河南省鹤壁市2022-2023学年化学高三上期中达标检测试题（含解析）

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2022-2023
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ᓄḄᑖᦑ⊝ᔣN2O4Ḅ!"#$Ḅ%&'(⊝ᔣ⌮ᓣ+,-⊝ᔣ⌮ᦑ+,.'஺ூ⚪234௃A.'(6"ᨬ.ḄᦑA┯9:B.,-6"ᨬ+Ḅ'(6"ᨬ.ḄᦑB┯9;C.,-ᨬ+'(ᨬ.ᦑC!<;D.,-.ᦑD┯9;ᦑ=ᫀ⌱Co9ஹCூ=ᫀ4᪆௃A.100gᑖᦪC46%ḄHCOOHDEFᵬ⏚ḄC46IClmoLᨵ21noiKLM᜜Oᨵ100-46=54IPᓽ3m01,ᨵ6moiKLᑣᐳKLᦪC8%ᦑ!<;B.ᙠ᪗WXYZ22.4LNHsḄᱥḄCImol,\]ᑖᨵ3]ᐳᵨᵯᡠaᑖFᐳᵨᵯᦪC3bᦑ!<;C.
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13ᔠᱥw°±ᮞªᦑড┯9:ঢ´µஹ¶ஹ·ᑖᦣ¹º»ᙠlnnTlOOnm¼½"¾#ᦑঢ!<;⌱Ao12ஹDூᑖ᪆௃ᐭ02—᩽ᓄᔠÃÄ.ÅᵯÆ!᩽ᓽ±ÇnÈ!᩽±ÇICÉ᩽஺É᩽"N(hᜫËᵯ:4NO4e+4NO3=4NO,!᩽C2N2O+O2+4e=4NO3".2255ூ⚪234௃A.ᵫᑖ᪆fÍYCN2O5,6Îᔠ⚪ÏA┯9;B.ᙠLᵯÐFᵯᵫ!᩽ᔣÉ᩽ÑÒᵯᵫ±ÇHᔣÉÓ6Îᔠ⚪ÏB┯9;C.ᵫᑖ᪆fͱÇICÉ᩽Ôrᓄ6Îᔠ⚪ÏC┯9;D.ᵫᑖ᪆fͱÇIIᵯ᩽ÕC:2N2Os+O2+4e-=4NO3-,Îᔠ⚪ÏD!<;=ᫀCD஺13ஹCூ=ᫀ4᪆௃A.᪷Ö×᪀ÙÕfÍÚᡡ᪻ÝḄᑖÕ"37H/3,⌱⚗A!<;B.Úᡡ᪻ÝᑖFᨵÞ]ßÚImolÚᡡ᪻Ýᨬàgp3molH2⌱⚗B!<;C.Úᡡ᪻ÝP4ÅᑮḄ⏣pßᵬ⏣6ãCäᱥ⌱⚗C6!<;D.Úᡡ᪻ÝᨵÝåஹæågÔrçᨵßÚgÔryᡂᨵæågÔrᓄ⌱⚗D!<஺=ᫀ⌱C஺14ஹCூ=ᫀ4᪆௃è⚪ᑖ᪆:A.IBryᐭNa2sDEḄ¬éêÕCIBr+S*=r+Br-+SbᦑA!<;B.IBryᐭKIDEF✌ᐜÔrIBr+I-=Br-+L,ᵫKIíᑣîÞïÔrL+r=b,ᦑB!<;C.IBryᐭNaOHDEF,6ÔrᓄOLCIBr+2OH-=Br-+KT+H2஺ᦑC┯9;D.IBryᐭAgNChDEF✌ᐜ"IBrpPrᡂHIOdHBr,ᵫHIO6ñᙠPFÔròᓄrᡂHIChdHLîórᡂAgldAgBr,Ḅ¬éêÕfC3IBr+5Ag++3HO=3AgBr|+2AgI+IOj+6H+,ᦑD!<ᦑ⌱D஺2ὃõ:ὃöᓴãᓄᱥÍø15ஹBூgᫀi᪆௃Aஹᵯi⛳
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1416ஹCூ⚪¾¿i௃A.¤'A1(OH)39&Àpᡠ¬ᔣtᓄ£9¥ÂÃ#ÀpᨬÄ-ᱥ'A1(OH)3
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Ç⏚ḄÆ⏚ஹsà⏚ஹá⏚âã9&äÇḄ⏚(᝞å⏚)Ü⌕Þ⏚ឋ©9&¨ßâ©9&Çß(᝞Àp)஺ᡠ¬ᙠçᑏéêÊ⍗ᑮÃ#Ḅìí⌕îïA1(OH)3³ᔲ9i஺17ஹDூ⚪¾¿i௃A.ñ⏚ᨵ6ᓄឋò⏚᪷ᨵôõឋöὅø6ᓄôõ2H++2NO3+3SO32=3SO42+H2O+2NOtᦑA⌱B.NazSiCh9¥ùᐭÃ#SChᡂò⏚s᪷ú³ò⏚᪷SiO2+2SO+2HO=HSiO3+2HSO3,ᦑB3222⌱C.Àp©
