2022-2023学年江西省新余市某中学高二上学期开学考试化学试题（含解析）

《2022-2023学年江西省新余市某中学高二上学期开学考试化学试题（含解析）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2022-2023ὃᓄ⚪
ᵨᑮḄH1C12N14O16S32C135.5Fe56Cu64Ca40ஹ⌱⚪⚪ᐳ10⚪⚪3ᑖᐳ30ᑖ஺ᙠ⚪Ḅ⌱⚗ᨵ⚗!"ᔠ⚪$⌕&Ḅ஺1.ᵨᓄᑡᑁᑖ᪆ᔠᳮ!A.ᡂ#“%&'(''Ḅ“&”!ᢣ-.Ẅ0(AS2O3)Ḅ⏀Ẅ0ᨵᒓ4ᐹᨵ67ឋ஺B.:ᾦḂᓄ=>ᵨ?᪆Ḅ@ABᾦC⏚EFᵞ:ᐙᑖᑖIC.JᕚᕚᵨLMN☘PQRSTᶭVWḄ☘PXᐸZ[ᒹ]⃓R_`D.abcd□ᙠgᕜ᧕jk᜿mnḄopq”……stᑣvwxyz{ᑴ}~᪷஺”Ḅ“~”!ᢣ஺ூᫀ௃Bூ᪆௃ூᑖ᪆௃ூ௃A.Ẅ0ᨵᒓ4AS2O3ồᐗXḄᓄᔠ+3ᓄᡂ+5ᑣẄ0ᐹᨵ67ឋᦑAB.ᾦC⏚EFᵞ:ᙠḄkᵨ᪆Ḅ@AᑖIᦑB┯C.☘PX᧕L⏚ᵨ⃓R_`QRᦑCD.᝱Ḅ¡n¢£᧕¤ᡂn¥¦n¡§¡B¨©ª¤ឋ¡ᨵ4ᱥª¬®F¯°±ᡂᓄnN²■'ᐸ¤ᡂn¦´~ᢣᕈ¶~⁐Ḅ¸ᦑDᫀ⌱B஺2.ᑡ»A¼½Ḅ!A.:ᾦ¡ᑖ¾ᓄᔠᱥ>ᵨᑴ⌼ÀḂF:ÁB.35%-40%ḄᵬMḄÃÄÅÆ᪍B¨©ª¤ឋ>ᵨÈᑴÉᱥ᪗ËC.ᜩᯠ¦ḄÎ⌕ᡂᑖ!ᵬÐ!ᵨḄÑᧇD.ÓÔÕᙠÖ×✌ÙÚÛᔠᡂᐹᨵ±ᱥÜឋḄ¨©ª——ÞᨔàáâXூᫀ௃Aூ᪆௃ூ௃A.:ᾦḄãᑖ¾ªäåᯠæᜧ¬èᑖ¾ᓄᔠᱥḄãᑖ¾ªäéḄê:ᾦ!ᑖ¾ᓄᔠᱥA┯B.ÄÅÆ᪍!ᵬMḄB¨©ªë±¤ឋ>ᵨÈᑴÉᱥ᪗ËBC.ᜩᯠ¦!ìᜧᓄíÑᧇ}ᐸÎ⌕ᡂᑖ!ᵬÐ!±î±ÜᵨḄïðñÑ

1ᧇcD.ᡃÓÔÕᔠᡂḄÞᨔàáâX!Ö×✌ÙÚÛᔠᡂḄᐹᨵÜឋḄ¨©ª¨©ªḄôËõᡂᓫ÷!øô⏚Dᦑ⌱Ao3.ì÷ᑖùᩭûAÓஹýÓஹ₹ᐲḄ
Ẇ“ᑖᘤḄᔠᡂ”2016ᓄᝄ஺ᑖᘤᑮᐵ#$ᘤḄ“%&”'ᵨ)*᝞,஺-ᑡ/0123Ḅ456জ58≈:6ঝ5=>?6ঞ5AB:6ট5DE?6A.জঞᙳGHIJᡂKLB.ঝটMNOᑖP᪀RC.জঝঞটᙳSTUD.জঝটḄVWXᱥᑖZN3[ஹ3[ஹ2[ூ^ᫀ௃Cூa᪆௃ூca௃A.জdeᨵgh$GijkJᡂlঞdeᨵmmno$GiHIJᡂKL$ᦑA23lB.ঝটḄᓄqᙳNCioHi6,r᪀1O$MNOᑖP᪀R$ᦑB23lC.ঞNAB:seᨵmt$1STU$ᦑC┯vlD.জdᨵ3[jt$VWXᱥᨵ3[$ঝdᨵ3[jt$VWXᱥᨵ3[$টdeᨵ2[jt$VWXᱥᨵ2[$ᦑD23lᦑ⌱C஺ூxy௃ᑨ{VWXᱥḄOᑖP᪀Rᦪ}$⌕᪷djtḄ[ᦪᩭ3$ṑdᨵ[Ḅjt$ᐸVWXᱥ[ᨵ[஺4.-ᑡஹr23ᨵᐵឋḄ4rᔣ⁐dJᐭ⏚⏚ᓄḄA¢£⁐¤¥dV¦ᙠso;*BaCb

