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时间:2019-10-29
《2019版一轮优化探究化学(苏教版)练习:章末排查练6 Word版含解析》由会员上传分享,免费在线阅读,更多相关内容在教育资源-天天文库。
1、章末排查练(六)一、原电池电极反应式或总反应式的书写1、铁镍电池(负极-Fe,正极-NiO2,电解液-KOH溶液)已知:Fe+NiO2+2H2OFe(OH)2+Ni(OH)2,则:负极:_______________________________________________;正极:_______________________________________________;阴极:_______________________________________________;阳极:__________________________________________
2、______.答案:Fe-2e-+2OH-===Fe(OH)2 NiO2+2H2O+2e-===Ni(OH)2+2OH- Fe(OH)2+2e-===Fe+2OH- Ni(OH)2-2e-+2OH-===NiO2+2H2O2、LiFePO4电池(正极-LiFePO4,负极-Li,含Li+导电固体为电解质)已知:FePO4+LiLiFePO4,则负极:_______________________________________________;正极:_______________________________________________;阴极:__________
3、_____________________________________;阳极:________________________________________________.答案:Li-e-===Li+ FePO4+Li++e-===LiFePO4 Li++e-===Li LiFePO4-e-===FePO4+Li+3、高铁电池(负极-Zn,正极-石墨,电解质为浸湿的固态碱性物质)已知:3Zn+2K2FeO4+8H2O3Zn(OH)2+2Fe(OH)3+4KOH,则:负极:______________________________________________
4、_;正极:_______________________________________________;阴极:_______________________________________________;阳极:________________________________________________.答案:3Zn-6e-+6OH-===3Zn(OH)2 2FeO+6e-+8H2O===2Fe(OH)3+10OH- 3Zn(OH)2+6e-===3Zn+6OH-2Fe(OH)3-6e-+10OH-===2FeO+8H2O4、氢氧燃料电池(1)电解质是KOH溶液(
5、碱性电解质)负极:_______________________________________________;正极:_______________________________________________;总反应方程式:________________________________________________.(2)电解质是H2SO4溶液(酸性电解质)负极:_______________________________________________;正极:_______________________________________________;总
6、反应方程式:________________________________________________.(3)电解质是NaCl溶液(中性电解质)负极:_______________________________________________;正极:_______________________________________________;总反应方程式:________________________________________________.答案:(1)2H2-4e-+4OH-===4H2O O2+2H2O+4e-===4OH- 2H2+O2===2
7、H2O (2)2H2-4e-===4H+ O2+4H++4e-===2H2O 2H2+O2===2H2O (3)2H2-4e-===4H+ O2+2H2O+4e-===4OH- 2H2+O2===2H2O5、甲烷燃料电池(铂为两极,正极通入O2和CO2,负极通入甲烷,电解液有三种)(1)电解质是熔融碳酸盐(K2CO3或Na2CO3)正极:_______________________________________________;负极:_______________________________________________;总反应
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