地黄产后加工过程中梓醇的变化规律研究

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1、山东大学学位论文U化合物A1一A5化合物A6化合物A7-A8化合物A9lu化合物Alo化合物All—A14化=厶物Als～A21化合物A挖rha-OUHO化合物A船化合物B1-B6化合物B7OHO化合物B8化合物B9化合物B10化合物B”图1．1地黄中环烯醚萜苷类和环烯醚萜类化合物结构Hg．1一lStmcmresofiridoidglucosideandnon-glucosidiciridoidsisolatedfromRehmanniaGlutinnosaLibosch表1．1地黄中的环烯醚萜苷类化合物Tablel一1

2、IridoidglucosidesisolatedfromRehmanniaGlutinnosaLibosch．序名称RIR2形态[alDmp(℃)来源号山东大学学位论文Asji081utosideAtl2IAmHWAP-158．8加托1．65．MeOH)FA‘二氢梓醇‘3lCP-74．4≯(c1．o．CHCl3)152-154FDL舢二氢马鞭草苷uqR=HDAI8-表番木鳖酸‘101R=OHCN-135．3”(c0．92，pyridinc)146--149DLA。京尼平苷1121CG+16．225(c0．75，StOH

3、)164--165FDAlojioglutosideB㈣WAP-50．1”(c1．II．McOH)FAll桃叶珊瑚剖31RfHCN·15722(cO．5，CHCl3)128-129FLA12单蜜力特剖31R--OHCN·170．0：玎(cO．5．CHCl3)172-174FDLAI，蜜力特苷‘3’R=--o-glcWP-31杆(c1．0．H20)176--177FDLA¨地黄苷D

4、31R---o-sopWP·26．722(ci．0，H20)196．5-197．FDLh2AI，筋骨草醇【31HWAP·172．1"(c0．5

5、3．MeOH)FDLAI‘6-o-E-fcmloylDfcruloHWAP·147．俨(co．33,MeOH)DajugolI!OlylA176-o-P-coumaroylP-coumaHWAP．144．9∞(c0．14,MeOH)DajugolI!OlroylAII6-o-Z-feruloyl7_,-fcruloHWAP-84．52S(c0．II．MeOI-1)DajugolIl们ylA196．o-P-hydmxybenzoatcP-hydroxHWAP-138．8a(cO．IO,MeOH)DAjugolH们ybcnz

6、oylA206-o-vanillateajugoltl仍vanilloylHWAP-135．229(c0．13,MeOH)DA21地黄苷c【31HgalWP·11．3巧(cO。5．McOrl)FA复氯化梓醇‘361WAP-50．820(c0．52，MeOH)DS如6心(r心a山WAP．156．028(c0．25,MeOH)Drhamnopyranosyl)vanilloylajugolll01Au筋骨草甙㈣注(以下同)：N—needles针状结晶CN-----colouflessneedles无色针晶WAP—whitea

7、morphouspowder白色无定型粉末AP----amorphouspowder无定型粉末wA-wIliteamorphous白色无定型状AfAmorphous不定型状OWAP---off-whiteamorphouspowder灰白色无定型粉末洲id固体p--prisms棱柱型WP—whitepowder白色粉末CO---Colourlcssoilysubstance无色油状物YNqellowneedles黄色针晶CP-----colourlessplatesWAS—州Ili忙amorphoussolidC㈨lou

8、rlessIp-a_mules无色颗粒F---freshrootsofRehmanniaglutino#aLibosch鲜地黄D-曲edriedRootofRehmannh2glutinosaLibosch生地黄S一_hesteamedRootofRehmanniagluti加#aLibosch熟地黄G_kcallustissueofRehmanniaglutinosaLibosch地黄愈伤组织I—hcleafofRehmanniaglutinosaLi幻$ch地黄叶DR埘s∞scdrootsofRehmanniaglu

9、tinosa13bosch表1．2地黄中的非苷环烯醚萜类化合物Table1．2non-glucosidiciddoidsisolatedfromRehmanniaGlutinnosaLiboschBI焦地黄素OMHC1WAP+63．3∞(cI．00，MeOH)SAI川c．12．山东大学学位论文B2焦地黄素HOMHCI