2021-2022学年福建省漳州市高二（下）期末化学试卷（附答案详解）

《2021-2022学年福建省漳州市高二（下）期末化学试卷（附答案详解）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

2021-2022
ḕᓭ☜ᓄᔁ1.2020
ᡃᙠᢈ⚞!"#$%&'ᓄ(ᑗ*ᐵḄᡂ.஺ᑡ1234Ḅ5A.“8ᧅὅ;”ᡂ=ᙶ?@ABCD᜜Fᩞᧇᑭᵨ$KLMᔠOPQஹὊῖ⇨VឋXB.ᓅᧅ[;ᐰᳫ^_`abc3defDᐸ`aLhᱏḄj⌕ᡂᑖ5mᓄấC.pq5;^_stḄᨴvwx“yzX{”3He,3//e',HeD.“ᜩ”ᡠᵨᑮḄὊឋX5KLᨵᑖᩞᧇ2.9⊤ᦪḄ஺ᑡ12¡34Ḅ5A.22᝞஺2£▲஺Ḅ¥ᔠᱥxᨵḄ§ᦪ¨11N.B.᪗«¬D®2247nLs஺2´µ¶·ᑴᡂ100mL´ºDSO,HSO.HSO^,SOj-223»¼ᦪ½¾£0.01SC.᪗«¬D®2.24LÀÁ´µÂÃNaOH´ºDÆÇᵯᦪ0.1%D.84gÌÍÎxᨵᐳÐÑḄᦪ½¨12Ml3.ᑡᨵᐵÔÕḄÖ×Ød34Ḅ5A.Sn´µFeCb´ºÛSn4-Fe3+=Sn4++Fe2+B.[4gNH32]NO3´ºfᐭH2SÛ2Ag++H2s=4g2sI+2W+C.NH/SQ´ºᐭÂÃBaOH2´ºÛHSO1+Ba2++OH-=BaS0i4+H02D.Cr0D3sçᐭNaOH´º£è஺2ᑴNazCrQpÛ2CrOH+3HO+3224OH-=2CrOl-+8HO24.ëDᑡᔜíÖ¨Xᙠᢣ¨´ºᜧÃᐳðḄ5A.ñò⏍ôõ⁐Ḅ´ºÛNa+ஹK+ஹS2-,S஺÷-B.0.10øᔆ14a3´ºÛC1/2+ஹMg2+.S0ஹHCO^C.xO.lmo/௃TFe3+Ḅ´ºÛNQ+ஹCU2+,ᔆஹNO]D.ᵫ¶ᵯÖþÿḄcH+=ICT௃2oi.1Ḅ.ஹSOfஹHCO&ஹCl-7n5.℉᠄Ḅ"#$%&'ᨵ-*┐,-Ḅ./0“*┐,-”Ḅ3ᳮ544g+2H25+஺2=2X+2“2஺0:ᑡ<=>?Ḅ5A.XḄᓄBC4g2sB.*┐,-F0GHIHJᑮᵯMC.NOAgPH2sᙳ5R3ᑺD.UVᡂImolX,NO[\27nolᔆ6.᝞⊤ᡠb5᪷de,fgPhiᡠJjḄkl>?Ḅ5

1⌱⚗e,fge,hiklopᐭr⏚⏚ᓄḄBaC%At⁐vwxyzᨵS஺ᔆBopᐭKSCNᕈ⊈}⁐xyᨵ~”+Fe?+CoHᐭᮞᮞHxy5CO2xyᨵNa+ᨵDᵨ↾ᯚ⁐NOᯚᕈ⁐K+A.AB.BC.CD.D7.Z5ᔠᡂoᱥḄ0ᐸᔠᡂ3ᳮ᝞஺:ᑡ<>?Ḅ5()XZA.ᵨ4gN03␺¡XPZB.¢Xᐹᨵ¤¥¦§Ḅ¥ᑖ©᪀Rᨵ4«C.XᑖMᡠᨵ¬3Mᐳ®☢D.XஹYஹZ±¢Na2c஺3NO²j஺஺28.³´µ¶5ᓄ·⚪¹ᵨḄx«µ¶º0:ᑡᨵᐵNOº¼BḄ³´>?Ḅ5()A.½¾:ÀFepᐭC1ZSO4Fe+C“2+=Cu+Fe2+,³´:ÀNapᐭᑮCUSO42Na+Cu2+=Cu+2Na+B.½¾ÁÂ⏚¢Ba(0H)2NOÃឋ2H++S஺Å+Ba2++2஺஻-=BaS0I+2HO,³´NaHSO,¢Ba(0H)2NOÃឋ2H++S஺ᔆ+42Ba2++20H-=BaS0I+2HO420ÇÈC.½¾ÉPÊHNO2Fe+3cz2Ë2FeCG0³´ÉPỚᓫÎNO2Fe+"#3/—2Fe/23D.½¾ᔣCa(C/O)2ᐭÐÑCO2Ca2++2CIO-+C0+H0=CaCOI223+2HCIO,³´ᔣCa(C0O)2ᐭÐÑSO2Ca2++2CIO-+S0+H0=22CaSOI+2HCIO39.hᨵxÒᔠᱥḄ0zᨵ:ÓMḄÔ«:K+ஹNHÕஹCÖஹMg2+ஹBa2+ஹC஺᜛ஹ§஺Ḅ.hÙÚᔜ100mL᝞:e,ÜxÚpᐭAgNgᨵvwÝVÕÜËÚpÞÑNaOHpßà0ᦈ%ᑮ0.08mo1HÕÜÙÚpÞÑBaC%à0JᑮÅâvw12.54g,ãÞÑä⏚#åஹÅâà0vÜ2⚓0ᐳ19⚓