2B¨ᙠ©kdªUḄ«¬ᐭ®⏣d°⁐±²⁐®⏣ᐹᨵ´tឋCᔣµ⏚⏚ᓄḄH2O2d¶ᐭFe(NO)±·¸ᓄឋ¹HO>Fe3+3222Dᔣ¥º»ad¶JỚ»±½/¾¥º¿À»aA.AB.BC.CD.Dூ^ᫀ௃Bூa᪆௃ூca௃A.Á1G᣸¢dᨵAg+ḄÃG$LᐜJ⏚$¾ÅÆJBaCL$A1Çᔠ⚪ÉlB.Á®⏣¨°⁐Ḅ¸ᓄ«´tN²⁐Ḅ«$ஹr23$BÇᔠ⚪ÉlC.Á1GÊᑖ4H2O2´4⏚ឋh᛻-Ì⏚᪷͸ᓄÎFe2+,23$r123$C1Çᔠ⚪ÉlD.¥º⍗Ớᓫѱ½$ÁÒ/¾Á»ad´ᨵ¥º$1G34ᔲ¿À»a$D1Çᔠ⚪ɹᦑ⌱B஺5.ÔᕜÖ×ØᐗÚWஹXஹYஹZஹQtÛᦪÜÝÞᜧ$àᡂḄᓄᔠᱥ4V[á⌕ḄâãäJᑺ$r᪀᝞,஺Z᪶᜜ᨬ᜜éᵯᦪX᪶᜜ᵯëᦪì஺WḄtíîᙠᕜÖ⊤dᨬð஺-ᑡᨵᐵñò23Ḅ4wwZ\I஻Q+Y—X-X/Iஹl_W஺ZôA.tíîᜧð¹Y>Z>QB.WஹYஹZ8[ᐗÚÃàᡂÍᓄᔠᱥC.Áᓄᔠᱥdᡠᨵtö8ᵯ÷r᪀D.ÁᓄᔠᱥḄ▢ÍdᡠᨵḄtÃGᐳ☢ூ^ᫀ௃Bூa᪆௃ூᑖ᪆௃ÔᕜÖ×ØᐗÚWஹXஹYஹZஹQtÛᦪÜÝÞᜧ$WḄtíîᙠᕜÖ⊤dᨬð$ᑣᐸNjᐗÚlüâãäJᑺḄr᪀,dÃýþ¢$Xàᡂÿᐳᑣᐸᨬ᜜ᨵ4ᵯᐸCᐗYᡂᐳᑣᐸᨬ᜜ᨵ5ᵯᐸNᐗZᡂᐳᐸᨬ᜜ᵯᦪ6,“Z᪶᜜ᨬ᜜ᵯᦪX᪶᜜ᵯᦪ“ᡠZOᐗQᡂQ+,ᑣᐸNaᐗ஺!"#$WஹXஹYஹZஹQᑖ'

3HஹCஹNஹ0ஹNa஺ூ*+௃A.YஹZஹQᑖ'Nஹ0ஹNa,ᑣᐸ-./ᜧ12Q>Y>Z,A345B.WஹYஹZᑖ'HஹNஹO,ᑣWஹYஹZ6ᐗ7ᡂ8ᓄᔠᱥNH4NO3,B45C.<ᓄᔠᱥ=◀?H᜜ḄᐸA-B8ᵯCDE᪀C345D.G-ᡂ4ᓫஹG-ᐸIJE᪀KL☢Nᑣ<ᓄᔠᱥḄ▢8=ᡠᨵḄ-37Pᐳ☢D345ᦑ⌱Bo6.ᡃTUẆWᕒYZ[ᑴᐝ^_Ḅ`a᪀bC112O—Pt/SiC/IrOxcdᔠᩞᧇᐝgᓄᑺᐸ=Fe2+jFe?+8klNafionm7noCO2ஹH0ᑖ'pq᪀b?rWsᐝᔠtᵨN2vᐸpqwᳮ᝞z{ᑡ}a┯ḄK!

4Ḅµ¶ᩭ¸Dấ©Kᔲᜫᦔ-ᳮ᝞{2CoCb¼⁐¾CoCb6H2O¿À⁐ÁᜫᦔḄấ©7²ÂÃ{ᑡ}a┯ḄKA.Äấ©Å¿À⁐}Æấ©ᜫᦔ?B.SiOK⏚ឋᓄᱥấ©7®¯HFjCl⏚ឋN22C.ᜫᦔḄấ©Ã²ÂḄÈÉ3ÊZËD.Äấ©⍗ᑮᜧḄᑖấÎÏᡂ?ZµÐ!"ᜫÑᔾ▬Òூᫀ௃Bூ+᪆௃ூ*+௃A.ᵫ⚪=ÔÕ7ấ©ᔾÖ×Åᡂ¼⁐ḄCOCL-6H2O¿À⁐ÁᦑÅᡂ¿À⁐Öᑣ}Æấ©ᜫᦔ?A45B.ᓄấ7jHFpqᦑấ©3P®¯HF,B┯C.ÈÉZË×Ø⁐ᑺ⌲Úᓄ"ᜫÑØ⁐tᵨC45D.ᵫấ©E᪀7ấ©ᵨt®¯ᑺKYZấÎÏjᑖÛJᡂÐ"ÜᑮᔾḄÝḄᦑÄấ©⍗ᑮᜧḄᑖấÎÏᡂ?ZµÐ!"ᜫÑᔾ▬ÒD452ᦑ⌱B஺8.Þcßᡷᵯáᙠâã=ᨵäåqᵨ஺ᨵr6æçᵯá᝞zᡠᐸᵯ᩽ᑖ'KAgzOjZn,ᵯ+¤éêKOHéê஺³ᵨᵯá=Ḅpq2Zn+Ag20+H0=Zn0H
+2Ag{ᑡë<ᵯá³ᵨḄìí345ḄK22oîᨵKOHéêḄ◞ðA.4᩽ᩞᧇKAg2஺B.ô᩽pqZn+2OH-2e-ZnOHÁ2C.ᵯᵫZn᩽ñ᜜ᵯòᔣAg?O᩽D.ᵯ+¤KOH×3õöὑ

