2022-2023学年江西省抚州市高二上学期开学考试化学试卷及解析

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2024
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ᵨᑮAl-27Na-23C-12He-4Fe-56P-31Cu-64Zn-65S-320-16ஹ⌱⚪⚪ᐳ10⚪⚪3ᑖᐳ30ᑖ஺⚪ᨵ⌱⚗ᔠ⚪⌕஺Vl.VmLAL(SO4)3ᨵmgA13+,4mLᵨ4VmL,ᑣSOᱥḄ!125m125mA.mol-L1B.--------mol-L"36V9V125m125mC.mol-L_,D.mol-L-154V18Vூ#ᫀ௃Aூ&᪆௃mo.mூ(&௃mgA)ḄᱥḄ!n(A)*+,ᙠmol,᪷/2Ags஺1ᐵ3453mmVVmLSCV-ḄᱥḄ!n(SOF)==x—mol=—mol,mLᵨ227184m11ফ4VmL,8SO4”ᱥḄ!c(SO42-)Rmolx%_;<ᓃ⌱A஺4VX10-3L=36V2.ᙳᨵ@ᕜBᐗDWḄXஹYஹZFGᱥHḄIᓄᐵ3᝞KᡠM•OᑡQRSTUḄVA.WWXVY
ZᐗDB.XWXV[ᓄᱥC.YஹZ\HḄIᓄWXV[ᓄ]^_`

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ZᐗD᝞X!NaHCCh,Y!CO2,Z!Na2cChuW!vᐗDA⚗TUxB.XWXV[ᓄᱥ᝞X!AI2O3,Y!A12(SC>4)3,Z!NaAICh,B⚗TUxC.YஹZ\HḄIᓄ4!⏚ᡈSWXV[ᓄ]^_`C⚗┯xD.X!A1(OH)3uY!AL(SC)4)3,Z!NaAlCh,YeZᙠ_`WgᡂX,D⚗TUxᦑ#ᫀ!C஺3.OᑡQRTUḄVA.36gH2஺ḄᱥḄ!1molB.OImolCLḄV22.4LC.0.5mol«L'NaClᨵ0.5molNa+D.ImolCChᨵḄᑖᦪ!6.02x1023ூ#ᫀ௃Dூ&᪆௃ூ(&௃A.36gḄᱥḄ!n=,=2mol,ᦑA┯x1OVB.᪷/£¤OV22.4L/mol,ᡠ¦lmol§¨ḄSV22.4L,ᦑmB┯xC.᪷/n=c-Vm0.5mol-LTNaClḄª«SX¬®¯°ḄᱥḄᦑC┯xND.᪷/11=Mᔆ5N=II-NAᑣlmol[ᓄvᨵḄᑖᦪ!N=1X6.02X1()23,ᦑDTUxᦑ⌱D஺4.ᵨNA⊤M³´µ¶ᦪḄ·஺Oᑡ¸¹TUḄᨵজImolFeCb¾¿ᡂḄÀᨵNAÁFe(OHᾯÀÃঝ3.9gNa2C)2Æᡠ▢°ᦪ!0.05NAঞ᪗ÊËÌO46gÍ⏣ᨵNAÁᑖটO2gШᡠḄ^ᦪÑ!NAঠImolCbÓᐭÕḄᨬ×gᡂImolHClO

