某中学2022-2023学年化学高三第一学期期中考试模拟试题（含解析）

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2022-2023
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C64|CH3,¥÷Ḅ¥¦§º»f«¬ᑣᨵøஹ¹ஹ53©,ᑖù᪀^¥÷Ḅ¥¦§º»úfrᵬ¬üᨵ6©ýᐳ9©:ᐹᨵÿ᪶ᐳḄ᪀ᨵ4ᑣᔠ⌕Ḅᑖ᪀ᨵ:9HOH9HOHH1C-O-CH.''ᫀ.IhC-O-CH-.H,C-Q-CH*,Î5
ᔠ⚪#$%&'(CH3—CH=CH2)CfhMgBr*ᧇᔠᡂH
-C—OHḄᔠᡂ-./*0CCH1Clb-ClI-CILClI>-ClI-C!IClI.RICllCCII^-Clbூ2ᫀ34௃6⚪ὃ8ᨵ9ᱥ;<=>ᓴ@AஹCஹ⏣EḄឋG(>ᑖHḄIஹᑖ᪀ஹᨵ9ᓄKLMNO)PQHḄRᑏE⚪#TᔠឋUᜧWX⌮ᔣ;[Ḅ\]^_`abE஺25ஹᔾᦈ⍎gᨵhḄCLஹSO2,■jklbḄmnloᐭLMqr■jSOChmIMnO2+4H++2ClMn2++Chf+2HOAICN6H2OsSOCLtᔠuvSOCbsAlCb6H2஺bḄᨔmxᵨzᡂ{mAlCb>SCh)2HC1lHC1ᢓᑴA1CLmI~⛳)mஹ⏚n50.0%WbuᐭBaNh2☟ruHNO3⏚ᓄuᐭAgNChz⁐ᑣbᨵcr

19ூ2ᫀI᪆௃(1)qrfḄxᵨᔾᦈ⍎gᨵhḄC12ஹSO2,■jklbḄmnloᐭLMqr■jSOC12mI(2)ᵨ¡¢ᓄ═s⏚ᐳvLMzᡂ¤ᓄ┤ஹ¤l)mLMḄ¦PQH*MnO2+4H++2C§uMn2++Chf+2HO;2(3)AlCb᧕mIAICN6H2OsSOCLtᔠuvSOCLsAlCb
6H2()bḄᨔmxᵨzᡂ{mAlCb>SO2)HC1lSOC12ᔾmᱥSO2)HC1mᕈ⏚ឋᢓᑴmIªz(4)ᵬbuv¬⏚®¯z¡¢ᓄ°±¯zᡂU²Ḅmn³ᦑᵬµ⌱·b18.4mol/LḄ⏚suvLM¸ᯠºᑴ¡¢ᓄ°»xU¼ᩖ¾¿ὑ⏚ḄU²⏚Ḅᑭᵨ᳛Ãᦑ·µ⌱Äb{ÅÆ⏚ÇÈÆ⏚ÉᐹᨵËÌḄ¢ᓄឋÍ(Î᧕ḄϬ⏚bḄÐ4ÑḄ¢ᓄ*Ð6ÑḄ⏚᪷¦Ó{ÔÕᑮ¡¢ᓄᦑĵ⌱~bLMzᡂ⏚×s¡¢ᓄÇᨵm~ᑴ¡¢ᓄØUᔠᳮᦑ2ᫀ*~(5)qrebzḄCbÚdÛoᐭÜ⚠Þßdàá¤l¾◀ãHCLᑣdbᡠᵨḄᑺᑖæ*⛳)mஹ⏚(6)$%¤ᓄ¬çè3*77࠷,$%SCLḄè3*50C,ᡠ(éᵨᑖ✂ḄPÔᓽÍÏìᑖ¦¿ὑ¤l*]=0.04mol,ᵫSO2+C12+SC12=2SOCLzᡂ().()8molSOC12ᑣSOCLḄ᳛*.Ôয=஻9Ḅ1஺Î஺()%=50%;(7)ᔣõÕḄSOCLbuᐭöNaOH₩ஹ☟jÕᑮ{⁐w,ø¬⏚᪷¦)¤¦ùwbúᙠḄCtḄPÔ{⁐üᐭbuᐭBa(NO3)2ýµz*j☟r.guᐭAgNChᨵ⁐zᡂÍ%{⁐bøᨵCL26>2MnO+16HU10C1=2Mn2++5ChT+8HOþ⊝
