2022-2023学年北京市丰台区丰台某中学上学期高三10月月考化学试卷含详解

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ᵨᑮḄHlC12O16Fe56Zr91ᑖ1.ᑡᐵIEẞḄ2.ᑡᓄᵨᡈ⊤ḄCH,CH,A.Ḅᵯ!""Q"HB.2-$%Ḅ&!'᪀"ஹc=C'C.SO,ḄVSEPR*+D.NO1Ḅ=>'᪀*+:A3.ᑡᱥ-ឋ-/0123/ẞḄA.ᐗ5Ḅᵯ6ឋ"Cl>S>NaB.ᓴ5ᓫ-Ḅᰚ:"I>Br>Cl>F,222C.;⏚Ḅ⏚ឋ"CH2cleOOH>CC13coOHD.@AᩩC1ᱥ-ᙠEFḄGHI"CHOH>CH(CH)OH253244.ᑡJKḄA.ℍ⃔NஹPQNஹⅅNᙳTUVWX&YB.Zᾦᙠ\]G^F1ᐙᑖEHaᑮᾦc⏚deᵞZC.g⏚hஹg⏚iஹj⏣lTmno-pឋD.no-ᐹᨵsឋ1EHᨬuvᱥwxy5.ᑡz{FḄ|⁐pᓄ1~ᓄ&YᐵḄABCD

1NaOHG^ᐭG^ᐭENa2sG^ᐭiᐭ⏚z{FeSCUG^FFAgCl^FFvVo⁐1G^p1ᵫo⁐⌲pvV⁐1pw⋎⁐⁐w⁐pw⁐A.AB.BC.CD.D6.ᙠᩩC1RO"eF2¡UV᝞&Y"RO"-+F+2OH=RO4_+2F+HO,£¤¡¥ᙠRO¦22F1ᐗ5RḄᓄᔠ¨A.+4B.+5C.+6D.+77.©ª1ᑡᔜ¬ᙠᢣG^FTᜧ°ᐳ²ḄA.ᵫEᵯḄc(H+)=l()T2moi´ḄG^F"NaᓝஹNH"ஹ஺-ஹK+B.⁐G^F"Na*ஹK+ஹCr?஺"ஹNO¦C.·ᨵFe?+ḄG^F"H+ஹNa+ஹC¹ஹNO¦D.pH=14ḄG^F"K*ஹCRTஹCO"ஹcr8.ᑡº»!¼ᑏḄ"A.¾ỚᓄÀÁ´⏚pÃ"2¹+4H++NO¦=I+NOT+2HO22B.ᵨÄ⏚◀ÆEÇ"CaCO+2H+=Ca2++H0+C0T322C.ᔣMg(OH%É^FÊᐭFeCL,G^"3Mg(OH)+2Fe,+^2Fe(OH)+3Mg2+23D.ᔣᓄÌG^FÊÍ°ḄÎE"Al3++4NH-H0=A10-+4NH"+2HO3229.ᙠsÏ@AḄBa(OH)2G^F1ᑖÐᐭᱥ-Ḅ°ÑI@ÒḄH2soஹNaHSO,G^1ᐸÔᵯTÕ4ᐭG^ÖpᓄḄ×Ø᝞ᡠ஺导电能力ᑡᑖ᪆ḄᐭG^ḄÖ

2A.জÜ⊤ÊH2sG^Ḅpᓄ×ØB.b:1G^Fᜧ°²ᙠḄNa+ஹOHC.c:1sG^F·ᨵ@A°ḄOH-D.aஹds:ÝYḄG^ᙳÞFឋ10.ßàFḄßá5ᐹᨵᢙã᷈ஹᢙåæÒVᱥçឋ1ᐸᰚ:w347è348࠷,'᪀ê!᝞ᡠ஺ᑡᐵëßá5ḄJKḄ◤íîï²ßá5B.ᑖF·ᨵ3ð·ñTòC.~óEôUVÊᡂ&YD.Imolßá5ᨬxT~3moiNaOH&Y11.⛳e÷ø(UP)OHVvùᔠᩞᧇH“ýᴻÿ”Ḅ᪛ᾦᩞᧇ஺᝞ẠᓄᧇᔠᡂUPᵬ1BrJCCLᵪHBrᓄT|জNaOH/⏣|ᓫ2!!"V,#C14H6ᓄᑺ/&»C4HQRr—©IF—>|ᓫ1(ᓫ3»UP6ᑡ*+,-.Ḅ/()A.234KMnO4⏚ឋ789:ᓄᑴᓫ1B.ᓫ23<=>⏣C.ᓫ1ஹ2ஹ3@ABCDᑴEUPD.F⁚ᓫḄᢗᧇIJKᑴmLnḄIMJNEឋ<,OḄPᑖRᩞᧇ12.ᓄTUVWXYZNa2c஺ঞLNaHC஺?]^ḄCDJUV_`ஹabcd᝞e.fgpHhᜧ,c(OH)hᜧJ78^ឋhk.eᑡ*+┯mḄUV_`UVaUVcdIIIIIIজnஹmᙳpqr⁐tu

3G"wᑺxঝ78pHᓄ᝞4XXeX}10mLIINag0.05mol/LNaCOa70.05mol/LNaHCOJ~xyzᮞ|j*I(ஹ^}|1088Q.HINaHCO.5(-5ioᐭwᑺḄ/mLA.irUVJ᣸◀ᓄnஹin78PHB.ILIIḄpHᔠJ*CO]OH,CDJIIqCDḄR:CO+Ca2+=CaCO?C.IllIIIḄpHJ*HCC)3]OHCDJIII¡¢qCDḄR:HCO+OH+Ca2+=CaCOJ+HO32D.inUVḄxyzᮞ|OH.ា¤¥ᐰCD§J78ᕈឋ13.ẆZWXYZNa2O2]|ḄCD஺ª1.56gNazCh«¬ᐭᑮ40mL|JᐙᑖCDE78A(78¯°±ᓄ)J²³eUV஺|´µ78TIUVii᠄ᐜ·,20s¸¹⁐ƽÇ⏚eᑡ*+J,-.Ḅ78Ay.ºAUViU⚠U¼VUVVpqᜧ½<¾78·⁐,78·⁐¿ÀᩈᩩÃlOmin^¹⁐ÄḄÅA.ᵫUViiiÉÊ3gJNazCh]H?OCDᨵH2O2qᡂB.ᵫUViiஹiiiஹiv3gJUVii78¹⁐]H2O2ᨵᐵC.ᵫUVivஹv3gJUViv78¹⁐Ḅc(OH-)ᜧD.ᔣUVii¹⁐¸Ḅ78ÎÇ⏚J78ᨬз⁐