2wÎÑC4.66g.çèC:kl>?Ḅ5()A.ÒᔠxyzᨵK+ஹNHtஹC()rஹSOr(zCrén(K+)>O.OAmolB.ÒᔠxyzᨵNH+ஹ஺0êஹS01~,zK+ஹcrC.ÒᔠxyzᨵNH3COêஹS஺ë0zMg2+ஹK+ஹCl-D.ÒᔠxyzᨵNH(SOl~,zMg2+ஹK+ஹCl10.oᓄìᔆᐙᑖᑭᵨìïðHḄco>co,ÀÊñஹÊòìïPᵬ⏣ὶᔠVÝ02öÐ÷ø᛻úû0ᐹü¼᝞஺:ᑡýþ┯Ḅ()A.ḄnḄ◤ᵨ□ᣚB.ḄC2H4+2CuCl=CHCl+2CuCl2242C.ᙠὶᔠCuC%!"ᓄ$ᵨD.ᳮ&'(ᡂlmo/C/OH*+ᑮ1ឤ0.244஺211.0ᓄ1(HP)20ᓄ3(P%)4567ᜓ9ᵨḄ:ᦔ<=ᩔ?ᑺ஺(1)4P⍗B=CDEFP%CG,IḄJKLᱥḄᓄNO(2)PPᐹᨵSTUឋWXCaS04YZ[\IḄᓄN]O^CuS0+PH+H0=Cu3Pi432+H3P஺4+HSO.ᨵ0.4mo,ᵯ`abcdᓄḄP“3ḄᱥeḄf24______moL(3)ghᑴᜓPH3Ḅj᝞lᡠn஺
(P,,IL_⏚⏚“(NaHzPOz)ᵊ⏚জp0⏚rsᐗ⏚ᐸᓄNO஺ঝx02yzYZḄᓄN]O^Oঞ|!}bᨵlmo1X~ᑣ᦮ghjᐳᡂmolPH.312.᪷⚪⌕ᐵ⚪஺প[ᑴ240niL1.0mo1/LNa஺”᪗YZ஺᝞^1.0mo//ZJVaO”᪗YZ[ᑴ^gNaOHGᵨ=✂BᙠyYᓾ¡¢`a£¤y2¥ᴻ§2
3pP`aᑮ¨ᘤᨬ¢«¬¨஺|¨b®¯

3°±²ᑣᡠ[YZḄ³±;|¨b\¯°±²µ¶Z☢ᨬ¸ᜐX°±²\º»¼½¾᎔`᤯ᒴÂZ☢ᨵᡠÃᑣᡠ[YZḄ³±µÄÅᜧஹÅÈᡈÊ˺஺µ2ºÍᔠÎ⏚Ï[Fe2µ0Hº6_2nµS04ºn]mÜÝᵨsBḄÞᓄ஺FeS04-7/஺UᧇãYஹdᓄஹBÍᔠä*ᑴᜓÍᔠÎ⏚Ï஺জåKfḄFes஺4•7%஺YséÎ⏚ᙠê70࠷ìᤅîìï᠒ᐭKfḄ஺2YZòóKôbõ+ᑮö÷⁐ùúZG஺“2஺2dᓄFe2+Ḅ]O;BÍᔠDýþYZḄpH஺ঝᔠ⏚᪵Ḅᑖᦪ᝱᪵3.000g,250mL┵%&'(ᐭ〉+,⏚'(-'.(/0ḄSnCG56SM+9Fe3+<=>/=>2+B,ᐙᑖDEF'◀H0ḄSM+஺ᵨ5.000x10-2^011-1X23075.QRS6.0T5஺UV2+DEWᡂCN+Z[3+B,\ὑ^_2஺7520.00mL.`abcde◀H0Ḅ5f+,᪵ᐗhḄᑖᦪḄij96k“mᜧ”ᡈ“mf”ᡈ“qrs”Btu᪵ᐗhḄᑖᦪ>஺13.vfwᑭᵨyzVNaOHᑴNaClOᐸឋজ4925஺4⁐'5஺ঝᙠ'3+Ḅᙠ%ᨵ6“2஺B4஺"B2]+ᕈ⁐ᙢ6“2஺B6ᕈ⁐'¡¢£ᑮq⁐஺¥ᑴᜓ61B4DEḄ§¨©Tªo62B¬®¯F,NaOH°ᐰDE'²A5pH=10,ᵨᓄ¶ᵨ·⊤¹ᐸ=º¥.ឋᡠ²A55mL¼½'ᔣᐸ(ᐭ/0Ḅ0.1mo//LFeSO45Z〉“25஺45'¢£ᑮq¿ÀW'5Á>⁐஺63BᵬöÄ5Á⁐Å¡ÆWḄDEÇÈᑡÊËÌÍÌÍ12Fe2++CIO-+2H+=2Fe3++Cl~+H02ÌÍ22Fe2++2CIO-+4H+=2Fe3++ClT+2HO22ÌÍ3CT+CIO-+2H+=ClT+H022ÏöÐ>ÌÍ2Z3eᔠᳮ'ᵨ§¨©T⊤¹=º஺ÒÓb'ÌÍ1Ô஺¥.Õ¬ÖII⁐5'ᑖ>4Ø'ÕÙÈᑡÚÛ.Ü4⚓'ᐳ19⚓