5ூᫀ௃Dூ+᪆௃ூᑖ᪆௃<-ᵯá=Znᐗᓄᔠᵫ0Å+2Agᐗᓄᔠᵫ+1Å0ᡠZnKô᩽ᜫᵯøᓄpqAg?OK4᩽#ᵯø§-pqᑖ᪆+஺ூ*+௃A.ᵫpq7Agᐗᓄᔠᵫ+1Å஺ᑣAg?஺#ᵯø§-pqt4᩽ᦑA45B.ô᩽Znᜫᵯøᓄpqùឋᩩ{ᡂZn(0H)2,ᑣô᩽pqZn+2OH-2e-=Zn(OH),ᦑB452C.ᵫᑖ᪆7Zn-ᵯáô᩽AgzO-ᵯá4᩽-ᵯá=ᵯ!ô᩽òᔣ4᩽ᓽᵫZn᩽ñ᜜ᵯòᔣAgzO᩽ᦑC45D.ᵯápqZn+Ag2O+H2O=Zn(OH)2+2Ag,ᵫpq7KOHḄ3ÅᦑD┯ᫀ⌱D஺9.ᡃTUẆWᕒü$CeChgᓄᔠᡂG⏚ᵬý(DMC)◤ñᔊ
᝞஺ᑡḄA.জঞᙳঝᡂB.ImolDMCᙠឋᩩ!ᐰ#$%ᡂ&2molCH,OH(ImolCO,)ᱥ+ᐳ-ὑ24molNaOHC.ᔠᡂDMCḄ+0CH3OH(CO2ᱥD.জ01ᓄᑺḄ4ᵨ6O-H789:ᓄூ<ᫀ௃Bூ$᪆௃ூ@$௃A.᪷B087(ᡂ7ḄCDᑖ᪆FᑮজঞᙳঝᡂᦑAIB.DMC0Jᨵ2LMNOP1molDMCᙠឋᩩ!ᐰ#$-ὑ2moiNaOH,ᦑB┯RI

6C.ᔠᡂDMCḄ+CH30H(CO?%ᡂDMC(#OPCH30H(CChᱥᦑCID.᪷BজḄFᑮজ01ᓄᑺḄ4ᵨᵬ⏣0Ḅ0-H789:ᓄᦑDIᦑ⌱Bo10.ᐵW02ᒹ)+[0পuiHQO(aq)+H+(aq)+Cr(aq)AH<0,^ᑮ_⊝aᑡbcḄA.ᓣefgh#0Ḅc(HClO)ijB.h#0ᐭlmn⏚pqrst_⊝ᔣvwc(HClO)xᜧC.h#z{,c(Cr)/c(HClO)xᜧD.}~h#ᑖAgNC)3(KIὅᨵ⁐aὅ⁐stᙠ▲gூ<ᫀ௃Dூ$᪆௃ூ@$௃A.HC1O᧕ᑖ$ᓣefgHC10ᑖ$_⊝ᔣvwc(HClO)ijAIB.h#0ᐭlmn⏚pqrn⏚᪷(ᔠ%ᡂn⏚ᑖgij_⊝ᔣvwc(HC10)xᜧBIC.h#z{_⊝ᔣvwc(HClO)(c(Cl-)ᙳijHCIOᙠᵯ_⊝HC10WH++C1O,z{¡¢&HOOḄᵯ6c(HC10)il£¤OP•_xᜧ,Cc(HClO)ID.h#0§⏚¨)%⁐0ᨵhh#0Ớᓄª%ᡂ&Ớᓫ¬0ᨵ®ᓄឋḄᱥ¬h¯(°h⏚±ᨵ®ᓄឋ²ᱥ(%ᡂᱥᐳᓽ²stᙠ▲gD┯RI<ᫀ⌱D஺´ஹ⌱¶⚪⚪ᐳ4j⚪¸j⚪4ᑖᐳ16ᑖ஺ᙠ¸j⚪¹ºḄ»L⌱⚗0ᨵ½Lᡈ}L⌱⚗¿ᔠ⚪À⌕Â஺ᐰÃ⌱ÄḄF4ᑖ⌱ÄᐰḄF2ᑖᨵ⌱┯ḄF0ᑖ஺11.²⊤ᑡḄÆÇÈA.ᵨÉmÊ#ᔾᦈÍÎϯ0Ḅso?Ð2NH-HO+SO=2NH*+SO3+HO3222

