河南省名校2022-2023学年高三上学期阶段性测试（四）化学试题（含答案）

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20222023
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1.ᔁᐳ100ᑖ஺ὃ90ᑖ஺2.ᔜ⚪ᫀᑏᙠ⚪ᓱ஺3.ᔁ⌕ὃᑁᦟ᱐!1,!2"#$஺4.%&ᵨᑮḄ*+,-./H1C12N14O16Na23Al27Fe56#ஹ⌱2⚪⚪ᐳ143⚪453⚪3ᑖ4ᐳ42ᑖ஺ᙠ53⚪67Ḅ89⌱⚗;4<ᨵ#⚗>?ᔠ⚪A⌕BḄ஺1.ᡃᐸ┶Sb!"✌$Sb%N,P&'(஺*ᑡᨵᐵSbḄ/0┯2Ḅ3A.SbḄᨬ6ᓄᔠ89+58B.:;ḄSbḄ<ᓄᱥᨵSb?O3ஹSbO25C.?@SbḄAᦪCDAᦪEF970D.┶ḄᓫDᨵHICJ╄HṃCJ┶3ṃᐗNḄ&NOPQ2.RSTᓄUVW஺*ᑡXᓄᱥDᙠRSḄᵨ⌶Ḅ\]^_6`Ḅ3⌱⚗RSḄᵨ⌶\]^_AcdeKMnO4fgḄấiᵨjklmnᑺKMnOqfgᐹᨵq<ᓄឋB☢ᒹtᵨuvᡭjxdᑺyᯏ☢ᒹuvᡭ{|}~ஹ᧕ᑖ^Cᵨᮞᜐᳮ⏚ឋkᮞqᐹᨵឋD╅ᔠᵨᑴj□╅ᔠ
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NᙠPQᵨR

2C.ᵨPᮞᑴCa2++2OH-+Cl=Ca2++CP+CIO-+HO22D.ᵨvwNa2s2O3Ḅឋ◀{g<ḄCl24C1+SO3-+5HO=10H++280^+8CE2229.¡}¢£¤<ᑴ¥¦wḄỚV¨᝞!©:¤¤ᮞ¤ᮞ«¬Ḅ®~/ᓄI,Ḅ~I2ḄCCI4ᓫAỚ10.!ᑡᨵᐵ²*BᓄᔠᱥḄឋA#bcḄ&')A.ᔣCaCl<´ᐭ¦wḄCO2?ᡂCaCC)3µ¶2B.NO?´ᐭg<2·ᑮ¹º⁐
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⍗¾¿WÀÁ⁐C,ÂÃÄ<ḄÅ⌕ᜧÈÉᱥWNOஹCO2PM2.5D.qËᱥAḄwḄSO2Cl2´ᐭg<ḄឋÌÍ11.ᔣl
XmLNaOH<´ᐭÎwḄCO2
ᐙᑖ78·ᑮXÐÑᔣᡠ·X<⌲ÓZᐭ0.2mol-LTḄÔ⏚>?CO2ḄᱥAḄw3ᡠZÔ⏚
ÕÖ×ḄᐵØ᝞ᡠ஺!ᑡᑨÚ┯%Ḅ&'A.NaOHḄxÛW2bmol-L1B.Ü2ab,ᑣᡠ·XḄAᡂᑖWNaHCCX,NaOH

