高考化学模拟试卷（含解析）

《高考化学模拟试卷（含解析）》由会员上传分享，免费在线阅读，更多相关内容在教育资源-天天文库。

ᑖ᪥2015ὃᓄᔁஹ⌱⚪ᜧ⚪ᐳ7⚪⚪6ᑖᐳ42ᑖ⚪ᨵ⌱⚗ᔠ⚪!"16ᑖ"#ᑡᨵᐵ&'()*Ḅ,"Aᐝ./0ஹ12/0ஹ34567ᨵ8ᑖ9ᓄᔠᱥBᙠᜧ<=⏀Ḅ?@(ABᨬDEᡂGᓫIC"ᙢLM”O?PQᜐᳮDTUᵨᩭᑴYḂD[Ẇ]^_Bᜐᳮ`ᩭabὅḄdᵨeᳮfg26ᑖ"#ᑡh9ijk@l┯nḄ,"*z.AᔣNaSiOpq(⌲sPᐭuvwx⏚:SiO+2H?HSiO{|"233232+*3+.BwFeNO
pq(ᐭwx⏚:Fe+4H+NO?Fe+NO?+2HO3232.2+CCuᱏᐭw⏚(:3Cu+8H+2NO?3Cu+2NO?+4HO323+2+,+2,DᔣNHAI+2Ba+50HSO
pq(Pᐭ?vḄBaOH
wpq:NH+AI+2SO442244.?2BaSO?+NH«HO+AIO+2HO4322236ᑖ"NPᦪḄ#ᑡ&')*Ḅ,"AA12gᨔ|(ᨵḄC,CḄᦪ2NABBIL1mol-LAICIpq(ᨵḄAlᦪN3ACᙠ᪗#ᐭvḄNaOHpq(ᵯ9ᦪNAD18ga
DO
ᨵḄ(9ᦪ10N2A46ᑖ"#ᑡdஹ¡]¢£ᙳ)*Ḅ,"

1⌱⚗d¡¢£A?¦§Ḅ¨⁐ª«☠®«¯E⁐NHCI°±¯ᑖ²4B?(³₩D☟¶#·q|¸⁐E¹NaOHpqT◀»pᙠ¼½(ḄBr2C?P±¾¿(pqÀ⁐ÁᡂGÂÃD?ᵯA᩽Åᨵ¨⁐Æ|᪆ÈÉḄ6ឋËÌÍA(AB(BC(CD(D5((6ᑖ)ÏÐAஹBஹCஹDஹE,ÑᕜÓ(e9ÔᦪÕÖ×ᜧḄ5ØÙÚᐗÜᐸ(ᐗÜAஹEḄᓫÞᙠß#ᕈ᝱ᐗÜBḄe9ᨬ᜜·ᵯ9ᦪ,ᐸᵯ9·ᦪḄ2ãᐗÜCᙠgᕜÓḄÙÚᐗÜ(e9äåᨬᜧᐗÜDḄᔠ,æÁç(ᵨḄ6ᩞᧇ(#ᑡ&')*Ḅ,()A(ᐗÜAஹBëᡂḄᓄᔠᱥß#ìᕈ᝱B(ᐗÜCஹDḄᨬíîᓄᱥïjḄaᓄᱥðñ¯òóÁijC(QôÅᵨᵯ²'ᑴᜓᐗÜCஹDஹEḄᓫÞD(ᓄᔠᱥAEöCEᨵfg÷øḄᓄù6((6ᑖ)ú⏚û(NaNO),Øᐹᨵýᕡஹᨵÿ
(NaCI)Ḅᵨ2ᵨᦑ(Ḅᑖឋ!᝞#$ᑡ&'┯Ḅ)()A(+ᵨ,-Ớᓄ01234␺6(NaCI)789⏚;(NaNO)2B(NH᩽᧕>?@AB)᩽ឋᑖC
7@ᑖCDE᧕FᡂHI24C(NaNO7NHᡂNaNḄJKLMNB:NaNO+NH?NaN+2Ho224322432D(᝞#ᡠQRᑮḄᓄTJKU)VᓄWXJK

27((6ᑖ)$ᑡ>Zᡈ\Zᐵ?^C_`Ḅ&'abḄ)()-A(cd_`Ḅe@f@ghḄiMc(NH)/c(NHHO)ḄjklᒹB(_`ᙳB0.1mol-LḄNaC஺ஹNaHCOqᔠ>Z:c(CO),c(HCO),
2C(Na)23333„=3[C(CO)+C(HCO)]332,M.C(0.2molLḄ4⏚(CHCOOH)>Z70.1mol-LNaOH>Zstuqᔠv:C(CHCOO)33,,+2c(OH)=c(CHCOOH)+2c(H)3,io.uD(w$,yz:K(AgCI)=1.8xlO,K(AgCrO)=2.0x10,ᑣAgCrO|\Zspsp22424.+Ḅc(Ag)cdl?AgCI|\ZḄc(Ag)ஹ⌱⚪(ᜧ⚪ᐳ4l⚪ᐳ58ᑖ)8((14ᑖ)yzᓄḄᰚB306?,B315?,᧕>?@
ᨵḄᔾ@ឋᔾᦈḄ@ᑖ(TlḄT7ḄJKRᱥ¡¢᝞$£¤¥¦§(1)¨©Ḅª«¬B((2)⛳3@Ḅᵨ)((3)JKc¯°Evᰐ²⏀´µ¶ᓾv¸¹!ºᴻ¼Rᦈ½ᘤḄᱥ!c¿ÀÁÂÃ┵FÅfᐭiÇḄg⏚3ÈÉÊᱥË(JKiMÌÍ₩)ᐙᑖJKvÐÑ᝞$¥¦§ÒÓÔ⁐>Zfᐭ1ᑺXᡂÓ×⁐>ZḄ^CJKLMNB?Ó×⁐>ZfᐭiÇHOv>Z×⁐fÙḄXA)(22(4)yz×⁐ÚÛḄ°ᨵtᡂÜݦB0(ÞlT×⁐ÚÛḄXAÐÑ£¤(2?ßÚ⁐v>ZàácàâfFeCI>Zãäåæᓄ;áàâf1ᑺX,>Zèé×⁐;3áàâfgHCI3BaCI>Zê⁐ë,(