ᑭF40%FeClᙠ422AB⛳Ḅ◀!ᨵḄHC1ூᑖ᪆௃ᵫ()*+A,-2MnO4-+16H++10Cr=2Mn2++5CLT+8H20,a./.01ᢝᑖ3ᧅᙊ678Ḅ
9:ᑭ஺B<=⏚?@C,-2Fe+3a2-2FeCb,ABCᓾCᦈFᑮFeCb,HIᱥ!ᨵFeCL,*ᑭᵨᐸMNឋᡈQK31Fe(CN)6]R-ᡂT⁐VWX)FY?@.FYZ[ᮞ*ᔾᦈ^_`Ḅa■cdeᐭC/gᓄijklᩭjn஺ூ⚪pqj௃(1)ᙠAᵨKMnOrQ<⏚_`ᑴt_`ḄuvwxyY2MnO4+16H++10Cl=2Mn2++5ChT+8HO,a./.01ᢝᑖ3ᧅᙊ678Ḅ
9:ᑭ2ᦑnᫀY|2MnO4"+16H++10C}=2Mn2++5C12T+8H20⊝
ᑭ(2)ᘤFḄ0?@.DḄ0Z[ᮞᐸᵨ0ᔾᦈ^_`Ḅa■cdeᐭC/gᓄij

20ᦑnᫀY|F3

tCḄIᱥᢥke|জt4.20gIRḄ⏚ঝᐭH2O2RঞᐭNaOHRটஹ7VWঠᡠ¡¢⁐£Y2.40g,*+¤ᓄiY2.40g,ᵫFeᐗ¦240஺§ឤ*+©᪵iᐗ¦Ḅ«ᑖᦪY,'160xl00%=40%,4.20gᦑnᫀY|40%4
জ¯⏚᧕ᢵ,^◀ḄHCLᵫFeCLFeḄ«ᑖᦪᜧFeCbFeḄ«ᑖᦪ*+ᵨ⚪pᡠ³ḄᑴḄIᱥiᐗ¦´µ¶´ᨵFeCLᩖ«ᦑnᫀY|;FeChঝH⌕ᑮº»¼Ḅ½ᓄi*¾tḄ“”ᦋeÂÃᙠAB⛳Ḅ◀!ᨵḄHCLᦑnᫀY|ᙠAB⛳Ḅ◀!ᨵḄHCLூnᫀÄÅ௃᪷Ç⚪Èᓄi᧕jᦑ◤?@M`■cdḄeᐭᑭᵨiᐗ¦§ឤjÊË⚪3
0ÌÄ஺27ஹCu+2H2so40=61504+502+21120¡RÍ⁐¡RÎឮÐNᩭḄ¡⁐DABCI-SO2ÑÒÓ᛻-I:=⏚ÕÖὑ=⏚Ø:Ùᑏᩩᔠᳮnᫀ2Cu+O2+2H2SO4=2CUSO+2HOᡈCu+H2O2+H2SO4=CuSO+4242HO2ூnᫀj᪆௃Þ⚪ᑖ᪆|1
CuQ

21Ö×=ÅᓄÖᨵØ=ÙÚÛ×;ᵨ`Ö⏚PÜÝÞஹÅ×^ßḄ&àᑴâãäḄÖ⏚Ý=!&'(G2Cu+O2+2HSO=2CUSO+2HO«2442ÑåCuæH2s04!ç=æÖ⏚⊤Q⏚ឋPÅᓄឋ஺éᐭÅ×ᡈêÅᓄëÅᓄᑺ;íYÖ⏚Ḅ·ὑï=ðíYÛ×ÙÚ஺28ஹ◀¸òPᨵóᱥNaAlOMNaAlOZPNaOHஹCa(OH)2ô;âᑖ)2Co3*+S(V-+H20=2Co2*+S0/+2H+2Fe2t+2Ht+H0=2Fe3t+2H0Fe(OH)(/Fe(0H)3PCaSO,CaCOs]õö}IᡈÍI÷øᑖ)95.55%2223ூᑖ᪆௃oùÜᧇû⌕ᡂᑖ)C02O3,oYïFezOsஹAI2O3ஹCaOஹMgO,òüᨵóᱥý=550'Cᯏÿ
