2021年新疆高考化学三诊试卷（问卷）-附答案详解

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2021
ᶢὃᓄᔁᔁஹᓫ⌱⚪ᜧ⚪ᐳ7⚪ᐳ42.0ᑖ1.
ᩞᧇḄᐙᑖ!“$%ᢈ'”“$%ᑴ⌼”+“$%,-”஺/ᑡᡂ2ᡠ45Ḅᩞᧇ678ᩞᧇḄ9A.“ᜩ;<=”>ᜩᘤ@ᵨḄB-CஹDEḄᩞᧇ-Gᔠ7B.“ᜩ=”IJKLᘤM□OḄᩞᧇPQRSTᔠU⏒WↈYC.“M□[\]^ᑜ”@ᵨḄM□[ᵯaḄᩞᧇ-bᓄcD.“⚞e”AG5OCfghijkl᪀ḄTᔠᩞᧇ-nᴻRSTᔠᩞᧇ2./ᑡᐵqᨵjᱥḄtuvwḄ9A.2-ᵬyz{|}6~z{B.eg%஺ᐳᨵ3ᨵḄᑖ~᪀C.ஹஹUᙳ@⏚ឋ⏚⁐D.⏚⏣ᓄᙳ783./ᑡḄvwḄ9tᑭFMh¡A.¢£X᝞¥ᡠ¦§ᑴ¨©ª«⋎⁐®kscNiVtiftt᝞¥ᡠ¦§¯⁐°«rC.n᝞¥ᡠ¦§ªᜧ-±²³´a᝞¥ᡠ¦§ᐜª·⁐®¸¹“º4.᝞¥⊤¦ᵬஹஹ¼½¾¿Ḅ[-°ᓄᐸ$H2ஹBrzஹHBrᙳ6±᝱஺/ᑡᨵᐵtuvwḄ9

1HH2Br„©0O©@@,14U»kJ-mo|-'00C00©%HBrᵬA.HÄÅÆᡂlmolH2ᔾᦈ436kJḄ[-B.BBᑖÅḄᓄឋBÓBrÄÅḄÕÖC.H2g+Brg=2HBrlÛH=-103kJ-mol-12D.ßàᩩâãᐙᑖäu^徿Ḅ[-°ᓄ5.AஹWஹXஹYஹZ9ÄÅëᦪíîïðḄñᕜókôᐗöᨬ᜜ùᵯÅᦪúû2ü=X-W,Wþᙠ5
᪶10ᵯḄᓄᱥᑖXḄᨬ᜜ᵯᦪᵯᦪḄ3,O.Olmol•LYAZX4%&ḄpH)20ᑡ,-./Ḅ01A.2ᓫ4567W>X>Y>Z>AB.;ᓄᱥḄ<=7X>WC.YAZX4ᐳ@ᓄᔠᱥB%&C⏚ឋD.ᨬG@HI⏚Ḅ⏚ឋ7Z>W6,KH2sMNOḄPᔠOQRᐭFeChஹFeC%MC11CI2ḄPᔠ%&Z[ᦈS,ᐸ_ᓄ᝞aᡠc0CuSe%fB1஺ᑡ,-┯iḄ01A.jkজmnoᑖpqrᵫt⏚qruᑮw⏚xjkঝZmnqrḄ4zk{)7s2-+2Fe3+=S+2Fe2+C.jkঞZ᪗11.2LO2qr_2moiᵯD.ᙠঝZFe3+IᓄᑺᙠঞZFe3+Iᓄᱥ7.᝞aᑭᵨnᱥKBZḄᨵᱥ0᝞1MONOḄᓄ_ᓄ)ᵯᑡ,-Z./Ḅ01A.j□4ᣚ¢ᵫ£ᔣ¥¦B.§X¨©ᵨᵯᘤ᪗ᨵ“+”Ḅ®C.Mᵯ᩽qr{70CHO1+7nH2஺-24ne-=6nCOT+24nH+6105n2D.³Mᵯ᩽nᱥKBZ16.2g_ᓄᣵ¶Nᵯ᩽n134.41ᵯ0᪗1·2⚓ᐳ22⚓