414.ÓÔ᪗Ö×ØJÙᑁᵬÛܽ,<ÝaO.O8mg/m3஺ãäåæ+3ᵨèéØÅᵬÛܽJᐸᳮজAg20ïᵬÛᓄCO2ঝpqḄAg]⏚ᓄḄFe2óSCUö378CDqᡂFeSOঞFeSCh]äåæ4óøᨵùúÇöûᡂᨵ⁐üᔠᱥJØþÿᐸᔾᐝFe2+Ḅᡂ஺ᑡᐵa~cḄᑨḄa.জḄᓄ!"#$%HCHO+2Ag2஺=C0+4Ag|+HO22b.ᳮ23ᔾᦈḄHCHO5ὑḄFe3+ḄᱥḄ%1:4c.;In??@AB3CDEFᐳHᑮFe2+1.12mg,LᑁᵬOPQ᪗A.ᐰTB.aஹbAc┯XCbஹcAa┯XD.aAbஹc┯XZ[Tᑖ15.ᢥ⌕`aᑏ᝞ᓄ!"#$஺d1eᔣNHaHCChijklᐭnNaOHijAᑏopḄqr"#$:஺d2es᯼uvḄ@wxyPᨵSO2,ᔣs᯼k|ᐭCaCCh}~SO2ᓄ%CaSO4,ᨵᦔ■SO2஺᪷᝞Aᵨᓄ!"#$■ᳮ:᣸Ḅ@w/——CaSO3CaOZSO(3)845j(ᨵᦔᡂᑖNaClO)ᵨA?@kḄ2s᯼uv/CaCO1h?@3Ḅ@w-FLCaSO4CO2ᨵᑭ5ᦔᓣAᵨᗂr"#$:d4eᔣijkAxᐭn஺Ḅr"#$:d5e⏚ឋKMnOaij₝⏚dH2c2OJAMnᐗ¨%M/+,ªvᡂ«¬®¯°ᮞ²³´µ@wAᑏopḄ¶r"#$:O16.ᡃ¹º!»Ẇ½Ḅᐰᳫ✌ᝅ“j᝱□ᐝ”⚗ÆÇÈÆ᪗ÉÊ«Ë஺p⚗ÆxÌÍ□½ᵯᵯ²ᑴÐAÑ~CO2|ÐᔠᡂCH3OH஺d1eÍ□ᵯÓÔḄÕ⌕ᩞᧇ%ᓫᨔấ஺জᓫᨔấÛᨔw஺ঝᓫᨔấḄᰚÞßàá°ḄA஺

5d2eᙠãᓄᑺåᵨACO?H?HᑮCHaOH஺জCO2ᑖrḄ?æç᪀%ঝCH30HéC0ᑖrkcrëᦪÆí%2ঞCH30HCO2ᙠ²kḄiᜧAð%d3eZrO2ãᓄᑺ}DòCO2ó⌱õឋ|ÐᔠᡂCH3OH,ᐸᨔöç᪀᝞ᡠ஺ঝNr஺øᨔöḄùúᑖû%apmஹýmஹcpm,ᐸᨔwþ%g-cm“dᑡÿ
஺:lpm=10-12m,NAᦪḄ17.ᡃᓄ!"#$Ḅ“ὶᔠᑴ)*”,-ᑴ)./0123ᜧ56஺78ὶᔠᑴ)*Ḅ9⌕;<=>ᑖᱥAᶍC
஺Di.NH3IJKLᡂ)NO⏚QRLᡂS,TUḄNaCU®VNHc1ᓄW
4᝞NH3+HNO=NHNO334ii.ᨵᐵᱥAḄI^_=20࠷
ᱥANaClNH4HCO3NaHCOaNH4CII^_/g36.021.79.637.2=1
ᰀi᮱kQRḄᓄl<,ᱥAXn஺opqk#LQRḄᓄl<

6஺2
7ᑡs*tuḄn=vwx
஺A.opqkᨵNaHCCh᪆1Nz{|ᩩ~7NaHCChḄI^_ᨬUB.k9⌕ᨵNaClஹNa2co3NH4clC.ḄḄnᧇḄᑭᵨ᳛3
./ᵨ)i)Lᓄ.N᝞ᵨ⛳)IOCbQRᑴ{ᙠLLkᵨJஹ¡ḄᱥAN¢£ᨵNaHCChLᡂN¤QRḄᓄl<no=4
)᪵kᩖANaCL§A¨agḄ᪵Nᐭª¨Ḅ«S⏚NᐙᑖQRN®ஹ¯°ஹ±iNᑮbg³´ᱥANᑣ¶᪵kNa2c03ḄA¨ᑖᦪ஺18.SCRNSRᢈ¸ᨵᦔº»¼½#¾¿ᙠÀÁ;¨ᩩ~7ḄN0,᣸Ã஺1
SCR=⌱ÅឋÇᓄÈ
.ÉᳮDËÌKIÍᓄᜐᳮḄÏÁNC
2ஹ஺2Ð
®ᑖ^NHDCO?N¤QRḄᓄl<DoঝQRᘤkNHDÈNOḄᓄl<Do2ঞÔÕ½k֨ףNÏÁkSO2ᙠ0?Éᵨ7ØÙᡂ=NHJ2SO4,ÚÇᓄᑺk¡Nᵨᓄl<⊤ÝNHJ2SO4ḄÙᡂD02
NSRNOxÞßÈ
.ÉᳮDNOஹḄÞßÈᙠࢣáâãäN᝞8ᡠÝ஺NOÈឋÏÁN2জç;BaOBa=NO
Ḅèé32Ba(NO)YPt32êᓄëìNC\ḄÞßÈNÞßN0ஹḄᱥAn

