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1、Solution-processed,high-performancen-channelorganicmicrowiretransistorsJoonHakOha,HangWooLeea,StefanMannsfelda,RandallM.Stoltenbergb,EricJunga,YongWanJinc,JongMinKimc,Ji-BeomYood,andZhenanBaoa,1DepartmentsofaChemicalEngineeringandbChemistry,StanfordUniversity,Stanford,CA94
2、305;cSamsungAdvancedInstituteofTechnology,Giheung-gu,Yongin-si,Gyunggi-do449-712,Korea;anddSchoolofAdvancedMaterialsScienceandEngineering,SungkyunkwanUniversity,300,Chunchun-dong,Jangan-gu,Suwon440-746,KoreaEditedbyJohnRogers,UniversityofIllinois,andacceptedbytheEditorialB
3、oardFebruary11,2009(receivedforreviewNovember23,2008)Thedevelopmentofsolution-processable,high-performancen-parts,however,organicwiresaretypicallymechanicallylesschannelorganicsemiconductorsiscrucialtorealizinglow-cost,robust,electromagneticallylessactive,andbroaderinsizea
4、ll-organiccomplementarycircuits.Single-crystallineorganicsemi-distribution;hence,theaforementionedalignmenttechniquesconductornano/microwires(NWs/MWs)havegreatpotentialascannoteasilybeappliedtothem.activematerialsinsolution-formedhigh-performancetransistors.Here,wereportan
5、approachforsolutionfabricationofHowever,thetechnologytointegratetheseelementsintofunc-high-mobility,air-stablen-channelorganictransistorsfromtionalnetworkswithcontrolledalignmentanddensitylagsfaraligned,single-crystallineorganicsemiconductingMWsusingbehindtheirinorganiccou
6、nterparts.Here,wereportasolution-N,N-bis(2-phenylethyl)-perylene-3,4:9,10-tetracarboxylicdiim-processingapproachtoachievehigh-performanceair-stablen-ide(BPE-PTCDI,Fig.1AInset).Thesingle-crystallineBPE-channelorganictransistors(thefield-effectmobility()upto0.24PTCDIMWsexhi
7、bitedashighas1.4cm2/Vsfortheindividualcm2/VsforMWnetworks)comprisinghighmobility,solution-wiretransistor,whichisthehighestreportedforsolution-synthesizedsingle-crystallineorganicsemiconductingMWs(asprocessedn-channelorganicsemiconductingwiredevicesaswellhighas1.4cm2/Vsfo
8、rindividualMWs)andafiltration-and-transferasanorderofmagnitudehigherthanthebestperformance