2¹ஹº»⚪(¾ᜧ⚪ᐳ1À⚪ᐳ14.0ᑖ)8.ᵞÃ⏚ÄÅÆÇḄÅ⃩ÉwᓄᑺÊËᵨfÌÅឋÍ⊈Ḅ⚜■MÑᶭ஺ÓÔ:ᵞÃ⏚ÄÅḄᓄ{)KMNCHzCOO^Fe,᥅×Ø204g•moL஺º»ÙÚÛᐸᔠᡂz-᝞a1ᡠc7*aᔠᡂÝÞaÓÔ:ᵞÃ⏚ßᢙá⊈⏚ᵞÃ⏚ÄÅFeS04-7H2O.FeCl24H2O(HNCHCOOH)22᧕%fB᧕%fBMã⏣ᨵt᧕%fB᧕%fB᧕%fB%fã⏥⏚ឋMwæ
ឋç%fã⏥ç%fã⏣᧕%fã⏣è[é7(1)᝞a2ᡠcᔠᡂÝÞZêᘤbḄëì஺(2)íîIIïḄz-ðñᵨò)ó■ôFe2+õIᓄ¾º»ö÷ḄíîZñøḄùúᨵ஺(3)ᑡ,-./Ḅ஺A.ûᐭ&Qürᐜᡭÿ
ᧅaḄᴻB.᪷⚪ᡠ⌱ᵨFes஺,-7H2஺஺C.DIḄᑖ!"#$%஺D.W,&'()Ḅ*+$,ᨬ.⌱ᵨ/0*+(4)ᑏ2ᔠᡂᵞ6⏚Ḅᓄ9!,:#஺ᔠᡂ$,◤<ᑴpH=5.5,>?@ᳮᵫ஺

3(5)FGᐭIJK⏣ḄMḄ#o(6)Pᵞ6⏚ḄᢗᧇST20.0g,Yᑮ'[23.2g,ᑣ^[Ḅ^᳛T%(aᶇ0cdeᦪ)gஹij⚪(kᜧ⚪ᐳ4e⚪ᐳ52.0ᑖ)9.p(Mo)rsᵨtuஹvwஹᓄxஹᵯz{ᵯ|ᢈ~ஹ{⚞஺ᓄ9ᐶeᑭᵨᓄᑺ(⌕ᡂᑖTM0S2,SC112S,Fes?)ᦈMoᑴᜓ⏚ᨔᐸ⌕¢,᝞¤1ᡠ¥¦应in催0z化ᒹᓛ9©
剂cªᢗ-.N/MM).-211.0ᵨᎷMM[W14IAQ-M.X),(1)0zᯏ¬Ḅ$,ᵨ᝞¤2ᡠ¥Ḅ“¯°⌮¢ᯏ¬”ᐸᯏ¬Ḅ³´#(µjc´)஺(2)z1⌕ᡂᑖT,x¶ᵨᔾᦈ஺()1To(3)¸ᔠ¤3,ᑨº»1Ḅᡂᑖ⌕ᨵ,CuOஹFeO»23(4)⏚#cÀÁÂJᜐᳮᑺÄÅ{ÆÇÈÉÊᑣËÌ⏚pÍḄ|!,:»(5)ÎÏ"ᑴᜓPᑭᵨeஹCO{A1ᑖÑÎÏSḄMOO3,ᡠÒὑÎÏᑺḄᱥÕḄSÖ×T«(6)ÙÚNazMoCUß
c(MoOv)=0.48mol-L_1,c(COg)=0.040mol•r௃஺ê⏚ß
ᑴᜓ⏚ᨔë◤GᐭBa(OH)2»Å◀ïC0ðñBaMo04òóÉÊëCOôḄï◀᳛T95.0%,ᑣKspBaMoOJ=஺(ÙÚKsp(BaCC)3)=1.0xù4⚓ᐳ22⚓

410-1°,$,ß
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)(7)⏚Ḅᓄឋᨵᵨᑺ᝞ᙠ⏚ᵨᑺ!⏚"#ᨬ%&ᡂ(⁐*ᱥM0CI3,ᑏ34"#Ḅ56789஺10.=ᓫ?@ᐸᓄᔠᱥᙠ&C&Dᵨ⌶FG஺HIJKL⚪(1)NOPJDᓄᑖ6RᑮDᓄ(0*),DᓄPJUVᓄSO2,Z[\◀^_஺ᐸDᓄ`8Ḅabᓄ᝞c1ᡠeᑣ&ᡂDᓄḄ^H0(j“>”“”ᡈ“=”),Dᓄ`8ᨵpqḄDᓄrsteV஺(2)wxKᑡzᓄ{7891.2CO(g)+6H2(g)=CH30cH3(g)+3HO(g)H=-122.6kJ-mol-122n.CH30cH3(g)+HO(g)=2cH30H(g)H=+23.4kJ-mol-12ᑣCO2®"#ᔠᡂCH30H(g)Ḅzᓄ{789஺ImolCOz!3m01%ᐙᐭ0.5LឤᘤᙠᓄᑺᵨK&"#q¡ᑁCO2Ḅ£ᓄ᳛¥¦§bᓄ¨©᝞c2ᡠeজT3q30min"#ᑮa¯Ḅ°ᙳV᳛v(Hz)=஺ঝ¥¦§ḄᓣµCO2Ḅ£ᓄ᳛ᐜ·ᜧ%¹ᳮᵫ¼(ὃ⇋ᓄᑺ¿"#ḄÀÁ)஺ঞwxc¯qᘤᑁḄÃP,ᙠTs¦§K4"#Ḅ°⊝Çᦪ஺(ᵨÉPḄᐵË9⊤e஺ÍJ°⊝ᑖÃ⊤eḄ°⊝Çᦪΰ⊝ᑖÃ=ÏÃXÑÒᑖᦪ)஺