4äåÚÛâãi(ᐭNaOH5—ii(ᐭçgN35⁐¿Àiii(ᐭNai5'è(ᐭ¬CC஻'ê₩Èìᕈí⁐iv(ᐭ¬//25஺45⁐Áïðñq⁐(4)bciḄâãª஺(5)bcii(ᐭ4gN03â⁐¿À'e¡òó5ᙠCô'=ºªo(6)õᧇ⊤ó'÷ᓄឋClO->Br>Fe3+>I.ᵬöÐ>ᵫbciiiḄâãÓó225ùᙠa஺-஺ÏöÐ>ᵬöḄúûeüý'þÿ
ᔲᙠQ஺-Ḅᫀ஺(7)iv⁐⁐!"ᔠᓄ%ᵨ'()*+_____஺ᜐᳮ|■~NaOHA14.0(C஺)234◤Ḅ67ᐗ9!:0ᓄᔠᱥᙠ<=ᑴ⌼ஹAឋᩞᧇE⚞GᐹᨵJKḄLᵨ!MNO⌕ḄᡊᶍST஺UVWᑡY⚪(1)Wᑡ[᝱ḄCo6^!ᵯ`ᨬ᜜cMdᵯeᡠ◤
7ᨬᜧḄ(h᪗j)஺A.[Ar]3d74s2B.[Ar]3d74slC.[Ar]3d74sl4PlD.[/lr]3d74p1(2)CoyCa{|}Mᕜ!ᨬ᜜cᵯeᦪE!ᓫC஺ḄᰚஹᙳᓫCa!*+o(3)C0ᔠᱥ[CO(N!3)5]G2⁐3!1஺஺5"3)5]”:ᨵḄ஺ᦪ,N%ᑖey<7஺3+¢ᡂᔠᱥ¤4-N-H¦(h“ᜧ”“¨”ᡈ“ª”)஺(4)Coᔠᱥ[Co(N3)(NH3)51SO4{3N3Ḅ¬᪀¯஺°ᓄ%±✌³ᡂ´ᑴµ:ᐰ·▢`e(Ag)ḄSTºCo(M)¼஺)4•4%஺!¾MNᔠᱥᑖe!஺஺35)2(!2஺)4Ḅ"᪀¼᝞ÀᡠÁ஺ÂSTºªᙠḄ6^ÃᵨÄᨵ(h᪗j)஺

5•-0•MCoa.o■b.7i■c.`ed.Æe.ST2ÈÉÄ(5)ᓄ%±ÊËᐹᨵÌÍឋḄCo஺2ᨔ3!ᐸc["᪀᝞ÀᡠÁ஺WᑡᵨÐÑÒÓḄOÔ"᪀ᓫᐗÁÕÀª
Ö×ᐸᓄ%ØᡂḄ(h᪗j)஺A.(B.15.ᾙ᪺ÛÜ(/)ᢙÞ߯à[áâḄãᙠᵨä!ᐸᔠᡂåÑ᝞W:CHjCHjBrHQ/NᔩH2CHOHCNJTH,CHCOOH0AUVWᑡY⚪:(1)ᾙ᪺ÛÜ(/)
èéḄêëᓄìí⁐+ᑖe:ᨵ(hᑏï
ðñ6⚓!ᐳ19⚓

6ôõ)஺(2)8-CḄöL÷¯,EḄ"᪀ø¼.(3)G-HöLḄᓄ%ù¼஺(4)ᓄᔠᱥYyDú}ᑖû᪀3!üýWᑡᩩÿজঝNaOHImolYᨬὑ3molNaOHঞ᪶ᐳᨵ4!!☢#$%&1126஺ᑣYḄ*᪀,-&(0ᑏ23)஺(5)᪷6789:;Ḅ<ᐵ>?@ABC&DᧇᔠᡂᓝᐳIḄ9:

