重氮膦酸酯与亚苄基二羧酸酯的不对称[3+2]环加成反应研究

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1、目录目录目录摘要..........................................................................................................................IAbstract....................................................................................................................III前言.......

2、..................................................................................................................1第一章文献综述.....................................................................................................31.1重氮膦酸酯作为亲电亲核试剂参与的一系列反应...................

3、.............31.1.1Seyferth–Gilberthomologation反应...............................................31.1.2串联反应..........................................................................................31.1.3Mannich反应........................................................

4、...........................41.1.4[3+2]环加成反应..............................................................................51.1.5同碳杂键的加成反应......................................................................71.2经由卡宾中间体发生的反应.............................................

5、.......................71.2.1插入反应.........................................................................................71.2.2氮杂环丙烷化反应.......................................................................111.2.3环丙烷化反应...............................................

6、................................121.2.4多组分插入反应...........................................................................131.2.5交叉偶联反应................................................................................141.3小结..............................................

7、............................................................14第二章重氮膦酸酯与亚苄基二羧酸酯的不对称[3+2]环加成反应...................152.1课题的提出与设计..................................................................................152.2催化剂的设计合成................................................

8、..................................162.2.1催化剂I(a-b)的合成.....................................................................162.2.2催化