3D.Üb=2a,ÞV'Ô⏚)aLeᑣ?78ḄjlWH++CO=HCO12.!ᑡßà3áâãä8bcḄ&')ßà3áâãZåæᨵ¦wNH4HCO3M
ḄçèéᙠçèêëIìíḄÀ⁐PîçïPANH4HCO3ñឋîçï¿ð¼?⁐µ¶Ð⁐µ¶ö÷BᜫSOFe
NC)3)2ᨔ
ù/CqFe
NOJ2ᨔ
Cy⏚ÑÓZKSCN¿Àᓄ¿Aᔣ2úæᨵ2mLöûxÛNa2sO3Ḅçè<ûeZᐭ1mL2%H2')2᳛ḄDᜧüýþᑮÿḄA.AB.BC.CD.D13.◀ᨵᵯḄH+ஹOH-!᜜#$%&ᨵ'ᱥ)Ḅ*ḄK?ஹNa\Fe2\Fe3\SO+ஹSO,Ḅ-./஺᪷2᝞4567#8ᔠᳮḄ;<>HI⏚ᔆL⁐N᪷PQR⁐DEFG—*•L⁐FGᵫ1U@.W⁐XYA.ABCDᨵFe3+ஹFe2+B.A%&EFGᙠSO,ஹSO,C.IJ⏚L*F#MᡂḄO⁐QRSNOTSO?D.↾VWXᯚ⁐#ZL[⁐\]ᴻBC&_`ᑮb⁐cᯚ14.dᑖNfSᱥ)Ḅᑖg7hᓄᔠj!kḄᐵm᝞4ᡠo#pᑡ8rᔠᳮḄ;<>

4A.ᙠuᓄᑺḄwᵨp#a%zcஹd}ᓄSbB.aᑖd'ḄTe'ḄᡠḄᙳឋC.p#Fe&Ḅe#&Ḅe'D.ᵨ]ᴻᑖ↾VḄaTḄe#]ᴻ☠FᨵMஹ⌱⚪+⚪ᐳ4⚪#ᐳ58ᑖ஺15.(15ᑖ).⊡¢£ᱥḄ¤⌕ᡂᑖSᴁ§⏚¨¢#W£©ª«&I⏚஺¬®E¬¯°±£ᱏFe?+ḄGᙠµCFe?’Ḅ*(Ꮇ¯ᩖ)¹7)஺º»K'lFelCN%À7Fe?+ÁM[⁐ÂÃ஺ÄÅpᑡÆ⚪+(1)ᵬE¬Sȱ£©Fe?+ḄGᙠ஺z£ᱥÉÊஹËLÌ஺VÍ*ᡠÌÎÏÐÑ#ᑖÒᐭK31Fe(CN)6ÀTKSCN#_`µ×Ø஺জᵬE¬LÌFÚÛḄpᑡÜwÝḄ;(ß᪗á)஺a.ᵨ]ᴻᙠâᧅᤅåæÒçLÌ᳛b.Ìèéêëâᧅéêc.zÌèìí#îᐸðñâᧅᑁóঝÌÒᐭK3ூFe(CN)6ÀᡈKSCNᙳ÷ø#ᐸ¤⌕AùS஺(2)ûE¬¯°᝞pC£ᱏFe2+Ḅ*஺56B+V£©10ᱏஹÉÊËÒýBCḄIþ⏚#ᙠ〉Ḅᩩᡂl(X)mL஺20.00mLᡠ!"஺#ᔣ!"%ᐭ'H2O2*+,%ᐭ'NaOH+/012+312'45ᩭ*78ஹ:;+<=>?@ឤB+0.64g>?஺জ"+2O.(X)mLGHᵨḄJᘤL(M“⏚PQBR”ஹ“TPQBR”ᡈ“25mLW”)஺ঝ#"+%ᐭHOYZ0[GḄ\]^_PL,<*ᡠ>?Ḅa⁐Lo22ঞf3#"ḄHOᣚLCl?jklᑮnḄ+oHᵨHOḄpᜐr஺2222টᵫuvᦪxyz+{ᱏ}ᱏ"~mgFe2+»(3)FeSOqjᵨ⊡ᑺ+HᵨY0C+ᵬ0C3Fe3+ᓄLFe?+,ᑭ?ᔾᦈ஺Lv+¡y᝞uvuv^ᫀuv¤¥〉Fe2(SOj3¨R"+%ᐭ0Cᱏ+©₩«*+Q%⏚ឋ®⏚¯°⁐±²