7JᫀL᪆1.ூJᫀ௃Aூ᪆௃4QᔠRSTUஹὊῖ⇨〉ᔠᵨ\ᑴ⌼_‷᜜bᩞᧇᦑAefB.ᨔhấ&jkḄlmhᩞᧇnᑴ⌼oᱏq⌕DᧇstᓄấvᐹᨵxឋzᦑB┯|C.3He,3"e"He}&~ᦑC┯|D.ᡂᑖ&ᔠRvnᨵUᑖᩞᧇᦑD┯|ᦑ⌱AoA.QᔠRSTUஹὊῖ⇨B.ᨔhấ&jkḄlmhᩞᧇC.zᦪ<~ஹ;ᦪv~Ḅ᪶}&~D.ᡂᑖ&ᔠR஺⚪ὃᱥzḄឋzᵨ⌶&U⚣ὃᱥzḄឋzஹឋzᵨ⌶&JḄᐵᑖ᪆ᵨḄὃᐗᓄᔠᱥ>?Ḅᵨ⚪Tvᜧ஺2.ூJᫀ௃Dூ᪆௃422gC0zLN2஺ḄᔠᱥḄᱥzḄ&%=0.5mol,£ᨵzḄᱥzḄ&0.5mo/X22=llnwl,£ᨵḄzᦪ2¤&11¥ᦑAefB.᪗§¨©ª224mLs஺2ḄᱥzḄ&°^,=O.Olmol,S஺2\±²ᑖ2240ᡂ³´⏚,²ᑖ¶ᯠBSQᑖ¸-¹ᙠ»6´DCᦪ¼ឤ>,S0ஹH2sO3ஹ2HSO3-S஺¾¿3Àᦪ$L&0.01MᦑBefC.᪗§¨©ª2.24LÁÂḄᱥzḄ&=0.1mol,0.1m4ÁÂ\ÃNaOH;ÄÅÆ0.1m஺/ᵯÄÅᵯᦪ&0.1ÉᦑCefD.84gÊËÌḄᱥzḄ&Í₹=lmol,ImolÊËÌ;£ᨵᐳÏḄᱥzḄ&lmo/x(6+12)=18mo/,£ᨵᐳÏḄᦪ2¤&18N”ᦑD┯|ᦑ⌱D஺ACO?L2஺ḄḄ᥅ÑzÒn44g/mosὅᑖ;Ò£ᨵ22CzB.stᓄ´\²ᑖᡂ³´⏚²ᑖ¶ᯠBstᓄ´ᑖ¸-¹ᙠC.ÁÂtᓄÔḄ;ÁÂÕntᓄᑺ×nØDᑺD.ÊËÌ;£6CÙÙᓫL12CC-H஺⚪ὃÛÜÝÞßàᦪḄᨵᐵAáLᑨã⚪TvᜧäkBᱥzḄ&;åḄᔜᓄçÛÜÝÞßàᦪḄᐵèéfᑖஹDஹD᪶ᑁz;᪶᜜ᵯḄ᪀ᡂᐵèë⚪ὃçḄᑖ᪆ᓄçAá஺ì8⚓ᐳ19⚓

83.ூJᫀ௃Dூ᪆௃4Sn\Fe%îïð-Sn+4Fe3+=Sn4++4Fe2+,ᦑA┯|B.MglN/RN%;ñᐭ“25îïð-2Hg(N“3)2]++4H2s+2N஺*=Ag2sI+4N“3T+2N0T+3SI+4HO,ᦑB┯|2C.N/HSO,;ÝᐭÃBa(0H)2ᡂ´⏚ஹ2ᔠôLefḄîïð-&H++S01-+NHt+Ba2++20H-=BaS0+NH-H0+H0,ᦑC┯4322|D.Cr(0H)3(s);~ÝᐭNaOHL2஺2ᑴNazCrO,îïð-2Cr(OH)3+3HO+40H~=2CrOl~+8W0,ᦑDef஺222ᦑ⌱D஺A.ᵯ₹v¼ឤB.[ag(N“3)2]N03;v¹ᙠîC.õᣵ÷᪷ît᪷îḄD.øឋÊ᛻ªútᓄûtᓄtᓄüᡂü⏚᪷î஺⚪ὃîïð-Ḅýᑏᑨã⚪T;þéfÿ
ᐵḄᑏᑣ⚪ὃḄᑖ᪆!"⚪஺4.ூᫀ௃Aூ᪆௃*4+,-./⁐Ḅ12ᕈ4ឋNa+ஹK+ஹ52-ஹsof\஺789:;<=ᜧ?ᐳAᦑACDEB.Al3\C/+FGHCO];<:ᜧ?ᐳAᦑB┯IEC.Fe3+ஹᔆ89KLᓄN;<:ᜧ?ᐳAᦑC┯IED.OᵯQḄc(H+)=10-12m0(.ᔆ1Ḅ12ᕈ⏚ឋᡈ4ឋNH}HCO3FG஺T;<”+ஹHC஺189K;<:ᜧ?ᐳAᦑD┯IEᦑ⌱*A»A.X12ᕈ4ឋYZ89:;<F:G[L᪷;

9ூ᪆௃*4ᵫ?{ឤ}~XḄᓄ
ᦑACDEB.;