7ঝᵨH2íîÏÁkÈឋÁ´Ẇð2Ba=NC
3
2ḄÇᓄÈ;R29⊤;<ᡈᐸ?<@iR௃HCjCH2+R0Hᱯ$%75◌2OOHii.Q+RC1AICI^>|jJ~R+HCliii.RCHO+RNH'R.CH=NR.+H^i22A10ABCDBEᡠGHI@JK,ATBḄLM஺

8(2)C—DḄᩩU஺(3)EᑖEᨵ2Yᵬ<[1Y]<E-FḄᓄ.(4)D+F-KḄᓄ஺(5)'ᑡᐵgJḄijklḄ஺a.noNa2co3stb1molJo⛳[yz{ὑ8molBr2c.nᓄஹ{[(6)GᑖEᨵ1)G-JḄᓄ஺(7)NḄ᪀஺(8)Q+Y-XḄᓄ஺20.ᓴoḄᓄᵯ᩽ᑖ᪆ᱥ+ᓄឋ[ឋḄ£ᓄ¤¥஺(1)¦§⏚oMnCh¬ᔠ®ᡂ¯஺¯°±⍎³´t¬ᔠᱥAE¶·ᙠ§⏚[MnO?জḄ"஺ঝᵯ᩽7i.7MnO2+2e-+4H+=Mn2++2H2஺ii.ᓄ7஺ঞ᪷Ãᵯ᩽ᑖ᪆AE¶·ᙠ§⏚[MnChḄÄ஺i.Åc(H+)ÆÇᡈc(Mn?+)¦ᓣ4MnChᓄឋÉÊ஺ii.Åc(Cl-)ÆÇ»ট⊡ᐙÍÎÏÍÐঞEḄᑖ᪆஺ÍÎÒÓÔᑺÕᱥIÙ¦H2s04ᨵ¯1ÔᑺII]aᨵ¯III1Ø´t¬ᔠᱥAa+bÛ¯a,b(2)ᑭᵨc(H+)¦ÞMnChᓄឋḄßàᓴ"Ḅឋ஺áâ¦ḄKC1ஹKBr[KIst,IoMnChᡠ◤ḄᨬÇc(H+)ᵫᜧᑮḄçè,᪀iéᳮᵫ______________o(3)᪷Ã(1)Eìíî7⏚ឋᩩU'ᐭ)ᓄᔠᱥn&ð4ñḄᓄឋMM+ᓄBMnCh஺ò

9ÍÎÏÍÐíîᓄᔠᱥ஺(4)Agᑖóolmol-UḄ§⏚ஹô⏚[Ớ⏚¬ᔠAgoỚ⏚öᣚÔøùÄ:(5)ú7ᱥ+ᓄឋ[ឋ£ᓄḄû¤¥

104üýþᓄÿ

ᵨᑮḄHlC12O16Fe56Zr91ᑖ1.ᑡᐵḄB.ḄC.D.⏚ூᫀ௃Cூ᪆௃ூᑖ᪆௃ூ௃A.ᑖᦣᔠᱥ!"ᑖᦣA#$;B.&ᣚ()*+ᓄ-.()ᓄᔠ()/ᑖ()ᨵḄ+ᓄ-.()ஹᨵḄ+ᓄ-.(),3ᑖ()*+ᓄ-.()B$;C.⏚#ᨵḄ4ᨵḄ5C$;D.67ᙠ9:;ᡈᰚ>?᝱ABᵯḄᓄᔠᱥᵯDD$;ᦑ⌱Co2.ᑡᓄGᵨIᡈ$⊤KḄCH,CH.A.LMḄᵯNOPP0PHB.2.RSḄ(OT᪀P)=&'IIC.SO2ḄVSEPR[\D.NO]Ḅ^_T᪀[\P1ூᫀ௃Dூ᪆௃ூ௃A.LMḄᵯNO`HP6ᦑA┯b;••CHmB.?xc=Z3`2-RSḄeOT᪀ᦑB┯b]C.SChᑖN#Ḅ#f.NghᵯNiᦪ2+cHஹH

116-2--------=3,ᡠlS.Nmᵨsp2ᩖᓄᦑSO?ḄVSEPR[\`o☢qrsᦑC┯b]^^x225+1-2D.NO]Ḅ#f.NghᵯNiᦪ3+----------=3,ᡠlN.Nmᵨsp2ᩖᓄtᨵuᵯNiᦑ♦x32NO-Ḅ^_T᪀[\`o☢qrsᦑD]ᦑ⌱D஺3.ᑡᱥDឋDḄxyez{ᴁḄA.ᐗ~ḄᵯឋPCl>S>NaB.ᓴ~ᓫDḄᰚPI>Br>Cl>F,222C,⏚⏚Ḅ⏚ឋPCH,C1COOH>CC1COOH3D.ᩩᱥDᙠ9#Ḅ:PCHOH>CH(CH)OH25324ூᫀ௃cூ᪆௃ூ௃A.ᕜᑮᐗ~Ḅᵯឋ⌲ᜧᐗ~ḄᵯឋPCl>S>Na,ᦑA]B.ᓴ~ᓫD`ᑖNᨔ"iᑖNDᜧᰚᓴ~ᓫDḄᰚPI>Br>Cl>F,ᦑ2222B]C.C1.N`ᔾᵯNḄMA-OHḄឋ¡ᑣCQ3coOH£᧕ᵯ¥¦¥N⏚ឋPCH2cleOOHCH(CH2)4OH,ᦑD]23ᦑ⌱PCo4.ᑡ®ḄA.ℍ⃔±ஹ²³±ஹⅅ±ᙳA¶·¸¹()B.ºᾦᙠ¡¼:;#ᐙᑖ9¾ᑮ¿ᾦÀ⏚/ᵞºC.Â⏚4ஹÂ⏚ÃஹÄ⏣ÅAÆÇDÈឋD.ÆÇDᐹᨵÊឋ9ᨬÌÍᱥ`ÎÏூᫀ௃Bூ᪆௃ூ௃A.ℍ⃔±ஹ²³±tᨵÐMA¶·¸¹()Ñⅅ±ÒÓÔÐMA¶·¸¹()ᐸ9ÍᱥÕl¶·A┯b]