2@56gØÙ§¨ᙠÚᩩÜOᐙᑖ_`ᨬ×Þὑ§¨ḄV33.6Lঢ142gNa2s04eNa?HPO4ḄÆáᔠᱥᡠ▢ஹ□°Ḅäᦪ!3NAA.1ÁB.2ÁC.3ÁD.4Áூ#ᫀ௃Cூ&᪆௃ூᑖ᪆௃ூ(&௃জ1ÁFe(0H)3ÀÃV×Áå[ᓄØḄæçᦑᡠ5Ḅå[ᓄØÀÃÁᦪè¾NAÁᦑজ┯xঝ3.9gNa2O2ḄᱥḄ!n=3.9g4-78g/mol=0.05mol,<é[ᓄ¯ᵫ2Á¯°e1Áé[᪷᪀ᡂᦑ0.05molé[ᓄ¯▢°!0.05NAÁᦑঝTUxঞ46gÍ⏣ḄᱥḄ!46g+46g/mol=lmol,ᨵNAÁᑖᦑঞTUxট§¨ᵫ§^᪀ᡂᦑ2g§¨ᨵḄå^ḄᱥḄ!n=2g+4g/mol=0.5mol,ᓽ0.5NAÁᦑট┯xঠCLeḄ_`!W⌮_`SXîïðñᦑᡠ5HC10ḄᱥḄè¾Imol,ᦑঠ┯xড56gØḄᱥḄ!n=56g+56g/mol=lmol,e§¨_`Þὑ§¨!1.5moLó§¨ᡠᜐḄË᝱SöUᦑᐸᱥḄøR¬ᦑড┯xঢNa2seNa2HpehḄ᥅úᙳ!142g/mol,ᦑ142gNa2sO4eNazHPCUḄᱥḄ!n=142g+142g/mol=lmol,ûüὅᙳᵫ2Á¯°e1Á▢°᪀ᡂᦑImoláᔠᱥ°ᐳ3NAÁᦑঢTU஺ᦑ⌱Co5.Oᑡ°ÿ
ᵨᩭḄ⌱⚗Aᓄ⏚Fe(OH),+2H+=Fe2++2HO2ᔣᓄ╅!"#$%&'⏚╋BMg(OH)+2NH,=Mg2++2NHHO232#)*+-ᓄ'.⏚ឋ0═⏚2#3C3SO,+2MnO,+4H+=2Mn2++3SO^+2HO2⁐56ᑴ89%ᐭ;ᨵ=ᲩḄDCl+2NaOH=Cr+C10'+2Na++H022NaOH#$)#?⁐3@

3A.AB.BC.CD.DூCᫀ௃Bூ᪆௃ூG௃A.⏚ᐹᨵIᓄឋ)J5Fe?+ᓄᡂFe3+LMᡂNONO)PQ┯S)TU⚪W,B.ᓄ╅ḄXឋIY9)Z[“IXᑴ]X^ᳮ”)PQab)Uᔠ⚪W,C.⚪dḄᵯ₹Tgឤ)abḄi5SO+2MnO,+2HO=2Mn2++4H++5SO^,PQ┯S)TU⚪Wj22D.NaOHJឋIX)kᑏiNaᓱnOH)abḄiCl+2OH-=CP+cio-+HO,PQ┯S)TU⚪W,22ᦑ⌱B஺6.rsᩩuvḄᔠᡂYwjN,+3H,xy42NH3,vᑡ{|ᦪ~⊤ᔠᡂYḄw᳛)ᐸ$⊤Ḅw᳛Ḅ()0V(N)=0.03mol.E'.min1ঝv(NH3)=0.()9molL?mini2(3)v(H)=().()45mol«L'•min1(4)v(H)=().135mol«L'»min122A.জঝঞB.(D@C.জঝটD.ঝটூCᫀ௃Dூ᪆௃ூG௃᪷~rᓄw$)ᓄw᳛ᓄ$ᔜᱥḄᓄᦪ)J5Tᱥ⊤Ḅᓄw᳛ᓄirᱥ(᝞N?)⊤Ḅᓄw᳛)ᑣঝv(N2)=0.045mol•LminT,ঞy(N2)=0.()15mol•E'l•minT,টV(N)=().045mol-U1-min-1,ᦑD⚗ab஺2ᦑ⌱jD஺7.ᵬᧇᵯ᪀⌼W¢᝞v)ᐵ¤ᵯḄ¥¦TabḄA.ᵯ#$Na+ᔣb᩽¨©B.b᩽Ḅᵯ᩽wjO+2HO+4e=4OH22C.a᩽ª᩽)«Mᓄw