5(3)ÓÔ᣸Ö×ØᨵḄÙᐗᓄØÛPJ\◀COஹNOÝḄÞßàÖ&ᡂᱥ§¥¦§ḄbᓄᐵË᝞c3ᡠe஺330áJKḄs¦â&Ḅã⌕"#Ḅᓄ{789¼஺(4)ᡃæ¿“Pçᔾ”Ḅé/ëᓄ=ᵯíḄẆïðRñẚឋóô஺4ᵯíḄÏ"#õᵯ9IN஺+3C()2—=+Cᐸöᳮ᝞c4ᡠe(õᵯqC&ḄᐙᵯNa2c஺3÷Ñøùú=ûü×)஺জõᵯqý᩽ᵯ᩽"#9஺ঝᐙᵯq=ûü×ÿ
ᵯḄ᩽஺11.┞ᐸ⌕ᓄᔠᱥᵨᙠᢈ⚞!"#஺(l)LiCoO,LiFeP04$ᵨ%┞&'ᵯ(Ḅ)᩽ᩞᧇ஺,᝱C03+᪶᜜M0ᵯ'᣸2324;,᝱67'#8ᵯ'ᓰ:Ḅᨬ<=0>?4:,᝱A7'᪶᜜=Bᨬ<Ḅᵯ'CᙠDEᨵGHIJᔣ஺(2)LiFeP04LMᓫA⏚P8Q
RḄSA⏚PᑣUVWXᩖA⏚P8᝞[ᯖA⏚]ஹ_A⏚]`஺ᯖA⏚᪷&'ஹ_A⏚᪷&'᝞bᡠd8efA⏚᪷&'Ḅᓄg3hᵨi3⊤d4(ᵨnl⊤P7'ᦪ)஺OA7'Oo7'ᯖA⏚᪷&'(3)p2஺U&'ᨔr8sᵨ%tᴻḄvᑖ8ᐸᨔx=hiy᝞bᡠdḄBom-Haberz{|}~ᑮ஺h8Li7'ḄVᵯ&=4kJ-mor1,0=0=4kJ-mol-1,ᨔx=4kJ-mol-1o6⚓8ᐳ22⚓

6-2908kJ-mol12Li*(g)+02-(g)------------------------------►LiOᨔr2▲A/1040kJ,mol-1703kJ,mol-12Li(g)0(g)▲▲318kJ-mol-»249kJ-mol'11V598kJ,mol_,2Li(ᨔr)+y0,(g)---------------------------------------4
LiAlH4Uᨵᔠᡂ#$ᵨḄ7ᑺ8LiAI*#Ḅ▢&'DE᪀U஺LiAIH,#ᙠ?஺A.B.&'C஺D.nE.5
ᓄ┞hᵨ%ᑺஹᑺ`஺LiCl-3H2஺)ᨔJr஺ᨔ¡ᦪ40.72nmஹl.Onmஹ0.56nm,¢ᨔ¡ᦪ4ᓫ£¤¥¦Ḅᙶ᪗h¢⊤dᨔ#ᔜ7'Ḅ£ª8«47'ᑖᦪᙶ᪗஺᝞bᡠd4¬zᢗ¯Ḅᨔ#ᡠᨵC1VḄᑖ2b°7'ᑖᦪᙶ᪗஺:±²³´ᨔ#Ḅᦪµ4஺LiClTMOḄ᥅·¸B4Mg-mo¹i,ºNA4»¼½¾¿$ᦪḄÀ8ᑣLiQ•3Á0ᨔrḄ¤4_____g-cm-3ᑡÄ|}⊤Å38ÆÇᓄM஺