3?ìß_`ḄFeCI>Zâf2â1ᑺX,>Zæ×íîᐭ0,ãäåæᓄ(23¥¦Ò&ä;¥¦ÒḄïḄ);ðèñò:>ZÚ⁐ḄXA)(9((14ᑖ)ᑴô!◚Fö÷øᑖCᩞᧇ(M)3ûüPETḄᔠᡂýþ᝞$§ÿᓄᑺ1818⏣᝞ᣚ:RCOOR'+R"OHRCOOR'+R'OH(RR\R"⊤ᨵ)(1)AḄᑖ28,AஹBᑖ!"ᨵḄ#$ᑖ%((2)BḄ'(((3)IḄ)*(⌱,-.)(a(/0b(10(4)ᨵᐵBஹCஹDḄ3456Ḅ(a.lmolBᨬ89:lmolCb(CஹD;$?⁐c(DNaOH=>ᐳB24C9DᑮB:C(5)B?DḄᓄFGHI((6)Cᨵ8JKᑖL᪀NOᐸ!QJᔠᡂTUUVWḄᓫNOYᑖᙠ⏚ឋ]᛻_`DᑮaJbᱥOdeḄᑖf16,YKᑖL᪀NḄg᪀hI((7)iḄᓄFGHI(10((14ᑖ)jklmᦈᑭᵨqᔠrsᧇ(u⌕"FeஹCuஹCoஹLiwOC஺ஹFe;!wyzr{)Ḅj|}H᝞~(1)r{MO1((2)/ᐭHOḄᵨ(ᵨGHI⊤)O/ᐭ_Ḅᵨ(22(3)ᐙᑖᯏḄᓄFGHI(

4(4)LiCO=_ᐸ⛳:=>Ḅᐵ⊤(2!O1C23BOᐸO90?Ksp(LiCO)Ḅ(23/?10306090J/mol?L(5)ᵨឋᵯ᩽ᵯ`ᰚ¢LiCOᑴ¤┞O□᩽ᡂaJ§NOᑣ□᩽Ḅᵯ᩽I(2311((16ᑖ)ᵬ⏣ª("ᩈ⏣"ᡈ"ᩈ®"O¯°64.7?,±⁐ᨵ⏀®§ᕡ᧕ᢵḄ>N(ᵬ⏣ᨵ¶O·¸5,10mL$¹ºᜫ¼Oᜧ¸ᵨ¾¿ÀÁÂ(ᵬ⏣Ã⌕ḄᓄFjkẠᧇ:>NÅᧇOᵨᑴ⌼ᵬÇ:ÈÉOÊËᵨᨵᱥḄ⃓¤ᑺ:⏀®ḄÍឋᑺw((1)jklᑭᵨCO:Hbᵬ⏣OGHI᝞~22.!CO(g)+3H(g)?CHOH(l)+HO(g)?H=QkJ«mol22321,1ªÎÏᧇD:iCHOH(l)+l/2O(g)?CO(g)+2H(g)?H=QkJmol32222,?HO(g)=HO(l)?H=QkJ-mol,ᑣ⊤ᵬ⏣ḄÅBḄBᓄFGHI(2231(2)jklᵨCO:HO(g)ᩭᔠᡂCO:H0ᐙᐭ10LÑÒÓÔÕᘤ!×ØᓄF2222CO(g)+HO(g)?CO(g)+H(g)?H.O,Ù×Øᑮ10minÚᑮÛ⊝,ÞßDH22220.6mol(màᑡâ⚪:?0,10minᑁHO(g)ḄÛᙳæ᳛(?èé/ê5æ᳛ḄKëìCOḄíᓄ᳛O9îᵨḄG4(a(ᓣìb(1ðÕᘤḄNñc(òᜧHO(g)Ḅ2d(/ᐭ〉ÙḄôᓄᑺ

50g
,ÃõÚᑮᓄFÛ⊝ö᝱OÞÛ⊝øᔠ§N!HḄNñᑖᦪú22=>úᎷüýC=>NñþÍÿ
ᔣᵬᐭabD᩽▬ᕈ⁐4ᑡ⚪?aᱥAᵯ᩽Ḅᵯ᩽!?#$%&Ḅ'ᓄ)*+!?
#$%&Cᵯ᩽ᦈ-ᑮ224mL᪗012&34ḄpH=5678ᑖ)᪥2015;<ὃᓄ)>?@ᔁBὃᫀD@⚪E᪆Gஹ⌱J⚪Kᜧ⚪ᐳ7N⚪ON⚪6ᑖᐳ42ᑖON⚪PᨵGR⌱⚗Tᔠ⚪V016ᑖ1ᑡᨵᐵXY&Z[ḄAᐝ]^_ஹ`a^_ஹbcdefᨵg<ᑖhᓄᔠᱥBᙠᜧjk⏀Ḅm+&noᨬqrᡂtᓫvC"ᙢyz”|m}~ᜐᳮqᵨᩭᑴḂDẄoᜐᳮᩭὅḄᵨᳮὃᨵg<ᑖhᓄᔠᱥḄ᪀ឋ;Ḅ5⌕ឋ;ஹஹỚᐸᓄᔠᱥḄᔠᵨ;zᾦḄឋஹ¢ᡂD᪀;noḄឋᵨ⌶ᑖ᪆A¤ᑖh¥ᙠ10000¦Ḅᨵgᓄᔠᱥ!<ᑖhᓄᔠᱥ§BnoE¨ᡂℍ⃔vℍ⃔vᑖE¨ᡂ⏀«§Czᾦᙠ¬ឋᩩ®E¨ᡂḂ§D¯E¨ᡂᐹᨵᔾ▬ឋḄ²³ᓄ´

