高中化学新人教版选修5：第 三 节 羟酸 酯

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PghiᡂRCOOHR'COOH,ᐸPRR'x÷I)஺ᕃNagù7KMnO»H*8GHsOH,9Hso.2n,©ᑡû⚪(1)üýᓄᔠᱥAḄ2tᑖuvþ90,AᑖuPÚஹÿᐗ
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ᑣAḄᑖ(2)BNaHCC>3ᐰᐸᱥḄ1:2,ᑣᙠ⏚Ḅ!ᓄ#B$ḄC2H50H%&Ḅᓄ'()*+,-;(3)A/01234ᵨ6789:;<Ḅ=>ᓄ?@⁐ᑣAḄB᪀D*(4)DḄEᑖF᪀GH:NaHCCh67CO?ḄᨵKᐸLḄB᪀D*oMᫀ(gHioO(2)HOOCCHCOOH+2c2H50H2H5OOCCH2coOC2Hs+2HOOᓄᡈQ22AR(3)CH3cH-CHCH2cH20H(4)2CH3cH2cH2coOH(CH)CHCOOH32S᪆ᵫ⚪W(YZ[\)/BஹC_`COOHᱥᵫC-Daᓄ/CCH3coOH,ᑣAHb_CH3cHeB᪀c(3)HANaஹdḄ=>ᓄ?/0efAg⏣+ᵫ(2)HᩩjBkᐗl⏚BᔠAg⏣/0noA_CH3cHepCH20HB᪀Ḅᱥᵫ(1)HḄᑖᦪ1-0.814=0.186,c16+0.186=86<90,/AHq_1rᑣ/sAḄᑖCnHO,tuᐸ86/ᑖCHO,vwA*xy2n51()ᑣB᪀DCHCH3cHeH2cH2஺{|`}eBHOCHy-CH?—COOH,BC2H50H/0%&Oᓄ஺ᑖC4HQzḄEᑖF᪀GH:NaHCC)3Ḅb⌚⏚C3H7CH—CH—COOH3-COOH,᧕ᑨfᐸᨵ2KEᑖF᪀GCH3—CH2—CH2—COOH,CH3

182O`"♦1.⏒ᩰ⏚ᓛ᪍*`KḄSஹஹ╋ᱥ*`Kᨵ¡⏚/COOHᐸB᪀D஺᧕¢:p£஺¤1molᓛ᪍p$8ᓄ3ᨬ¦◤8ᓄ3A.1molB.2molC.3molD.4molMᫀCS᪆⏒ᩰ⏚p$NaOHḄ()/⊤Z-^+3NaOH-+OCH3coONa+2HzO஺2.ᨵᱥAᙠ`oᩩj#S&ᡂᵬஹ¬Kᨵᱥᵬ:®ᡭᙠLEᩩj#LEḄᵬஹ¬K°9ᡠᓰḄG³LEᙠ#ᑡᨵᱥHµᔠ⚪¶Ḅ*A.⏚OB.ᵬ⏚OC.⏚·OD.1`¸¹ºMᫀBCS᪆⛳p`ᐗ⏣¼`r?½Ḅ⛳p`ᐗ¾⏚ḄLᑖL¿஺3.ᙠ#ᑡÀÁḄ(ÂH:ÃᨵᓄᔠᱥA.Ä$ḄNaOHᐳÆÇtᐭkᓄ?xÉuB.ÊᐙᑖÌÆtᐭ$ḄkᓄC.ÍH2s஺4ᐳÆÌᐭ$NaOHD.ÍH2sᐳÆÌᐭ$NaHCChMᫀADS᪆A⌱⚗-Ì$NaOHᐳÆ%&OḄS,ᦑA⌱⚗µᔠ⚪¶B⌱⚗-ᨬÑtᐭS02&ᡂḄH2sCh

19⏚ឋÔ¢⌚⏚wÕÖ×Ø☢᝞ÛÜ4SO2ᨬÑÝÃ`COONaaᓄ`COOH,B⌱⚗Ö/\—COONaµᔠ⚪¶C⌱⚗-ᨬÑÌᐭNaOH,Þßàáp⌚áᨬÆ&ᡂ‘ã'ஹåᵯ,Öµᔠ⚪¶D⌱⚗-ᙠÍH2SO4çᙠ#%&SÆ,COONaèéNaHCChê:`COOH;ᐸaᓄ'"`å`,ᦑD⌱⚗µᔠ⚪¶஺4.◭.ß⏚O(MMF)*ᘤîïðHᢓᑴóôõöᨬᵨḄᱥ஺#ᑡᐵ¢MMFḄøÂùnḄ*()A.MMF:¢B.MMF:%&QRpúC.1molMMF:6mol9%&ÌᡂD.1molMMF:_3molNaOHᐰMᫀDS᪆⌱⚗AHᵫ¢ᑖH◀`OH᜜ᐸᙳþ᩽ឋ
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,-)ᨵ2.Ḅ/Ḅ0᪀ᡠ23moiNaOH34ᐰ஺,-561.7ᑡᔜ:ᱥ<ᨬ>?@,AB,CᱥDB,ᑖF᪀GḄB()A.JKஹMJNB.O⏚ஹᵬ⏚ᵬ/C.OKஹ1RKD.ᵬSஹᵬ⏚ᵬ/TᫀD2.V/4ᐰWXᡂYᱥ<ḄZḄCO?2HzO,[/.\ᑮ^⏚B2⏣C,`⏣Caᓄ\ᑮ^⏚D,cB(Dde,ᑖF᪀Gᑣg/'B()A.CHCHCOOCH(CH)B.CHCHCOOCHCH=CH32323222C.(CH)2CHCOOCHCH(CH3)2D.C2H5cH2coOCH2cH@3)232TᫀD

20101.᪆᪷jWXᡂC022n0ḄZopCqHe1q2,uv[/e⛳2/⏣C⏚DᑣᡂḄ⏣yᯠᨵCH20H{'aᓄᡂ⏚/
|}~ᦪ1c?,{'BஹDde,ᑖF᪀G஺3.Vឋᨵᱥᙠ⏚ឋᩩ7.ᡂᑖZ@,ḄA2B,ABឋᱥ<B(Na2cChG[ᨵᱥBA.CH3co0C3H7B.CH3coOC2H5C.CHCOONaD.CH3cH?Br3TᫀA.⛳2ᐗ⏚2⛳2ᐗ⏣Ḅ@¡ᑖ?᝞7·ᡠ¸•7ᑡº¨»oḄBC1C1oCHCHC-C~—OCHzCOOH3ZCHZA.ᑭ¯⏚¼ᱥᑭ¯⏚ᵬ/Ḅᑖ?BCHC1O14I424B.ᑭ¯⏚ᑖᑁᜐ,À☢ḄÂÃ10C.1molᑭ¯⏚'(7molH$ᡂ2D.ᑭ¯⏚'(FeCb3É⁐TᫀA.᪆ᵫᑭ¯⏚Ḅ0᪀>?Ìᑏᑭ¯⏚ᵬ/Ḅᑖ?eCl3Hl2cl2O4A»oᙠᑭ¯⏚ᑖ(ÎM@Ḅ2ÎM§Ḅ~ᐳ12«ᙠÀ☢§ᦑB┯ᵫᑭ¯⏚Ḅ0᪀>?Òᐸ)ᨵÎMஹC——2/ᦑ1molᑭ¯⏚ᨬÓ'(5m01H2$ᡂC┯Ôᑭ¯⏚)*+
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