7'))B.hᓄpqrÑÒ⏚ÓᔠÐHSO+2C1=SOT+஺2T+HO2422C.ᵨÒ⏚(-K1ÔÕỚÖ0ḄI0×IOI+5r+6H+=3I+3HO22D.Ø0ᐭBa(OH)?6SOÐាÚ!ᐰÐ2Ba2++3OH+Al3++2SO^=2BaSOI+A1(OH)J43ூ<ᫀ௃ACூ$᪆௃ூ@$௃A.ᵨÉmÊ#ᔾᦈÍÎϯ0ḄS02,Ê#Ém%ᡂÛÒ⏚Ü(#ḄÆÇÈ2NH3•H2஺+SO=2NHÐ+SOÐ+HO.ᦑAI22B.hᓄpqrÑÒ⏚Óᔠ%ᡂÒ⏚p(hᓄH2soÈ)+2NaCl=Na2SC)4+2HClT,ᦑB┯RIC.ᙠ⏚ឋᩩIO3ÝỚ®ᓄᓫ¬ỚÆÇÈIO-+5I+6H+=3I+3HO,ᦑCI22D.Ò⏚᪷ាÚ!ᐰÞ´ὅᱥ¬Ḅmßà1Ð2,ᑣḄÆÇÈ2Ba2++4OH+Al3++2SO^=2BaSO4<+AlO+2HO,ᦑD┯RI422ᦑ⌱AC,12.ឤfᱥ¬Ḅmßà2Ð1ḄSO?(02ḄÓᔠ¯rᙠäå2LḄឤäæçäᘤ0é%Ð2s02ê)+02ê)=25஺3ê)(ì)"SO?)íÞîᓄᐵï᝞⊤ᑡḄÞî/min012345n(SO)/mol0.200.160.130.110.080.082A.ðäᘤ0¯rḄægÞñ^ᑮ_⊝ò᝱B.5ᑖôÞᔣäᘤ0ᐙᐭlmöឋ¯r÷᳛C.ùúûᑮ^ᑮ_⊝ᵨSO3⊤Ḅ_ᙳ÷᳛0.01mol/(L-min)D.äᘤᑁ^ᑮ_⊝ò᝱ÞḄýÑþûÞḄýßà4Ð5ூ<ᫀ௃BDூ$᪆௃ூ@$௃A.ឤäæçäᘤ0¯rḄ¬mஹråᙳÓᔠ¯rḄægûÿ
ᑣ
ᑨᔲᑮ⊝᝱ᦑA┯

8B.5ᑖᔣឤ!ᘤ#ᐙᐭ&'(ឋ*++,#ᔜᱥ/Ḅ1ᙳ3ᦋ
5᳛
ᦑB78C.ᵫ⚪<⊤>ᦪ@AB4minᑮ⊝GHᓄJḄᱥ/Ḅ'Ḅ
ᓄ'K(0.20-0.08)mol=0.12mol,ᵫᓄWXYḄᓄWZ'ᦪ[\]^ᔜᱥ/Ḅ
ᓄ'[\A0.12moiB_HᓄJḄ
ᓄ'K0`2moiᑣᵨSO3⊤eḄᙳ5᳛KGߟ=0.0154minmol/(L-min),ᦑC┯D.ᵫ⚪<⊤>ᦪ@ABjkGHᓄJlH*Ḅᱥ/Ḅ'ᑖmK0.20mo1lO.lOmol,4minᑮ⊝GHᓄJḄᱥ/Ḅ'Ḅ
ᓄ'K(0.2D.08)mol=0.12mol,ᵫᓄWXYḄᓄWZ'ᦪ[\]^ᔜᱥ/Ḅ
ᓄ'[\AB⊝GHᓄJஹH*l_HᓄJḄᱥ/Ḅ'ᑖmK0஺8molஹ0.04moK0.12moLᵫឤqឤ*+rs[\]^ᱥ/Ḅ'[\Atᑮ⊝᝱ḄrsujkḄrs[\K(0.08+0.04+0.12)molw(0.2+0.l)mol=4w5,ᦑD78;ᦑ⌱BD஺13.z{|}~ỚḄ(◀H2஺᜜~ᨵCCI4ஹ12ஹI])#ᦈỚᐸz{Y᝞ᑡᔜ⚗⌱ᵨḄ78Ḅ()ciCCUJ-JL_____.~**-1IX-,*ᓄ—----TY|TZ~~~►11CCLCCL⌱⚗ABCDZ(¡¢ᜳXHᓄᢝᶍ¦)114:$¨A.AB.BC.CD.Dூ«ᫀ௃Cூ®᪆௃ூᑖ᪆௃~ỚḄ~ᨵCC14ஹbஹ±]ᐭNa2s஺3µLKrwH2O+SO32-+l2=2I+SO2-4+2H+ᑭᵨXµ¸uCC14ᑖ¹ᡠ»XKᑖ¼ᳮKᑖZK¾¿஺