5ᵫ³´uvkᔲ5“0C3Fe3+ᓄLFe2+”Ḅ¶·¸¹º»¼½ᳮᵫ஺16.
14ᑖÀÁᑭᵨÂÃÄᓄᑺÅ~ÆÇNiஹAlஹFeÈᐸÊᓄᱥ+Ì~ᨵÎḄÏᾦÀᑴᜓNiSO^GH?஺ḄÓÔÕ_᝞N&RFGZ[G\╨^ᓄᑺ#►3—Hf⏚HaZNni••⏚F►◀c►⏚ᓄ#♦NiSO/6HqNiOஹ³Ö×ØÙ+K[Fe
OH]=l.
xlO-3\K[Ni
OH]=2.0x10-15osp3sp2¹ºᑡÛ⚪Å1ÀSᐗᙠᐗᕜà⊤"ḄâãL0
2“Tä”ḄnḄråLæ“Tä”ᦔ᳛+éḄêëᨵÅìᑏîïÀ஺Å3“Tä”Yᨵð?0ᡂ,ᑣòð?LÅMᓄPÀ+ᑏ50ᡂóð?Ḅᓄ^_P஺Å4“⏚”Y◤⌕ᵨᑮ2moiḄö÷⏚+uvøᑭᵨù÷⏚ᑴuvᵨḄö÷⏚◤⌕ᵨᑮḄúᴻJᘤ◀ýþஹWஹ!᜜
ᨵ஺
5“⏚”cNi2+=0.2mol-LT,ᑣ“⁚ḄpH”ᑴḄpHo[c
Fe3"<1.0XIO_5mol-I71H>J,Fe3+ᐰ]17.
14ᑖ#$ᐗ&ᙠᙢᳫ*+,-.$/ᐸᓄᔠᱥᙠ4567897:ᨵḼ<⌕>ᵨ@AᓄᱥBC⌕ḄᜧEFGᱥ஺HIᑡK⚪M1#+ᨵNO9NO2Ḅ46NEOPᑭᵨNaOHᔾᦈᜐᳮ஺C⌕VWNO+NO+20ET=2NOX+HOஹ2NO+2OH-=NOX+NOX+HO»2222?জᑡ[\]^_`NENO9NOa◀᳛Ḅᨵe᪗g#஺2A.hijᐭlEḄm᳛B.nᵨEஹ⌮pḄqrᔾᦈlEC,ᔾᦈlEḄstuv⊡h〉,NaOHঝz2.24L{ᣚ}ᡂ᪗Ḅ#ᵫNO9NO?ᡂḄᔠEjᐭILO.lmol-L^NaOHᐙᑖVEᐰᔾᦈ#ᔾᦈḄஹᨔஹsஹஹᑮᨔ7.22g,ᑣᔠENO9NOḄᱥḄ,W஺2

6(2)NOONa?஺?VᐸVW2NO+Na2(D2=2NaNO2஺£▅¥ᧇMa.6NaNO+3HSO(W=3NaSO+2HNO,+4NOT+2HO,224242b.⏚ឋᩩ³NO^MnOM,AᓄᡂNOX஺¶·¸¹ᑭᵨ᝞»¼½ᩭ¿ÀNONaOḄV(¼½O<ÁÂᵨ)஺22ঝᐙᑖVÃĸ¼½Dᔲ7ᡂÆNaNO?,ÇÈḄ·¸qᫀW(3)ᵨNaClOBOPᔾᦈ46lEḄNO஺ᐸÌᩩ³ÍÎNOÏᓄWNO,ḄÏᓄ᳛ÐNaClOÑÒpH(ᵨÔÕ⏚⁚)ḄÖᓄ᝞»ᡠØ஺a.ᙠ⏚ឋNaClOHC1OAᓄNO7ᡂCÚ9NOX,ᐸÛÜqtrWb.NaClOḄÑÒpHݹNOÏᓄ᳛Ý`ᐸÞ஺18.(15ᑖ)+áᱥᙠ787:ᨵ<⌕>ᵨ஺(1)âá⏚┛ḄᑴᜓMzáEjᐭPᵯæçèC⌕ᡂᑖWCa(OH)29CaecalWᧇᡭᡂḄìᧇ“Aᓄ”,ᐙᑖVsèas,ḄCa(OH)29CaCC^î஺জ"áᓄ”⌕〉ðñòjᐭCl2m᳛ḄóḄঝᡠ+ᨵḄ▢ÛÜᨵOH\Cl\CRTஹCIOX,CÚஹCRTஹCIO1ḄᱥḄ,ᑖøWaஹbஹc,ᑣaஹbஹcùḄᐵûWo

