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1、OrganicChemistry有机化学双语教学试卷及参考答案（部分）王梅大连理工大学1Name:DalianUniversityofTechnology__________StudentCourse:OrganicChemistry(1)Band:ANumber:School(Department):SchoolofChemicalEngineering__________Department:Date:January10,2005Total:5pagesChemistryClass:12345678TotalStandar
2、d__________points201282062068100Scores1.Giveasystematicoratrivialnameforeachofthefollowingformulasorwriteamolecularstructureasrequiredforeachgivenname(20points,2pointsforeachnameorstructure).(1)OCH3CH2CH3(2)COOHOCH3(3)CNN(4)Ph-O-CH2CH=CH2(5)2(6)CH3H3CCOOCCH3C=CCH3HC
3、H3(7)2-formylthiophene(8)1-pentylamine(writethemoststableNewmanprojection)(9)(1S,2S)-1-fluoro-2-isopropylcyclohexane(writethemoststableconformation)(10)(2R,3S)-2,3-dihydroxybutanoicacid(writeaFischerprojection)2.Asrequired,comparephysicalandchemicalpropertiesforeach
4、ofthefollowinggroups(12points,3pointsforeachproblem).(1)CHOClCHOH3CCHO(C)(A)(B)(dipolemoment)(2)NHNH2NH2(C)(A)(B)(basicity)(3)(C)(A)(B)(boilingpoint)(4)CH3OCH=CH2NCCH=CH2CH=CH2(A)(B)(C)(thereactionrateoftheabovecompoundswithBr2)33.Identifythefollowingpairsofcompound
5、sasidentical,enantiomersordiastereomers(8points,2pointsforeachproblem).(1)CH3H(2)HClClCH3ClHClHCH3CH3CHOH（4）(3)HOHH3CCHOCH3OH4.Givemajorproductsofthefollowingreactions,whenthereactionsarestereoselective,showthestereostructuresoftheproductsbythree-dimentionalformula(
6、20poins,2pointsforeachproduct).(1)HHcolddiluteKMnO4C=C-PhPhOH(2)HCl(3)HBrROOR+(4)H3CN(CH3)3OHNaCN(5)ClCH2CH=CHCl4(6)H3CHCHCl3C=CHNaOHCH3Ph(7)H3CHNaOEtHBrEtOHCH3CH3OHOH2SO4(8)CH3COOH()H3CHNaOCH3CH3OH5.Showallstepsinthemechanismfortheformationoftheproduct(6points).Br2
7、H2OOCH2CH2CH2OHBr6.Designsyntheticroutesforthefollowingproductsfromtheindicatedstartingcompoundsandothernecessaryreagents(20points,6pointsforeachproductofproblem(1)and(3);4pointsforeachproductofproblem(2)and(4)).(1)fromtoHCCHCH3CCH2CH3OBrBr(2)fromtoPhCCPhPhPhHHBr(3)
8、fromto(CH3)2CHCHCH3(CH3)2CHCH2CHO5(4)fromtoCH3CHCH2OHCH3CHCH2NH2CH3CH37.Thereare4compounds(A,B,CandD)in4testtubes,pleasedistinguisheachcom