12B.ºᾦ×ØᱥDᙠ¡¼:;#ᐙᑖ9¾ᑮ¿ᾦÀ⏚/ᵞºB]C.¡⏚ஹ¡¼/ÚÛÜÕlÆÇDÈឋÑÂ⏚4ÆÇD¶·᪆C┯b;D.ÆÇDᐹᨵÊឋ,ᐸ9ᨬÌÍᱥ`ÞM⏚D┯b]ᦑ⌱B஺5.ᑡàá#Ḅâ⁐Èᓄä+ᓄ-.()ÔᐵḄABCDNaOH:;êᐭðñ:;êᐭò9Na2s:;êᐭøÃùúᐭûü⏚àáFeSCU:;##AgCl÷;##Í·Ç⁐ÿ

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ýþ⋎⁐⁐⁐⁐A.AB.BC.CD.Dூ!ᫀ௃Cூ$᪆௃ூ&$௃ᑖ᪆(A⚗
⁐⋎⁐*Ḅ,-4Fe(OH)2+O+2HO=4Fe(OH)3;B⚗
22⁐⁐:HC1O⊤=>?ᓄឋBC⚗
⁐⁐*Ḅ,-2AgCl+Na2S=Ag2s+2NaCl(D⚗
ᵫ⁐⁐*Ḅ,-2NO+O2=2NO2஺&$(A⚗
NaOHJᐭFeSCUM⁐Fe(OH)2
⁐⋎⁐*Ḅ,-4Fe(OH)2+O+2HO=4Fe(OH)3
N,-OᐗQᓄᔠSᨵᓣV
?ᓄWX,-BB⚗
YZM22[ᙠ,-CI2+H2O=^HC1+HC1O,ᵫ`YZᕈ⏚ឋ
cdJᐭᐜ
⁐⁐:HC1O⊤=>?ᓄឋ
fᨵ⁐ᱥhi?ᓄWX,-BC⚗
⁐⁐*Ḅ,-2Agel+NazS=Ag2s+2NaCL,-OᐗQᓄᔠSl
l:?ᓄWX,-BD⚗
CufnHNCh,-ᡂCu(NO3)2ஹNOrH2O,ᵫ⁐⁐*Ḅ,-2NO+O2=2NO2,,-OᐗQᓄᔠSᨵᓣV
?ᓄWX,-Bf?ᓄWX,-ᐵḄ:C⚗
!ᫀ⌱C஺uv(w⚪ὃz?ᓄWX,-Ḅᑨ|
ᑖ᪆}⁐ᓄḄX~ஹᳮ$?ᓄWX,-Ḅᱯ:$⚪Ḅᐵ஺6.ᙠᩩ
RO(rF2i᝞,-(RO"'+F2+2OH-ROB'+2F+HO,ᙠROB2M
ᐗQRḄᓄᔠS:A.+4B.+5C.+6D.+7ூ!ᫀ௃Aூ$᪆௃

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-n+2x(-l)=-2+2x(-l),$n=2,ROBMRᐗQᓄᔠSx,ᜫᵯឤᨵ(6-x=2xl,$x=+4,IJROBM
ᐗQRḄᓄᔠS:+4,!ᫀ⌱A஺7.
ᑡᔜ£¤ᙠᢣM¦ᜧ¨ᐳ[Ḅ:A.ᵫZᵯ¤Ḅc(H+)=10-i2moi/LḄM(Na
NH(ஹCªஹK
B.⁐M(Na+ஹK*ஹCrOB-,NOB2C.«ᨵFe?+ḄM(H
Na
CªஹNOBD.pH=14ḄM(K+ஹCRTஹcojஹcrூ!ᫀ௃Dூ$᪆௃ூ&$௃A.Zᵯ¤Ḅc(H+)=10-7moi/L,NZᵯ¤Ḅc(H+)=l()T2moi¬ZḄᵯ¤ᑮᢓᑴ
⏚±²ᢓᑴZḄᵯ¤
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¦¿ÀÁ?ᓄᡂÂSÁ
C┯¸BD.pH=14ḄM(K+ஹC10>CO(ஹCᔆ¦ᜧ¨ᐳ[
DÄÅBᦑ⌱D஺8.ᑡ¤ÆÇÈÉᑏÄÅḄ:(A.ËỚᓄÍÎÏÐJn½⏚Ñ(2F+4H++NOB=I+NOT+2HO22B.ᵨÓ⏚◀ÕZÖ(CaCO+2H+=Ca2++H0+C0T322C.ᔣMg(OH)ØÙMÚᐭFeCl(3Mg(OH)+2Fe3+^2Fe(OH)+3Mg2+2323D.ᔣYᓄÛMJÚܨḄÝZ(Al3++4NH,-H0=A10*+4NH(+2HO22ூ!ᫀ௃Cூ$᪆௃ூ&$௃A.ËỚᓄÍÎÏÐJn½⏚ÑÞß⏚ឋᩩ½⏚᪷¿Ớ¤?ᓄᡂỚᓫh(6E+8H++2NQ-=3I+2NOT+4HO,A┯¸B22B.Ó⏚:á⏚
◀ZÖ,-Ml¦â
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l`ܨÝZ(A13++3NH-HO=A1(OH)J+3NH(,D┯¸B323ᦑ⌱C஺9.ᙠåæçèḄBa(0H)2M
ᑖéJᐭᱥhḄ¨êëçìḄH2soஹNaHSO,
ᐸîᵯ¦ï4JᐭðᓄḄñò᝞óᡠõ஺导电能力A.জ÷⊤JÚH2sḄᓄñòB.bu
Mᜧ¨[ᙠḄ¤:Na,ஹOH-C.cu
åM«ᨵçè¨ḄOFTD.aஹdåuø-Ḅᙳ»Mឋூ!ᫀ௃Cூ$᪆௃ூᑖ᪆௃ᔣBa(OH”MJᐭú⏚i,-ḄᓄûÆÇÈH2SCU+Ba(C)H)2=BaSO41+2H2O,ᔣBa(0H)2MJᐭNaHSCU
ḼNaHSOýḄJᐭþi,-Ba(OH)2+NaHSO=BaSO41+HO+NaOH,NaOH+NaHSO4-Na2SO+HO,îᵯ¦ïf¤êëᡂÄ4242ÿ᪷জᙠaᵯ0,ᨬBa(OH)2H2s04ḄᑣঝBa(0H)2NaHSCUḄ#ᑖ᪆&'஺ூ*+௃A.᪷ᑖ᪆জ-⊤/0H2s04Ḅ1ᓄᦑA456B.᪷aBa(0H)2H2s04ា8H2so9NaHSCUḄᱥ;Ḅ<=>ᑣb;NaOH,ᡠ@bAᜧ