4D.ᵯ®᜜ᵯ°±bᵯ᩽³ᔣaᵯ᩽ூCᫀ௃Dூ᪆௃ூᑖ᪆௃®W¢J¶)aᵯ᩽iᧇᵯḄª᩽)bᵯ᩽iᵯa᩽)·ᵯ#iX#)LJᑏ¸ᵯ¹wiCH4+2O2+2NaOH=Na2CCh+3H2O,ª᩽wiCH4+IOOM-8e=CO2-+7HO,a᩽wi2஺2+8┐+4H2O8OH)32ூG௃A.^ᵯ$)ᵯ#Ḅ□ᔣa᩽¨©)ᡠÏÐᔣb᩽¨©)ᦑAab,B.b᩽ia᩽)ᵯ᩽wiO2+2H2O+4e=4OH,ᦑBab,C.a᩽ª᩽)ᵬᙠª᩽ᜫ@ᵯ)«Mᓄw)ᦑCab,D,ᵯ®᜜ᵯ°±aᵯ᩽³ᔣbᵯ᩽)ᦑD┯S,ᦑCᫀ⌱D«8.vᑡᱥḄÕÖᵫ0ᑮÙ᣸ᑡḄÛÜ@CH(CH)2CH3@CH3(CH)3CH@(CH)CHট(CH3)2CHCH2cH3322333A.টঞঝজB.©©জঞC.ঝটজঞD.ঝটঞজூCᫀ௃Cூ᪆௃ூG௃à^|ᦪTḄá)à^|ᦪâᜧ)ÕÖâ0)à^|ᦪḄá)äåâæ)ÕÖâÙ)ᑣ{çáḄÕÖᵫ0ᑮÙ᣸ᑡḄÛÜiঝটজঞ)ᦑ⌱C஺A.bḄᑖè᪀OéᨵdnpìçB.bஹdஹpḄ-8îᱥᙳéᨵðçC.bஹdஹpᙳJñ⏚ឋ0ò⏚2#wD.bஹdஹp$éᨵóḄᡠᨵ^ᜐrõ☢ூCᫀ௃Dூ᪆௃ூG௃A.bi÷)øḄᑖè᪀OJiùúá)ûJiåúü)᝞HCmC-CH=CH-CH=CH2,ᑣᑖè᪀OTþþdnpìç)ᦑA┯S;

51B.d
᝞,Ḅᱥᑖ1ஹ2,1ஹ3,1ஹ4,2ஹ3ᦑB┯C.bp⛳"#$%═⏚()*ᦑC┯D.dஹp+,ᨵ⛳".ᐹᨵᵬ1Ḅ2᪀ᱯ5ᑣdஹpᡠᨵ)8ᜐ:;<☢>ᨵ“<☢@2᪀ᦑDAB;ᦑ⌱Doio.EFGHIJ;K⊟ᱥMNᑺPEQFGHRSḄ,IJTᵨ)V┡ᑁYZ[Ḅ\⌕ᡂᑖ஺`ᑡᐵEFG"PEQFGḄcdABḄJA.ef+gᵫFGijkᡂ*lᑮB.efḄᑖ+),nC.EFGoᾦᨵqrḄstuᵨPEQFGḄᓄwឋyzq{|D.ef+8ijkᡂ*+8}⏚ឋ%═⏚(s~⁐ூᫀ௃Bூt᪆௃ூᑖ᪆௃ூt௃A..EQFGᵫFᯋijkᡂ*lᑮPEQFGJᵫEQFGijkP*lᑮᡠgὅ+)8ᵨFGijkᡂ*lᑮᦑA┯B.ὅ+>,C"ᓴᐗᡠgὅ+),nᦑBABC,PEQFG),..)⛳"ឋyqᡠgPEQFGᓄwឋy){|ᦑC┯D...)⛳"8ijkᡂ*8⏚ឋ%⏚(s~ᓄ}⏚ឋ%⏚(s~⁐EFG,ᨵ..)⛳"8ijkᡂ*8}⏚ឋ%⏚(s~⁐PEQFG),..)8ijkᡂ*ஹ)8}⏚ឋ%═⏚(s~⁐ᦑD┯ᦑᫀB஺ஹ⌱⚪⚪ᐳ4⚪⚪4ᑖᐳ16ᑖ஺⚪ᨵ;ᡈ⌱⚗¡ᔠ⚪£⌕¤ᐰ¦⌱l4ᑖ⌱§)ᐰḄl2ᑖᨵ⌱┯Ḅl0ᑖ஺11.`ᑡᔜ⚗ḄKᱥy)©gªKz«¬ᔠ>⌕¬ᔠᱥḄᱥyḄ®;ᑣ¯ᐰ°±²ὑOḄy®´ᢝ)¶ḄJ2A.C3H6ஹC4H6஺2B.C2H6ஹC2H6஺

