新型环保涂层阻燃剂的开发和工艺探究

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1、时的阻燃、水洗表现，确定HY-MPOP为体系最适阻燃剂；碳源、气源和协效剂的比较是在已选粘合剂和磷系酸源的基础上，设计实验考察各样品在与其复配制胶后阻燃胶的阻燃效果，结果显示季戊四醇（PER）作为碳源、氤尿酸三聚氧胺（MCA）作为气源、氢氧化镁作为协效剂时，复配体系具有最佳的阻燃效果。确定组分后，通过单因素实验对比了酸源、碳源、气源的最佳比例，垂直燃烧实验表明：比例在8：2：2、协效剂用量为阻燃组份5%时，膨胀阻燃体系具有最佳的阻燃效果；而阻燃组份和粘合剂的用量比在1：2.5时，整理后的织物具有最好的耐洗阻燃效果。在此配比下分别对厚/薄织物进行涂层整理，增重率为35%

2、可达到耐洗的阻燃效果，浸洗后的垂直燃烧炭长为95mm,续燃阴燃均为0s。设计正交实验筛选出了阻燃胶的最佳整理工艺:二次刮涂＞100°C烘干150s、180°C焙烘150so在最佳配方和工艺条件下对织物进行涂层整理，测试整理前后织物的应用性能的变化，撕破强力实验显示织物强力损失较少（小于10%）,但耐静水压有明显提高，应用性能基本保留。对整理后织物的TG和织物燃烧后的残炭SEM分析，并结合膨胀型阻燃剂的阻燃特性，探究了本阻燃涂层胶实际的阻燃情况和阻燃机理。关键词：环保；膨胀型阻燃剂；涤纶；涂层THEDEVELOPMENTOFECO-FRIENDLYCOATINGFLAM

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