10ᡂ±Lᓄ`ᦑD┯IEᦑ⌱*BoA.XT:mÉᵫÊḄÖ*B.XḄÑᑖÒ᪀·mᨵÔÕÖ×Ø»⏚T[ÖÙÚᡠÜÝᔠᩩsḄÑᑖÒ᪀·ḄZÞGö⏚Ḅ÷ÕT[ZÞ×ÑEC.⛳`ᐹᨵᵬìí᪀ᱯiED.-COOHNaze%12;<ᡂCO2஺d⚪ὃᨵøᱥḄí᪀ឋὃÕẠÇḄᮣûüᵨjDýþ!ᐸឋḄᐵÿ
⚪ᐵ⚪ᜧ஺8.ூᫀ௃Bூ
᪆௃
4Naᢗᐭ⏚ᐜ!ᡂNaOH,NaOH#CuSᑁ%!&ᑖ
ᑣ)Na*ᐭCUSO4+,-./02Na+2H2஺+C/+=/T+2Na++Cu(0”)21,ᦑA┯45B..6⏚7Ba(0H)28ឋ:;ὅḄᱥ?Ḅ@AB0161,+,-./02H++SO42-+Ba2++20H-=BaS0i+2//O8NaHSO,7Ba(0H)2842ឋ:;ὅḄᱥ?Ḅ@AB0261,+,-./02H++S06-+8a2++20H-=BaS0I+2HO,ᦑBCD542C.EFḄGᓄឋIJỚᓫ?MEF:EFN)MGᓄ0+3OᓄP-./
0296+3஺2Q29603RỚᓫ?SN)MGᓄ0+2OᓄP-./0Fe+
—Fel>ᦑC┯452D.U@SO2VᐭCa(CO)2!ᡂEᓄ┛ஹ⏚┛ஹYE⏚CDḄ+,-./0S0+3CIO~+H0+Ca2+=CaS0X+Cl-+2HCIO,ᦑD┯45224ᦑ⌱B«A.Naᢗᐭ⏚ᐜ!ᡂNaOH,NaOH#CUSO4%!&ᑖ
5B.6⏚78[0”)28ឋ:;ὅḄᱥ?Ḅ@AB01618NaHSQj7Ba(0H)28ឋ:;ὅḄᱥ?Ḅ@AB02618C.ỚḄGᓄឋ\]SN)MGᓄ0+2OD.QGᓄ^QGᓄᙳNYE⏚┛.QGᓄᐹᨵbcឋdYE⏚Gᓄ0⏚஺⚪ὃfg+,-./ḄhᑏjDk?l+,-./hᑏ-m
⚪ᐵno+,⍳qrstkஹ⍳qc,uᦪஹᵯ₹ᦪyឤ{|noᱥᵨ@~Ḅ⚪ᜧ஺9.ூᫀ௃A

11ூ
᪆௃
*ᐭZgN03,ᨵ!jNᙠCஹ஺஺ᡭஹS*8Q:*@NaOH*!ᡂḄ0.08஺F0FᑣᨵNH6ᱥ?Ḅ@00.08mo18:᪷⚪4.660⏚,“BaSQO==ᑴ=0.02mo/;12.54g0⏚^⏚ᡠ£^⏚Ḅᱥ?Ḅ@0¤5¥¦=0.04m48#᪷ᵯ₹yឤCᵯ₹0n(+)=n(NHj)=0.08m஺5n(-)=2n(C0f-)4-2n(SO1-)=0.12mol,ᦑᨵK+,8U0.04mo18᪷£§ᑖ᪆ᙠK+ஹNH7ஹCOgஹSO8¨NᨵC©ᙠE+,ª+,Ḅᱥ?Ḅ@ᜧJ0.047HO/8©ᙠE+,ª+,Ḅᱥ?Ḅ@00.04m஺/,ᡠ£ACDᦑ⌱4*ᐭ4gN3ᨵ!jNᙠCrஹCO8ஹSO¬5Q*@NaOH*!ᡂḄ0.08molF0FᨵNHj,ᱥ?Ḅ@00.08mo/8N®7Eᓄ!ᡂ¯⁐Ḅ0^⏚᪷+,ᡈ⏚᪷+,᪷⚪4.66g0⏚12.54g0⏚^⏚⚞³´µ¶^⏚᪷+,⏚᪷+,Ḅᱥ?Ḅ@5#᪷ᵯ₹yឤ·¶ᔲᙠª+,.⚪ὃfg¹º▢ஹ□+,Ḅ½¾-m⚪¿À⚪Álᑮ᪷ᵯ₹yឤÃÄ+,ḄᙠnoÅÆÇȹº+,Ḅ½¾-mÀ⚪ÉÊgP!ᮣÌᵨᡠPÍḄNÎ.10.ூᫀ௃Dூ
᪆௃
4Ï.II0ᵯ
⛳ÑÒᵫJC%ஹÔÕᔠ᧕%!ᰦÙ!ᡂHC1,C%NaOH᧕%!!ᡂNaClONaCl,ᡠ£0ÚUÛḄ%!Ï.HḄÜÝ◤ßᵨ□+,àᣚâ)□᩽!ᡂḄC27▢᩽!ᡂḄ"2ஹNaOH◞åᦑACD59ᑺB.æç.èÏ.éêëḄEᓄ0C2H4+2CuCl—CHCl+2CuCl,2242ᦑBCD5C.æç.èIIIéEᓄᙠὶᔠ!Ï.íᑮîᓄᑺðᵨᦑCCD5D.Ï.IILIVñ0C2H4+Cl=CHCl,!ᡂlmo/C2H452òὑ1ô஺õ2,2cᔆ+2242<ᵯ2HO—2OH-+HT+ClT,!ᡂImoN"ø:!ᡂ16஺¶2,Ô7ùFCOஹC”222>ᓄ@Aᓄᑺ!ᡂC%஺”Ḅ0஺஺+2/QCO+3H—CHOH+H0,ᑣ·ᑮ2232Imo%"4c'G·ᑮC“3஺”Ḅᱥ?Ḅ@01
\tnol

