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1、Chem.Rev.2010,110,341934783419ABerzeliusReagent,PhosphorusDecasulfide(P4S10),inOrganicSyntheses,§TuranOzturk,*ErdalErtas,andOlcayMertIstanbulTechnicalUniversity,ScienceFaculty,ChemistryDepartment,OrganicChemistry,34469Maslak,Istanbul,Turkey,TubitakMarmaraResearchCent
2、re,FI,41470Gebze-Kocaeli,Turkey,MiddleEastTechnicalUniversity,DepartmentofChemistry,OrganicChemistry,Ankara,Turkey,andTUBITAKUME,ChemistryGroupLaboratories,PBox54,41470,Gebze-Kocaeli,TurkeyReceivedJuly6,2009Contents1.Introduction34192.ReactionsofP4S1034212.1.Ketones
3、34212.2.Thionoesters,Dithioesters,Thionolactones,3426Dithiolactones,Thiolactones,andDithiolethiones2.3.AmidesandLactams34352.4.Imides34482.5.Thiophenes34512.6.Thiazolines,Thiazoles,andThiazines34542.7.Dithiazoles34562.8.Thiadiazoles34562.9.ImidazolinesandPyrimidines
4、3456TuranOzturkwasborninKizilcaoreninDivrigi,Turkey.Hereceivedhis2.10.Alcohols3458Ph.D.degreefromtheUniversityofEastAnglia,England,onthesynthesis2.11.PdOtoPdS3461ofAmphimedinealkaloid.HewasthenmovedtotheUniversityofKentatCanterbury,England,asapostdoctoralfellow,wher
5、eheworkedon2.12.Reduction3462thesynthesisofnewBEDT-TTFtypeorganicsuperconductorsand2.13.Nucleotides,Purines,andPyrimidines3463developedanewmethodforthesynthesisoffused1,4-dithiinand2.14.Miscellaneous3467thiopheneringsfrom1,8-diketonesusingLawesseonsreagentandP4S10.2
6、.15.PSvsLawessonsReagent(LR)3473HetookupapositionatTUBITAKMRC,Turkey,andthenMiddleEast410TechnicalUniversity,Turkey,andjoinedIstanbulTechnicalUniversityas3.Conclusion3473afullprofessor.HehaspreviouslybeenBritishCouncilResearchFellow,4.Acknowledgments3473NATOResearch
7、Fellow,andHonoraryLecturerattheUniversityofKent5.References3473atCanterburyandSeniorResearchFellowatUniversityofWaterloo,Canada.Hisresearchinterestsconcentrateonthedevelopmentofneworganicmaterialshavingelectronicandopticalproperties,aswellasthe1.Introductiondevelopm
8、entofneworganicreactions,particularlythenewreactionsofSynthesesoforganiccompoundshavingasulfurhetero-LawessonsreagentandP4S10.atomhavebeen