22323.XaCO+2H=Ca+HO+CO?;2NHCI+Ca(OH)CaCI+2NH?+2HO;?;322422322(2)%&'⏚┛()ᐙᑖᤅ-.ᔲᨵ:;<ᦔ[.?ᨵ:;<ᦔ[.ᑣª«!"#$.ᦑ¢ᫀ!:%&'⏚┛()ᐙᑖᤅ-.ᵨ012ᐝ᯿5.67ᔲ89:;<=>.?ᨵ:;<=>ᑣ!"#$.?Bᨵ:;<=>ᑣC"#$+(3)ᓄ╄ᙠ)S89)^⏚ឋ.ghij:+HONHHO+H,ᦑ¢ᫀ!®ᝄ=NH.⏚+HONH«HO+H;232(4)sQRuNᜐᳮ.ᦑ¢ᫀ!:tuNᔾᦈQR(y±z²⚪ὃ³ᓄ¥ஹghijḄ~ᑏ´.µ¶S´.·¸"#ᩞᧇ1ᵨ:;<ᦔ[ᑨ(10((14ᑖ)®º»NaCIஹNHஹCO´!eᧇᐜᑴNaHCO,½¾9¿À`(ᨵᐵZ[Ḅᓄ323¥ij!:NH+CO+HO=NHHCO32243NHHCO+NaCI=NaHCO?+NHCI;2NaHCONaCO+CO?+HO433432322

201
⏚⛳HÂ)Z[.Ã᪆⏚ÄᨔOḄefCÆÇ᪗a⏚ĵÉ)b⏚ÄÊË᧕ᑖc⏚ÄḄ¶ÍÎÏÐ.ᡠ»ᙠS✌ᐜIᨔ᪆d⏚ÄḄÒÓឋᜧÉ⏚Ä2
ÕÖ×ÐØ᪷mDᑴ`eᳮ.½Ù⏚ÄḄᑴᜓ?ÜÝ¥%ÞßᓄNOKᐭàḄ⛳HÂ)Sᑴᜓ⏚Ä.QR᝞âãᡠlãSᜳᢝஹæÓᵨḄᘤçèé¢âᑡᨵᐵë⚪z?ìQRSḄèᑺ⛳H⏚Äᐸïᵨ◀ðCOSḄHCINO2?:QRSñò⏚ḄïᵨᔾᦈZ[XḄNH;3?I0P.ᑖgNaHCOᨔOḄóï\]ᑖgóïḄ.sóïᡠ◤⌕3Ḅᚁᴻᘤᨵøᴻùஹ£ᧅஹúû?üÜÝ¥ᵨãSýQRᐸþQRç½Ù?ÿ
ᐜaᐭ᩽᧕ᡂᜧḄᨵᑭᓄ"ᔾᦈ%ᡂ&'Ḅ"⏚)*++?-ᨵ./01ᙠ345Ḅb6789:45ᳮᵫ=>ᜧ?9@☢BCDCOḄᔾᦈ᳛+2

21(3)"⏚)GHIᡠKL?MNḄOᮞᐙᑖSTᡠKUVWXYஹ[\]N^ᑣᡠKL`"⏚GḄ]Nᑖᦪ^86.3%((4)bcdefghijklᑴnoN"⏚)GḄpq:ᵨ"⏚)*?〉N⛳vwxST(ὃ{|}~(ᑴ~q)(⚪|i⌕Ḅᐸᓄᔠᱥ(ᑖ᪆|(1)"⏚)Gᑖ᪆ᑨ(2)?পᑴnᓄ"ᨵᓄ)ᑖ᪆ᓽ(II)¡⏚?STᑖ᪆¢(III)ᑖ£L?¤ᵨḄjk¥¦ᑖ᪆¢?(1)ᑴn"⏚)Gᐜ⌕KᑮḄ⛳vwx¨᧕ᑖ᪆ᑨ(II)45ᦋª«STᱥḄ9@☢B¬ᜧᑖ᪆ᑨ(3)ᓄ/p®¯ᔠST°ᑖ᪆ᑨ%ᡂUV^"⏚┛²I"⏚)Gᑖ«Ḅ³ᔠᱥ]Nᑡpfµ(4)⚪[¶·¨ᡠ/Ḅᑴn"⏚)GḄ¸¹ºᓽ()aஹ"⏚)G᧕;ᦑa½¾ᔠ¢|:(1bஹ"⏚)GḄHIᑖ?¿ÀÁÂᐵᦑb½¾ᔠcஹ"⏚)GḄÄÅឋ½᝞"⏚G;ᵫᓄ╋ᩭ"⏚)GḄ&hÊᡠ¨T✌ᐜ᪆gdஹ"⏚)GḄÄÅឋ"⏚Gᦑd½¾ᔠᦑ¢ᫀ^:c((2)?পᑭᵨx⏚ᑴnᓄ"ᓄ"`ᨵᓄ)"⏚)G?x⏚STᡠ¨°⛳v"⏚)GḄ=^Í◀ᣵ`Ḅᓄ)`ḄHCIᦑ¢ᫀ^:⛳v"⏚)GḄ;◀ÐCO