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6s6ᓄuḄOH-Ö¦!ᡂs6ᓄ×ØéêÊᦑD⌱ᦑ⌱D஺ூgᫀÙÚ௃S*(-24)ஹSOM+44)ஹIஹFe2+$ᨵü¨Ḅôõឋ⍗ᑮýþᱥ"✌ᐜ⌕ᑮḄឋ᝞Ḅᱥᨵᓄឋ(᝞KMnChஹ⏚ஹ⏚ஹFe3+)⌕ὃ⇋Ḅ!ᔲ#ᓄ஺18ஹBூ&ᫀ(᪆௃AஹḄ!AlO2-+H++H2O=Al(OH)3jஹBa2++SO2-=BaSO4hA1(OH)3+3H+=A13++3HO,42ᐰ-ᡂ/ᓄ0O.lmoL◤⌕⏚0.05mol,ᡂ23BaSChO.OSmoL◤⌕4ὑ⏚0.05moL67ᡂO.lmol2384ὑ⏚Ḅ9:#0.5L,ᦑ<=>?@ABᔠᦑA┯EFBஹḄ!OH-+H+=H2஺ஹBa2++SO2-4=BaSO41ஹH++AIO2-+HO=A1(OH)31,A1(OH)+3H+=AP++3HO,GH<=>?@I/ᓄJHḄOHK⏚232HH+l
1HL8Ba?+SO4?-ᢥ᯿1
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15ᐭKᓄ«ÔrA13++3OH-=A1(OH)31ஹFe3++3OH-=Fe(OH)3bn(Al3+):n(OH-)=l:3,n(Fe3+):n(OH-)=l:3,ùúûyKᓄ«ÔrA1(OH)3+OH-=AK)2-+2H2O,n(Al(OH)3):n(OH-)l:l,6ÎᔠüýḄᦪþÿᓄ
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17NM>KHOCM>—OKWXYZ⚪Ḅ\W]^ᑖA᪀_Ḅᑨaᐜ᪷⚪(ᡠᑏ^ᑖA᪀_]ᵬ⏚;“HCOOC-C-C”,ᯠNd!eefgᯠNhᑏijḄ=HCOOC(CH3)=CH2,ᱯlmneefgopWq^ᑖA᪀_ᨬNᑨa||A.He—0^—24ஹOH+HSO3=SO2+HOAB3NO2+HO=2HNO+NO3223ூᑖ᪆௃(1)uAvwḄx8ᓫzᯚ⁐ᕈ~⁐Na,X/⁐S02,ᑣBH2,CNaOH,DNa2sO3,ENaHSCh;(2)uA~⁐Na2(h;uXBᨬvwḄ⌼ᡂᦔḄ_RᓄeH(3)uAx8RᓄᱥB_⍗⁐ᑣBNO,ANCh,X]Fe,ᵫᓄᐵCᐹᨵRᓄឋᑣCHNCh,EFe(NCh)2,7ᑖ᪆¡஺ூ⚪£¤P௃(1)᪷¥¦ᑖ᪆ANa,XSO2,ᑣBCNaOH,DNa2so3,ENaHSCh,CEḄ§%&OJT+HSCh=SCh3+HzO;(2)জuA~⁐Na2O2,uXB⌼ᡂᦔḄ_CO2,©!!CNaOH,DNa2cO3,ENaHCO3,␺l¬®Ḅe⏚¯5e⏚°¯±Bᵨ³⏚ᡈ´ᓄ⚞AB⚗·¸°Rᓄ┛5±ὅᙳᡂ¼⁐½¾¿/␺lC⚗┯ÁHᦑ¡ᫀAB(3)᪷¥¦ᑖ᪆NO25OḄ%&3NO2+H2O=2HNO3+NO஺25ஹ(1)EஹDஹB(2)■Å/ᡂḄNOÆRᓄᡂNth,⌼ᡂÇA(_ÈᱥÉÊ⌼ᡂË᡾(3)জD(ᐭRNÎ⁐_ঝÐÑNChÒᐰᓄ(44NO+O2+4NaOH=2H2O+4NaNO3OÔ>ᙠ5NChÈNO,⌼ᡂÇNOḄᩭÖ×Ø¿Ù(5)2NaNO2+HSO4NOT+NChT+Na2sO4+H2O஺24ூ¡ᫀP᪆௃Ú⚪ᑖ᪆Y(1)ᙠAÛÜ(/ḄᨵY2NaN(h+H2so4()=^=Na2so4+2HNO2,2HNO=^=NOt+NO2T+HO«ᵫ9_ᓄḄ®YN0;21࠷,NO
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