◀ᨵᱥᐭᓄᐸᓄᡂ⏚Co0,FeGஹMgOᑣ!Ḅ#⌕ᡂᑖ&⏚23(ᡈNaAlOzNaOHஹCa(OH))ᔣ*ᑮḄ,-ᐭ./⏚0/⏚0/⏚1Co/ஹFK+23&2Co2\Fe2+,*C02+ஹFe2+>Mg2+>Ca2+ᙠ4050࠷ᐭH2O2,ᓄFe?+ᓄ&Fe%5ᓣ788085࠷,ᐭ⏚9pH85,*ᑮᓄ:;<=ᡠ*#⌕?ᨵCM+ஹMg2+ஹCa2+@AC0C2O4BCḄDE᪷G5COC0-5[(NH)2c2OJ-2KMnO4ᐵIJK!DḄC0C2O4ḄLMᓽO!᪵CḄDEG
Qᑖ᪆S஺244ூ⚪WX௃?Z[ᧇ#⌕ᡂᑖ&C02O3,?]MFez஺?ஹAI2O3ஹCaOஹMgO,_ᨵᱥ`550࠷ᯏb
◀ᨵᱥᐭᓄᐸᓄᡂ⏚Co0>FeO,MgOᑣ!Ḅ#⌕ᡂᑖ&2323⏚(ᡈNaAlOzNaOHஹCa(OH))ᔣ*ᑮḄ,-ᐭ./⏚0/⏚0/⏚1Co"ஹFe3+23&2Co"ஹFe2+,*C02+ஹFe2\Mg2+>Ca2+ᙠ4050tᐭH2O2,ᓄFe?+ᓄ&Fe%5ᓣ788085࠷,ᐭ⏚9pH85,*ᑮᓄ:;<=ᡠ*#⌕?ᨵC02+ஹMg2+ஹCa2+@AC0C2O4BCḄDE᪷G5;COC0-5[(NH)2c2OJ-2KMnO4ᐵIJK!DḄC0C2O4ḄLMᓽO!᪵CḄDE244(1)cᔠ
Qᑖ᪆e“550࠷ᯏb”
◀ᨵᱥgQᡠhi⚪Sᫀkl◀ᨵᱥ஺(2)cᔠ
Qᑖ᪆eᐭᓄ,ᓄᡂ⏚ᡠ
!Ḅ#⌕ᡂᑖ&⏚(ᡈNaAlOzNaOHஹCa(0H))gQᡠhi⚪SᫀklNaA10(NaA102Na0HஹCa(0H)2n*ᑖ)஺22(3)“Z!"sCo"tᓄ&Co",ᑣSOB1Co"23&Co஺uvwᓄ&SOBxyz{|s}&:2Co3t+S032+H0=2Co2++S02+2irgQᡠhi⚪Sᫀkl2Co3t+S02"+H0=2Co2t+SO?+2ir2432o(4)“ᓄ◀ᩖ1”s◤ᙠ4050࠷ᐭ஺20:z{ᓄ&:z{2Fe2t+2Ht+H0=2Fe3t+2H05ᓣ222788085C,ᐭNa2c9pH85,
*ᑮᓄ:;<ᡠ
“I”Ḅ#⌕ᡂᑖkFe(0H)3(Fe(0H)3CaSO”CaCOsᡈᙳ)gQᡠhi⚪Sᫀkl2Fe2++2H++H02=2Fe3++2H0Fe(0H)3(SFe(0H)322CaS(hCaC03ᡈᑖ)஺(5)1.00g᪵C1ᐸᵨ〉ᑺtᓄ&₝⏚[(▬)2C2OJ5ᵨM./⏚⏚ᓄᵨ0.1000mol/L═⏚AᑮAᐳᵨ═⏚26.00mL,᪷Gᵯ{*ᜫ¢ឤ
*!5coe2஺¤5[(◌)2C2OJ