22(II)jk°`ᨵᒕÒÓ¡⏚?STᡠ¨¡⏚Ḅ¦ᵨ=ᔾᦈÔSTḄNH,ᦑ¢ᫀ^:ᔾᦈÕSTÖḄNH;33(IH)ᑖ£gNaHCOᨔḄ¥¦=ᑖ£L?¤ᵨḄjk¥¦=°Ø¥¦;¿¥¦3ᡠ◤⌕ḄÚᴻÜᘤ^:ÚᴻÞஹßᧅஹáâᦑ¢ᫀ^:°Ø;ÚᴻÞஹßᧅஹáâ?(1)ᑴn"⏚)Gᐜ⌕KᑮḄ⛳vwxᡠ¨TᐜᐭÓ᩽᧕ᡠ¨a7ᐭÓãäÍbᐭᓄ"ãäÍᓄ"ḄᐙᑖST;᩽᧕ᡂᜧḄᨵᑭᓄ"ᔾᦈ%ᡂ&'Ḅ"⏚)*ᦑ¢ᫀ^:;᩽᧕ᡂᜧḄᨵᑭᓄ"ᔾᦈ%ᡂ&'Ḅ"⏚)*(II)45ᦋª«STᱥḄᓄ"?Ḅ9@☢B¬ᜧCDÍᓄ"Ḅᔾᦈ᳛ᦑ¢ᫀ^:>ᜧ?9@☢BCDCOḄᔾᦈ᳛2(3)"⏚)GHIᡠKL?MNḄOᮞᐙᑖSTᡠKUVWXYஹ[\]N^ᑣᡠKL`"⏚GḄ]Nᑖᦪ¨ᓄ/p®åæfµKᑮç%ḄST^2NaHCO=NaCO+CO?+HO,32322NaHCO+Ca(OH)=CaCO?+HO+NaOH;NaCO+Ca(OH)=CaCO?+2NaOH;ST%ᡂḄ"⏚┛ᱥ3232232312glOOg/inol]ḄN==0.12mol;e²I«ḄL12,28g`"⏚Gᱥ]ḄNx,"⏚)Gᱥ]ḄN^y,⚪éKᑮ|Kᑮx=0.1mol;y=0.02mol;0.liriolX106g/inci].12.28gᑣᡠKL`"⏚GḄ]Nᑖᦪ=xl00%=86.3%,ᦑ¢ᫀ^86.3%;

