2022-2023学年湖南省长沙市湖南高二上学期入学考试化学试题（含解析）

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ᓭᜧ▬2022-2023ᐭὃᓄ
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=-687.9kJmor'<0»ᦑ298Kஹ100kPa38"#&KLMNC⚗┯7fD.ᓄᑺi@ᦋQ"#j᳛J@ᦋQ"#YᔣD⚗┯7஺ᦑ⌱CD஺12.mn:A1g
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sᙳ92.0LḄឤstusᘤ=L$᝞3"#02NO(g)+2CO(g)^=iN(g)+2CO(g),ᔜsᘤ=ÆÇᱥḄAȶ!"#r¶(m22n1>12=13)᝞⊤ᡠ0ÆÇᱥḄAȶ/(mol-LT)sᘤr¶/࠷NO(g)8(g)N2(g)co(g)2ᵬT,0.100.1000ÒT2000.100.20ÓT,0.100.1000

8"#ÔÕ=ᵬஹÓsᘤ=CO?ḄᱥḄARQᓄᐵÖ᝞ᡠ஺3ᑡ5JdeḄA.8"#Ḅd"#9g"#{⊝ᦪK1TJv1⌮2ூ\ᫀ௃Cூ_᪆௃ூᑖ᪆௃mn>12=%ᵫÜ&nᵬ{⊝}᝱ÝÞᓄßᱥḄA<5r¶àB{⊝⌮ᔣMN⌮"#9ᔾg"#d"#9g"#ூa_௃A.ᐜãᐜ{r¶Bᵬ{⊝}᝱ÝÞᓄßᱥḄA<5r¶àB{⊝⌮ᔣMN⌮"#9ᔾg"#d"#9g"#r¶TI>T2,{⊝ᦪKTIT2,"#9g"#r¶æç{⊝dᔣMN.ᱥḄA;<.×Ø;<Ò.ᱥḄA9ᵬḄ2Ù,èC§ᜧ×Ø{⊝dᔣ³´.ᱥḄA;<yᑮ{⊝RÒsᘤ=Ḅ×Øp¾

9D.ðᔠ⊤ñ=ÓḄᐵᦪòóô¿õö“02NO(g)+2CO(g)U$(g)+2CO(g)2Ç(mol/L)0.10.100Q(mol/L)0.060.060.030.06{(mol/L)0.040.040.030.060.062X0.03…{⊝ᦪK=——0--------T=42.2,Ósᘤ="#yᑮ{⊝¦,Úᐙ0.10molNOw0.100.042X0.042o.r)x0.03[0.06+ømolCO2,ȶᖪQc----------=28VK,{⊝dᔣMNÛR0.04+—Ix10.042v1dÿv
⌮ᦑDᫀ⌱C஺14.Ḅ╅ஹᡂḄᔠᱥᐭᑮ#$⏚&'()ᐰ+,
Ꮇ./0&123ᱥᐰ45NO஺ᔣ/09Ḅ+:&ᐭ3moi/LNaOH+:CDE)ᐰFGHᡂDEḄI2ᔠ'ḄJ5.1g,ᑣOᑡQR&Ḅ5A.THᡂDEUᑮᨬᜧXYZὑNaOH+:Ḅ\]^100mLB.T'(ᐰ4+,Yᦈbᑮ᪗dOḄNOe\Ḅ\]^2.24LC.g/0Ḅ'(Ḅh56.6gD.T'(ᐰ4+,Yg/0Ḅ$⏚ḄᱥḄ50.4molூᫀ௃BDூ,᪆௃ூn,௃Ḅ╅oᡂḄᔠᱥᐭᑮ#HNCh&'()ᐰ+,
Ꮇ./0&123ᱥqᨵNO,tH/0u3Mg+8HNO3
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OH|+2NaNOCu
NO2+2NaOH=Cu
OH21+2NaNO,DE^~32333ᓄ╅o~ᓄHᡂDEḄI2ᔠ'ḄJ5.1g,ᑣ~ᓄ╅o~ᓄ5.1gᨵ~᪷Ḅ^5.1g,~᪷ḄᱥḄ^|=0.3mol,᪷ᵯឤᑣ17g/mol╅oḄhḄᱥḄ^0.15niol;A.$⏚ᒕᑣg/0~ᓄḄᱥḄ0.3moL◤⌕~ᓄ+:\]=0-3m01=0.1L=100mL,$⏚ᨵᒕZὑḄ~ᓄ+:\]ᜧ100mL,ᦑA┯3mol/L

10B.╅oḄhḄᱥḄ^05mol᪷ᵯឤHᡂḄNOᱥḄ^Q'15rn°lx2=0.1mol,ᑣᙠ᪗dOHᡂNOḄ\]^0.1molx22.4L/mol=2.24L,ᦑ3BC.╅oḄhḄᱥḄ^0.15mol,Ꮇᐰ^╅^015molx24g/mol=3.6g,ᐰ^^015molx64g/mol=9.6g,ᡠg/0Ḅ'(Ḅh(m)^3.6g3)=3n('(¦0.15molx§=0.4mol,ᦑDᦑᫀ^BD஺§ஹ¨⌱©⚪15.XஹYஹZஹJஹQ«¬ᕜ¯°±ᐗ³2´ᦪ¶·Jᜧ஺ᐗ³Zᙠᙢ¹&ᨬºJᐗ³Ḅᯚ⁐½¾ᕈÀ⁐QḄᨬ᜜ÂᵯᦪÃᐸᵯhᦪÅI^3u8,XÆÃJÇᡂÈᓄᔠᱥÉḄÊËᜧx-ḄÊËÌḄᓄᱥ5Çᡂ⏚ÍḄ°⌕ᱥÅ஺ÎÏu(1)Qᐗ³ᙠᕜ¯⊤&ḄÑÒ^஺(2)Ó«¬ᐗ³Ḅ2ÊËÔᜧᑮÕ᣸ᑡ᣸ᙠקḄᐗ³5(Øᐗ³ÙÚ)஺(3)ᐗ³Ḅ¨'(ឋuZ(ØᡈOᑡᔜ⚗&ßÆàáÓâãḄäåᨵ(Ø᪗Ú)஺A.QḄ~ᓄᱥḄæ+:çÒᙠèe&éêëìB.ZÃQÅíÇᡂḄᓄᔠᱥ&ᐗ³ḄᓄᔠîC.ZoQḄᓫḄ᝱D.ZoQᙠᕜ¯⊤&ḄÑÒ(4)XÃQᙠᩩòOÇᡂ᩽ßôḄ2õᦪI^1u1Ḅᓄᔠᱥöᓄᔠᱥᑖ&øᨵ᩽ឋùúᨵ¨᩽ឋùᑏüöᑖḄâ᪀£u஺(5)MoNᙳ^ÿ
ᐗḄᡂḄᓄᔠᱥMNᵯ஺MNᨵ!ᨵ"#$%ᑏMNḄᓄ'()*+஺ூ-ᫀ௃(1)1ᕜ31VIA4(2)N(3)জ.>ঝ.C(4)H—S—S—H(5)Na2s2O3+H2sO4=Na2sO4+SJ+SO2T+H2Oூ᪆௃ூᑖ᪆௃XஹYஹZஹJஹQ
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