15ᦑ⌱^Co10._`AḄ_abᐹᨵᢙf᷈ஹᢙhi>Wᱥjkឋᐸᰚ347n348°C,o᪀qr᝞tᡠu஺tᑡᐵx_abḄyP45ḄDB.ᑖAzᨵ3{zO|}C.~[W0ᡂD.Imol_abᨬ~3moiNaOHூ'ᫀ௃Cூ+᪆௃ூᑖ᪆௃ூ*+௃A._abḄᰚ347n348C,tz⍗᧕Oᓄ1;◤CA456B.᪷o᪀qr_abAzᨵḄzO|}ஹ⏚zᨵ3{zO|}B456C.z~[W-z~[W0ᡂC┯S6D.᪷o᪀qr_abAzᨵ3ᡠ@Imol_abᨬ~3molNaOHD456ᦑ'ᫀ^C»II.P⛳UP
OHDWᔠᩞᧇ“¤ᴻT''Ḅ᪛ᾦᩞᧇ஺᝞D@Ạᓄª«ᧇᔠᡂUP¬:()A.¯°±KMnCU⏚ឋ²Oᓄᑴᓫ1B.ᓫ2°Dµ¶⏣C.ᓫ1ஹ2ஹ3¸¹ᑴºUPD.»⁚ᓫḄᢗᧇ¾¿ᑴmnḄ¾ÀÁºឋPQḄÂᑖᩞᧇூ'ᫀ௃A

16ூ+᪆௃ூᑖ᪆௃᪷¹ḄÂᱥ~ᓫÃÄḄᐵÅ°ÆP⛳(UP)ḄᓫᨵÈᑖÉDHOCH2cH2OHஹHOOCCH-CHCOOH,HOOCH^^-COOHÊᔠᡂUP¬ᩭÌᵬz4C,2P⛳DᔠᡂᓫHOOCCH=CHCOOHḄ«ᧇoᔠÎLḄ~ḄÏÐᓄḄ0ᡂ°ÆÑᵬÒᓄª«ᧇ1,4Ó¶Ô(CH2=CH-CH=CH2),ᵬ~Õᓫ;W0ᡂWᡂµÆѵ111cHF'µ[+°ºᑮ¯ᑣ¯ᫀ1cH×Ø"¯~HBrW0ᡂ°ºᑮÚÛܸIÝÞOᓄߺᑮÓᑣÓ“ªߟ“cmÓWàáºᑮᨬâḄᓫ1(HOOCCH=CHCOOH),ᨬâ¸I¹HOOC-CH-CHr-COOHºᑮUP,#ᑖ᪆&'஺ூ*+௃A.᪷Ûãᑖ᪆°¯9×-åᙳ°±KMnO4⏚ឋOᓄP²ºᑮᓫ1(HOOCCH=CHCOOH),ᦑA┯S6B.ᓫ2°Dµ¶⏣(HOCH2cH2OH),ᦑB45^C.ᓫ1ஹ2ஹ3¸ῃ[¹°ᑴºUP,ᦑC456D.»⁚ᓫḄᢗᧇ¾¿ᑴmnḄ¾À°ÁºឋPQḄÂᱥᦑD456'ᫀ⌱Ao12.ᓄjéêëìíNa2co3NaHCOm~MḄéêîïஹIðoñ᝞t.ò^pHóᜧc(OH)óᜧMឋóô.tᑡy┯SḄDéêîïéêIéêoñIIIIIIজnஹmᙳWõ⁐YZঝ÷øApH1ᓄ᝞G•úᑺxJX
X
IINagX
0.05mol/LNa2cO30.05mol/LNaHCC)310I✄10mLüýþᮞHINaHCO.5(5io-ᐭᑺḄ/mL

17A.I#$%&'(᣸◀+,ᓄ.HஹinpHḄ01B.I2nḄpH34567ᔠ(9:co;-?@(nABC?@ḄDEFGHI
CO;+Ca2+=CaCO,C.IllJIIḄpH34KL(9:HCO

18|T|&'ii᠄ᐜ,,20s¡⁐1M(8Wqr⏚ᑡ9²A,>.ᵫ⚢Ḅ#AA&'iy.£&⚠&¥V&'V¦Cᜧr¨,I⁐,,I⁐ª«ᩈᩩ®lOmin^¡⁐¯Ḅ°A.ᵫ&'〉Aµ¶fg(NazCh#mn᪷DEÊËḄᐵÌ(ᦑB}~;C.ᵫivஹvfg(ᙠA⏒,⁐2mn᪷DEÊËᨵᐵ(Imol/LḄmnᓄsA»ᐭÎ,⁐(10ᑖÏ¡⁐(лᐭ⏚?@mn᪷DEÊËÑ(,⁐(9:ivA⁐¡Å#+Ic(OH)ᜧ(ᦑC}~;D.iiA⁐¡ÅḄÆ⌕¹+#CᡂÈÃnᓄmᐹᨵnᓄឋ(Òᨵ⁐ᱥÔnᓄI⁐ᱥÔ(ᔣiiA¡⁐ḄA»⏚(ᨬ½>Õ,ᡂ⁐(ᦑD┯஺[ᫀ⌱D஺14.Ö×᪗ÙÚÛ(ÜᑁᵬßÂr>¨àÃO.O8mg/m3஺á=âãä²fᵨæçÛ$°AᵬßÂr(ᐸ¹ᳮI
জAg2OëᵬßnᓄICO2ঝ¦CḄAg<⏚ᓄḄFe2(SCU)3?@CᡂFeSO
ঞFeSCU<âãä4(=îᨵïs)ðᡂᨵ⁐ñᔠᱥ(=ÛòóᐸᔾᐝË