6C.C2H2ஹC6H6D.C3H6஺ஹC4H8஺2ூᫀ௃Aூt᪆௃ூᑖ᪆௃>⌕¬ᔠᱥḄᱥyḄ®;¯ᐰ°±²ὑ02Ḅy®´ᢝ)¶ᑣImolᔜÅᑖ²ὑÆḄ®ÇÈÉt஺ூt௃A.C4H6஺2gᦋᑏC3H6*CO2,ImolCH6$ImolC4H6஺2ὑ®Ç,¡ᔠ3⚪ÎᦑAABB.C2H6஺zC2H6Ð10ImolC2H6$ImolC2H6஺ὑ®)Ç:)¡ᔠ⚪ÎᦑB┯C.C2H2ஹC6H6ᨬÓÔÇ:ImolC6H6Ḅὑ®ImolC2H2ὑ®Ḅ3Õ)¡ᔠ⚪ÎᦑC┯D.C3H6஺ᦋᑏC3H4•+0,C4H8஺2ᦋᑏc3H8•C02,zqImolC3H4ஹImolC3H8Ḅὑ®ὅcᦪ£Ç:§C3H8Hᦪ£qÐᦑὅᔜImolὑ®):)¡ᔠ⚪ÎᦑD┯ᦑ⌱Ao12.Ú¬ᔠÆÛᵫKÆ᝱°Åᡂ஺2.24LÞ¬ᔠÆÛ¯ᐰ°±ßlᑮ4.48Lᓄ.HÆÛàᢚâᡂ᪗äåæI"3.6gè஺ᑣéKÆÛ8JA.CHê"C3H8B.CH4"C3H4C.C2H^tlC3H4D.C2H4"C2H6ூᫀ௃Bூt᪆௃ூᑖ᪆௃ூt௃2.24LÞ¬ᔠÆÛᓽO.lmol¯ᐰ°±ßlᑮ4.48Lᓄ.HÆÛàᢚâᡂ᪗äåæI"3.6gè஺ᓽᓄ.ḄᱥyḄ®0.2mol,èḄᱥîḄ®0.2mol,ᑣ<ᙳᑖÔC2H4஺A.CH4"C3H8Ḅ<ᙳᑖÔnᦪ)8J4,A┯B.CE"C3H4ñᢥ1:1¬ᔠ<ᙳᑖÔC2H4,BABC.C2H4"C3H4¬ᔠÆÛ<ᙳᑖÔ.ᦪ)82,C┯D.C2H4"C2H6¬ᔠÆÛ<ᙳᑖÔnᦪ)8J4,D┯ᦑ⌱Bo13.ᙠ120࠷ஹlOlkPa`amLᵫnÆஹFGÅᡂḄ¬ᔠÆÛᙠbmLÆᐙᑖ°±ßឮüᑮýþ"ÿ
b>3a,2mL,ᑣḄ16bb
bஹA—mLB.—mLC.%a—&mLD.1688

