四丁基氢氧化铵的电解合成工艺-研究

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1、万方数据青岛科技大学硕士研究生学位论文STUDY0NTHEELECTROSYNTHESISOFTETRABUTYLAMMONIUMHYDROXIDEABSTRACTAsakindofquaternaryammoniumhydroxide，tetrabutylammoniumhydroxideismainlyusedaselectronicchemicals，phasetransfercatalysts，molecularsievetemplateagent，etc．Withthedevelopmentofitsapplication，thedema

2、ndfortetrabutylammoniumhydroxideincreasesrapidly．Howerer，atpresent，thesyntheticmethodsoftetrabutylammoniumhydroxidehavesomedisadvantages，forexampletheimpuritycontentishigh，therefore，thestudyofsynthesisprocessoftetrabutylammoniumhydroxidebyelectrodialysishasagoodapplicationpros

3、pect．Firstly,astudyonthepreparationoftetrabutylammoniumbromidefromtributylaminewasperformed．Theoperationparameterssuchasthetypeofsolvent，thedosageofsolvent，themixtureratioandthereactiontime，wereinvestigatedintheprocess．Theresultshowedthattheoptimumreactionsareasfollows：acetoni

4、trileasthesolvent，themixtureratioofn(tributylamine)：n(n-butylbromide)：n(acetonitrile)21：1．2：4．thereactiontimeof24h，thereactionconversionratereached93％，recrystallizationsolventofethylacetateusedforfourtimes．theaverageyieldoftetrabutylammoniumbromideachieves86．6％．Fromthesynthesi

5、sexperimentoftetrabutylammoniumhydroxidebyasinglemembraneelectrolysis，TC-1ionexchangemembranewasthemostappropriateoneallowedtetrabutylammoniumionstopassthrough．Inordertosolvetheproblemsofsinglemembraneelectrolyticcell，theexperimentschemeofthree—embraneandfour-chamberelectrodia

6、lysisWaspresented．Applicationofcontinuousfeedandcontinuousdischargingwaycansolvetheproblemoflowcurrentefficiency．Theelectrolyticfactorswasoptimized，thebestelectrolyticsolution：current200A／m2，flow150L／h，rawmaterialconcentration50、玑％，alkaliconcentration6wt％，providingahighcurrent

7、efficiency．III万方数据四丁基氢氧化铵电解合成工艺研究KEYWORDS：Tetrabutylammoniumbromide；Tetrabutylammoniumhydroxide；electrodialysis；ionexchangemembrane万方数据青岛科技大学硕士研究生学位论文目录第一章绪论⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯．11．1四丁基氢氧化铵⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯一¨．1四丁基氢氧化铵应用⋯⋯⋯⋯⋯⋯⋯⋯⋯1．I．2四丁基氢氧化铵合成方法⋯⋯⋯⋯⋯⋯⋯1．2离子交换膜⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯⋯．．1．2．1

8、离子交换膜发展历史⋯⋯⋯⋯⋯⋯⋯⋯⋯1．2．2离子交换膜的机构与分类⋯⋯⋯⋯⋯⋯⋯1．2_3离子交换膜结构及性能要求⋯⋯⋯