70.72nm(0,0.78,0.75)(1.0,0.78,0.75)u(0.5,0.72,0.25)(0.5,0.28,0.75)XJ,0.22,0.25)(1.0,0.22,0.25)x---------------------------12.ỚlᓄᔠᱥEÊᓄᔠᱥHᙠCr-NiËᓄÌh¢ÍᏔὶÐ8ᔠᡂVWSÑ=ÒḄᓄᔠᱥM,ᐸᔠᡂÓÔ᝞bᡠd:1,05?°rr'h'1OÕᓄᑺ<>--------"QHsbyO'Ø0l)ÙWH0LCHUÚ»n7ÛQ,jÞHINaOHfHQ-CH=C-C—HßVCHO+H-C—C—H|I+H02II"H0H0ÞàÌᑡá⚪[(1)A#Ñ=ÒãäU஺B4ᓫlå8A-BḄÐf4஺(2)ᵫBᡂCḄᓄgJç34஺(3)DḄè᪀M34oXÊDé4êᑖë᪀r8ìᐹᨵîᐰðêÑ=Ò஺XḄ᪶ñᐳòóôd_WÆêᓄg{᛻Ḅ8ᐸö☢øùú43[3[2஺>ᔠûüᩩþḄXᨵW஺(4)FḄãä4,ᑖ'#ᐳÿ☢Ḅᨬᨵ஺GḄᑖ(5)ᨵ4Ḅᡈឋ஺M᪗Ḅ(᝞8⚓ᐳ22⚓

8#ᡠ%&'ឋ஺Cfhoif”::*+,ᱥ1./+,ᱥ20C-CH£0CHO+,ᱥ2Ḅ1᪀34+,ᱥ25607ঞ◤⌕Ḅᐸ<=ᑺᨵ?ஹ

9AᫀCD᪆1.ூAᫀ௃AூD᪆௃DIA.JᔠL'ᔠLᩞᧇᵫPQᡈPQRḄLSTᑗVᔠC1ᔠᡠ᪀ᡂḄᱥXᔠLSYLSᩞᧇᦑA[\4B.]^_`'ᐗbcᡂḄdQᓫX'fghLSᩞᧇi⏒kↈm'ᨵgnᑖᔠᡂᩞᧇ'LSᩞᧇᦑB┯p4C.qᓄs'dQtuvᩞᧇ'LSᩞᧇᦑC┯p4D.wᴻ_`'ᵫᰚzwᴻ{|}~ᡂḄ'LSᩞᧇᦑD┯p4ᦑ⌱IAoLSᩞᧇ'ᢣᐹᨵᐝஹឋஹ᧕uᵯஹឋXḄᩞᧇ4A.JᔠL'ᔠLᩞᧇSYLSᩞᧇ4B.]^_`'ᐗbcᡂḄdQᓫXi⏒kↈm'ᨵgnᑖᔠᡂᩞᧇ4C.ấᓄs'dQtuvᩞᧇ4D.wᴻ_`'ᵫᰚzwᴻ{|}~ᡂḄ஺⚪ὃᱥXḄᑖ⌕ὃLSᩞᧇD⚪Ḅᐵ'DLSᩞᧇḄ஺2.ூAᫀ௃DூD᪆௃DIA.2-ᵬ¡¢£ᨵ,52-ᵬ¡¢¤¥¦¢ᦑA┯p4B.CgHio£ᨵ§¨Ḅᑖ¥᪀v©ª£ᨵ1«¬®-CH2cH3ᨵ1Q1᪀4©ª£ᨵ2«¬®2-CH3,Pᵬ©ª¯Y°¯ஹ+¯ஹ±¯ᡠR²ᔠᩩ´Ḅᑖ¥᪀vᨵ4QᦑB┯p4C.µ¶C·µ¶£ᨵ¸ª¹⏚ឋn═⏚¼½¾¿⁐iµ¶£¸,ᡠRiµ¶ª¹⏚ឋn═⏚¼½¾¿⁐ᦑC┯p4D.Â⏚C⏣ᙠdᩩ´Åª56Æᓄ07-COOHஹ-0HǪCNa07ᡠRµ⏚Cµ⏣©R56Æᓄ07ÈÉὅǪCNa076ᡂËÌᦑD[\4ᦑ⌱IDoA.2-ᵬ¡¢£ᨵ54B.CgHio£ᨵ§¨Ḅᑖ¥᪀v©ª£ᨵ1«¬©ª£ᨵ2«¬410⚓ᐳ22⚓

