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1、3・AbstractReactionsbetweenhexanuclearmanganesepivalatewithlanthanidesalts(chloridesornitrates),inthepreseneeofpotassiumhydroxide,2-pyridylmethanolandsodiumazideleadstoformationofanewfamilyofhexaheteronuclearmanganese-lanthanideclusters・4.AbstractTwonovelmetal-organicframeworksof
2、[M3(ptz)2(N3)4(H2O)2](M=Zn(1),Cd(2))(ptz=5-(4-pyridyl)tetrazolate)havebeenpreparedhydro(solvo)thermallybyreactionsof4-cyanopyridineandexcessNaN3inthepreseneeofzincandcadmiumchloride,respective!y.Theoverallstructuremotifofcomplexes1and2showpillaredlayeredframeworksandfeatureanunp
3、recedented3-nodalnetworkwith(3,5,6)-connectivity.ThelayerisofparticularinterestasitisconstructedbyM1J-N3"andMij,3-N3'bridgingmodes,simultaneously.Furthermore,thesolidfluorescentpropertiesandTGAwerestudied・5.AbstractStructuralcharacterizationofanewselfassembledcoordinationpolymer
4、ofCu",hexamine(hmt)andbenzoate(OBz),[Cu4(OBz)8(hmt)]n(1)3revealsthatitisacubicnorvinterpenetratingdiamondoidnetworkformedbythecoordinationofthep4-hmtligandtoalinear[Cu2(OBz)4]spacer.ThemagneticstudyrevealsthattheCu(ll)ionsareantiferromagneticallycoupled(J=-323.5cmthroughthesyn-s
5、yncarboxylatebridges・6.AbstractSimplePETchemosensorsbasedonanthraceneshowaselectiveturn-onfluoresceneesensingforCu2+.Theflexiblereceptorisfavorableforturn・onsensingduetochelationenhancedfluorescenee.Interestingly,theturrvonfluoresceneesensingforCu2+ishardlydisturbedbythecompetit
6、ivecationsandotherhighlyprevalentspeciesinbiologicalandenvironmentalsystems,implyingapotentialinthebiologicalandenvironmentalapplications.4.AbstractMetallacyclodimericcomplexof[(Me4en)Pd(L)]2(PF6)4(Me4en=A/,A/,A/；A/^etramethylethylenediamine;L=133-bis(4-pyridyl)tetramethyldisilo
7、xane)isasensitivecontainerfordioxaneviaappropriatesizeeffect.TheequilibriumbetweentheMineluded"and"free”dioxanespecieshasbeenmonitoredbytemperature-dependent‘HNMRspectra・8・AbstractAnunprecedented(ethanol"clusterisobservedinaphotoluminescentsilver(l)coordinationpolymerhost,[Ag2(d
8、mt)2(nda)-2EtOH]n(1,dmt=2,4-diamino-6-methyl-1,
