2022-2023学年上海市某中学高二上学期10月阶段测试化学试卷含详解

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2022-2023ᓄ10ᨴᨴὃ
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14uCA.aஹbzᵯ|⊤Lpq~ᵯB.aஹbz|ᵯLpq~ᵯC.aஹbz|ᵯJ᧕ῖ⇨D.aஹbzᵯ|⊤ᡈz|ᵯ/J᩽ூᫀ௃Cூ௃Aஹ᝞uc~⏣ᵯWᑣaᔠ᪀ᡂᵯḄᩩ8ᦑA┯cBஹ᝞uc~⏣ᵯWLᵯ~᪀ᡂᵯᦑB┯cCஹz|ᵯ᝞"▢᩽ᢥ᯿ᵯᳮῖ⇨ᦑCjKDஹ᝞zᵯ|⊤᪀ᡂᵯ"᩽᝞z|ᵯ᪀ᡂᵯ᩽Ḅ¡~▢□᩽ᦑD┯c஺14.t࠷§ᙠ6¨S~2L«¬ᘤ0¯ᐭ:;ᱥAஹB,EF᝞9:;A³sµ+2B³gµ03c³gµ஺:;º»0Ḅ¼ᑖᦪ½᝞⊤ᡠ¾9ᑡstjKḄᱥW¿À2ᑖÁ4ᑖÁ6ᑖÁA2.0mol1.4molB6.0mol4.2molCOmol2.7molA.Æ2ᑖÁᑁBḄ:;O᳛~B.4ᑖÁ§:;È=ᑮ@⊝É᝱C.ᓣÌÍ3j:;O᳛Qᜧ⌮:;O᳛UVD.L:;=ᑮ@⊝Yᐸ▲3ÐtᦋCூᫀ௃Bூ௃A.Æ2ᑖÁᑁᱥWAḄ:;ḄX~0.6mol,ÑÒᓄÓÔ»ÕJÖ:;BḄᱥWḄX~1.2mol,ᑣBḄ:;O᳛~×■Ùmol-LT-minT=0.3mol-LT•minT,A┯2x2

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BaCL⁐XY=ᨵZ⏚᪷ᡈ^⏚᪷ᑣ`a=bᵫᔜᱥGḄHIJKde`=ᨵNa+ஹK+,fCOQஹSOQ:<ᨵᐸ@hᦑAjᔠ⚪m஺noᡠq/ᫀrA஺20.ᵫN?஺uNOvwxᡂN?uNO?Ḅ<zᓄ᝞}ᡠ~஺?ᑡX┯Ḅ᝱N(g)+NO(g)22--------------------------------->vwA.ᵨᓄᑺ;>᝱Ḅ<B.vwᱥ<uᜧxᡂᱥ<uC.NO(g)+NO(g)=N(g)+NO(g)AH=-139kJ-mol-1222D.vwᱥḄ

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19ூ/ᫀ௃Aூᑖ᪆௃bÚᵯÖ×᩽JÛᑣFeᵯ᩽r▢᩽ÍÎᵯ᩽r□᩽஺ூ45௃A.AMr¤¥ᏲḄNaCl¡ᵯßxvw2H2O+2e-=2OH-+H2f,ᑣbᵯ᩽▬̾Á⁐AB.AMrCuS04CM+ᙠ▢᩽(Fe)⊤☢âᵯxᡂCu,ã▬Ḽᙠb⊤☢ÍÎr□᩽CiP+a<ᙠᐸ⊤☢âᵯBaC.ÃÄÑÒÈᵯÓÔḄᔣQᵯÖ×᩽-FeஹÍÎᵯÖ᩽ᵯa<åᵯ5GCaD.AᵯÖvᢥMrNaClᑣbᵯ᩽r□᩽ᵯ᩽vwrFe-2e=Fe2+,Daᦑ⌱Ao23.?ᑡæçèḄ⊤qḄA.ᔣỚᓄêb@¤Vëì⏚QNO+3Fe2++4H+=3Fe3++NOT+2H,0B.ᔣNaClO@¡ᐭVSO2QSO+CIO-+HO=HSO+HC1O22C.ᔣí9@ᐭNa?஺”2NaO+2H,8O=4Na++4OH-+18O12222D.ᔣZïZ⏚½@ᐭëð⏚QSO+2H+=SOT+S^+HO222ூ/ᫀ௃Dூ45௃A.ëHNO3VñòឋQ$óFe2+,w
$ᐜvwvwr2NO+6I-+8H+=3%+2NOT+4HQ,A┯3B.SO?VC1CFõö⏚<«·¨ᓄZ¨ᓄrZ⏚᪷DH+ÚCKTxᡂõö⏚ᑣvwrSC)2+3ClCr+H20=S0+C$+2HC10,B┯C.Na2஺÷ßxøᓄvw஺2@ḄOᩭúNa?஺÷ᑣ஺wᙠOH-@C┯D.ᔣZïZ⏚½@ᐭëð⏚ßxvwxᡂ·¨ᓄZஹZrSO^+2H+=SOT+S+HO,D222ᦑ⌱D஺24.?ᑡᔜûᱥGḄü⁐zᓄ;ᵨý⊝ÿ
ᳮḄA.NON2O4⊝ᔠ⁐2B.ᓄ₩⁐C.ᐝ᯿⁐D.Ớ⍗#$ூ&ᫀ௃Cூ)௃A.NO?N2O4⊝ᔠ*+,-.*ᔜᱥ123ᜧ*⁐,