7.b.(a-----)mL16ூ)ᫀ௃Cூ,᪆௃.ᓰூ0,௃᪷2345672H2+஺2^=2஺(8),CH+3O2CO+2HO(g)24222
C,H4ᐙᑖ=>ᓄ
ᦑ2LAH,BCm16ḄDEᩩGH
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᪷234ᓰ2H2+C)2=2H2O(g)Q
2mLRSᐰ34
1mL,⚪VᓰmL,ᡠXYὑḄRḄ2mL,ᦑC,H&Ḅ(a-P)mL,C1688[\⚪]^ᦑ⌱C஺14.100mL`aᔠ⏚d
C(HNC>3)0.3mol/L,c(H2soJ0.25mol/L஺ᔣᐸdiᐭ3.2gkl
mᐙᑖ34
nᶍpq>ᓄ
HᑡstPuḄAA.34pqdC(CF)0.45mol/LB.᪗wxyH
zᡂNOḄ448mLC.34d{|0.09molᵯ~D.34kᨵᒕ
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ᯠᨵᒕூ)ᫀ௃BDூ,᪆௃3.2gூᑖ᪆௃3.2gklḄᱥMḄNn(Cu)=j/\=0.05mol,aᔠpqdn(H+)=100mLxl(?64g/mol3L/mLx0.3mol/L+1OOmLx10_3L/mLx0.25mol/Lx2=0.08mol,n(NO^)=0.03mol,᪷23CU+8H++2NO>3CU2++2NOT+4HO,FT\
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᪗wxyH
zNOx2x22.4L/mol8

8=0.448L,ᓽz᪗wxyHNOḄ448mL,ᦑBPu^C.᪷2B⌱⚗ᑖ᪆
zᡂNOḄᱥMḄN0.02moLᓽ{|ᵯ~ᱥMḄN0.02molx5-2
=0.06mol,ᦑC┯;D.᪷2ᑖ᪆
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75.A

10ঝ|}⏀fgh7~A#᪵"ঞᐭᦪᑖ`rḄN?টᐵK1]K2ঠᐵKrᓃ7ᡭ[K,ডᡭ[K1(3)H#ᐭḄḄo(4)ᑡ$Ḅ஺A.IḄDCD9fߟb—a—d,e—cB.ᑴᜓᔠ⏚┲rMᐜᐭCO2,■ឋNᡂᱥU⏚C.᪷¡8¢7£⁐¥"^^!℉=3:1r7«ᑴḄ᪵"#$%La(OH)CC)3D.IIB#Ḅ@ᑺ¬⏚7:BḄ®6.ᡂIIḄḄ(5)¯°ᔠ⏚ᓄRU#,ᨔᦪx=(ᵨ%mrm,m4ḄU±⊤³7$2ᵨᓄ´)஺ூJᫀ௃(1)2LaCl+6NH+3CO+(x+3)HO=La(CO)-xHOI+6NHC1332223324(2)জ.ঠঝ.ঝঞ.ডট.ঞঠ.টড.জ(3)¸b>9¹᣸+ᑁ¥7■¥#CO2¼᡾;¸¾>9¹/#¿ᶇḄCO?ᐰÂ᣸ᐭC#Ãᔾᦈ7ÆÇÈ(4)BD326(m-m,)2---------------------H-Do(5)m-m,418ூÉ᪆௃ூË1ÌÉ௃ᵫ⚪#ÏLMᱥ9LaCbஹNH3ஹCO?ஹH0,ᑣLM#Nᡂᔠ⏚┲ḄᓄRST2U92LaCh+6NH3+3CO+(x+3)HO=La(CO)-xHOJ+6NHC12223324ᦑJᫀ2LaCl+6NH+3CO+(x+3)HO=La(CO)-xHOI+6NHC1332223324ூË2ÌÉ௃nḄᐹWXY9ᡭ[KÓK?]K3,ᦪᑖ`N?9¹᣸+ᑁḄ¥7■¥#¼᡾bঠᐵKjஹK3,ᡭ[K4bঝ|}⏀fgh7~A#᪵"bᰐd⏀fghbডᡭ[K1bঞᐭᦪᑖ`rḄN?9¹#¿ᶇḄCO2ᐰÂ᣸ᐭC#