234⚪[¶·NHHCO+NaCI?NaHCO?+NHCI;Kᑴn"⏚)GḄpq.ê¤ᵨá4334~`ᐭ°NCO;ë⛳vNaCO`ᐭ°NCOìKᑮ"⏚)G2232ᦑ¢ᫀ^:ᵨ"⏚)í?〉N⛳vwxST+ᡈëá~`ᐭ°NC஺;ë⛳vNaccas`ᐭ°NCOì-+2{ð|ñ⚪ὃòÍᑴ}~Ḅóvᳮô⚪=h⍝jkö÷øᔠ⚪ᐙᑖḄùúÍᓄ/¸¹Ḅpp☢☢¿⚪øᔠឋûüᜧýþ/%ÿᙢḄឋᨵḄ1116ᑖூᨵᓄ௃ᨵᱥXCHOBrᑖᨵ!"#$ᐸ&᪀()*1213600H0IIIIII-O-C-CH?—CH-C-0-nᐸLn*,-ᑖḄ&᪀*./XḄᑖ&᪀$01᝞3Ḅ4ᓄ56ᔣEḄ89:;ᐭFeCI9:=>?⁐ABCGஹME"FNaHCO9:AB5331MḄ&᪀()*HOOC,COOH;Gᑖᡠ!"#ḄHIJ⁂LஹMLC2EN"=>ḄABᨵ⌱PQRb;aSᡂABbUVABcWᓄABdXYABZᓄᑺ-A3ᵫB4ᓄᡂDḄᓄ]^)JHOCHCHOH+OOHC,CHO+2HO;22224Gᙠ`aᩩcd=>AB>ᡂᑖeᡂ*CHOḄᨵᱥfᨵᱥghiḄjkᓄl9…HO—C-CHj—CH—rsABḄᓄ]^)HOOC,CH=CH,COOH+HO;2

245
6ᙠXᑖ&᪀$Itᨵ"FFeCI9:=>?⁐ABḄ!"#$uEᑖvw3O0H0HOTS-OC-CHj-CH-C-O-ahCHṺrḄ`kYᱥyᨵ`$ᑣXḄ&᪀()JC6
FFG{*|ᑖ}᪀~$FḄᑖyᨵLஹMLL!"#$u|`lrN"|ᨵMLᑣFḄᑖ&᪀ᨵ2ὃ5ᨵᱥḄ.⚪5ᨵᱥḄᓄឋ.ᑖ᪆5X=>8ABᑮAஹBஹC,Bg=>WᓄAB>ᡂM,M"FNaHCO9:A3B$ᑣBᨵ⏣ML$MᨵL$ᵫMḄᑖ)g$M*HOOC,COOHA⏚ᓄᑮE,ᔣEḄ89:;ᐭFeCI9:?⁐$ᨵML$NᡠᑮG,G"3FNaHCO9:AB$ᑣGᨵL$5
Xᑖ&᪀$Itᨵ"FFeCI9:=>?⁐33ABḄ!"#$uEᑖvwrḄ`kYᱥyᨵ`$&ᔠᨵᱥXḄᑖ)ᨵḄ&᪀,gB*HOCHCHOH$ᑣD*OHC,CHO,G*22,EḄ&᪀B*5$X&᪀()*.00H0HOT$V0-C-CH2cn-c-o-ah

25,(5:X=>8ABᑮAஹBஹC,Bg=>WᓄAB>ᡂM,M"FNaHCCh9:AB$ᑣBᨵ⏣ML$Mᨵ○L$ᵫMḄᑖ)g$M*HOOC,COOH(A⏚ᓄᑮE,ᔣEḄ89:;ᐭFeCI9:?⁐$ᨵML$NᡠᑮG,G"3FNaHCO9:AB$ᑣGᨵ£L$(5)Xᑖ&᪀$Itᨵ"FFeCI9:=>?⁐33ABḄ!"#$uEᑖvwrḄ`kYᱥyᨵ`$&ᔠᨵᱥXḄᑖ)ᨵḄ&᪀$gB*HOCHCHOH$ᑣD*OHC,CH஺$G*22,EḄ&᪀B*5$X&᪀()*_0OHOHO-rVoc-CHj-ai-c-o-ahHO-E-CHு—fH-E—OHOH(1)ᵫrsᑖ᪆g$MḄ&᪀()*HOOC,COOH,G*$ᑖᡠ!"#ḄHIJ:LஹML$ᦑᫀ*:^1஺0(,(0஺ᓃLஹMLC(2)E*$ᨵvw$gFª«=>SᡂAB$¬®$᧕°Wᓄ$g=>XYABN"=>UVABᦑᫀ*:b;(3)ᵫB4ᓄᡂDJHOCHCHOH=>ZᓄWᓄ>ᡂOHC,CHO,AB]^)*
22ZᓄᑺZᓄᑺ-AA

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