金催化的累积三烯酮的环化反应研究及1,2-二羰基苯类化合物的合成

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1、王二娟硕士学位论文答辩委员会成员名单姓姓名名职称称单位位备注注尽尽伟伟研气毅毅身东!沛人人主席席扭扭侧浪浪剐剐、触振振年伞‘币久久久刘刘札方方导‘吸吸}}}‘}}}}敲钱务车饰农农农华东师范大学理学硕士论文目录摘要··························································································……lAb5tract············································

2、········································……n第一章:累积多烯研究背景·························································......……i第二章:累积三联烯醇的合成与转化···········································……，’’··…13第一节:引言························································

3、···················……13第二节:金促进的累积三烯醇的环化反应研究····································……152.1反应条件的探索··························································...··……162.2反应的普适性研究····························································……17第三节:由累积三烯醇高选择性的生成

4、二烯炔····································……19第四节:金催化的累积三烯酮的环化反应研究····································……212.4.1工作的设想··································································……212.4.2累积三联烯酮的合成··········································……，’’···……212

5、.4.3联烯酮环化最优条件的探索·············································……242.4.4底物的拓展··································································……252.4.5可能的反应机理····························································……26第三章:邻苯二甲酞基苯的研究背景···············

6、·······································……283.11，2一二拨基苯类化合物的应用··········································……283.21，2一二拨基苯类的合成方法介绍·······································……30第四章:DDQ促进的二氢异苯并吠喃氧化反应的研究一1，2一二拨基苯类化合物的合成···········································

7、··················································……34第一节:引言··············································································……34第二节二氢异苯并吠喃原料的制备················································……35第三节:二氢异苯并吠喃的氧化·····························

8、·························……394.3.1用氧气作为氧化剂条件的探索··········································……394.3.2用DDQ做氧化剂氧化条件的探索·······································……404.3.3反应的普适性研究·························································……41少华东师范大