organic chemistry（牛津大学有机化学教材） (1)

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1、01Whatisorganicchemistry?02.Organicstructures03.Determiningorganicstructures04.Structureofmolecules05.Organicreactions06.Nucleophilicadditiontothecarbonylgroup07.Delocalizationandconjugation08.Acidity,basicity,andpKa09.UsingorganometallicreagentstomakeC–Cbonds10.Conjugateaddition11.Proton

2、nuclearmagneticresonance12.Nucleophilicsubstitutionatthecarbonyl(C=O)group13.Equilibria,rates,andmechanisms:summaryofmechanisticprinciples14.NucleophilicsubstitutionatC=Owithlossofcarbonyloxygen15.Reviewofspectroscopicmethods16.Stereochemistry17.Nucleophilicsubstitutionatsaturatedcarbon18

3、.Conformationalanalysis19.Eliminationreactions20.Electrophilicadditiontoalkenes21.Formationandreactionsofenolsandenolates22.Electrophilicaromaticsubstitution23.Electrophilicalkenes24.Chemoselectivity:selectivereactionsandprotection25.Synthesisinaction26.Alkylationofenolates27.Reactionsofe

4、nolateswithaldehydesandketones:thealdolreaction28.Acylationatcarbon29.Conjugateadditionofenolates30.Retrosyntheticanalysis31.Controllingthegeometryofdoublebonds32.Determinationofstereochemistrybyspectroscopicmethods33.Stereoselectivereactionsofcycliccompounds34.DiastereoselectivityPericyc

5、licreactions1:cycloadditions35.Pericyclicreactions2:Sigmatropicandelectrocyclicreactions36.Rearrangements37.Fragmentation38.Radicalreactions39.Synthesisandreactionsofcarbenes40.DeterminingreactionmechanismsSaturatedheterocyclesandstereoelectronics41.Aromaticheterocycles1:structuresandreac

6、tions42.Aromaticheterocycles2:synthesisAsymmetricsynthesis43.Organo-main-groupchemistry1:sulfur44.Organo-main-groupchemistry2:boron,silicontin45.Organometallicchemistry46.Thechemistryoflife47.Mechanismsinbiologicalchemistry48.Naturalproducts49.Polymerization50.Organicchemistrytoday51.Inde

7、xWhatisorganicchemistry?1OrganicchemistryandyouYouarealreadyahighlyskilledorganicchemist.Asyoureadthesewords,youreyesareusinganorganiccompound(retinal)toconvertvisiblelightintonerveimpulses.Whenyoupickedupthisbook,yourmusclesweredoingchemicalreactionsonsugarstogivey