22-2KMnO4ᐵ/ᡠ1m(CoC20D=5/2x26xl07xO.1x147=0.955g,ᦑ⏚2᪵4Ḅ6780.9555/lxl00%=95.55%9:ᡠ;<⚪>ᫀ@A95.55%஺29ஹ2KC1O+H2C2O4+2H2SO4=2C1O2+2CO2+2KHSO4+2HO5323NCI3+6CIO2+3H2O=6C1OT+3NHT+3CI+3OHCTBOHACD6Fe2++ClO+6H+=6Fe3++Cl+3HO12332342KFeO32HO242ூᑖ᪆௃(DGHIஹᙠ⏚KL⏚M₝⏚O+ᓄPQᡂ*+ᓄLஹ*+ᓄRஹ⏚SMBTGH*ஹᵫVWXYZNCbBNaClOzO+ᓄPQᡂCIO2ஹN%BX,ᵫGW[YZXK\ᨵḄᜧ^Ḅ▢`a8C1-BOH-(2)জcdefḄ+ᓄᱥKfḄᓄᔠijᵨḄlᑺ@n⏚ஹ+ᓄMஹ⏚ឋp═⏚Mঝ⏚ឋᩩtuᐹᨵ+ᓄឋḄC1O3-ᐹᨵPQឋḄFe2+O+ᓄPQᡂFe3\BHO2;ঞKNO3ஹKOHBFezChyᐳ{O+ᓄPQᡂpf⏚Mஹ|}⏚MBT஺ூ⚪~௃(1)GHIஹL⏚Mᐹᨵ+ᓄឋ₝⏚ᐹᨵPQឋᙠ⏚KL⏚M₝⏚O+ᓄPQᡂ*+ᓄLஹ*+ᓄRஹ⏚SMBTḄᓄGW[82KCIO3+H2c2O4+2H2so4=2C1O2+2CO2+2KHSO4+2H2O,ᵫGW[YZᡂ2moi*+ᓄL2moiᵯaᑣᡂ5moi*+ᓄL5moiᵯaᦑ>ᫀ8A2KCIO3+H2c2O4+2H2so4=2C1O2+2CO2+2KHSO4+2H2O5GH*ஹᵫVWXYZNCbBNaCKhO+ᓄPQᡂClChஹN%BX,Ḅ`aGW[3NCI3+6CIO2+3HO=6C1O2t+3NHt+3C1+3OH,ᵫGW[YZXK\ᨵḄᜧ^Ḅ▢`a8஺IBOH,23ᦑ>ᫀ8A3NC1J+6C1O+3HO=6C1Ot+3N%t+3C1+3OHClBOH222(2)জcdefḄ+ᓄᱥᐜᐭ⏚fḄ+ᓄᱥᵫn}⏚ᐹᨵ+ᓄឋ|f`a+ᓄ8f`a⏚⌱$+ᓄ|f`aḄn⏚ᔣḄKᐭᓄMcd@ᔲᙠf`aᐭ⏚ឋp═⏚Mcd@ᔲᙠ|f`aᑣcdefḄ+ᓄᱥKfḄᓄᔠijᵨḄlᑺ@n⏚ஹLᓄMஹ⏚ឋp⏚Mᦑ>ᫀ8AACDঝIKOḄ8⏚ឋᩩtuᐹᨵ+ᓄឋḄC1O3-ᐹᨵPQឋḄFe2+O+ᓄPQᡂFe3\BHO,Ḅ`aGW[86Fe2++CIO3+6H+=6Fe3++Cl+3HO,ᦑ>ᫀ8A6Fe2++ClO+6H+=6Fe3++Cr+3HO2232ঞᵫ⚪YZKNO3ஹKOHBFezOjyᐳ{O+ᓄPQᡂpf⏚Mஹ|}⏚MBTḄᓄGW[8Fe2O3+3KNO3+4KOH^^2K2FeO4+3KNO2+2H2O,ᦑ>ᫀ8A1342KFeO32H2O஺24ூ>ᫀ௃KNO3ஹKOHBFezChyᐳ{O+ᓄPQGW[KzFeOKfᐗᓄᔠi8+6,ᑣ+ᓄfKfᐗ+3i8+6iᓄᔠiᓣp3X2=6iKNO3KNᐗ+58KNChKḄ+3iᓄᔠi2iᵫᓄᔠiᨬ¢£¤ᦪ86¦§+ᓄfḄ/ᦪ81ஹKNO3Ḅ/ᦪ83,ᯠ᪷©^ªឤ§¬GW[஺