72#·¸ýᑴþC1?ÿᓄ
ᦈC%ᡠ◤Ḅᢥᔣᵫᔣ஺3!"#$%&'()⁐+,-./___________1ᑖ3஺456/CF■9ᙠḄ;<=>?@஺4BCDEFGHI+C1?ᙠ"C'(/Ḅ'3Eᵨ'3C12ḄᱥOḄPQE⊤ST'(QEUᓄ஺ᙠNaCl'(FY⏚/ClḄ'3E[=ᔜ]^_`ḄQEUᓄ᝞b஺2জᙠᓄd'(/+eᡂC1gḄhijkoঝTḼY⏚QEpᜧ+Ḅ'3Eᐜst!pᜧḄuv@a西繁Q±(moO.05:L，-)——HC1Q0246HNaCiyCmol-L1)c(HCMm“L)ᵨIN1C1'(QE
'3C1[^_`ḄQEUᓄb2Y⏚QE
'3Cl1ḄQEUᓄ20222023wExᓭḕ{|w}▤ឋὃᓄὃᫀ1.Cூ3᪆௃gSbḄOiᦪ51,/iᦪ70,/iᦪFOiᦪ19,C⚗┯஺2.Aூ3᪆௃⚪⌕ὃᓄ
eḄBᐵ¢£+¤¥ὃe¦§Ạ¢£Ḅ©¢#ª஺«ᯏ☢ᒹᑭᵨḄ@t°ᡭ²³᧕ᑖ3µeCO2,B⚗┯g¸ᮞ¸Ḅ⌕ᡂᑖ@CaCC3+CaCC3º»Y¼+C⚗┯g╅¾ᔠÀÁEtஹHE{ஹὊῖ⇨+D⚗┯஺3.Cூ3᪆௃HC1O/OÈᡂÉÊᐳÌÍ+HFC1ᔜÈᡂÎÊᐳÌÍ+ᦑÐ᪀kH—O—Cl,C⚗┯஺4.Bூ3᪆௃⚪⌕ὃÓᓄÔuÕÖḄBᐵ¢£+¤¥ὃe¦§Ạ¢£Ḅ©¢#ª஺×⏚ØÙÚÛᔾUᡂ×⏚ØᨔÚ+Þß⁐+"º»ÓᓄÔuÕÖ+B⚗àᔠ⚪á஺5.Bூ3᪆௃⚪⌕ὃᵯ3O'(ḄBᐵ¢£+¤¥ὃe¦§Ạ¢£Ḅ©¢#ªFãᓫÖᵨ#ª஺

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Óᓄ!Ḅçèᔠ+@é/Fஹêë+ìÓÓᓄ!ç/eᡂḄ⏚+íᨵSC>2eᡂ+B⚗┯஺6.Dூ3᪆௃¸ñ/ḄSi஺ó#
NaOHÕÖ+"#⌱ᵨ¸ñᚈᤴᰚøNaOHÙÚ+D⚗┯஺7.Dூ3᪆௃⚪⌕ὃùúûüýþᦪḄ¢£+¤¥ὃeᑖ᪆F3ÿ⚪Ḅ஺ᵫᵯḄᦪA⚗┯ᵫឋ"Fe2+>Br-,ᡠ.O.lmolFeBr24O.lmolC1789:ᡂFeChஹBr,:ᡂḄBr?ᑖᦪ@0.05NA,B⚗┯ABCDᱏ⍗GH⏚JK:LᓄN2OPQK:78RSTUᦪC⚗┯஺8.BூX᪆௃[⚪\⌕ὃ_`abcᑏeḄᑨghiὃ_j:ᑖ᪆kXl⚪Ḅ஺mᜫᵯoឤஹᵯ₹oឤA⚗rᔠ⚪tuvwᐭyᮞ{ᑴ}~yᮞ{ᓄ┛C⚗rᔠ⚪t78ᔠᱥឋJ:ᡂH+D⚗rᔠ⚪t஺9.DூX᪆௃[⚪\⌕ὃ_ᓄjḄᵨhiὃ_j:ẠḄ8ᵨ஺aḄᨵஹXஹ¡ஹ⃓£ஹ¤¥¦ᨵ¤K§ᨔD⚗rᔠ⚪t஺10.BூX᪆௃ª⏚Ḅ⏚ឋ«¬⏚uᓄ┛k®ᓄª78A⚗┯CO?¯°v±²ᱥ,C⚗┯;´µᱥ¶Ḅ·ḄSO2kCI2wᐭK:ᓄ78"Cl+SO+2HO=HSO+2HC1,22224Ḅ}~ឋ¦ᨵ¼½D⚗┯஺11.CூX᪆௃[⚪\⌕ὃ_ᱥ¶Ḅ·ᙠᓄj·Ḅ8ᵨhiὃ_j:ẠḄ8ᵨ஺ᔣXÁᐭ¬⏚9ḄH+ᐜ4OH-78:ᡂÄ4CO"78:ᡂHCO,ᨬÆ4HCO78:ᡂkCO?,ᵫSÇgÈÉb=2a9Ḅ¶ÌᨵNa2co3Ð2a>b,ᑣḄ¶@NaOHkNa2co3,Ð2a