10C.iµ¶£¸4D.Â⏚C⏥ᙠdᩩ´Åª56Æᓄ07-COOH,-0HǪCNa07஺⚪ὃᨵgᱥḄ1᪀CឋXÎÏὃẠÑÒḄÓÔCᮣÖ7ᵨªØÙ\Úª.ᐸឋXᐵÛஹᑖ¥᪀vQᑨÝÞß'D⚪ᐵàáCiµ¶£¸DA᧕┯â஺3.ூAᫀ௃CூD᪆௃DIA.⛳C·ᓄä½¾åᐭçèéᑮë⋎⁐íᑮËîᓄäïv'ë⋎⁐ðñᦑA┯p4B.KSCN½¾åᐭ·ᓄòä½¾fóôᦑB┯p4C.Ëîᓄõ½¾åᐭ=öC÷56076ᡂø÷⏚õCËÌ,6ᜧúÌûᦑC[\4D.üèåᐭ·ᓄ÷½¾6ᡂËîᓄ÷ý⁐ðñþÿ
ᦑD┯ᦑ⌱C„A.ᓄB.ᓄKSCNC.ᓄ!"ᡂ$⏚!&D.ᓄ'ឋᓄᱥ*+,⏚,-+.⏚.-஺0⚪ὃ34ᑴᜓஹ89:;ஹ89ឋ<=>?@AB89ឋ<:;⚪ᐵD⚪EFGᜧ஺4.ூJᫀ௃Dூ᪆௃A.1molNᑖ"ᡂHP9ᔾᦈ436kJḄ*TᑣHP9Vᡂ1molWXN436kJḄ*TᦑA┯B.YZᓄ[Dᔾᦈ*TᑣBoᑖ9Ḅᓄ[ឋ<\BrP9Ḅ]^ᦑB┯C.H2ஹBr2ஹHBrᙳ`&᝱,ᑣᵫdef,&(g)+Br(g)=2HBr(g)AH=-103kJ•moL,2ᦑC┯D.HBrḄD*g>hiᵫᰚk=+YZᓄ[DᔾᦈḄ*TlmᡂDnXḄ*TopqrsḄ*TkᓄᦑDtu

11ᦑ⌱D஺A.Vᡂᓄ[DXN*TB.*Tz{z]^C.᪷~NஹBr,HBrᙳ`&᝱ᑏᑨY2C.ᯚk=+YZᓄ[DᔾᦈḄ*TlmᡂDnXḄ*TᔠHBrḄD*g>ᑨY0⚪ὃ3ᯚk`⚣ὃ@B*Tkᓄஹᯚkopஹᓄ[s`JḄᐵDᑖ᪆ᵨ*Ḅὃ3⚪EFGᜧ஺5.ூJᫀ௃Dூ᪆௃ᔠᑖ᪆e>A`H,W`C,X`0,`Na,Z`SᐗA.ᵯ9z¡89¢£zᜧᵯ9᪀¥¦§᪶ᵯ₹ᦪzᜧ89¢£z«ᑣ¬ᓫ89¢£Z>W>X>Y>A,ᦑA┯B.WḄᓄᱥ`°±P9ᦪ²¡Ḅ³´µ¶`·᝱ᐸ¹@ᜧ+ºᦑB┯C.YAZX4`NaHSC¼4+89ᓄᔠᱥᦑC┯D.½ឋS>C,ᑣᨬ¿À⏚Ḅ⏚ឋZ>W,ᦑDtuᦑ⌱DoAஹWஹXஹYஹZP9ÂᦪÃÄÅ
ḄÆᕜÈÉÊᐗWËᙠ5P9᪶10ᵯ9Ḅᓄᱥᑖ9ᑣW`CᐗXḄᨬ᜜ᵯ9ᦪᵯ9ᦪḄ3ÐᑣX`0ᨬ᜜ᵯ9ᦪÑÒ2Y=X-W,Ḅᨬ᜜ᵯ9ᦪ`3=1,ᐸP9Âᦪᜧ+0,ᑣ`Na´µ¶0.01mol×TYAZX4ḄpH`2,YAZX”`NaHSO*ÝijA`H,Z`Sᐗàáᑖ᪆J஺0⚪ὃ3P9᪀ᐗᕜÈâḄᵨ⚪EFGᜧãYᐗ`JᐵDäåABᐗᕜÈâᑁçè´éᐗᓄᔠᱥឋ<ê⚪ὃ3["Ḅᑖ᪆*èëìãᳮ*஺6.ூJᫀ௃Bூ᪆௃A.rsজð"Ḅñ$+ô11ô12=ô1$1+2õ1öᑖᵫ÷ᓄ1"ᡂᓄᵫ.⏚"ᡂ,⏚ᦑAtuB.rsঝð"Ḅ89s`CuS+2Fe3+=S+2Fe2++Cu2+,CuSF+ü12⚓ᐳ22⚓