12Ꮷᓄ@COஹ஺஺2ᡂC%஺"CO+2“2'-C/஺"ஹC0+2A4≎3H—CHOH+H0iniCaC2ḄC2+2CUC=2CIZC2,IV232XftfPJ'(Ḅ)ᓄC2H4+2CuCl—CHCl+2CuCl,-.ᑖ᪆12஺22423⚪ὃ67ᓄ89:;Ḅᳮ1ᵨ>⚪?ᡠABCDᓄᓄ8EFG᧕ᑖ᪆IJ>KLᵨᓄ8⊤NOᩭ,QRBCḄᑖ᪆ᑨT,⚪?UVW஺11.ூ2ᫀ௃4(0H)324111283240.05-HPOP+3NaOH+3H0=PHT32423+3NaHPO2.522ூ1᪆௃1d(1)4P⍗ᑮhijklmOP“3jnoᔠqrsឤIuᓄ8dAIP+3HO=Al(OH)+PHT,Iuvwx;ᱥḄᓄ84(OH)3233ᦑ2ᫀd4(஺“)3{(2)Cuᐗ~ᓄᔠᵫ+2+1,Pᐗ~ᓄᔠᵫ-3ᓣ+5ᡂ1LCu3Pᐳ3ᡂ1Lᨴ3஺஺4ᐳᓣ8ᦑC”3PḄᦪ8,”3஺஺4Ḅᦪ3EḄd24஺஺4+IIP/+12஺=8Cn3P1+3HPO+24HSO3424iᨵ0.4m஺/ᵯrlDᓄḄP%ḄᱥḄ0.05mo/,ᦑ2ᫀd24{11{12{8{3{24{0.05{(3)জNaOHᡂNa/POzKL஺2ᑖr¡¢ᵯ£OwLH+,¤⏚wᐗ⏚{ᐸᓄ8“3஺2ᦑ2ᫀdw{HPOF32ঝ᪷-©NIuª«¬®ᡂ¤⏚¯ªP%‖+3NaOH+3HO=PHT+3NaHPO,2322ᦑ2ᫀdP+3NaOH+3H2஺=PHT+3NaHPOF4322ঞᵫP4+3NaOH+3H2஺=PH3T+3NaHPO^^2HPO=PHT+HPOnJ2232334ulm஺³´ᐜᡂPH31mozª3mo/NaH2PO23mozNa/P஺2¶ᡂ3moi¤⏚3moi¤⏚ᑖ1ᡂ1.5moP“3ᑣᐳᡂP/ZSm஺ᦑ2ᫀd2.5஺(1)4P⍗ᑮhijklmOP“3jnoᔠqrsឤIuvwx;ᱥ{(2)Caᐗ~ᓄᔠᵫ+2+1,Pᐗ~ᓄᔠᵫ-3ᓣ+5ᡂ1LCu3Pᐳ3ᡂ1L/PQiᐳᓣ8ᦑCu3PḄᦪ8,Ḅᦪ3;(3)জNaOHᡂNa஺2KL/P"ᑖr¡¢ᵯ£OwL“ᓝ¤⏚wᐗ⏚{ঝ᪷-©NIuª«¬®ᡂ¤⏚¯ªP%{ঞᵫP4+3NaOH+3“2஺=P3T+3NaHPO^n^2HPO=PHT+H3P0,G22323u160½4´lmol^3molNaHPO3molNaHPOy.±)&3mol2222¤⏚3moi¤⏚ᑖ1ᡂ1.5m஺¾/-.¿À஺

