浙江省六校联盟2021-2022学年高三压轴卷化学试卷含解析

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2021-2022ὃᓄᔁ⚗1.⚪ὃᐜḄஹὃṹᑏ!ᩩ#ṹ$%&ᙠᩩ#ṹ()ᑁ஺2.⚪,-ᢥ⌕0ᵨ2஺3.-ᢥ᯿⚪45ᙠ⚪ᓱᔜ⚪8Ḅ⚪()ᑁ9:;⚪()<ᑏḄᫀ>ᦔ@ᙠ₝BCஹᔁD⚪>ᦔ஺4.9EFᐜGᵨH2I;$JKLMᵨN⁐PQḄRP2SN஺5.Tᢝᓱ☢WX⌕ᢚZஹX⌕[ẚஹ[]XGᵨ^ᦋ`ஹabcஹdCᑐ஺fஹ⌱h⚪ij⚪kᨵfm⌱⚗nᔠ⚪p1ஹᓄqrஹstuvwwxᐵ஺zᑡ|}b$Ḅ~A.ᨵ“fcf”~“”Ḅ⌕ᡂᑖ~B.⏚ḄᾦḄḂᓄ~ᑖᡂᑖḄC.f¡¢£¤¥ᐸ8Ḅ~§¨©ª«¬ឋD.“᳝ᐢ°”Ḅ±□³ᵯµ¶·Ḅᩞᧇ~°ºᓄấ2ஹGarnet¼½᝱ᵯ«¿ÀÁ~┞ᵯµᨬÄឋ³½᝱ᵯ«஺LiLaZrTaOᩞᧇ~8³ÅᑮᨬᵯÇ᳛ḄGarnet¼ᵯ«஺ÉGarnet¼Fᐙᵯ┞ᵯµ¥ᵯ,Ë9Ìᳮ᝞EᡠÐÑ¡ÒÓÁLixC+Lii-6¥ᵯLaZrTaO^===^LiLaZrTaO+6C,zᑡ|}Xb$Ḅ~xᐙᵯA.¥ᵯ,a᩽ÁÕ᩽uºᓄÑ¡B.LiLaZrTaO½᝱ᵯ«Öᑮ×ÇLi+Ḅ9ᵨC.ᐙᵯ,b᩽Ñ¡ÁLiLaZrTaO-xe=xLi++Lii-LaZrTaOxD.ᐙᵯ,jØÙxmolᵯa᩽ÚÛ7g3ஹᵨNA⊤ÐÝÞßàáâᦪḄäzᑡåæb$Ḅ~
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2

1B.ᔣMg(OH)2ûü`éøßFeClð`3Mg(OH)+2Fe3+=2Fe(OH)+3Mg2+23C.ᔣNa2s2O3ð`éßᐭþóôÿ⏚
2s2O32-+4H+=SO4*+3S1+2H20D.ᔣᐭCO2
2c6H5(T+CO2+H2O=2C6H5OH+CO32-5ஹXஹYஹZஹWஹMᙳᕜᐗ஺25࠷ᐸᨬᓄᱥ#$Ḅ&ᓄᱥ(()ᙳO.Olmol/L)ḄpH*+,-.Ḅᐵ0᝞2ᡠ4஺5ᑡ789:;Ḅ<()A.XஹM>ᓫ@,-.ᜧBCD
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5ᑡ78┯vḄ<()A.P$Ë◤⌕9Í⊡ᐙFe2+B.□᩽P$F<2HC1-2e=Ch+2H+C.ᵯÐÑÒ1molᵯ,Óὑ᪗]55.6LD.ᵯÖP$צ<4HC1(g)+O2(g)=2Ch(g)+2HO(g)210ஹ5ᑡØÙÚ¦*ØÙbÛoÜḄÝÞ:;Ḅ<ØÙÚ¦ØÙbÛÝÞßàOỚ&RAcßàᐭỚ&Ớ&â⁐ãᑖä¢åP$BᔣFeSChkmK3[Fe(CN)6]®Ræ⁐çèFeSChérCᔣkᨵêḄNaOHᐭSChë⁐âìSO2ᐹᨵî¬ឋᔣ2mL0.1mol/LḄNaClkm3kd^()ḄAgNCh,ᯠᐜ®R¬⁐çèᯠQrKsp(AgI)