12*ÿ
ᦑB┯C.ঞ᪗11.2LO2ḄᱥḄ0.5mol,$ᐗ&ᓄᔠ)ᵫ+),-./)ᑣlmolC122345674moiᵯᑣO.SmolO22345672moiᵯᦑC<=D.ᙠঝAᐗ&ᓄᔠ),-BCDE45ᦑFe3+J$ᓄᑺᙠঞAᐗ&ᓄᔠ)ᓣMBC$ᓄ45ᦑFe3+N$ᓄOᱥᦑD<=ᦑ⌱QBoA.জBCḄ45H2s+CuCl=CuS1+2HC12B.ঝBC45Ḅ
YQCuS+2Fe3+=S+2Fe2++Cu2+C.ঞ᪗11.2LO2ḄᱥḄ0.5mol,2345672molD.ᙠঝAᐗ&ᓄᔠ),-BCDE45ᙠঞAᐗ&ᓄᔠ)ᓣMBC$ᓄ45஺[⚪]^H2s6ᓄSJ_`ὃbc$ᓄDEḄᵯ67]d$ᓄᑺDEᑺḄᑨfஹH2shFeChḄឋ]d45klmnopqcrCsḄtr᝱vhwxyzḄᓄr᪶|&q[⚪}ᨵḄv⌱ᩞ஺7.ூᫀ௃Cூ᪆௃Qᵫ⚪ᑭᵨCᱥ^ᨵᱥ⌕ᡂᑖNCGHIOOS%Ḅᓄr6ᓄᵯḄᓽEᵯ¢ᵫ£N᩽¦NO,M᩽ᨵᱥᑣN᩽<᩽BCDE45,M᩽.᩽,BC$ᓄ45.᩽Ḅᵯ᩽45CGHIOOS%+7nH2஺-24ne-=6nC0T+24nH+,Eᵯ¢□
7ᔣ<᩽2A.®□
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7ᔣ<᩽஺[⚪ὃbEᵯ¢Ô[EᳮÖ×ὃbrCØÙÚÛஹᑖ᪆ÜfÝ᪷ßᓄᔠ)àᓄ=<.᩽áNᵯ᩽45ḄâᑏäEᵯ¢hᵯ¢EᳮNMὃM⚣á⌕æçèé஺8.ூᫀ௃ë⚠íîï3ð¦ᐭÊË3ᐭòᢙô⊈⏚CDFeCl•4H0+222HNCHCOOH+2NaOH=(HNCHCOO)Fe+2NaCl+6HOpH-úO᳛,Ḅ222222EüNH+x¶H2NCH2coOHḄþÔ45QpHMxCOÿ
ᵞ⏚ᙠḄᐸᨔ᪆◀ᩖ᳛85.3ூ᪆௃&(1)᪷+,-ᔠᡂ012ᘤb56⚠89ᦑ;ᫀ5&6⚠89(2)>?nABḄC550EFGHIABḄJKᵞ⏚⛳MNOᐭQRRSOTNUVᤅXNḄYᵨᤅXF[A\ᓄ^_`a᳛bc◀NḄdRAᐭeᢙg⊈⏚eᢙg⊈⏚ijk⏚ឋMmnoឋpU■rstudRdᓄᦑ;ᫀ5&IABOᐭQRAᐭeᢙg⊈⏚(3)A.01ᵨḄwឤyzN{ᧅzᐭN}~◤ᡭzN{ᧅaḄᴻᦑA┯B.FeS07H2஺᧕jj⏣ᙠAᐭ⏣᪆ᵞ⏚cᐭᩖFeC12-4H2஺᧕j⏣ᐭᩖ¡`⌱ᵨFeC12-4H2஺ᦑB┯&C.Aᐭ⏣᪆ᵞ⏚>?m5ᑖsN}M¥}Ḅ¦YᑖsJKwT§ᦑC¨©D.>?IVᵨ®¯°◀⏣,²ᑮ´µḄᵞ⏚ᵞ⏚¶᧕udᓄ·¸T¹ᨬ»⌱ᵨ¼½·¸ᦑD¨©ᦑ;ᫀ5&CD(4)ᔠᡂᔠᡂᵞ⏚Ḅ_`ᱥwH2NCH2COOHஹÂdᓄÃMFeC12-4H2஺ᓄ^J¹Ä5FeCk-4H2஺+2HNCHCOOH+2NaOH=(HNCHCOO)Fe+2NaCl+6H0,pH222222TH+ÌH2NCH2coOHḄÏ_`᳛Ð
pHTÑᡂÂdᓄÒᔠᡂT¹◤ÓᑴpH=5.5,ᦑ;ᫀ5&FeCl-4H0+2HNCHCOOH+2NaOH=(HNCHCOO)Fe+2NaCl+2222222Õ14⚓ᐳ22⚓