9ூÀ®௃A.XKᑖzÁÂÃÄḄÅÆ+Ḅᑖ¹ᡠ<Ç78A⚗78B.BÈ¢HᓄÉÊ⁚ÌᵨÍᴻᳫÐA»ÑᜧÓÔ☢ÖÌ×*uØᐙᑖ᎔ᡷḄÛᧅKÂ■Þ+᎔ᔾᵨNaOHᔾᦈà*×*■Þáâᜧ*B⚗78C.ã⌕zÁḄÃÄḄ+Ḅᑖ¹ᡠ»åᵨᑖ⌱ᵨuA⚗¼᪵Ḅ⚪<ḄçzÁḄèé^+Ḅᑖ¹C⚗┯D.Z¾êᡠ<Ḅ¾êÇ78D⚗78ᡠ»«ᫀ⌱ëC⚗஺ூìí௃î⚪ïðὃòᑖ¹Ḅᳮ¢ᵨᡠ<4óḄô⁚õᙳöᨵ÷⚪஺14.ឤqឤḄ!ᘤ#ᙠùúᓄᑺ⊤☢õüýþḄᑖ®w2NH3ÿg
#Ng
+3Hg
,
10°mol-Liᓄᑺ⊤☢22Ḅᓄ᝞⊤ᡠᑡ⚗Ḅ"#$020406080জa2.402.001.601.200.80ঝa1.200.800.40Xঞ2a2.401.600.800.400.40A.%&জ0~20min,vN
=1.00xl0smol-L1-min-12B.%&ঝ60minᜐ*+⊝-᝱XH0.40C./ᩩ1234Ḅ567᳛2ᜧD./ᩩ123ᓄᑺḄ⊤☢567᳛2ᜧூ;ᫀ௃Cூ>᪆௃ூ@>௃A.%&জA0B20min,4ᓄCD2.40xl03mol-E'^.OOxlO^mol-E'=4.00xl0-4molE'VNH
=4-00-10mol-L'.=2.00x10-5mol-L-1-min1,567᳛EFG*ᓄHICᦪ3'M20minEFvN
=1vNH
=1.00xl0-5molL'-min-1,ANO23B.ᓄᑺ⊤☢ᜧPQRS567᳛RS+⊝%&ঞA4UV%&জAW᪵%&ঞYᑮ+⊝4D4.00xlTmoi.L[ᑣ%&জY+⊝4]D

104.OOxIO'moll[^ឤ`ឤaᩩ1%&ঝ/b*%&জDcPde+⊝Nᔣghij%&ঝ60minᜐ*+⊝-᝱x<0.4,ᓽx/).4,BNOC.%&জஹ%&ঝA0B20minஹ20minB40min4ᓄCm"4.00xl(Tmol•U%&ঝA60min56Yᑮ+⊝-᝱%&জ%&ঝᓄᑺ⊤☢/%&জA4U"%&ঝA4UḄno%&জ60min56pYᑮ+⊝-᝱/ᩩ1234567᳛qrᨵ2ᜧCNOD.bF%&জ%&ঞ4/%&ঞAᓄᑺ⊤☢"%&জAᓄᑺ⊤☢Ḅ2o%&ঞᐜYᑮ+⊝-᝱%&ঞḄ567᳛ᜧu/ᩩ123ᓄᑺḄ⊤☢567᳛2ᜧDNOᦑᔠᳮ⌱⚗DCo*ஹ+⌱⚪15.z⏚|(ZnSOj"ᑴᜓᔜ|ᩞᧇḄᧇᙠ■ῖஹᵯ╄ஹHᨵ6ᵨ஺z⏚|ᵫ|ᑴᜓ஺|Ḅ⌕ᡂᑖDZnCOaᩖDSi஺CaஹMgஹFeஹCuGḄᓄᔠᱥ஺ᐸᑴᜓ¡᝞¢£¤জ£¤ঝ£¤ঞ£¤ট¦;ᑡ§⚪¢(1)|ᯏ«¬ᡂᓄ|ḄᓄH®¡¯D஺(2)D°±²|Ḅ³´ᦔ¶·´Ḅ¸¹ᨵஹ஺(3)3ᐭᱥX»¼½pH=5,ᨬ〉ÀÁᵨḄX"(Â᪗$)஺A.NH,♦HQB.Ca(OH)C.NaOH2£¤জḄ⌕ᡂᑖ"Fe(OH)3ஹஹ«(4)ᔣ80B90࠷Ḅ£½জAᑖᢇ3ᐭ〉CKMn஺,¼½ᐙᑖ56ÉÊ££¤ঝAᨵMnO,ËÌ56ḄÍIÎḄ"ᓄFe?+,ᑏÐÑÒ®¡¯஺2(5)£½ঝA3ᐭ|ÓḄÎḄ"஺(6)£¤টVH2sC\56ÔÕHFqÖ×ᑭᵨ
ᑮḄÙÚᱥ"Wஹ,-ூ;ᫀ௃(1)ZnCO^=ZnO+COt32