312ஹᑡḄ!"#$%&'Ḅ(A.)⏚+Ḅ,-CO2+HO=HCO+OH-323B.)⏚.┛012ḄNaOH
Ca2++2HCO+2OH=CaCO3+2H2O+CO233C.34+
056ᓄ)CHO+CO2+HO=C6HOH+CO326525D.78⏚012Ḅ9:3Fe+8H++2NO3=3Fe3++2NOT+4HO213ஹ;<=>?⏚@MSOMM2+B⊤Ba2\SB)ḄDE-F⊝HI᝞KᡠM஺OPQp(M2+)=-lgc(M2+),p(SO42-)=-lgc(SO42-)»ᔣlOmLO.Olmol/LNaSO4
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C.fgchiSrSCh
jᔣah>klmSrCL
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ᕈ¡ឋB."¢£Qr(Z)>r(Y)>/-(X)>r(W)C.¤ᓫ¦᝱.ᓄᱥḄ¨©;ឋQW

4D.ᑴᧇ——!ᮞ#$ஹ&⌱(⚪(+⚪ᒹ-5.⚪)17ஹᓄᔠᱥA2ᨵ4ஹ5ஹ678ᐗ:ᐸ<=>?3:1:4,B?ᨬAᓫḄ✏CD?ᨵ✏DᕡḄF஺HIJKḄᣚᐵN᝞P:,ÓÔ.ÖÍÍ»JH,CH,Î2HlpঝRSPᑡU⚪:(DAḄV᪀AX.ফCḄZ[\____________________________________________বCH2cH3Ḅ_`aᱥᨵ8஺(bὃ⇋efg᪀)(4)hiটḄᓄklX_________________________________________________________________18ஹmnofAḄpᡂឋ<stuvwxᡂ᝞Pᓄ஺Ayz{|Xᵫ~8ᓄᔠᱥpᡂXᐭyy⁐஺Xᐭ=6Xᐰᔾᦈᑮ_8⏚ᑮ1000mL,yḄPH=Lᙠy2KSCNyyᕈ⊈⁐஺RS|(1)ofAḄᓄkX.(2)ᑏ¡hiজḄᓄklX.(3)ᑏ¡hiট£ᡂAḄ¤¥lX஺19ஹ¦§¨©ᵨ«¬⏚(NaNO?)®¯°ᑺஹ²³ᑺஹ´ᩞ¶⇨ᑺஹ¸¹ºᜐᳮᑺ஺½ᐶ¿.pᵨPᑡÀÁᑴᜓNaN஺?wmnNOஹNO2Ḅ½_ᓄkឋ<(AºÀÁzᶍÅ)஺RSPᑡU⚪:ঝNO[⏚ឋKMnO46ᓄᡂNO,MnCh-ÇMn2+3

5পÀÁA7⚠ÊËÌ£hiḄᓄklX஺2
ᵨ¨ÍḄÀÁᑴᜓNaN஺?ᐸÎÏÐÑ|hÒᢥDÔlᔣᵨ.ᑏÖ×⊤ÙÚÛÜÝÞK1ஹ◀᝞àá®oবEÀÁÌ£hiḄ¤¥lX?஺4
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Xᵨ6ᨵ[\ᓄᑺஹ^_ᵨᩭ╄┱஺b>cdefᵨghḄViᰚkḄ┱ᑴᜓSnChn⛳NaClRSpqJi.SnChᙠsi᩽᧕vwᡂSnOrxHzOÙii.ᨵᐵᱥzḄᱥᳮឋz᝞~⊤ᡠ஺ᱥz⁐ᰚ/࠷/࠷Sn⁐2322260SnCl⁐2476522SnCI⁐-331144

6~ᑡ⚪J(1)$%EḄᘤ8,$%CḄᑺ8oফ$%GḄ6ᵨ8஺(3)DEḄ56.জ$%Aᜐ⏀¢£ঝ$%Dᜐ⏀¢£ঞᡭᑖS¥ᧅ§¨(4)HᑮḄ©ª«¬⁐8®ᨵ¯°____,FGᔣᐸ´ᐭᓫz(Lᱥz)¸◀º஺»¼0ᑖ½¾¿©ªÀÁḄ568஺(5)©ª®¯°SnCh,Â骿ÄḄ?ÅJÁ0.400g©ªRÆÇ°ÈÉ⏚´ᐭËÌRS6ᢣᑺᵨ0.010()mo/LỚ⏚Ï᪗ÑRSÒÃÓÔÕὑ᪗ÑS8.00mL.জÒÃ×ᳮ᝞~ØᡂiÙḄ½Ú?@A஺i.Sn2++IO3+H+=Sn4++Û+ii.IO3+5I+6H+=3I+3HO22ঝÒÃÔḄ-.8.ঞ©ªḄ¿Ä%(Þᶇàdᦪ)஺21ஹâ⏚8ã<äBåæFGᵫ~ᑡᵬஹéஹêëMᱥzᔠᡂ஺COOHIHQN-CH-CH-CH-COOH22ᑁ(1)ᵬ«⏚ឋḄíîï8(L)஺(2)~ᑡᐵÆéḄðÅḄ8(Lñ)஺a.ᑖÚò×Ú/ó×ÚḄôᦪõ875b.öÆ÷✏åᓄᔠᱥc.ùî/É⏚úî/ûüᓄýRSd.öÆþÿḄ
ᱥ(3)Ḅ
ᑖ᪀ᑡᩩḄ᪀a.ᨵb.ᙠ⏚!"ᨵ#⏚$ᡂnஹ\I*\*V/n(4)ᵬ()*+ᑡ,-ᔠᡂ(ᑖ0123ᐸ56ᱥ78ᶍ:)<