146H0&pHT᳛Ð
ḄowH+ÌH2NCH2coOHḄÏ_`&pHTÑ2Ò(5)ᵞ⏚᧕jj⏣>?inAᐭ⏣
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ᵞ⏚ᙠḄᐸᨔ᪆◀ᩖ᳛;(6)ᵞ⏚ḄᢗᧇÜ520g,ᵞ⏚ḄᱥḄÜᔁmol,Ñᡂn[(NHCHCOO)Fe]=ᔁmol,ᳮâḄÜ5ᔁmolx204g/mol=27.2g,᳛5222åḄæ▭Üx100%=x100%«85.3%,åḄèâÜ27.2gᦑ;ᫀ5&85.3oᙠᵞ⏚⛳MNAᐭ¡ᵫj¡᧕udᓄᡠ[Aᐭeᢙg⊈⏚OᐭQRíîstᯠðAᐭÂdᓄÃNñ⁚pHóIABôᡂᵞ⏚õᔠᱥö(HNCHCOO)Fe÷,øAᐭ⏣᪆ᵞ⏚õᔠᱥö(HzNCHzCOO"Fe÷Ḅûå222øAᐭüý>´²ᑮᵞ⏚õᔠᱥö(HzNCHzCOO^Fe÷(1)᪷+2ᘤbḄᱯ
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ᔠᔠᡂᑖ᪆(6)᪷,qrឤ
ᔠs᳛=vwxx100%{|஺}⚪ὃkḄ/ஹ⊤ᙠ/ஹ⊤ᑮᨵᵨᑭᵨᨵᐵ⚪஺⌕ὃᨵḄᘤஹஹk⌕ᗐH᦮ᔠ⊤ᦪ,¤¥¦§¨gẠᮣ«¬ᵨ⚪J®¯ᜧ஺9.ூᫀ௃¶ᜧ·¸☢ºjhi᳛xᓄ»]Iᡈὅ¾ᮞÀMO0MoOi-+Cu2+=CUMOOI3322.4x10-82MoOg+3Zn+16H++346Cr=2MOC1+3Zn2++8HO32

15ூ᪆௃(1)ËᯏÍḄÎᵨ᝞/2ᡠÑḄ“ÓÔ⌮ÖᯏÍ”ᐸᯏÍḄÙ2¶ᜧ·¸☢ºjhi᳛ᦑᫀV¶ᜧ·¸☢ºjhi᳛(2)W1⌕ᡂᑖVxᓄ»ÛÜÝᵨ]Iᡈὅ¾ᮞÀᔾᦈYZ1VᦑᫀVxᓄ»]Iᡈὅ¾ᮞÀ(3)ᑖ᪆ÖàᯏÍáâᑮMOO3ஹCuOFe2()3XWãᔠᱥᦑᫀVMOO3(4)åæ⏚çàèéêëìmnᑣd»⏚îhiïâᑮî⏚îmnᑣðñVMoO|-+Cu2+=CUMOOJ-,4ᦑᫀVMoOf+Cu2+=CUMO0i4(5)qòᑴᜓæõᑭᵨHzஹCOAlᑖöq÷ḄMOO3,ᢥâᜫᵯᦪrឤ3ûᓄqhiüýḄᵯþᦪÿ
lmolH2ஹCOA1ᜫḄᵯᦪ223,ᑣὑᑺḄᱥḄ332,ᦑᫀ332(6)Ksp(BaCO3)=1.0x1஺௃஺
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ᐳ22⚓

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⚪°<'.10.ூᫀ௃³0.18CO(g)+3H(g)CHOH(g)+HO(g)AH=-49.6kJ/2232mol0.12mol/(L-min)b´µ
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30min"#Ùᑮ·a´
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CO(g)+3H2(g)uCH30H(g)+HO(g)22()(mol)1300cᓄ(mol)0.51.50.5O.S¸⊝(mol)0.51.50.50.5