11(2)জ.2ᜧdeஹÜᯏ«ÉḄÚᱥÝÞঝ.2ᜧ56ᱥḄßà☢ஹ2ᜧz⏚ḄG®¯±²|Ḅ³´᳛(3)জ.Bঝ.CaSCMঞ.SiCh(4)3Fe2++MnO+7H2O=3Fe(OH)31+MnO2J+5H+(5)áᣚCu?+DCuä^Ê£◀æ(6)জ.CaSCUঝ.MgSO4ூ>᪆௃ூᑖ᪆௃Ü|²`ç«56Ú¬ZnOஹCO,CaஹMgஹFeஹCuGḄᓄᔠᱥç«Ú¬2CaOஹMgOஹFeO,CuO,SiChè¬56஺ᯠÉᵨH2sO&⏚³ZnOஹCaOஹMgOஹ23FeO,CuODZ11SO4ஹCaSO,MgSChஹFeSChஹFe2(SO)3.ᯠÉ3ᐭCa(OH)2»᦮¼2344½pH=5,ëᡂCaSCUஹFe(OH)3ìíSiChV⏚56îᐭ£¤জA£½জAᨵZn2\Fe2\Cu2\Mg?+ïCCa?+ᔣ£½জA3ᐭKMnCh¼½ÜFe?+ᓄDFe(OH)3,KM11O4ðñDMnCh;£¤ঝAᨵFe(OH)3ஹMnCh;ᔣ£½ঝA3ᐭZnÓV¼½AḄCu2+è¬áᣚ56Ú¬CuᓫÊ£◀æCuÊCḄZnÓᔣ£½ঞA3ᐭHF,56Ú¬CaF2ஹMgF2ìíóÊÊ£◀棽AᨵZnSCU,ᯠÉôõèöஹ÷ᓾùᨔஹÊ£
ᑮZnSO#7H2O஺ூP§1@>௃²`|²`ᰀ«ZnCCh56Ú¬ZnOஹCO,Ë56ḄᓄH®¡¯D¢ZnCCh—2ZnO+CO2T;ூP§2@>௃ä567᳛ḄRSiüὃ⇋D°±²|Ḅ³´ᦔ¶·´Ḅ¸¹ᨵ2ᜧdeஹÜᯏ«ÉḄÚᱥÝÞ2ᜧ56ᱥḄßà☢ஹ2ᜧz⏚ḄG®¯±²|Ḅ³´᳛ூP§3@>௃A.NH3H2O᧕ᑖ
N%ᡂAᔠ⚪B.Ca(OH)2ᐭḄᩖᡂBᔠ⚪C.NaOHᐭᩖNa+,ᡂCᔠ⚪ᦑᨬ〉"ḄXᱥ$Ca(OH),ᔠᳮ⌱⚗$B2()*+ᐰ-./0123IO,mol/L,(./+ᐰ)*-pH=5-4ᨵFe3+7ᡂFe(OH)3)*8ᦑ9:জ<ᨵFe(OH)3=ᵫ3CaSO?$@Aᱥ⏚ឋDᓄᱥSiChA3⏚ᦑ9:জḄF⌕ᡂᑖ$Fe(OH)3ஹCaSO>SiCh;4ூ2J4K
௃ᔣ80N90࠷9Pজ

12YḄ./Z[\]3Fe2++MnO+7H2O=3FehOHi3j+MnO21+5H+ூ2J5K
௃9Pঝ⚠@Aঝ.AEBDC2᣸HIJ■LMᡂNOO02Qᓄ3জ.3Cu+8HNO3=3CuNO32+2NOT+4H2஺ঝ.VWX⁐Z[4\]^_ᨵCaNCh2ᩖ650.12molூf᪆௃

13ூᑖ᪆௃ijk⌕ᑴmno⏚┛rstuvwᵨxQᓄyzsQᓄ┛
ᡠ|}~sᔣrᐭyJᔿ^ḄQJᯠ⏀ᔣ>⚠@A^o⏚4zo⏚
MᡂxQᓄyJrsE^Ḅ◀J^Ḅo⏚rsB^ᓄ┛JrsD^sQᓄ┛
Mᡂno⏚┛ᨬrᐭC^⏚VW^Jᜐᳮ஺|¢f9஺ூ£¤1¥f௃ᵫ§vw¨4ᱏḄªᘤ¬>⚠@A®rs|/ᑖ᪆vw/¯ᢥJ±²ᔣ³´Ḅµ¶AEBDC®ூ£¤2¥f௃^ᨵIJIJ^ḄQJv|zxQᓄy
ᦑrᐭN2Ḅ¸ᵨ¹᣸HIJ■LMᡂḄNOO஺2Qᓄ®ூ£¤3¥f௃A^
4zo⏚
Mᡂo⏚4zxQᓄyzᓄº²»3Cu+8HNO3=3Cu(NO3)2+2NOT+4H20®᪷¿tu⏚ឋᩩÂÃNOÄÅKMnCUVW
MᡂNO,zMM+ᑖ᪆C^
ḄÉʲ»3MnO®+4H++5NO=3Mn2++5NO®+2H?0,ËÌᑮḄÎϹVWX⁐Z[®ூ£¤4¥f௃n(NO)n(N02)