6EE:Aᐝ]^_Ḅᡂᑖ³ᓄấ¤ᑖh¥¸N¹<ᑖhᓄᔠᱥᦑA┯¼§BnoE¨ᡂℍ⃔vℍ⃔vᑖE¨ᡂ⏀«ᦑB┯¼§Czᾦᙠ¬ឋᩩ®E¨ᡂḂᵞzᡠᵨ"ᙢyz”|m}~ᜐᳮqᵨᩭᑴḂᦑCZ[§DẆE¨ᡂᐹᨵᔾ▬ឋḄ²³ᓄ´¹ᐹᨵÀ³ᓄឋPÁᵨf◀ÃḄÄÅᱥÆoᵨfᩔÈÉÊᦑD┯¼ᦑ⌱CËK⚪ὃ̸!ᔠÍ5fᓄ)D¨ÎஹÏ᛻ḄὃÌ!<⚣ὃÒÓ⚪ÔᨵᑭfÖ×)¨ØÙḄÚ)Û×Ü<)ÝḄÞ᩽ឋßà¹ᜧáVᐵâẠäåḄÞæ26ᑖ1ᑡçh*+┯¼Ḅ1•z.AᔣNaSiO34&⌲é}ᐭê¥ëì⏚:SiO+2H?HSiO1233232**3*.BëFeNO
34&ðñᐭëì⏚:Fe+4H+NO?Fe+NO?+2H஺óCuᱏðñᐭëõ⏚&:3Cu+8H+2NO?3Cu+2NO?+4HO323+2+,+ZDᔣNHAISO
34&}ᐭm¥ḄBaOH
ë34:NH+AI+2SO+2Ba+50H34.?2BaSO?+NH«HO+AIO+2HO43222ὃçh*+Ḅöᑏᑖ᪆Aấ⏚øDì⏚¨ᡂấ⏚ᓄø§Bᵯ₹¹úឤ§CüDëõ⏚¨ᡂõ⏚üG³ᓄý§D²³ᓄþm¥¨ᡂÿ⏚
ஹᔠ⏚


7.2.:A(ấ⏚⏚:SiO+2H?HSiO(),ᦑA"#$323ze.B('Fe(NO)()*+ᐭ'⏚,:3Fe+4H+NO?3Fe+NO?+2H஺,ᦑB┯3232/$0Cuᱏ+ᐭ'2⏚*3ᡂ2⏚56ᓄ8:3Cu+8H+2NO?3Cu+2NO?+4HO,32ᦑC"#$.3.2.2.D(ᔣNHAI(SO)()*+ᐭ:;ḄBa(OH)'(),:NH+AI+2SO+2Ba+50H“2"4?2BaSO?+NHHO+AIO+2Ho,ᦑD"#$«222ᦑ⌱:B(>?@⚪ὃCDEᑏGH#IJK⚪ᐵMGNOᱥᵨ;RḄSTG⌱⚗DV᧕┯⌱⚗(3((6ᑖ)YNVZ[+\]^ᦪḄ`(aᑡcd"#ḄK()AA(12gefgᨔ*iᨵḄC,CḄᦪkV2NA.mB(IL1moMAICI()*iᨵḄAlᦪkVN3AC(ᙠ᪗naGopqᐭr;ḄNaOH()*stᵯᦪVNAD(18gv(DO)iᨵḄ*ᦪV10N2Aὃ>Z[+\]^ᦪ(ᑖ᪆AஹxyefgḄᱥJḄ;Gᯠ{᪷}Imolefg*i2molC,CMᩭᑖ᪆;3,BஹAIK□ᙠ()*$CஹopḄVᓄ$DஹvḄ᥅J;V20g/mol(:Aஹ12gefgḄᱥJḄ;VImol,Imolefg*i2molC,CMGᦑA"#$mBஹAIK□ᙠ()*ᦑ()*AIḄᦪN,ᦑB┯/$A

8Cஹ᪗naGopḄᱥJḄ;V0.5mol,opḄVᓄGlmolopstlmolᵯGᦑ0.5molopst0.5molᵯGᦑC┯/$DஹvḄ᥅J;V20g/mol,ᦑ18gvḄᱥJḄ;V0.9mol,lmolv*ilOmol*ᦑ0.9molv*i9mol*GᦑD┯/(ᦑ⌱A(>?@⚪ὃCDZ[\]^ᦪḄᨵᐵGḄᵨᱥJḄ᪀K⚪ᐵMGᜧ(4((6ᑖ)aᑡIஹᙳV"#ḄK()⌱⚗A?0¢£Ḅ¤⁐g¦§¨☠ª§«¬§¨⁐NHCI®¯ᑖ4B?*°₩{☟³a´)µ⁐¶NaOH()·◀¹(ᙠº»*ḄBrzC?+¯¼p½*()¾⁐3ᡂD¿ÀD?qᵯA᩽Âᨵ¤⁐Ã᪆yÄḄeÅឋÇ5ÈA(AB(BC(CD(Dὃ>ᓄÉIᫀḄ?Ë(ᑖ᪆A(ᑖÌᑮḄpHCIÎᔠVoᓄÏ$B(Ð6ᓄÑGÒ»Ó(GÔÕᜧ$C(ᢵ×yḄ¿⏣Ù·Ú⏚ឋÛ═⏚Ý()¾⁐;