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21Bᑖ@½CC14¾¿cct,½ÀÁ7Cᑖ@KNO3NaClÂÃᨔKNC)3Ḅ3ᜧÆNaClD◀ÈuÉ[ḄÊ⏚ËÌuÉÌÍfឋ.ÆÊ⏚ËA.AB.BC.CD.Dூ&ᫀ௃Bூ)௃A.º⏣Ï*A┯<=B.CCL½ÀÁ7*8ÐÑᵨ¾ÒḄOYᑖ@Óὅ*BPQ=C.KNOḄ3ÕF3Ö×ᜧÆNaCl,ᦑᑖ@KNONaQ8Ð⌱ᵨØFÃᨔḄO33Y*c┯<=D.ÌÊ⏚ÕÌ7ᑖ*Ê⏚ËÕÌᑖBᡂÙஹஹÚᓄÊ*ᦑuÉÌÍfឋᜧÆÊ⏚╄*D┯<=ᦑ⌱B஺27.Ü,ḄᵬஹºÓSÜᘤ*ᑖßᐙᨵàᱥ1ḄáḄSO202,ᙠF3|B2502â)+02â)=2503})*åæᑮ⊝*ᙠ覧[*ᵬÜᘤéᢝÜ,7*ºÜᘤéᢝë7*ìᵬÜᘤ[S02Ḅíᓄ᳛?a,ᑣºÜᘤ[SO2Ḅíᓄ᳛?()A.àÆaB.ᜧÆaC..ÆaD.ðYᑨòூ&ᫀ௃Bூ)௃ᐜᎷfᵬஹºḄ+,´7*æᑮ⊝`éᢝºḄë7*è++,-.Ḅ*>è*õà+,æ⊝*öéᢝºḄë7*÷◤⌕-.+,஺-.+,ᑣºḄëúᜧ*⊝ᔣ++,-.ḄOᔣ:*⊝Pᔣ:*ᡠÐ*ìᵬÜᘤ[S02Ḅíᓄ᳛?a,ᑣºḄSChḄíᓄ᳛ᜧÆᵬḄ*ᓽᜧÆa,ᦑ⌱B஺ூÁü௃PQᳮàᦔ⊝Ḅ
ᳮ⚪Ḅᐵ஺⚪ᐜᩩ⊝ᦋᩩᔠ⚪ᩩ᪷ᦋḄᩩ⊝Ḅᑖ᪆!⚪"#ᑓ%&'஺28.(ᑡ*+,ᕈឋḄ/()A.pH=7Ḅ*+B.c(H+)=c(0H-)Ḅ*+C.ᵫ4⏚ஹ47ᱥ9Ḅ:;<=ᑮḄ*+D.?ᵯ&9*AB=ᑮḄ*+ூDᫀ௃BூG&௃A.ᙠIJ(pH=7Ḅ*+ឋKJLM/IJᑣpH=7Ḅ*+M,/ឋ*+┯P஺B.ᙠQRJL(c(H+)=c(0H)Ḅ*+,ឋ*+ST஺

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23(Fe)´n(S)=0.4mol´0.5mol=0.8.ᡠ\A-0.8,ᦑB┯P¬C.ᵫBᑖ᪆dµH2sḄᱥ9Ḅ:n(H2s)=n(FeC12)=0.4moLᦑC┯P¬D.Fe-SS-2yaᡂSᓄᔠy0,ᑣaᡂO.lmolS,aᡂH2sM`aᓄᔠyᓄᑣᐳ°·ᵯ£0¸molx2=0.2mol,aᡂ¹oº£M»ᙠᓄᔠyᓄᑣ᪷°·ᵯ£¤ឤ=n(Fe3+)=0.2mol,ᑣn(Fe2+)=0.4mol-0.2mol=0.2mol,ᡠ\Fe?+zFe+Ḅᱥ9Ḅ:¼0.2mol´0.2mol=l´1,ᦑDST¬ᦑ⌱D஺30.ᙠឤ½½ᘤᵨCO2H2ᔠᡂᵬ⏣´CO(g)+3H(g)^CHOH(g)+HO(g)ÄÅÆᑁMJL(ÈImolCO?223203molHᙠ;<ᘤ;<Ê,CH3OHḄb᳛Ìb᳛=(Í▭b:/ᳮÐb:)xioo%ÓzJL2ḄᐵÔ᝞Öᡠ×஺(ᑡSTḄ/

24100产率(8o一Ø)<6o一忙5oI凿4o一,旺2O一460480500520540560T/KA.ÖXÛÜ᳛VS,V⌮B.Þ;?@ᵬ⏣ḄC᳛C⚗E&D.0GHᑖIᦪᦋLḄᵫMᘤHO.ᦑQRST⊝=ᔜᱥWḄXYQRSTḄ⊝ZᦪD⚗┯%&ᦑ⌱C஺.ஹ/ᔠ⚪ᐳ60ᑖ31.ῙN2HJdefᵨhiḄᓄklᧇ஺kn*ᐜᔠᡂrGsteuᑴᜓᨴy஺zᔠᡂrNg+3Hg2NHgAH<0oᡂ9ᑡ2231ᔠᡂr◤⌕⌱ᔠ〉Ḅᓄᑺᑖ⌱ᵨAஹBஹCfᓄᑺtᡠ᝞ᡠᐸᩩ8

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