7জÛÜÝḄÞß(»ঝÛÜIËwᙠᔠᡂᵬ1$SḄâḄ(.ঞÛÜIVḄᓄä#$%n____________________________________=ὃ?ᫀஹ⌱⚪Øç⚪èᨵê⌱⚗ìᔠ⚪íî1ஹCூ᪆௃A.ïðḄ⌕ᡂᑖ(òY¶>ᦑA┯bÙB.ôõ⏚öḄ÷-(ᑖ"¿ᡂøᑖ"Ḅ1$>ᾦ~úᑖ">ᦑB┯bÙC.ûüýþÿ
ᐸḄឋᜫឋᦑCD.ấ“᳝ᐢ”Ḅ□"ᵯ$%&ḄᩞᧇấᦑD┯*ᦑ⌱C஺2ஹDூ᪆௃᪷/⚪123ᵫᵯ$567ᳮ9ᑖ᪆<=ᵯ$56
ᵯ>Li+ᔣb᩽ABᑣb᩽Dᵯ$Ḅ᩽EFG7HI,ᵯ᩽HIKDLxLi++Lii-LaZrTaO+xe=LiLaZrTaO,a᩽Dᵯ$ḄM᩽EFNᓄHI/Pᑖ᪆QRS⚪஺xூ௃A.᪷/TUᑖ᪆<=ᵯ$56
ᵯ>a᩽Dᵯ$ḄM᩽EFNᓄHIA⌱⚗B.ᵫᵯ$567ᳮ9<=LiLaZrTaOW᝱ᵯQYᑮ[Li+Ḅ6ᵨB⌱⚗C.ᵯ$ᐙᵯ>b᩽D□᩽EFNᓄHIᵯ᩽HIKDLLiLaZrTaO-xe=xLi++Li!-LaZrTaO,C⌱⚗;xD.ᐙᵯ>a᩽D▢᩽EFḄHID6C+xe-xLi+=LixC6`aAxmolᵯbcd7xg,D⌱⚗┯*Rᫀ⌱D஺3ஹAூ᪆௃A.Imolfghiᨵ9moiᵯbiᨵḄᵯbᦪD9NA,ᦑAB.᪗mnᓫpqrq"ᵨ᪗mnḄr᥅tuvw2.24LxḄᱥḄzᦑB┯*

8C.1001«10.101011-1(113<20(^^|}hCH3COO-~EFQᦪO.OINA,ᦑC┯*D.rzNᓄHI✌ᐜHIK᝞nL2NaOH+CL=NaCl+NaClO+H2O,ᙠHIhrᓫrᐙNᓄᑺᐙG7ᑺḄC17bNᓄᡂD+1G7ᡂD-10.1molḄrᙠHIhaAᵯbᦪᯠO.INA,ᦑD┯*RᫀA஺4ஹBூQ᪆௃A.ᔣAgNO3|}h¡¢f£z~¤ᡂ¥f¦§bHIḄ§bKDLAg++2NHyHO=[Ag(NH)]++2H2O,232A┯*B.ᵫMg(OH)2Ḅ|Q¨ᜧFe(OH)3Ḅ|Q¨ᡠ«ᔣMg(OH)2¬}h¡¢FeCb|}~EF®¯aᓄ¤ᡂFe(OH)3®¯§bHID3Mg(OH)2+2Fe3+=2Fe(OH)3+3Mg2+,BC.ᔣNa2s2O3|}h¢ᐭ±z²⏚EFHIFᡂNa2so4ஹᓫSஹSO2ஹHO,§bKDL2S2O32+2H+=S+SOT+H2O,C┯*2D.ᔣ´µ|}h¶ᐭ·zCO2rEFHIFᡂ´µ¸¹⏚HIḄ§bKDLC6H50+CCh+H2O=C6H5OH+HCO3,D┯*ᦑᔠᳮ⌱⚗B஺5,BூQ᪆௃XஹYஹZஹWஹMᙳD¼ᕜ¾ᐗÀᵫ9Áᑖ᪆<=7bÂLM>W>Z>Y>X,MḄ7bÂᨬᜧÄO.Olmol/LᨬÅNᓄᱥÆIᓄᱥ|}ḄpH=12,ᑣMDNaᐗÀ().()lmol/LWḄᨬÅNᓄᱥÆIᓄᱥ|}ḄpH<2,ᑣWDSᐗÀO.Olmol/LZḄᨬÅNᓄᱥÆIᓄᱥ|}ḄpH=2,ᑣZDClᐗÀXḄÂᨬᐸ0.01mol/LḄᨬÅNᓄᱥÆIᓄᱥ|}ḄpH=2,ᑣXDNᐗÀO.Olmol/LYḄᨬÅNᓄᱥÆIᓄᱥ|}Ḅ2Na+,A⌱⚗B.ZDC1ᐗÀᐸḄᨬÅNᓄᱥḄᓄᱥḄᓄÑKDHCIOsB⌱⚗┯*C.XஹYஹZஹWஹMÒÓᐗÀhᨵNaᐗÀÓÔÕᐗÀC⌱⚗D.XḄᨬÈᓫᓄᱥDN%,ZḄᓄᱥDHCLὅHIÖFᡂḄᓄᔠᱥDNH4C1,§bᓄᔠᱥi§b×ᵫiᨵᐳ×D⌱⚗Rᫀ⌱B஺ூÙÚ௃