9DAÞßᵯàá᩽GV▢᩽G56ᓄឋÇÄ6ᓄឋÈqᵯãA᩽ᨵCu᪆y
:Aoᓄ╄®¯ᑖVpHCI,®å{pHCIÎᔠVoᓄæGᦑ¢£Ḅ¤⁐g¦§¨☠ª§«¬§¨⁐GᦑA┯/$BÐ6ᓄÒGÒ»Ó(GÔÕᜧG☟³{G()ᑖ´Ga´)µ⁐¶·ÚᵨNaOH()·◀¹(ᙠç»*ḄBr,ᦑB"#$2Cᢵ×yḄ¿⏣Ï⏚ឋÛ═⏚Ý6ᓄV¿⏚GÙ·Ú⏚ឋÛ═⏚Ý()¾⁐GᦑC┯/$DAÞßᵯàá᩽GV▢᩽GqᵯãGAᵯ᩽×3èéGᨵCu᪆yG56ᓄឋÇÄ6ᓄឋÈGcHZnḄeÅឋÇCuÈGᦑD"#Gᦑ⌱BD>?@⚪ὃCIᫀY?ËGC⌱⚗V᧕┯>GÉ3ê᧕ὃ⇋¿ÀGìᶍᢵ×yḄ¿⏣GKRÉ3îᔠïðḄὃCG*ñ56ᑖòóôAஹBஹCஹDஹEKõᕜ÷*éøᦪùúûᜧḄ5üýþᐗ
ᐸᐗAஹEḄᓫᙠᕈ᝱
ᐗBḄᨬ᜜ᵯᦪᐸᵯᦪḄ2
ᐗCᙠᕜḄᐗᨬᜧ
ᐗDḄᔠ"#$%ᵨḄ"'ᩞᧇ*ᑡ,-./Ḅ*0AᐗAஹB1ᡂḄᓄᔠᱥ56ᕈ᝱BᐗCஹDḄᨬ789ᓄᱥ:;Ḅ<ᓄᱥ=>?@A$B;CCDEᵨᵯF-ᑴᜓᐗCஹDஹEḄᓫD*ᓄᔠᱥAEICEᨵKLMḄᓄNOὃQRS᪀IᐗḄឋ*ᑖ᪆RᐗBḄᨬ᜜ᵯᦪᐸᵯᦪḄ2
BX2YᵯZ
BXC,X3YᵯZXS,AஹEḄᓫᙠᕈ᝱
ᐗCᙠᕜḄᐗᨬᜧ
ᑣCXNaᐗ
ᐗDḄᔠ"#$%ᵨḄ"'ᩞᧇ
ᑣDXAI,Sᔠ\ᦪ]^_ᜧ
ᑣEXCl,B`@XC,AXH,ᯠbSᔠᐗcᐸᓄᔠᱥḄឋᩭFe*FeRF:ᐗBḄᨬ᜜ᵯᦪᐸᵯᦪḄ2
BX2YᵯZ
BXC,X3YᵯZXS,AஹEḄᓫᙠᕈ᝱
ᐗCᙠᕜḄᐗᨬᜧ
ᑣCXNaᐗ
ᐗ

10DḄᔠ"#$%ᵨḄ"'ᩞᧇ
ᑣDXAI,Sᔠ\ᦪ]^_ᜧ
ᑣEXCl,B`@XC,AXH,A*ᐗAஹB1ᡂḄᓄᔠᱥh@X᝱ஹijஹkj
᝞mnCᦪop4YXj
qrYᦪ_sXijஹkj
ᦑA┯vwB*ᐗCஹDḄᨬ789ᓄᱥ:;Ḅ<ᓄᱥᑖxXNaOHஹy9ᓄz
@A$B;
ᦑB┯vwCCஹDஹEḄᓫXNaஹAlஹCl,CDEᵨᵯFᰚ|ḄNaCIᑴᜓNa,ᵯFᰚ|Ḅ9ᓄz2ᑴᜓz
ᵯF~ᓄiᑴᜓ~
ᦑC./wD*ᓄᔠᱥAEXHCI,ᐳ8O
CEXNaCI,O
ᓄNOLM?
ᦑD┯vwᦑ⌱CQR⚪ὃஹS᪀ஹឋḄᐵc;ᵨ
ᐗḄFeḄᐵO
ᐗḄឋcᓫஹᓄᔠᱥḄឋᓽhFe
⚪*66ᑖ0⏚NaNO
5ᐹᨵᕡஹᨵ
8¡¢£¤
NaCI
¥¦ḄCDᵨ2¤§v¨£¤©ᵨª«s¬ᦑA$*®Ḅ¯ᑖឋ᝞°ᑡ,-┯vḄ*0Ahᵨ±²Ớᓄ´µ¶·£¸␺x£¤
NaCI
I⏚
NaNO
2BNH᩽᧕p<
¼X®᩽ឋᑖI<ᑖ=>᧕½ᡂyO24CNaNOINH$ᡂNaNḄB;¿ÀÁX:NaNO+NH?NaN+2Ho224322432D᝞°ᡠÃcᑮḄᓄNB;Å9ᓄÆB;ὃQR⏚¤;yOḄÈᙠ:ᱥឋḄÉÊ;9ᓄÆB;*ᑖ᪆RA*⏚ᐹᨵËḄ9ᓄឋ
⏚ឋÌ᛻@ÎIỚᓄ´A$9ᓄÆB;$ᡂỚᓫwB*Nஹ0ஹFḄyᓄᱥh½ᡂyO
yOÉÊ<ឋwC*]Ï°ÐᓄᐵhÑ:NaN஺INH$ᡂNaN·<
B;Nᐗᓄᔠ8ᵫ+38ஹ
22243