17¸⊝,ᔜᱥḄᱥḄ0.5mol+1.5mol+0.5mol4-0.5mol=3mol,K=pO.Sc0.5_p(CH3OH)p(H2஺)_ûXPX^XP_&p(CO)p3(H)—XPXýXP)3_3P222ᦑᫀញ(3)ᵫ¥P330ÿ
ḄC02ஹ"0ᓽ⌕ᡂᱥᦑḄ⌕Ḅᓄ!C0+2NO^Z1Q+NO,C22+“—,.ᓄᑺᦑ0ᫀ2CO+2NO^O1-N02C22ᵯ(4)জᵫLV”+3cs?@+2NaCO4-CABCᵯEᵯFNaH᩽ᜫKᵯ3ᐙᵯLCᵯMN᩽OEᡂC,23co2+4Na++4e-=2Na2cO3+C,ᦑ0ᫀ23co2+4Na++4e-=2Na2cO3+CSঝᐙᵯᵯVFᵯVFW2Na2c()3+C=4Na+3c஺2,CᜫKᵯLᡂCO2ᓽYZ[\□᩽^᜜`ᵯaN᩽bcᦑ0ᫀ2N஺(1)dᱥḄWeᜧgᡂᱥḄWeᑣCijbSᵫkABlmMḄnᓄe0.75eV,ᨵmMḄnᓄe0.57eVS(2)᪷tuvwx21x(I+n)|}23+3H2(g)=CHOH(g)+HO(g)S32জT3M30minᑮaCO2Ḅᓄ᳛60%ᑣ4n(C0)=lmolx0.6=0.6moL2ᑣ4n(H)=0.6molx3=1.8mol,ᔠv=ᔁS2ঝbᑮ⊝᝱ᓣ᳛`bᑮ⊝᝱ᓣ⊝⌮ᔣ¡¢Sঞ¤BcM¥ᘤᑁḄ¨©P,@«ᓄYḄᓄ᳛50%,ᑡᓄ⊝?CO(g)+3H2(g)UCH30H(g)+HO(g)222¯°(mol)1300±ᓄ(mol)0.51.50.50.5⊝(mol)0.51.50.50.5⊝Mᔜᱥ³Ḅᱥ³Ḅ0.5mol4-1.5mol+0.5mol4-0.5mol=3mol,K=pp(CHOH)p(HO)32p(CO)p3(H):22(3)᪷tᡂᱥ¶·Ḅ±ᓄᐵ¹kAB330K
ḄḄ⌕ºᱥt»¼ᑏḄᓄSᵯ(4)ᵫ1.¥஺+S᜛஺஺2-T+CABCᵯEᵯFNaH᩽ᜫKᵯLᐙᵯÀ18⚓ᐳ22⚓

18N᩽ÃC|ᑮᵯLSᐙᵯᵯVF□᩽^N᩽bc□᩽ᜫKᵯL«ᓄ஺Ä⚪ὃÇiḄஹᓄ⊝ḄÈÉÊËஹᓄ⊝ḄÌÍÎὃÇᑖ᪆eÑஹÒkeÑÓeÑ᪷t⚪ÔÕÖᔠuvwxஹ×ØᱯᑡEᳮஹᓄ⊝?ÌBÒV0»⚪Ûᜧ஺11.ூ0ᫀ௃3s23P63d6N3(Pn()3n-i)(n+2)-5204982908Nà☢âBC4ä஺à஺å௃஺äæூV᪆௃V2(l)Co27çᐗËé᝱C03+Ḅ᪶᜜ᵯL᣸ìIs22s22P63s23P63d6,ᐸMïᵯL᣸ì3s23P63d6SFe!26çᐗËé᝱ñEL᪶᜜ᵯL᣸ìIs22s22P63s23P63d64s2,ᵯLᓰtḄᨬeïÀàeïeïôçNP!15çᐗË3PeõᵯLöeᨬᵯLöᙠ?øùúûḼxஹvஹzþ3ÿᔣᦑᫀ3s23P63d6N3(2)ᵫ2Pᐳᨵ10ᑣ⏚᪷ᨵnP&'nPC),*+,-6-1)0ᓽ஺ᦪ24n-(n-l)=3n+l,7ᡂ1ᩩP-0:Ḅ஺<᜜>?1ᵯᓽAᵯ₹ᦪCDE᪀G7ᡂ1ᩩP-O:Ḅ0ᦪ2ᦑAI(n+2)ᓫKLᵯ₹ᦑMNO⏚᪷AḄᓄQRᵨTR⊤V(PnO3n-l)(n+2)-,ᦑᫀ(PnO3n-l)(n+2)-;(3)LiḄYZᵯA[Li(g)ᜫ^1ᵯ7ᡂLi+(g)ᡠ◤⌕Ḅ[bᦑLiḄYZᵯA[1040kJ/mol+2=520kJ/mol0=஺::[iᢣklImolO=0:nᡂ0(g)ᡠ◤[bᦑ0=0:Ḅᨔp2X249kJ/mol=498kJ/molt0ᨔu[iLi+(g)'()2-(g)7ᡂImolLizOᨔwxyḄ[bᦑLi?஺ᨔu[2908kJ•mor1,ᦑᫀ5204982908(4)[A1H4GA1ᵯᦪ='ᙳ=0,ᵯᦪ=4+0=4,VSEPR☢wᨵᵯ᪀☢wNa+ஹ[Al*]-GA7ᡂA:[GA1'H7ᡂTᐳ:ஹK:ᙳDa:ᨵ:ஹn:ஹ:ᦑᫀ☢wBC(5)ᦪx=0ஹx=1ḄᜐDyz☢yz☢ᨵ4wᑁᨵ2ᦑᨔpGC1ᦪ24x+2=4,ᨔp¤b⊤Vᨔpw¥=1.0x10-7cmx0.75x10-7cmx0.56x10-7cm,ᨔw©ª=

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