19C.lm3ᐳᑮFe2+1.12mg,ᑁᵬ᪗A.ᐰB.aஹbc┯"C.bஹca┯"D.abஹc┯"ூ$ᫀ௃Bூ'᪆௃ூ)'௃a.ᵫ⚪,-.HCHO/Ag2O012ᱥCCh3Ag,ᦑᓄ6789HCHO+2Ag2O=CC>2+4Agj+H2஺,ᦑa⚗;b.ᵫ⚪,-.n(HCH0)~4n(Ag)~4n(Fe3+),ᡠ?ᳮAᔾᦈḄHCHO/DὑḄFe3+ḄᱥḄ14,ᦑb⚗஺.1.12mgFe2+ᱥḄ0.02mmol,Gn(HCHO)H4n(Ag)H4n(Fe3+)Hn(Fe2+),ᦑHCHOḄᱥḄ0.005mmol,m(HCHO)=0.005mmolx30g/mol=0.15mg,Imᦑᵬ0.15mg/m3,IJKL᪗Mᡠ?ᑁᵬI᪗ᦑc⚗┯"஺ᦑ$ᫀBoNOᑖ15.ᢥ⌕STᑏ᝞Wᓄ6789஺(1)ᔣNH4HCO3[\]^ᐭ`NaOH[\ᑏab01Ḅcd789:(2)f᯼2hḄijkᨵSO2,ᔣf᯼]mᐭCaCCh-nSO2oᓄCaSOd,ᨵᦔ■rSO2st஺u᪷w᝞Wxyzᵨᓄ6789'|■r}ᳮ:᣸ḄiCaSO3CaOso(3)84D\(ᨵᦔᡂᑖNaClO)ᵨ]Ḅf᯼2h/C2aCO3Ḅi-CaSO4CO2ᨵᑭDᦔᓣᵨcd789'|}G:(4)ᔣ[\]jᐭ`01Ḅd789:஺(5)⏚ឋKMnCU[\/₝⏚(H2c2O4)01MnᐗoMn?+,hᡂᮞḄiᑏab01Ḅ789_______

20ூ$ᫀ௃(1)NH+HCO+2OH-=NHj-H2O+H2O+CO(2)2CaCO+2SO2+O2=2CaSO4+2CO32(3)CIO-+C0+H0=HCIO+HCO22(4)2Fe2++4Br-+3Cl=2Br+2Fe3++6CP22(5)2Mg+5H2c2O4+6H+=10COT+2Mn2++8HO22ூ'᪆௃ூ¡1)'௃¢⏚£¤]¤᪷cd3¢⏚£᪷cd¥-?/£¦᪷01£¦ᓄ§`ᑣ©ªhWᑡ01NH+HCO3+20H-=NH3•H2O+H2O+CO;ூ¡2)'௃¢⏚┛®ᩩ°Wᑖ'hᡂ¦ᓄ┛¦ᓄ┛3O¦ᓄ±01hᡂ²±⏚┛³¦ᓄᡂ±⏚┛ᓄ67892CaCO3+2SO2+O2=2CaSO+2CO42ூ¡3)'௃O¦ᓄ¢[hᡂ⏚ឋ´µ⏚¶Ḅ¢⏚ᑭᵨ¶⏚ᑴ¸⏚Ḅ}ᳮhᡂ´µ⏚CIO-+CO+HO=HCIO+HCO-,´µ⏚ᐹᨵº»ឋ3¶¦ᓄឋ22ூ¡4)'௃¼ᓄ²½]²½3¾cd¥¿ᐺÁḄÂ}ឋcd`ḄµÃ¦ᓄᑺnOὅ¥¦ᓄᡂÆ1ḄÇȽcd3Éᓫ2■++4Br-+3C/=2Br+2Fe3++6Cl-22ூ¡5)'௃⏚ឋKMnCU[\/₝⏚(H2c2O4)01MnᐗohᡂᮞḄiᓽO¦ᓄ¢᪷w¦ᓄÂ}01ÍÎḄÇᜧ}ᑣᜫÑឤஹᵯ₹Ñឤ3ᐗÑឤÍÎ78Õy₝⏚¿¸⏚Ö×2MnO+5HCO+6H+=10COT+2Mrr++8HO22422o16.ᡃKÙ6LẆªḄᐰᳫ✌ᝅ“\᝱□ᐝ”⚗ãä¢ã᪗åæç஺b⚗ãjJè□ªᵯᵯ'ᑴ£énCC\m£ᔠᡂCHQH஺(1)è□ᵯëìḄí⌕ᩞᧇᓫᨔấ஺জᓫᨔấóᨔi஺ঝᓫᨔấḄᰚö÷øùḄ}G¿o(2)ᙠûᓄᑺÃᵨWC0/H01ᑮCH30H஺22