11138ÕX
8wD(9ᓄÆB;×Øᨵᓄᔠ8ḄÕᓄ(FeRF:A(]Ï°ÐᓄᐵhÑ
⏚ᙠ⏚ឋÌ᛻@Î9ᓄỚᓄ´$ᡂᓫỚỚIᑮ±²ÕÙ
~ᓄ·KI?B;hÚᵨᩭ␺x~ᓄ·⏚
ᦑA./wB(ᨴÜ·<ᑖÅ᩽ឋᑖ
Ýὅ=>@½ᡂyO,ᡠÚàáᨴÜF
ᦑB./wC(NaN஺INH$ᡂNaN·<
B;Nᐗᓄᔠ8ᵫ+38ஹ28ÕX
8
]Ïãᜫᵯ224313åឤB;¿ÀÁX:NaNO+NH?NaN+2Ho,ᦑC./w22432D(ç°ÐᓄᐵhÑ⏚I~ᓄ╄iB;$ᡂ⏚é·~ᓄ
'pêᑖFB;
?Èᙠᐗᓄᔠ8Õᓄ
?'p9ᓄÆB;
ᦑD┯vwᦑ⌱:D(QR⚪⌕ὃì⏚Ḅឋ·9ᓄÆḄÑí
F⚪ᐵOᙠpî/°Ðᓄᐵ
ï៉A$ḄᓄNB;
⚪(7((6ᑖ)ᑡiᡈói
ᐵpôḄ,-./Ḅ().A(56ôḄé<õ<ö÷ḄøÀ
c(NH)/c(NHH0)Ḅ¢ùúûপ,I2..B(
ᙳ0.1mol.LḄNaCOஹNaHCOᔠ:c(CO),c(HCO),+2c(Na)233332,=3[C(CO)+C(HCO)]33”.C(0.2molLḄ⏚(CHCOOH)0.1moMNaOHᔠ:C(CHCOO)33,,+2c(OH)=c(CHCOOH)+2c(H)3,io,i2D(!"#$%&:K(AgQ)=1.8xlO,K(AgCrO)=2.0xlO,ᑣAgCrO()spsp22424

12++Ḅc(Ag)*+,-AgCI()Ḅc(Ag)ὃ/012
ᜧ,Ḅ45(ᑖ᪆0A(89:;<=*9ᔠ>ᵯ1@Z.B(ᔠ$COḄ9ABCCᜧ-HCO,DᙠᱥᧇHឤ$᪷KᱥᧇHឤᑨM@33C(Nὅᔠ$ḄPᱥPḄQ
ḄCHCOOH,CHCOONa,Dᙠᵯ₹Hឤஹ33ᱥᧇHឤ@D(ST&UᔲU⛳X$ᡠZ[\]+^12
ᜧ,(A_0A:A(89:;<=*9ᔠ>ᵯ1$ᡠZn(NH)`ᜧஹn(NHHO)a,$ᑣc«2.(NH)/c(NHHO)`ᜧ,ᦑA┯d@"2.2.B(ᔠ$COḄ9ABCCᜧ-HCO,ᡠZc(CO),c(HCO),Dᙠ3333*2.ᱥᧇHឤ$᪷KᱥᧇHឤg2c(Na)=3[c(CO)+c(HCO)],ᦑB┯d;33C(Nὅᔠ$ḄPᱥPḄQ
ḄCHCOOH,CHCOONa,Dᙠᵯ₹Hឤ33“…,c(CHCOO)+c(OH)=c(Na)+c(H)ஹᱥᧇHឤ2c(Na)=C(CHCOOH)+C(CHCOO),333iᡠZgc(CHCOO)+2c(OH)=c(CHCOOH)+2c(H),ᦑCj];33D(ST&UᔲU⛳X$ᡠZ[\]+^12
ᜧ,$ᦑD┯d@ᦑ⌱C(/l0m⚪ὃo12
ᜧ,45$pqὃorsᑖ᪆ஹᑨMtu$v]ḄPw

13+,᝞yᓫ{ὃ⇋cNHᐸឋPUAm⚪ᐵ$HឤḄᮣᵨ$᧕┯⌱⚗UA
ஹaNH.HO
,Nὅ
a,$᧕ᑨM$ὃ⇋ᱥPḄQ᧕ᑨM$᧕┯/32Nஹ⌱⚪mᜧ⚪ᐳ4,⚪$ᐳ58ᑖ814ᑖ%&ᓄḄᰚ/306?,/315?,᧕-9ᨵḄᔾ9ឋ$tᔾᦈ¡¢£Ḅ9ᑖ¤¥A¦r§,¨Ḅ©rª¢Ḅ«¬wᱥ®¯᝞#°±²³0
1
´µḄ¶·¸¹aஹgஹhஹdஹeஹbஹcஹf◀»¢Ḅᓄ¼¢
2
⛳X½¾9Ḅ¿ᵨU3
«¬*ÀÁÂᰐÄ⏀ÆÇ$ÈᓾÊËPÌᴻÎwᦈÏᘤḄᱥP*ÑÒÓÔÕ┵×Ø$8ᐭÚQḄ:¾⏚XÛÜÝᱥÞ«¬ÚBß₩$ᐙᑖ«¬$=â᝞#²³03+.?ãä⁐8ᐭæᑺXsᡂãé⁐Ḅ12«¬êBëFe+3SCN?FeSCN
32,3*?ãé⁐8ᐭÚQHOé⁐8ìḄíîUFeïHOðᓄsᡂFe,ñ¤`ᜧFe22223,,
$FeஹSCN«¬sᡂFeSCN
,ñ¤`ᜧòᔠᱥ
34
%&é⁐ó»Ḅ©Áᨵ¢sᡂ$ôõ³0ö,¨©rªé⁐ó»Ḅíî=â°±2?øó⁐ùú*ùû8FeCI[vüýᓄ;úNùû8æᑺX,þÿ⁐;3HCIBaCI⁐2?ḄFeCI2ᑺX,ᐭO,!"ᓄ32.3.%&?'!SCN()*+,-.Fe(*+;%&/Ḅ0Ḅ.᣸◀HOᑖ4ḄO5222“zᓄSCNḄ78;9:;<:>⁐Ḅ?@.HOASCN5ᓄᡂSO22“ὃDEFGᱥIḄJᡂᡈLMᱥIḄNM