11Ãᔾᦈ7ÆÇÈTটᐵK1]K2Tজvᓾᑮy
75.AᦑJᫀঠஹঝஹডஹঞஹটஹজூË3ÌÉ௃II#ᐭḄḄ¸b>9¹᣸+ᑁḄ¥7■¥#CO2¼᡾;¸¾>9¹/#¿ᶇḄCO2ᐰÂ᣸ᐭC#Ãᔾᦈ7ÆÇÈ஺ᦑJᫀ¸b>9¹᣸+ᑁḄ¥7■¥#CO2¼᡾;¸¾>9¹/#¿ᶇḄCO2ᐰÂ᣸ᐭC#Ãᔾᦈ7ÆÇÈ஺ூË4ÌÉ௃A.X9ÕÖ7ᵨᐸ◀Ù¾Úᓄ#ḄÛᓄÜ7YᑴÝÞ7ZᑴÝ⏚┲La2(CC>3)3,ᵫßÞ᩽᧕âß#7ᵨᳫä¼å4■᎔ᔾ7WᑴݾÚᓄW7ᡠIḄDCD9ffb—a—d,e-c,ᦑA஺B.ᑴᜓᔠ⏚┠rMᐜᐭNH3=ᐭCO27ᦑB┯Ç஺C.᪷¡La(CO)-XHOᓄRUÏ”ê2஺3)=n(CO)=1:3ᓽ£23322ìíîï=3:1r7«ᑴḄ᪵"#$%La(OH)CO3,ᦑC஺D.nB#Ḅ@ᑺ¬⏚ᵨßᔾᦈᑖÉNḄð7ᡠ$ñBḄ®6.ᡂnḄḄ7ᦑD┯Ç஺ᦑJᫀBDூË5ÌÉ௃᝞òᑴḄ᪵"#$%ᨵLa(OH)CO.„ᑣᵫLa?(CO?}XHOᓄRUÏ2nóLaO
^123᪷¡ôÏõö7nu-mi9÷((203)3,*ᐘ0Ḅù.7nu-mi9÷஺3ḄnCO
-32ù.7m“m39C02Ḅù.7B#ᨵ¬⏚7C#ᨵ0ᮞ7D#0ᮞḄmᵨ■¥#C02]û0FᐭᑮC#üý,ò7¸b>ᐭN2Ḅ᣸◀#Ḅ¥7■¥#C02¼᡾,ò7¸¾>ᐭN2/#¿ᶇḄC02ᐰÂ᣸ᐭC#Ãᔾᦈ7ÆÇÈ7n(LaO)=n[La(CO,)-xHO],þ+ᔠ⏚┠ᓄRU23232326óm-m,
2#,ᨔᦪm—ni|''4x=-------------!------------18326(012-mJᦑJᫀ18

1217.ᨵAஹBஹCஹDÿᨵᱥAஹBᱥCஹDḄᱥ஺AᑖᦪᨬᜧḄᨵᱥᑖ᪀☢BḄᳫ"#$CḄ%&ᑖ46,'(Na)*+,'(NaOH-)*.DḄ/0ᐙ2#$3ᔣ6ᱥḄ78-9:;<⁐>?8-8-@A⁐஺BCDEᑡG⚪.(1)AḄᵯI,C9J'KḄLM஺(2)BḄ᪀NI,6ᱥP;Q)*ḄᓄSTUI஺VᓄᑺACu/Ag,A(3)XYBZ[P᝞]^ᓄ_U.BfCfCH.CHO,`ᡂ^ᓄজஹঝ)*Ḅᓄজd஺®o2STUI.জ___________;ঝ<>HூDᫀ௃জ.HCHঝ.noCH=CHট.nCH,=CH,T*•2222VᓄᑺHA1CH?—CHz2ঠ.CHCHHOCHCHOHড.2=2+2A322CHCHOH+O-2cH3cHO+2HQ322Cu/Agூp᪆௃ூᑖ᪆௃AᑖᦪᨬᜧḄᨵᱥrᑖ᪀☢sAᵬu;BḄᳫ"#$,BvwCḄ%&ᑖ46,'(Na)*+,'(NaOH-)*ᑣCv⏣DḄ/0ᐙ2#$ᔣ6ᱥḄ78-9:;<⁐>?8-8-@A⁐ᑣDv⏚.{|ᑖ᪆sD஺Hூ}p௃(1)ᵫᑖ᪆ZYAᵬuᑣᵬuḄᵯICv⏣ᐸᨵḄJ'H