21জCCý2ᑖdḄÿ᪀O@CHOHco?ᑖ஺ᦪ஺3ঞCH30HCO2ᙠḄᜧ!"#3$Zr஺?'ᓄᑺ*+,CO2-⌱/ឋ12ᔠᡂCHஹOH,ᐸᨔ9᪀᝞;ᡠ=஺ঝZrC$2ᨔ9Ḅ?@ᑖAapmஹapmஹcpm,ᐸᨔEFg-cm"#ᑡKL$஺MNOlpm=10-12m,NAST1UVWᦪḄXூZᫀ௃#1$জ.ᐳ`ঝ.ᓫᨔấcdeᙳghᐳ`ᨔEijklmhấjkliiḄ@mhấấḄ@iiḄnᜧhấấcdeḄᰚp-hấ#2$জ.qrsঝ.5O2ঞ.CH3OH!᩽ឋᑖஹᵬ⏣ᑖxᑖynzᡂ2C0?!{᩽ឋᑖxᑖy|nzᡂ2᪷~jᳮCH30HCO2ᙠḄᜧ#3$জ.O2'ঝ.Aᳫ8x1+6xg=4,Bᳫ8᪷~ᓄLZrO,B⊤0?-ঞ.284x91+16x8a2cxNx\O-ioAூ᪆௃ூm1௃□nᵯḄ⌕ᩞᧇᓫᨔấ஺জᓫᨔấấjyᐳ`zᡂ¡᪀ghᐳ`ᨔE஺ᦑZᫀOᐳ`£ঝᓫᨔấᰚp¤hcdeḄj"!ᓫᨔấcdeᙳghᐳ`ᨔEijklmhấjkliiḄ@mhấấḄ@iiḄnᜧcdeḄᰚp-஺ᦑZᫀOᓫᨔấcdeᙳghᐳ`ᨔEijklmhấjkliiḄ@mhấấḄ@iiḄnᜧhấấcdeḄᰚp-hấ£ூm2௃

22জCO2ᑖij¥ᵨspᩖᓄ©y᪀qrs஺ᦑZᫀOqrs;ঝCH3OHᑖ3C-Hஹ1C-0ஹ10-Hᐳ5஺CC)2ᑖ2C-OO■CH3OHCO?ᑖbᦪ5O2஺ᦑZᫀO5O2£ঞCH30HCO?ᙠḄᜧ!"CH30H!᩽ឋᑖஹᵬ⏣ᑖxᑖynzᡂ2,CO?!{᩽ឋᑖxᑖy|nzᡂ2᪷~jᳮCH3OHCO?ᙠḄᜧ஺ᦑZᫀOCHyOH!᩽ឋᑖஹᵬ⏣ᑖxᑖynzᡂ2CO?!{᩽ឋᑖxᑖy|nzᡂ2᪷~jᳮCH'OHC0?ᙠḄᜧ£ூm3௃জ᪷~ᙳ¯°Aᳫ8x1+6x^=4,Bᳫ8᪷~ᓄLZQ,B⊤O'ᦑZᫀOAᳫ8x2+6x£=4,Bᳫ8᪷~ᓄLZrO2,B⊤O'82ঝᨔ9³ᦪapmஹapm>cpm,ᑣᨔ9E¶(axlO10)2xcxlOlocm3,¸ᨔ9¹ᨵ0j8Zr4+1.91x4+16x8m4x91+16x8ᦪ8x^+6x5=4,ᨔ9»¼------------g.ᑣ¸ᨔEḄF.2cx,VxML஺gym',ᦑZ4x91+16x8ᫀ:-77?,ÁÂ30£஺acxNxlOA17.ᡃÄᓄÅÆUÇÈÉḄ“ὶᔠᑴÍ°”ÏÐᑴÍÑÒÓÔÕÖᜧ×Ø஺Ù;ὶᔠᑴÍ°Ḅ⌕Nad(⛳Û)Ü(Ýᑖᱥ»Mᶍà)஺MNOi.NH3hãᡂämḄN&CåæNH4c1(ᓄç)Íx⏚éêãᡂë᝞NH3+HNO3=NH4NC)3ii.ᨵᐵᱥ»Ḅ(20࠷)ᱥ»NaClNH4HCO3NaHCOaNH4CI

23/g36.021.79.637.2(1)ðñ᮱éêḄᓄóÜL,ᱥ»X!oõöÈãéêḄᓄóÜL0(2)Ùᑡ÷°øùḄ!(úûü)஺A.õöᨵNaHCCh᪆Ô"Âþᩩ
NaHCChḄᨬB.⌕ᨵNaClஹNa2cChNH4clC.ḄḄ!"#$ᧇḄᑭᵨ᳛(3),-.ᵨ/012304567ᓄ,59:᝞ᵨ⛳/0=Cb?@.ᑴBCDᙠ454FGᵨHIJஹKLḄᱥN:OPᨵNaHCCh4ᡂ:R?@ḄᓄSTUV!஺(4)6/0᪵9ᩖNNaCLZN[\agḄ᪵9:^ᐭ`[Ḅab⏚:ᐙᑖ?@f:^gஹhiஹj3:BᑮbglmᱥN:ᑣo᪵9Na2cChḄN[ᑖᦪ\஺Aூsᫀ௃(1)জ.2NaHCCh=Na2cO3+CO2T+H2Oঝ.C0ঞ.2NaCl+CO2+NH3+HO=NaHCOl+NH4Cl23(2)AC(3)2NaCO+C12+H2O=NaCl+NaCIO+2NaHCO323(4)106(b'a)xl00%Ilaூ᪆௃ூᑖ᪆௃ᐜᔠᡂᔆ45Ḅᐭ⛳b:0ឋ:ḄᔾᦈC02,fᐭ[C02,᪆ḄNaHCCh,fᰀ3NaHCChBᑮ⏚ஹᓄ:ᐭNH3,OP^ᐭ¡!NaCl⚩£:¤¥᪆NHKXூ¨I©௃A᪷«ᑖ᪆:ᰀ3᮱\ᰀ3⏚:ᓄSTUV\2NaHCO3=Na2CO3+CO2f+H2O,ᡠ°ᵨḄᱥNX\CCh±²³´NaCl=NH3ஹCCh?@᪆⏚:ᓄSTUV\NaCl+CO+NH3+H2O=NaHCO31+NHCl±24ூ¨2©௃A.᪷«⚪i"¶Ḅ⊤¸¹ᧇ:²³´ᨵNaHCCh᪆:!º\C»ᩩ
NaHCChḄᨬ:A½¾±B.²³´Ḅ?@\NaCl+CO2+NH3+H2O=NaHCO31+NH4஺:f⌕ᨵḄ!NHQ,Áᨵ⏚:B┯ÃÄ