14ᑖ᪆E(1)᣸ᑡQRSTUḄᑴ/WT/XY/ZT[Ḅ*+/\Tᜐᳮ_(2)⛳abcᔾᦈZᓄf,ᢓᑴZT4_3.(3)?᪷iFeKSCN*+ᡂjᔠᱥlmᓄ[,nᕈ⊈⁐_2+3+3+?FeqH05ᓄᡂFe,r,sᜧFe_22,(4)᪷i?FeCI!"ᓄ'!SCN()*+,-.Fe(*+3HCIBaCI⁐'!ᡂ)l⏚᪷_2᪷i/ḄFeCI2ᑺX,ᐭ0,!"ᓄ'!-85ᓄSCN(4wE4(1)l⏚ᐹᨵᔾcឋ8{ZTXYᑺஹ}~ᮞᐹᨵ}ឋ,ᔾᦈZTஹ⛳abcᔾᦈZᓄf,ᢓᑴZT4᣸ᑡQRSTUḄᑴ/WT/XY/ZT[Ḅ*+/\TᜐᳮᡠQRSa?g?h?d?e?b?c?f,ᦑwᫀS:aஹgஹhஹdஹeஹbஹcஹf;(2)⛳abcᔾᦈZᓄf,ᢓᑴZT4ᦑwᫀS:◀ZTḄZᓄfTU_3m.(3)?FeKSCN*+ᡂjᔠᱥlmᓄ[,nᕈ⊈⁐*+SFe+3SCN?Fe3*.(SCN);ᦑwᫀS:Fe+3SCN?Fe(SCN);332*3*3*3..?FeqH05ᓄᡂFe,r,sᜧFeFeஹSCN*+ᡂFe(SCN),r,sᜧj2232.3+3বᔠᱥ⁐ᦑwᫀS:FeqH05ᓄᡂFe,r,sᜧFeFeஹSCN22*+ᡂFe(SCN),r,sᜧjᔠᱥ_3.3.(4)᪷i?FeCI!"ᓄ'!SCN()*+,-.Fe(*+3

15HCIBaCI⁐'!ᡂ)l⏚᪷_2᪷i/ḄFeCI2ᑺX,ᐭ0,!"ᓄ'!-85ᓄSCN,ᡠ5ᓄSCNḄS5c_.3.ᦑwᫀS:SCN()*+,-.Fe(*+;᣸◀H0ᑖ4Ḅ05ᓄSCNḄ78;222,2.H0ASCN5ᓄᡂS0(224DE⚪FGZT[*+ὃ)ᱥIឋI%&ᫀḄ⚪0ᜧZT[*+Ḅ¡¢ஹ*+?ᳮ!£ᱥIឋI%&ᫀḄ?ᑣ⚪ᐙᑖὃ)¦Ḅᑖ᪆ஹᳮ48§¨ᓄ¦%&8§(9((14ᑖ)ᑴ{«I◚®¯°ᑖ±ᩞᧇ(M)´µPETḄᔠᡂ¶·᝞¹EᏧᓄᑺ1818-A»¼µ⏣7(᝞¹µ¾ᣚ*+:RCOOR'+R"OHRCOOR"+R'OH(RஹR\R"À⊤ᨵÂÃÄ)(1)AḄÅÆᑖ±IM.28,AஹBᑖ±NᨵḄÇ8ÄᑖÈ.ÉÉÊஹËÃ((2)BḄÌÍ.ÎÏ⏣(a(⌱ÑÒÓ)((3)*+IḄ*+ÔÕ.a(´*+b(Ö´*+(4)ᨵᐵBஹCஹDḄ'Ø£Ḅ.b(a.lmolBᨬÚ7lmolC*+b(CஹDÛ8nBrḄCCI>⁐c(DNaOHᐳÝ24Þ79ᑮBCàHS5PCH-C-COOH*HOCKCH<«CH-C-COOCHjCH

16(5)B?DḄᓄ¦.((6)CᨵÚáᑖâ᪀Uᐸåá.ᔠᡂæççèéḄᓫUëᑖ±ᙠ⏚ឋí᛻¹c49ᑮïáᱥðñḄÅÆᑖ±IMÅò16,ëᑖâ᪀UḄ;᪀ó.CHCOOCH=CH(32(7)*+/Ḅᓄ¦.COOCHCHOHôᓄᑺẄH*"THCCKCHOHõCOOCHCH'OH(ὃDEᨵÂᱥḄö÷(ø⚪EᨵÂᱥḄᓄ¦ឋI¨ö÷(ᑖ᪆E᪷iMḄ;᪀ó7¼DSCH=C(CH)COOCHCHOH,D(´*+9M,AḄÅ2322Æᑖ±IM.28,AùᓫIᡂஹ}ឋc49B,BCᙠl⏚Ýᩩû¹9D,᪷iDḄ;᪀7¼BSHOCHCHOH,CSCH=C(CH)COOH,üåýö9ASCH=CH,HOCHCHOH22232222COOCHJCHJOHCOOCH2cH20H(þÿḄE,ᔠEḄᑖEEḄPETB,⚪(:᪷MḄ᪀DCH=C(CH)COOCHCHOH,D!M,A2322Ḅ#$ᑖ%&'28,A()ᓫ%!ᡂஹ-.ឋ0B,B(Cᙠ23⏚!5ᩩ78D,᪷DḄ᪀BHOCHCHOH,CCH=C(CH)COOH,9:;<ACH=CH,HOCHCHOH22232222(ḄE,ᔠEḄᑖEEḄPETB,COOCHJCHJOH6COOCHjCOOCHzCHjOHCOOCHj

17(1)ACH=CH,BHOCHCHOH,=>?ᨵḄABCᑖD'EEFGஹHI,2222ᦑᫀ:EEFGஹHIM(2)BHOCHCHOH,BḄNO'PQ⏣22ᦑᫀ:PQ⏣M(3)᪷T☢Ḅᑖ᪆IḄWX'!ᦑ⌱a,ᦑᫀ:a;(4)ᨵᐵBஹCஹDḄ[\a(Bᨵ]^HIᡠlmolBᨬa2molCᦑa┯c;b(CஹDeᨵEEFGeBfBrḄCCIghi⁐ᦑbkl;c(D(NaOHg24hᐳ5nᑮBCḄpqᦑc┯cᦑ⌱b;CH^CO«HOCHCH<«'+A(5)B?DḄᓄstu'CH
HSQClt-C-COOH+HOCHCHḄ#$ᑖ%,ᙠᑖᡂT#:^wᑖx᪀yḄ᪀'CHCOOCH=CH,32ᦑᫀ:CHCOOCH=CH;32(7)Ḅᓄstu'COOCHCH-OH
11-1
HOCHcH*A1OOOCHCH,OH