133⚪ὃ6ᱥḄᑴᜓÃÄ⚣ὃÆÇÈᱥḄឋஹᑴᜓqᳮஹÃÄÊËḄÌᵨஹÃÄᢈ¢12ᐵÏÐÑᑖ᪆ÃÄ¢ÒḄὃ6⚪?UVÓᜧ஺12.ூ2ᫀ௃10.0250mLGÕÖᜧÓ×2Fe2++HO+2H+=2Fe3++2WOM222ØÖᜧ11.2%ூ1᪆௃1d(1)ÃÄÙÚᨵ240mLGÕᑴ240mLi.0mo/LNa஺᪗Ü®Ý⌱ß250mLGÕᑣn(NaOH)=eV=0.25Lx1.0mol/L=0.25mol,m(NaOH)=nM=0.25mo/x40g/mol=10.05,ᓽáâNaOHãnḄ10.0g,ᑴdᵨiähᙠ«æ1NaOHãnçᓾéÙêEDé250mLGÕëì«æªíᴻï2
3¤DᑮGÕᨬEñòóGôóGõö÷Vøᑣᡠ®ḄnùVÖØúVÖᜧôóGö÷VøûüÕý᎔D᤯ᒴ
☢ᨵᡠ
ᑣᡠḄ
ᦑᫀ10.0;250mLᜧ;(2)জ⏚ឋᩩ!
“2஺2#ᓄFe2+%ᡂ/e3+)஺
*+Ḅ,-./02■2++HO+2H+=2Fe3++2HO$Fe3+12345c(஻+)8ᜧ
ᑣḄpH9:
222ᦑᫀ2/^2++”2஺2+2+=2;03++2<஺9:ঝSn2+ᐹᨵ>?ឋ
@A/(>2஺7#ᓄ
BC2(>2஺7Dὑᜧ
ᑣ᪵G5HḄIᑖᦪḄLMNOPᜧ:Q2஺7R⊈2+*+Ḅ./0Q2஺>+6Fe2++14H+=2Cr3++6Fe3++7HO,FeVឤᨵFe?+
Fe3+,ᑣᐵY0C^Oᡭ
6Fe3+,2n(Fe3+)=6n(\]2஺7)=6x5.000x10-2mol-L-lx0.02L=6.000x10-3mol,m(Fe)=nM=6.000X10~3molx56g/mol=0.3360g,᪵G5Feᐗ_IᑖᦪFeᐗKḄMNx100%=100%=11.2%,᪵PḄQMNᜧ11.2%஺(1)ᑴ240mL1.0mo//LNaOH᪗b+c⌱e250mL
᪷gn(NaOH)=eV)m(NaOH)=nMhijḄNaOHI
ᑴḄklhiஹjஹ2ஹnᓾஹpஹqrஹMஹ᤯ᒴஹtu᪗v᪷gc=1ᑖ᪆xyz{(2)জ⏚ឋᩩ!
஺2#ᓄ|2+%ᡂFe3+)/O,Nᔠᵯ-Vឤஹᵯ₹Vឤᑏ*+Ḅ,-./0Fe3+12345c(H+)8ᜧঝSn2+ᐹᨵ>?ឋ
@Aᓰ(>2஺7#ᓄ
34(>2஺7Dὑᜧᓰ(>2஺7RFe?+*+Ḅ,-./0Q2஺>+6Fe2++14"+=2Cr3++6Fe3++7HO,᪷gFe2?-VឤᑮᐵY0জ஺>
6Fe3+,n(Fe3+)=6n(/CCrO7)'Nᔠm=nMhi22Hᐗ_ḄIIᑖᦪ஺⚪ὃMᱥIḄḄᑴஹᱥILM
ᑴḄxyz{ᑖ᪆.ஹᱥIḄឋI*+ஹ#ᓄ>?*+./0Ḅᑏ2⚪ᐵ
ᑖ᪆@ஹhi@Rxy@Ḅὃ
¡ᐵY0Ḅhi+ᵨ
⚪£¤5஺¥14⚓
ᐳ19⚓

1413.ூᫀ௃+20W=cr+CIO-+HOCIO-+HO^HCIO+0H-Cl+2Fe2+=2222Fe3++2Cl-«%¬⋎⁐¯°«%¬⋎⁐¯°±⁐5²ᙠS஺-,R4g+*+%ᡂ4925஺4¶⁐¯°·II5±⁐¸¹º5
»ᐭNaBr
½»ᐭMCCI4
¾₩
☟Á
ᑖÂ
ÃÂᕈŬ⁐
ÆDzᙠS஺-±⁐5Fe3+Ḅ²ᙠÉ0[/=>(“2஺)4(஺“)2]+Ë»H+[/=>(2஺)4(஺“)2]++2"+=Í6(“2஺)6]3+ᔣÏpÐ
ÑÒ±⁐Óூ2᪆௃2(1)45ÔÕRNaOHᑴ·NaClO,,-./0Cl+20H-=Cl-+2CIO-+H0,2ᦑᫀCl+20H-=Cl-+CIO-+H0F22(2)Ö×ØÙ
NaOHÚÛᐰ*+
5C஺-%12BᕈÝឋ
,-./0CICT+H2OWHCIO+0H7ᦑᫀCC+MOUHCIO+OH-F(3)±⁐Ḅ?ÑFe2+ÞᓄFe3+,Ã5²ᙠC%C%<@#ᓄ2+,ßà2)3ᔠᳮ
,-./0Cl+2Fe2+=2Fe3++2Cl-i2ᦑᫀCl+2Fe2+=2Fe3++2Cl-F2(4)±⁐5²ᙠFe3+,»ᐭNaOH%ᡂâ#ᓄH¬⋎⁐¯°
ᦑᫀ«%¬⋎⁐¯°(5)ã,-@Rä⏚᪷ஹå⏚᪷ஹâ#᪷ஹÔ,-%ᡂ¶⁐¯°
c±⁐5ᨵå⏚᪷
ᦑ5»ᐭ4gN03
%ᡂ4925஺4¶⁐¯°
@æÇ?5ᨵCç
ᦑᫀ±⁐5²ᙠSO61R2g+*+%ᡂ45஺4¶⁐¯°(6)#ᓄឋClO->Br,Cl஺-èéPBL#ᓄ8ê
·II5±⁐¸¹º5
»ᐭ2NaBr
½»ᐭMCC஻
¾₩
☟Á
ᑖÂ
ÃÂᕈŬ⁐
ÆDzᙠSOIᦑᫀ·H5±⁐¸¹º5
»ᐭNaBr
½»ᐭM
¾₩
☟Á
ᑖÂ
ÃÂᕈŬ⁐
ÆDzᙠc/஺-(7)±⁐5Fe3+Ḅ²ᙠÉ0[;6(“2஺)4(஺“)2]+Ë»H+ᵪ6(“2஺)4(஺“)2]++2"+=2("2஺)6]3+ᔣÏpÐ
ÑÒ±⁐Ó
ᦑᫀ±⁐5Fe3+Ḅ²ᙠÉ0[Fe(H20)4(0H)21+Ë»“ᓝ
[Fe(HO)(OH)]++2"+=▬(<஺)6]3+ᔣÏpÐ
ÑÒ±⁐Ó஺242(1)ÔÕRNaOH*+%ᡂNaClஹNaClO8(2)NaC1஺ðÝñ⏚ò
12óÝឋ(3)*3+ó±⁐
Ã5²ᙠC%èé2+#ᓄFe3+8(4)Fe3+)0/T*+%ᡂâ#ᓄH¬⋎⁐¯°(5)ã,-@Rå⏚᪷*+%ᡂ45஺4¶⁐¯°(6)#ᓄឋCIO->Ba(C஺-èéP8ᔆ#ᓄB72,õö⃓·øyùḄ²ᙠ(7)᪷g;6(“2஺)4(0")2]++2"+:[;6(“2஺)6]3+»ᐭâ,-
û34*+ᔣÏpÐ
ÑÒ±⁐Ó஺