9A⚪⌕DE$FGHIJKLMNᓄPQஹ⏚RឋTpHḄᐵVWFGXYZNᓄ[ឋ\ᔠ]ᩭ_`aᐵᐗcḄᑨefE$ḄgᔠFh⌕DijᙠklḄEm⌕nofaᐵpqrḄstu஺6ஹDூ
᪆௃c(NH
\c(OH-]10-3]0-3A.wxlyz{|!pH=lLᑣc(0H-)=l~3mol/L,~4——----------------^Xll^mol«L_1,⌱⚗AC(NH^HO)0.52B.-2ᓄᐭᓄ0Keᜧ0KᜧᵯFhbஹcrfᵯFh⌕T0Kᵯ᳛ᨵᐵ⌱⚗BCஹ᪷-1(pbr6$ᨬᜧ¡¢fḄ-2ᓄᐭᓄcr6$¡¢ᨬᜧ£¡¢¤¥"cd¦§$Ḅ¨Al(0H)+0H=[Al(0H)]\⌱⚗C34Dஹa
(1.5molLT)NH3H203KOHᐭ©aVὃ⇋«᪷0K!"eஹf¬ᐭ0K

10B.HC1ᙠ□᩽ᜫᵯKæᑮCL3H+,ᵯ᩽¨<2HC1-2®=CL+2H+,BC.᪷ᵯKæᜫðឤᨵ<024e,ᵯ,òó1molᵯKôὑ0.25mol¯᪗÷©5.6L,CD.ᵫø(p¨ᱥHCl(g)3(h(g),$ᡂᱥH2O(g)3CL(g),ᦑᵯ"s¨(ùÏ4HCl(g)+O2(g)=2Ch(g)+2HO(g),D஺2?ᫀ⌱A஺10ஹDூ"᪆௃A.Xü*ᐭỚ!Xü*ᐭỚ!üTỚ!§$þ¬ᡂ¨A⌱⚗┯®B.ᔣFeSO
K3[Fe(CN)6]
⁐
ᨵFe?+,FeSCh
ᨵᑖB⌱⚗┯C.ᔣᨵ"ᲩḄNaOH
%ᐭS()2'(SCh⏚ឋ+ᓄᱥ./01ᡂH2so3,3NaOH,456
7⁐89.ᐸ;<ឋ=ᐵC⌱⚗┯D.<⁐ḄAgCl?ᓄ@A⁐ḄAglBKsp(AgI)VKsp(AgCl),D⌱⚗CDEᫀ⌱D஺11ஹBூJ᪆௃AஹᵫNOPQCO2+H2ᙠNa-Fe3(hSᓄᑺ⊤☢01ᡂWᚗ᪷Zᐗ\3]^_ឤQᐸ01@aNa-FeO342co2+6H2=CH=CH+4HO»ᦑA┯222BஹdᱥFe5c2=eᱥ?ᓄ@ᨵeᱥḄdᱥ?ᓄḄᐵfᦑBCDCஹSᓄᑺHZMS-5Ḅgᵨi01j᳛lm⊝᳛oᨵpqᦑC┯DஹᵫPᑖ᪆78%r⊤sCO2?ᓄ@tuḄ?ᓄ᳛ᦑD┯ᦑEᫀ@aB஺12ஹBூJ᪆௃A.v⏚w
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.+ᓄv01"ஹNaHCCh,01O@C6H5O-+CO2+H2OC6H5OH+HCO-C┯D.⏚.Ḅ01Fe2+,3Fe+8H++2NO3=3Fe2++2NOT+4H2O,D┯ᦑᔠᳮ⌱⚗B஺13ஹC

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Ba?+cᜧஹc
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