9C⚗5ᔠ⚪8஺14.Dூ?᪆௃B⚪C⌕ὃFGHIᐗKSஹNLᐸᓄᔠᱥḄQᐵSTUὃFVWXYẠSḄ[ᵨ]^஺ᙠ_ᓄᑺḄaᵨbaccஹdfᓄgbḄijaaᑺA⚗5ᔠ⚪8ald'Ḅᡠopqrឋ]q⏚ឋB⚗5ᔠ⚪8uvbFe⍗ᑮyz⏚ஹy{⏚ᙳ}~ᓄC⚗5ᔠ⚪8஺15.1জab2ᑖঝl2ᑖ2জ⏚2ᑖ@HO+2H++2Fe2+=2Fe3++2HO2ᑖ⁐1ᑖ222ঞ1ᑖ@2242ᑖ3]WKCᐹᨵឋᐸi⏚ឋ⏚⁐ᑣ¡ᨵFe?+Wᡂ3ᑖூ?᪆௃B⚪C⌕ὃFᴁ¤⏚¥¦Ḅ§¨©ªὃFVWXYẠSḄ[ᵨ]^஺Iঝlᡠ¬ᔣ®¯ᐭK3[FeCN%]ᡈKSCNᙳµ¶·q·¸஺2জ?¹ᕈ⏚ឋ[ᵨ⏚஺ঝ»¼½¯ᐭH2O2¾Fe?+¿ᓄgFe?*,ᵫᑏ¶Á[ḄÂjÃĹᡠoÅg¿ᓄ¦¿ᓄ¦ḄÆ⁐g⁐஺ঞH?஺ÇÈÉ⁐¿ᓄᑺᵨÊ஺?ḄËᜐÈ஺টÃÄo0.64gÅFeO,᪷(¦ᐗK+ឤÑᱏᱏÓFe2+ḄÔg23co112100mL0.64gx——x--------ᗞ20mL=0224g=224mg»3§¨·¸]¨ÝÞßàgWKCᐹᨵឋWKCi⏚ឋ═⏚⁐ᑣ¡ᨵFe?+Wᡂ஺16.1â½ᕜäVIAæ2ᑖ2◀èéᾦஹë¬L¿ᓄë2ᑖᤅíஹ〉ïᓣvᡈñòóôõö÷ᔠᳮùᫀ2ᑖ3H2ᑖ2A1+2NaOH+2HO=2NaAlO+3H,T2ᑖ2224ýᜮஹÿᴻ
2ᑖ531ᑖ;71ᑖூ᪆௃⚪⌕ὃᓄᑺᑴᜓ⏚╅Ḅ!"#$%ὃ&'()*Ḅᳮ,-./ᔠ1ᵨ,-஺

