高等有机合成2-8-ReactionsofCarbonNucleophileswithCarbonylCompoundsppt课件.ppt

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1、ReactionsofCarbonNucleophileswithCarbonylCompoundsProf.YueChen(陈悦)Oct.31th,20082.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions2.4.1.2.OlefinationReactionsInvolvingPhos

2、phonateAnions.Wadsworth-Emmonsreaction-UsuallyEisomerformed2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.

3、1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompoundsPetersonreaction2.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethylsilylcar

4、banionswithCarbonylCompounds2.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationReaction2.5.ReactionsProceedingbyAddit

5、ion-Cyclization2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.1.2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRel

6、atedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelatedNucleophiles2.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.6.ConjugateAdditionbyCarbonNucleophiles2.6.

7、1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAddition

8、ofEnolates2.6.2.Con