14C.01ᑭᵨᧇD.ᧇC02Ḅ'4ᑖᦪ63
78ᩩ:;2Lឤ=>?=ᘤᐙᐭImolCC^B3mO1H2,ᙠCᓄᑺEᵨFGHIJK5minLCO?Ḅᓄ᳛ᙠMN)OPQḄRᓄ᝞T1ᡠV஺T1জT4PQHIᙠ஺Y5minᑁ[ᙳHI]᳛VH2^=mol/(L-min)஺ঝb`aIḄbHI]᳛v6b^c`aI⌮HI]᳛v6⌮^d"Yᡈ“=”^஺ঞlHIᙠC`Ḅ'(mnop0.8
MPa,ᑣc`HIḄKp=MPa
-2Kprpᑖn⊤VḄ[⊝uᦪ^஺64
Ti஺?vCᓄᑺᐝCᓄxCO?yzᑴK|ᧇᵬ⏣ᐸᳮ᝞T2ᡠV஺.2জCB᩽ḄᵯVB᩽Ḅᵯ6d“”ᡈ“”^஺ঝឋᩩ:ᵬ⏣|ᧇᵯḄ᩽HI஺ூᫀ௃(1)-90.8(2)BC25(3)জ.0.21ঝ.<ঞ.12(4)জ.ঝ.CHOH-6e+8OH=CO^+6HO32ூ᪆௃ூ1௃a.CO2(g)+H2(g)-CO(g)+H2O(g)AH1=+41.2kJ/mol

15b.CO2(g)+3H(g)-CHOH(g)+HO(g)AH=-49.6kJ/mol232᪷8b-aKCO(g)+2H(gXCHOH(g)AH=-49.6-41.2=-90.8kJ/mol232ூ2௃A.ᙠᧇᐭ〉H20(g),ᜧ¢£¤Q[⊝⌮ᔣ¦§CO2ᓄ᳛¨ᦑ)⌱AB.&'()*ᑖ,-ᵬ⏣ᵬ⏣¤Q«[⊝bᔣ¦§CO2ᓄ᳛ᓣᦑ⌱BC.01ᑭᵨᧇᧇᑭᵨ᳛C02ᓄ᳛ᓣᦑ⌱CD.ᧇC02Ḅ'4ᑖᦪᜧCChḄ¤QCChᓄ᳛¨ᦑ)⌱Dᦑ⌱BCூ3௃জHIaI®¯p°CO()+3H(g>CH3OH(g)+HO(g),ᵫTV²PQ5min2g22LCOḄᓄ᳛p70%,ᓽCOḄᓄ=lmolx70%=0.7mol,ᦑHḄᓄ2222.1mol=3x0.7mol=2.1moLᑣv(H?)=2L=0.21mol/(L-min)5minঝb`PQஹᵬµ¤Qc`PQbaIḄbHI]᳛v(b)

16HI1°2CH(g)^^CH(g)+3H(g)AH,4222HI2°2CH(g)^=±CH(g)+2H(g)AH42422üýᑡ⚪°(1)ÿ
ᱥḄ(AH)ᦪ᝞ᱥCH4(g)C2H2(g)C2H4(g)H2(g)(AH)/(kJ/mol)-890.3-1299.5-1411.0-285.8জᑏ⊤C2H2(g)Ḅᓄ஺ঝ1231AS=+220,2J.moP1-K-2:ᑣᑡᡠ>?@ABC23DEFGḄH(I᪗K)஺A.0࠷B.25࠷C.1250࠷D.2000࠷(2)ᙠឤ?ឤQRSQᘤUᐙᐭ〉YCH&E[\]231^232,ᑡ_`aAbc\]23dᑮf⊝h᝱ḄH(Ijk)஺A.lmnopaqrstᓄB.lmR@aqrstᓄClmfᙳ᥅wYaqrstᓄD.H2mxᑖᦪaqrstᓄ(3)2cH2H2(g)+3H2(g)Ḅ{᳛}vuk^clCHj:v⌮=k^c(C2H2)y2(H2)(kஹk⌮}ஹ⌮23{᳛ᦪ:?@ᨵᐵ)஺ᐸᩩ:࠷dᑮf⊝rk=1.5k⌮:Tz'Cdᑮf⊝rk=3.0k⌮஺ᵫ:T,T?(I::::“::ᡈ”=::)஺(4)?@:ᙠnopᢝឤ}121kPar:ᔣ£RSQᘤUᐙᐭCH’^N2¦ᡂḄ¨ᔠlm(N2aª23):«¬CHḄf⊝ᓄ᳛®ᐭlmUCH4ḄᱥḄYᑖᦪ4Ḅᐵ¯᝞°ᡠ஺