24C.²³´ᰀ3᮱?@BᑮḄ5ᱥÅ.Æ\ᑴZ/0Ḅ$ᧇ:ᦑḄḄ!"#$ᧇḄᑭᵨ᳛:C½¾ÄÈÉᡠÊsᫀ\ACூ¨3©௃᪷«⚪Ë:.?@ÌÍÎÏÐ4:✌ᐜÒ?@4ᡂb⏚ÓÒ⏚:b⏚ÓÒ⏚=⏚?@4ᡂÓÒ⏚⏚:ᑣ?@ḄᓄSTUV!2Na2cO3+C12+H2O=NaCl+NaClO+2NaHCO3,¨4©௃agḄ᪵9:^ᐭ`[Ḅab⏚:⏚=b⏚ᐙᑖ?@f4ᡂÒᓄ:?@TUV\Na2co3+2HCl=2NaCl+H2O+CO2T:^gஹhiஹj3:BᑮbglmᱥN\Òᓄ஺᪷«?@Õf$Ö×ឤ:ᩖNNaClḄᱥNḄ[\xmol,⏚ḄᱥNḄ[\ymol,ᑣbgb—ab—a58.5x+106y=a,x+2y=”7:By=----mol,⏚ḄN[=nM=-----molxl06g/mol=58.5g/mol1111106fb:)106(b-a)Cã"g:ᑣo᪵9Na2cO3ḄN[ᑖᦪ\—H—_106(b-a)oinno/mno/Ii----------------------X1UU/o=---------X1UU/oaIla18.SCRNSRᢈë.ᨵᦔíîïðÐñòᙠó[ᩩ
ḄNO᣸õ஺X(1)SCR(⌱÷ឋøᓄù$),Æ$ᳮ:ÿ
ᓄᜐᳮfḄýN2ஹ0জco(NH2)
(NO,஺2þ)2SCRᓄᘤᑖNH3CC)2,Ḅᓄঝᘤ!N&"#NO,Ḅᓄ஺ঞ&'(!)*+,-./01!SO?ᙠ3ᵨ567ᡂ(NHJ2SO4,:ᓄᑺ!(NHJ2SO4Ḅ7ᡂ஺(2)NSR(NOX?@"#)A3#ᳮN஺ஹḄ?@"#ᙠCD.EFGHI/᝞Kᡠ>஺

25জNOBaOBaPNCQ3Q2ḄRSTᓄUVNO*Ḅ?@"#/?@NO*ḄᱥXYঝᵨH2Z[01!"#ឋ1]Ẇ_`BaPNCQ3Q2Ḅᓄ"#O/OᑖabHI/5K⊤>OcdbeὑḄHgBaPNC
3Q2ḄᱥXḄ+hY2ঞ"#O!/ᨵ.6jkl1N2஺Q஺ᵨDm>noẆ_pVl1ḄjkgNOᨵᐵ஺ᙠᨵrᩩt5-NOgNH?udvw./xᑮḄl1z{|YL5NNO஺}Ḅᓄ⊡ᐙ᦮—□15NNO+OHO2ூᫀ௃প[COPNH
]+HOS2NHT+C0Tঝ.8NH3+6NO2⇪72+120222320,2SO+O+4NH+2HO=2NH
SO2232424P2
জ.BaOঝ.8:1ঞ.415NO+3O+4NH—415NNO+6H.O23ூ᪆௃ூ1௃জ[COPNH2Q21
ᑖNH3CO2,Ḅᓄ[COPNH
J+HO®2NHT+COT2232

26ঝᘤ!N&"#NO?kᡂN2H20,NH3ᐹᨵ"#ឋ/pkḄᓄ:8NH+6NO—7N+12HO3222ঞ01!SO2ᙠO?NH33ᵨ567ᡂPNHJ2SO4,kᡂPNHJ2SO4Ḅᓄ2SO,+O+4NH+2HO=2NH
SO232424ூ2௃জᵫK?@O!/NOg6kᡂNCh,pkḄᓄ2NO+O=2NOBaO22,NO2kᡂBaPNO
,ᑣ?@NOḄᱥXYBaO32XঝᵫK/cdbNᐭH2gBaPNC>3Q2jkNH3,cbḼḄHIjkNH3/kᡂᱥN2,ᑣcdbḄᓄ8H+BaNO
=2NH+5HO+BaO,cdbeὑ23232ḄH2gBaPNO,
ḄᱥXḄ+h8:12ঞᨵrᩩt5/UNOgNH,udvw./xᑮḄl1z{|YUNNO,r1/᪷xᜫᵯ£¤ឤ#£¤ឤ/Ḅᓄ4I5NO+3O+4NH-4I5NNO+6HO»232XY-ᑖ£¦§¨£©ᔠᑺ/u5Ya«ᱥXḄᔠᡂ¬:RHC-"CH2ᱯvᑺRூHC—CH2OR2Di.\/d+R20H±IN²)+RC1—³—>UpK+HCldvᩩtR,CHO+RNHFRCH=NR+HO22I22(1)Aµ¶/B!ᡠ)·¸¹º»YA-B¼½Yo

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eὑ8molBr2c.pkrᓄஹeàáâ(6)Gᑖ£!äᨵ1«å#£/G-JḄᓄYo(7)NḄç᪀éYo(8)Q+YTXḄᓄY஺ூᫀ௃(1)জ.êêëìஹêíìঝ.îï(2)NaOH/HO,2COOHCI+H(3)C20CH3ò*⏚(4)HC—CH—CHOH+HC=C-COOH222VCH0o6neூ᪆௃ூᑖ᪆௃AḄC⛳÷1,᪷(1)⚪úAµ'/ᦑAüµ/ᓽCH2=CHCH3,ÿAஹBḄᑖA—BᦑBCH2=CH-CHC1᪷C!ᨵ#ᱥ%&B—C2'(()*+ᓄᡂ.*ᓽ஺1஺"1CH?஺5cஹDᑖ%&C—D89:;,OCOOHH2C—CH—CHjOH,>xḄ@᪀ᑖ᪆GDEEHO—1H(?%,ᓽD:KLMNLᡂFOCH3

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