18,ᦑᫀ:COOCHCHjOHIl@-BQCHJCHJ஺*H•-1)HOCHcH0H13COOCH

19ᑖ᪆ᔠ£¤ᧇ(¦⌕?FeஹCuஹC஺ஹLi¨C஺ஹFee'©ª£«çèᐭq⏚±²ᑮ£«Mé(q⏚Ḅê)ëh!ᐭ±ᓄìᓄíî´î´!ᐭ·0¸⁚ghPHfî´ºᓄìᓄﱯ°±²ᑮghA!ᐭ₝⏚╄gh»¼ò´±²ᑮghB¦⌕'┞´Ḅgh!ᐭE⏚p»¼┞´±²ᑮE⏚┞;ᨔ᪆ëCoCO-2HOô&õÝö¾ᑮᓄò⚪(242:ᔠ£¤ᧇ(¦⌕?FeஹCuஹCo.Li¨C஺ஹFee'©ª£«)!ᐭq⏚±²ᑮ£«Mé(q⏚Ḅê)ëh!ᐭ±ᓄìᓄíî´î´!ᐭ·0¸⁚ghPHfî´ºᓄìᓄﱯ°±²ᑮghA!ᐭ₝⏚╄gh»¼ò´±²ᑮghB¦⌕'┞´Ḅgh!ᐭE⏚p»¼┞´±²ᑮE⏚┞;ᨔ᪆ëCOCO-2HOô&õÝ÷¾ᑮᓄò242(1)Tøᑖ᪆ᑨ£«MCu,¯°±²¯°ᦑᫀ:Cu;±²M(2)!ᐭH0Ḅ°ᵨ'ᓄíî´î´Ḅ´tuëz++3+3*2Fe+HO+2H=2Fe+2HO;!ᐭ·0Ḅ°ᵨ'¸⁚ghPHfFeºᓄFe(OH)»¼222327mᦑᫀ:2Fe+HO+2H=2Fe+2H0;¸⁚ghḄpHfFeºᓄFe(OH)»¼M2223ᯏ¾(3)CoCOᯏ¾ᡂC஺஺ஹC00Ḅᓄstu4CoCO?2HO+3O2CoO+824232242223H0+8C0,22ᯏ¾ᦑᫀ4CoCO?2Ho+3O2CoO+8H0+8C024222322(4)LiC0¿gÀ0gúÂᓣüýþÿ,
LiCOḄᜫ2323♦2,90?c(LiCO)Ḅ
0.10mol/L,ᑣc(Li)=0.20mol/L,c(CO)=0.10mol/L233z

20,3!]Ksp(LiCO)=0.20x0.20x0.10=4.0xl0,23Jᦑᫀ
:LiCOḄᜫ;4.0x10;23(5)ᵨ"ឋᵯ᩽ᵯᰚ'LiCOᑴ)┞□᩽,ᡂ./012
34ᓄ6740ᵯ᩽8232.9:
2CO,4e=O?+CO?,aᦑᫀ
:2CO,4e=O?+CO?(322;<=>⚪@⌕ὃCᱥEḄᑖGHIḄJᔠ2ᵨ
L⚣ὃ;NOPQ,Ḅᑖ᪆ST7UVSTஹXYSTḄὃCJᔠឋZ[\]^UVḄ_97`ᳮbcd(11((16ᑖ)ᵬ⏣ij"ᩈ⏣"ᡈ"ᩈn"o;64.7?,pq⁐ᨵ⏀n0ᕡ᧕ᢵḄx1(ᵬ⏣ᨵyz{5,10mLS|}ᜫ~ᜧ{ᵨ(ᵬ⏣pO⌕ḄᓄQẠ`ᧇ7x1ᧇᵨPᑴ⌼ᵬ7ᵨᨵᱥḄ⃓)ᑺ7⏀nḄឋᑺd((1)ᑭᵨCO7H,ᵬ⏣89:᝞=22,iCO(g)+3H(g)?CHOH(l)+HO(g)?H=QkJ«mol22521iCᧇ:¡CHOH(l)+l/2O(g)?CO(g)+2H(g)?H=QkJmol3222232,?HO(g)=HO(l)?H=QkJ.mol,ᑣ⊤£ᵬ⏣Ḅ¤ḄᓄQ89:
1CHOH(I)+O22332,(g)?CO(g)+2HO(l)?H=(2Q+3Q+2Q)kJ«mol(221231(2)ᵨCO7HO(g)ᩭᔠᡂCO7HOᐙᐭ10L¨©ª«¬ᘤc®¯ᓄQ°22222CO(g)+HO(g)?CO(g)+H(g)?H,0,±°2®¯ᑮlOmin³ᑮ´⊝¶·H2222
0.6mol(¸ᑡº⚪=?0,10minᑁHO(g)Ḅ´ᙳ°2½᳛
0.006mol/L»min(2?ÀÁÂÃÄ°2½᳛ḄÅHLCOḄÆᓄ᳛ÇÈᵨḄ8Épac(a(ᓣLË