17CH&Ḅf⊝ᓄ᳛/%®²lmUCH&ḄᱥḄYᑖᦪজ°UqḼ®ᐭlmUCH&ḄᱥḄYᑖᦪḄ´ᜧ:ᵬ·Ḅf⊝ᓄ᳛¸¹Ḅº⌕¼½H᱄È)ঝ1M¿ÀᯋḄ⌱Ãឋ}75%[ÀᯋḄ⌱Ãឋ=xl00%]oC?@n(CH)+n(CH)2224:232Ḅf⊝ᦪKp=kPa(ÊËᶇ2Íᨵᦔᦪj:KpHÏᑖo⊤Ḅf⊝ᦪ:ᑖo=noxᱥḄYᑖᦪ)஺ூÒᫀ௃(1)জ.C2H2(g)+gc)2(g)=2CO2(g)+H2O(l)AH=-1299.5kJ/molঝ.D(2)B(3)<(4)জ.ᙠᐸ×ᩩatr:qḼ¨ᔠlm23ᱥUCH4ḄmxᑖᦪḄ´Ø:23m¯nop´ᜧ:ᓄf⊝⌮ᔣÙÚ:ÛÜᵬ·Ḅf⊝ᓄ᳛2ݸ¹ঝ.7.56ூß᪆௃ூáâ1ãß௃জH1moläᱥåᐰç[èḄéᓄᱥrêḄY஺᪷⊤ìᦪäÀíḄ}-1299.5kJ/mol,ᑣ⊤ÀᯋḄᓄ}CH(g)+|22O(g)=2CO(g)+HO(l)AH=-1299.5kJ/molï222ঝ᪷ᱥḄ:ä¬ᓄ(i)CH4(g)+2O2(g)=CO(g)+2HO(l)AH=-890.3kJ/molï225(ii)CH(g)+-O(g)=2CO(g)+HO(l)AH=-1299.5kJ/molï22222(iii)H(g)+ïO(g)=HO(l)AH=-285.8kJ/molï222᪷ñòó:পx2-(ii)-(iii)x3ä¬2cH2H2(g)+3H2(g)AH=376.3

18kJ/molïAHi-TASO,23äÏDE,ᑣõö231◤⌕376.3kJ/mol-Tx0.2202kJ-moE'-K-2<0,◤⌕ᨬ¹?@}1708.9K,ᦑ⌱Dïூáâ2ãß௃A.23ᙠឤ?ឤQRSQᘤUFG:231^232ûHlmᱥḄYE[tᓄḄ23:ülmnopaqrstᓄ:ᑣlmḄᱥḄYat:23dᑮf⊝h᝱:Aaýᔠ⚪ÿB.ᙠឤឤᘤḄᔠᱥḄᑣᔠ!"#᪷%ᑨ'ᔲ)ᑮ+⊝-᝱B/ᔠ⚪1C.ᔠᱥḄ஺152ᱥḄ78ᓄḄ:+ᙳ᥅=>?@ᓄᑣḄᱥḄ)ᑮA+⊝-᝱C/ᔠ⚪1D.ᙠCDEF8ᡂᱥHIḄᱥḄ78ᓄ:H2ᑖᦪ>?@ᓄᑣH2ḄᱥḄMNOᱥḄ)ᑮ+⊝-᝱D/ᔠ⚪1ᦑᔠᳮ⌱⚗BூUV3XY௃᪷%H[\]^_2cH4(g)UC2H2(g)+3H2(g)AHi=+376.3kJ/mol,tḄuᔾw஺ᓣyᓄz+⊝uᔣ|}ᓄz+⊝~ᦪᜧ஺2cH4(g)UC2H2(g)+3H?(g)Ḅ᳛v/kmcZCHQ,v⌮=kc(C2H2>C3(H2),vu=v⌮kc2(CFU)=k⌮1Hc(C2Hj.c()_1C3(H2),ᙠTi࠷)ᑮ+⊝?k,1.5k⌮C2(CH)k⌮'4T2࠷)ᑮ+⊝?k=3.0k⌮K=3.O,K2>K”ᡠTIḼᔠᱥCH4ḄᑖᦪḄ¯NO£¤ᜧᓄz+⊝⌮ᔣ|}¡¢ᵬ±Ḅ+⊝²ᓄ᳛³´µঝᎷ¸¹ᐭḄCH4ஹN2ᔠOᱥḄ10amol,ᙠM¿CHᓰOᱥḄḄ40.6,ᑣ¹ᐭCÁḄᱥḄn(CH4)=6amol,n(N)=4amoLᵬ±+⊝²ᓄ᳛40%,ᑣ2ÅὑḄCH4ḄᱥḄ6amolx40%=2.4amol,ÈḄᵬ±ḄᱥḄ6amolx(l-40%)=3.6amoU᪷%M¿?ÊËḄ⌱Ìឋ75%,^_1Î2cHMg)UC2H2(g)+3H2(g)ÅὑCH4ḄᱥḄ2.4amolx75%=1.8amol,᪷%ᱥ²ᓄᐵN^

19_ᐸ8C2H2(g)0.9amol,8H?(g)2.7amol782Î2cHg)UC2H4(g)+2H2(g)ÅὑCHḄᱥḄ2.4amolx25%=0.6amol,᪷%ᱥ²ᓄᐵN^4_ᐸ8C2H4(g)0.3amol,8H4g)0.6amol,ᑣ+⊝?OᱥḄn(O)=n(N2)+n(CH4)+n(C2H2)+n(C2H4)+n(H2)=4amol+3.6amol+0.9amol+0.3amol+(2.7a+0.6a)mol=12.1amol,ᡠtᩩÒ2Ḅᓄz+⊝~ᦪK=p0.9a33a22(xl21kPa)(^-xl21kPa)P(CH)-P(H)_H2421=7.56kPaop2(CH)3.6a24xl21kPa)12.1a