10
2“56”8%9ᐭḄNaOH;<=>?◀ABᾦ%D>?◀AEᓄᑺFḄGHI.JᓄI஺K,p[Ni
OHJ5Ni?+KLMN8%᪷PKsp=cNi2+xc2
OH-QR>S,C20H=ᑣcNi2+c
OH-=lxlO_7molL7,,Z[\%pH=7]Fe'+^ᐰMN8%c30H=`abH,c
OH=lxlO"molL7',Z[\%pH=3,ᦑd⁚pHḄgh3i7஺17.
1জA
2ᑖঝ3l7
2ᑖ
2জBfCfBfDfBfE
2ᑖ]ᔾᦈNO,■pqrst2ᑖঝuvwDFxyzḄ{|}~F%9ᐭ⏚%'⁐t~%⁐t~ᙠ⁐%ᑣ'ᡂNaNO?
2ᑖ
33HC1O+2NO+HO=3CP+2NO'+5H+
2ᑖ];©¨tªᐙᑖᙢᔾᦈ%ᔾᦈ¨tḄ$F®¯⊡9〉|NaOH;<%>¡¢tḄ²ᓄ᳛஺ঝ᪷PNᐗ´ឤ>QRS¶ᨔ~F¸ᨵḄNaNOsḄᱥ»Ḅ|0.02mol,NaNO,Ḅᱥ»Ḅ|0.08mol,ᵫtᔾᦈḄ⌕xyNO+NO+2OH-=2NO'+HOஹ2NO,+2OH-=NO]+NO]+HO>½,2222'ᡂ0.02molNaNC3¾ὑ0.04molNO,,ᑣÀ'xyNO+NO2+2OJT=2NO]+H2஺ḄNO.NO?ḄÁᱥ»Ḅ|0.06mol,ᵫÂ>SNOḄᱥ»Ḅ|0.03mol,NO2Ḅᱥ»Ḅ|0.03mol+0.04mol=0.07mol,ᦑNO.NO2Ḅᱥ»Ḅ|ÃÄ3l7஺2জ᪷P)*ÅḄ%>½vwḄÆÇÈÉNOḄÀ'vwAft~ÊᓄvwᒹÌ◀ACO?ḄvwBஹÍ*CO?hᔲ◀ÏḄvwC.ÐÑvwBfNOÒNaOḄxyvwDT■ÐÑvwBf¨tᜐᳮvwE஺22ঝ>ᑭᵨÖᧇbFḄxyÍ*vwDFhᔲ'ᡂNaNO஺23᪷P⚪ÅØÙ%ᙠ⏚ឋNaClO;ÞxyḄ

11ßÝ$§l3HC1O+2NO+HO=3C1+2NO]+5H+]ᙠ⏚ឋᩩä\%஺0å²ᓄᡂHC10,;<ḄpH2%'ᡂḄHC1Oᜧ%HC1OḄJᓄឋ%ᑣNO²ᓄ᳛¢஺18.1জéêtëìJᓄ┛ᐙᑖᔾᦈîxy%¡¢êt²ᓄ᳛2ᑖ@a=b+5c2ᑖ2cdbaet2ᑖ3HC1O2ᑖ]u{|᪵÷F%9ᐭøùAgNC3;<%ᨵü⁐MN'ᡂ%ᑣýwêþFÿᙠcr2ᑖ4®Cl,+Cl==Clj2ᑖঝ⏚Ḽ⏚ḄᜧC1H?OḄ#$%ᢓᑴ()*+,-Ḽ⏚Ḅᜧ.ᡂC1012⌕#$4567CL*+3ᑖூ+᪆௃1জ“(ᓄ”⌕〉B,CDᐭCLF᳛ḄHḄIJ()%KLᓄ┛ᐙᑖᔾᦈ5#$QR()Sᓄ᳛஺2UVWᑴXḄC%Z[ᨵHC1ஹH?஺^_`Da⛳cdeஹf⏚ᑖg◀iHC1ஹH2஺jᦈkCLl7mn)ᜐᳮqrstḄuvwuxy1cdbaeo3(eZJ*⁐ḄᱥIHC1O,(et-J*⁐^(eZHC1Oᑖ+஺VCᙠḄI᪵ZᐭAgNC3*ᨵ⁐.ᡂᑣ¢t(eZᙠ