13HKnoᦑDᫀ.H.C.Hno••H(2)Bvwᐸ᪀NICH2=CH2ᐸP;Q)*ḄᱥQvwᓄSTUInCH,=CH,T-ECH—,ᦑDᫀ.CH=CHnCH,=CH,T222;2222VᓄᑺVᓄᑺ~ECHZ—CHz.(3)vw(7ᙠVᓄᑺsᵨ;ᩩEP;ᡂ)*ᡂv⏣ᑣACH=CH+HO-CH3cHlOHv⏣(ᙠsVᓄᑺ;ḄᩩEPVᓄ-92720Vᓄᑺ3-Aᓄ)*ᡂvᑣ2cH3cHlOH+O)->2CHCHO+2HO,ᦑDᫀ.39Cu/AgA&CH,=CH,+H,OTCH3cH,OH2cH3cH,OH+O,f2cH3cHe)+2H,0஺222Vᓄᑺ--Cu/Ag18.(1)᪷{⌕CDEᑡG⚪.CHa.Mb.0H2O2C.C2H6CdHi஺d.CH-C-CH"J.,,,,,CHvCIi-LHj-C11.CHCHCᓾ3HJeCH.-CH-CH-CHj1HCH3[ᔜᱥ9¡¢Ḅ£ᱥḄᑖ¤᪀ḄᱥḄ஺([2¦§)(2)⊤ᐗ¢ᕜ«⊤¬ᑖBᵨᓄSᵨ®CDEᑡG⚪஺ᕜஹIAIIAI1IA1\'\VIAVIIA02aঢ3জQ)ডত•4i.ᙠᐗ¢জঝঞ9²ឋᨬ´Ḅᐗ¢;ii.µ10ᐗ¢Ḅᨬ¶·ᓄᱥ&*Ḅ7ᓄᱥ9⏚ឋᨬ´Ḅᱥ.iii.Bᑏ¹ᐗ¢ঠঢ»ᡂḄ¼᩽ឋᓄᔠᱥḄᵯI.iv.¼²ឋᨬ´Ḅᐗ¢¿ᙠᐗ¢ᕜ«⊤9Ḅ¡À஺(3)ÁÂḄÃᱏᱏᵨÅÆÇÈÉÊᐭCuSO48-9ÌÀ᝞]ᡠÎ஺

14জ6ÌÀ9Ãᵯ᩽P______________)*஺ঝ)*¬ÏÐ0ᑁ8-ḄÒ;2Óᑣ6Ð0ᑁÔ_ÅÆḄᵯḄᱥḄmoLூDᫀ௃জ.aঝ.cঞ.d©.eঠ.K©.HC1Oঢ•.6=Cp6.4ণ.Fত.3èᕜ«3VBAìথ.ᓄ@4ூp᪆௃ூ}p௃(1)ᦪ%9ᦪ,Ḅ¬ᐗ¢»ᡂḄ,᪶¢¡¢ᑣ[ᔜᱥ9¡¢ḄðO᪷0,Dᫀ⌱a᪀%óᑖ%ôõö÷CH2øKḄᨵᱥ£ᱥC2H6C4HU)ᙳuᑣ£ᱥḄC2H6C4H10,Dᫀ⌱cᑖI%᪀,Ḅᓄᔠᱥᑖ¤᪀ᑖ¤᪀ḄC(CH3)4(CH3)2CHCH2cH3,Dᫀ⌱d᪀ឋ`ᐰ%ḄᱥᑣᱥḄCHCH3}ýH/H-CHDᫀ⌱eICH3(2)᪷ᐗᙠᕜ⊤ḄজথᑖNaஹKஹMgஹAlஹCஹSஹ0ஹFஹClஹSi,'I]i.,-./0ᑮ234ឋ⌲789:,ᕜ/;ᑮ<34ឋ⌲7=>:ᑣᙠᐗজঝঞ:34ឋᨬ9ḄᐗKCii.D34ឋE9:ᨬFGHI⏚Ḅ⏚ឋE9:ᑣ0K10MᐗḄᨬFGIᓄᱥ•QḄRᓄᱥ⏚ឋᨬ9ḄᱥSFT⏚:ᓄUVWHC104Ciii.ᐗঠঢ\ᡂḄD᩽ឋᓄᔠᱥCO2,ᵯbVWc6cᐸf6cCiv.,-./0ᑮ2D34ឋ⌲78>:,ᕜ/;ᑮ