15⚪ᱥIឋIxy.ᫀḄüh
ὃýþ%ᨵᐵ#ᓄ>?*+
ᱥIᑖ,ÿ

ᑁ
ὃ
஺14.ூᫀ௃BC஺!ᓫ#$%ᑁ&ᵫᵯᦪ*+
ᡠ-ᓄ/0ᜧ
2340521T6ᜧ789ceDூ:᪆௃:<(1)⌕ᵯᨬ᜜@ABᵯAᡠ◤DEFABᡠ◤DEF12,/2MG
CஹDFIJ᝱
ᡠ◤DE0L
ᦑᫀF

16£¤¥¦ᱥN᪀kឋN:⚪Ḅᐵ4஺15.ூᫀ௃««¬4ᓄ®¯^^>-CH=CHCOOHூ:᪆௃:<(1)ᾙ᪺¹º(/)Wᨵ««¬4
Dk¼J½¾ᡂ®¯
¿À¼ḄÁÂᓄ«ÃÄÅ⁐
ᦑᫀF<««¬4V(2)ÈÉCCHprᙠNaOHvÃÄv:½ᡂCHCHOH,22Î>ACH2cH20HÑᓄFÎ>-CH2cH஺J½ᓄ®¯V]TDஹFḄ᪀
ᔠEḄᑖÕ
D⏣×ØᙠÙ¹⏚ஹ¾/ᩩÜÝJ½Þß®¯½ᡂE,ᦑEḄ᪀àÕF<^>-CH=CHCOOH
ᦑᫀF<ᓄ®¯V<^>-CH=CHCOOH;(3)᪷åæឤèHḄᑖÕ
ᔠGஹI᪀àÕ
ëìëìGḄ-SHḄwîஹḄ-BrJ½ðñ®¯½ᡂᨵòᱥHîHBr,ᦑHFNH,NH,

17OH(4)ᓄᔠᱥYk஺mFóᑖô᪀$
ᑖÕF஺9ᓃ0஺3,YöᔠÝᑡᩩÜ<জDv:
!DJ½ùú®¯
ûüWᨵᵬ⏚9ᡂḄþØ<ঝNaOH
ImolYᨬὑ3moiNaOH,ᑣᨵஹ-OOCHঞ᪶ᐳᨵ4☢"#$%1&1&2&6,'()ᙠ+,-᪀ᨵ2/ᵬ1-0H.—OOCHᜐ3+452/6C76஺“ஹ6OOCHᙳ;<ᡈᙳ;>ᑣYḄ-᪀^^-C%-CHpr@ឋᩩCDEFGᡂB%IJ6CH2cH20H,BLGMᓄOᓄGᡂC(Q-CH2CH஺)CHCNᐜLGTᡂஹULGEFGᡂ஺(0H_I),+$DஹFḄ-᪀-ᔠEḄᑖ[\1DLG]GO^W2vjnLkjunᡂE,E^_SOCLLG]GᡂᦑE%
^-CH=CHCOOH,ClᵫGḄ-᪀b\ஹHḄᑖ[\ஹIḄ-᪀b\1Gᵫ5^^ᑖ[>ῃ]1ᑖ[HBrGᡂH,HFdᡂ⏒fgᑮI,i1H%j18⚓ᐳ19⚓

18(5)LgJ.Ḅᓫm%nD'H—COOHs᯿uvᔠᡂwxḄyᵨ⌮ᔠᡂᑖ᪆pq—C8Hᵫ7|HCNஹH+gᑮ/~ᵫ/VCH0H1MᓄOᓄgᑮ஺⚪ὃᨵᱥi|ᔠᡂ+ḄᳮF᪷IḄ-᪀b\ஹ-ᔠᩩCy⌮ip;-ᔠᑖ᪆iᔜᱥ-᪀b\,⚪ᙢὃGḄnஹᑖ᪆iᳮஹ1ᵨ஺