21bÌͬᘤḄ1ÎcÌÏᜧHOg
Ḅ2dÌÂᐭ〉±ḄÑᓄᑺ0g
,OÒ³ᑮᓄQ´⊝Ó᝱¶´⊝Õᔠ01cHḄ1Îᑖᦪ
25%22xÌᎷØ°2Ùx1ÎÚÛ±ᔣᵬÝÞᐭ01a7bD᩽▬àᕈâ⁐̸ᑡº⚪=„2.?aᱥEpCH0H,Aᵯ᩽Ḅᵯ᩽°2:
CHOH,6e+8OH=CO+6HO3332Þᵯ?ãäåcḄæᓄQ°289:
2NaCI+2H02Na0H+CI?+H?222?±ãäåcCᵯ᩽ᦈèᑮ224mLÌ᪗êÛ01ëcxḄpH=lὃ;=ᓄQ´⊝ḄXY;ᵨìí©î®¯ᨵᐵ°2ḄXY;ᵯ`ᳮÌᑖ᪆=
1
ðñᓄQ89:7ìí©îXYᑖ᪆ᑮᡠ◤ᓄQ89:ô
2
?´ᙳ°2½᳛=XYᑮôc"At?ÀÁÂÃÄ°2½᳛ḄÅHLcoḄÆᓄ᳛ðñᓄQ°2ö÷øù7´⊝úû`ᳮᑖ᪆⌱ýḄᩩÿ?ᔠ⊝ᦪᭆᓄ⊝ᑡᑮ3
ᵬᵯஹᵯᔣᵬ"ᐭ$%a&b'D᩽▬*ᕈ,⁐./DᵯḄ▢᩽CᵯḄ□᩽b3᩽a4᩽E□᩽F▢᩽5aᵬ⏣ᵯ᩽ᖪᓝ9:;<=ᓄ><ᡂ@⏚B?CDᵯ᩽⛳&FBG?ᵯ᩽>H&ᵯIJឤᡠMNḄPH

22jPQW(l)?C0(g)+3H(g)?CH0H(l)+H0(g)?H=QkJ.mol2232112R(g)?CO(g)+2H(g)?H=QkJmol?CHOH(I)+C)22223,?HO(g)=HO(l)?H=QkJ«mol,TUVW5x2+?x3+?x2ᑮQ223132⊤Yᵬ⏣ḄZ[\Ḅ\ᓄ]^CHOH(l)+O(g)?CO(g)+2HO(l)?H=(2Q+3Q+2Q)322212332RᦑPᫀQCHOH(l)+O(g)?CO(g)+2HO(l)?H=(2Q+3Q+2Q)kJ.mol;3222123(2)abcᵨCO&HO(g)ᩭᔠᡂCO&HOᐙᐭ10LgVhijᘤClmᓄ>HQCO2222(g)+HO(g)?CO(g)+H(g)?H,0,>HlmᑮlOmin'nᑮ⊝o'pH22220.6mol,ᓄ⊝ᑡCO(g)HO(g)?CO(g)+H(g)222+qrs(mol)11.50031.1ᦑPᫀ:6xl0mol»L»min;0.6moi10LlOmin?0,10minᑁHO(g)Ḅᙳ>Hv᳛==0.006mol/Lmin;2ᦑPᫀ0.006mol/Lmin;?CO(g)+HO(g)?CO(g)+H(g)?H,0,>HD$%%yz{Ḅᔾ\>H}~3222

23>Hv᳛Ḅ'coḄᓄ᳛cᵨḄ]Da(ᓣ>Hv᳛ᜧ⊝3ᔣlmᦑaᔠb(jᘤḄ%yᜧ⊝z{v᳛ᜧz2014-2015=ᓄ@ᓄ᳛ᦑBzᔠc(ᜧHO(g)Ḅ>Hv᳛ᜧ=ᓄ@ᓄ᳛ᜧᦑcᔠzd(ᐭ〉Ḅᓄᑺᦋ{>Hv᳛zᦋ{ᓄ⊝=ᓄ@ᓄ᳛z{ᦑdzᔠᦑPᫀ:ac;06X0.60.4X0.9?⊝ᦪK==l0(g),<ᡂ$ᱥḄsx2CO(g)+HO(g)?CO(g)+H(g)222.6{ᓄs(mol)xxxx1.4,x1.4,x0.6+x0.6+x⊝s(mol)(0.6+x)(1.4-x)2=10.6+0.41.4+1.4+0.6+0.6o'⊝ᔠ$%CHḄ%yᑖᦪ=xl00%=25%2ᦑPᫀ25%;(3)ᵬᵯஹᵯᔣᵬ"ᐭ$%a&b'D᩽▬*ᕈ,⁐./DᵯḄ▢᩽CᵯḄ□᩽b3᩽a4᩽E□᩽F▢᩽.2?b¡ᑖ᪆c£aᱥᵬ⏣ᵯ᩽>H:CH0H,6e+80H=C0+6H0;532

24z.ᦑPᫀ:CH0H;CH0H,6e+80H=C0+6H0;3332?CDᵯ᩽⛳&FBG<ᡂ¥$&$ஹ=ᓄ¦MN>HḄᓄ]^:2NaCI+2Ho2"ᵯ2Na0H+CI?+H?;22"ᵯᦑPᫀ2NaCI+2Ho2Na0H+CI?+H?;2220224L22.4L/mol?§¨CCᵯ᩽ᦈªᑮ224mL«᪗®¯$%'<ᡂ¥$ᱥḄs==0.01mol,,2CI,2e=CI?,ᵯI°0.02mol,Cᵯ±⏚²Ḅ>Hு"ᵯ2CuSO+2HO2Cu+O?+2HSO,ᵯI°4mol,>H2mol±⏚²<ᡂ±⏚2moI,ᵯ422240.02inol0.2L.I°0.02mol,<ᡂ±⏚O.Olmol,´I=0.02mol,cH
==0.1mol/L,MNḄpH=lᦑPᫀ19µQ¶⚪ὃ¹ºᓄ⊝ஹ>Hv᳛Ḅ»¼½¾ᑖ᪆ᑨÀ⊝ᦪஹ>Hv᳛ḄHᵨᵯᳮḄᳮHᵨ&ᵯCMNPHḄHᵨÂÃÄẠDᐵÇ⚪ÈÉCÊ«