15(1)¹⊤ºCH30HḄ»ᓄḄ¼஺(2)2ᑡ¾¿ÀÁÂFwQÃ᳛Ḅᨵ(ÆᵨÇÈÉÊË)஺a.ᓣFÍÎb.ᐭÑᓄᑺc.8ᜧÕ9d.×ᑖØÙCH30H(3)2ᑡÚKÁÛÜwQÝᑮÞ⊝à᝱Ḅ—(ÆᵨÇÈãÊË)஺a.C0äH2ḄåÎæᢝÀ»b.v(H)=2v(CO)2c.COḄᱥSḄᑖᦪæᢝÀ»d.¶ᘤᑁéê´ÎæᢝÀ»e.}vᡂImolCHQHḄ,ᨵ2moiH-Híîï(4)CH.QHð02ḄwQñᓄUÁòᓄWᵯÁ:ᐸ¨óôᳮ᝞¹ᡠº:¹CH30H/(ÊAᡈB)ᐭ:b᩽Ḅᵯ᩽wQV»e-ZKOHூûᫀ௃(1)b(2)d(3)ac(4)জ.A©.O2+4e+2HO=4OH'2ூ
᪆௃ூᑖ᪆௃(l)CH30Hᱥᜧ⊝ᱥḄCOᱥḄḄ!ᓄn(CO)%(2)᪷()*ᓄ+,᳛Ḅ./ᑖ᪆%(3)01ᑮ⊝3᝱5⌮,᳛78ᔜᱥḄ:;ᦋ!ᵫ>?@ḄABᱥᳮD:!%

16(4)CH30HE02ḄFGᓄ+HIᓄᵯHKᡂḄMᵯNᵬ⏣ᙠR᩽ᜫᵯUV@Wᓄ5᩽WXYᑮᵯUV@ZM஺ூ\]1^
௃CH30HᱥᱥḄᜧ⊝ᱥḄC0ᱥḄḄ!ᓄn(CO),⊤`COḄᱥḄ0~3s!ᓄ=0.02mol-0.007moi=0.013moLᡠbcd`eᨵbgᔠ.>i⚪5klᫀb%ூ\]2^
௃ᓣopஹᜧrstuᵨwᓄᑺyHuᓄ+,᳛ᜧzᑖ{|CKOH,u@ᡂᱥ}\⌮,᳛}\⊝5ᔣ5,᳛D}\.>i⚪5klᫀd%ூ\]3^
௃a.COtH2Ḅᢝ:!1ᑮ⊝3᝱ᦑa5k%b.,᳛8ᓄ+ᦪv(H2)=2v(CO)5,᳛ᦑb┯%c.ᑮ⊝Ḅ`COḄᱥḄḄᑖᦪᙠ:ᦋ!0COḄᱥḄᑖᦪᢝ:!1ᑮ⊝3᝱ᦑc5k%d.᪷(ឤᔠᱥ:!ᘤḄ¡:!ᑣᘤᑁᔠXḄ¤:!ᡠb:H(>ᑨᔲ1ᑮ⊝3᝱ᦑd┯%e.§@ᡂImolCH30H¨ᨵ2moiH-H©ªᙳ⊤¬5,᳛ᡠb:H(>ᑨᔲ1ᑮ⊝3᝱ᦑe┯஺.>i⚪5klᫀac%ூ\]4^
௃ᵯUᵫaᔣbaR᩽b5᩽CH30HE02ḄFGᓄ+HIᓄᵯHᵬ⏣ᜫᵯUV@WᓄᡠbCH30HA®B®ᐭWXbᵯ᩽V@Ḅᵯ᩽WXYᑮᵯU@ᡂ°W᪷{Uᵯ᩽±O+4e+2HO=4OH-,22.>i⚪5klᫀ±A%O2+4e+2H2O=4OH-»