河北省衡水十三2021-2022学年高三压轴卷化学试卷含解析

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444444444444জàᙠá1âãᓄ¦ᨔÛḄäåáঝuæ`çèḄ¦`ᨵ@éuêé¦`çèḄ¦`ᨵ@é஺29ஹ10ᑖ¿ëìᑁîïîðBᙠñòóô<6õ?NO11Co(NO)C(O)020.010.012.5x10-30.010.025.0x10-30.030.024.5*10-2تJK,᳛Ú\VE=KÛxcm(NO)Mcn(O),ᑣm=,KÛ=L2•2mol'2•s'1বᙠ¸L-v(ឤL)"ᔣ=b½Ḅ{ᘤᐙäNO?å="æUJK2N(h(g)=N2O4(g),å=ᑖçèéêḄ½ᓄᐵì᝞B1᝞D஺জXJKḄçíî⊝¤ᦪK=Pঝ4séçðñò(ñòóᶍ'õ)ö{ᘤ=½:=Ḅ1/2,6sé÷øᑮî⊝"ᑣP(NO)=kPa.24(4)¸©ù¿úᑭᵨB2üýþÿᔣ
ᐭᜐᳮḄᓄᱥ஺ᑣNOᙠbᵯ᩽Ḅ2ᵯ᩽!"#»+ὃ-ᫀ%ஹ⌱(⚪(ᐳᒹ-22./⚪஺0/⚪ᙳ2ᨵ%.4ᔠ⚪6Ḅ⌱⚗)1ஹDூ:᪆௃XஹYஹZஹW#=>?ᦪABCᜧḄEᕜGᐗYஹW#I%ᕜGᐗJW=>Ḅᨬ᜜Mᵯ>ᦪNOY=>Ḅ᪶

12᜜ᵯ12ᦪ᪷45ᡂḄ78ᓄᔠᱥ;᪀;ᔠᔜᐗ?5ᡂḄ@ABCDXEHஹYECஹZENஹWEO஺A.HᕜJᐗ?KLᑮNO1PQRSTUᦑO1PQ:Y>Z>W>X,⌱⚗A┯[\B.]ᓄᔠᱥ^ᔜᐗ?ḄO1◀`O1ᨬ᜜bE2ᵯ1;᪀ᐸdᙳfg8ᵯ1;᪀⌱⚗B┯[\C.XhY5ᡂḄiᐗᓄᔠᱥᨵk8l7mEn᝱᝞pC6H6,⌱⚗C┯[\D.XஹYஹZஹWB5ᡂO1qᦪr8123ḄᓄᔠᱥNH4”CO3,⌱⚗Dst஺-ᫀ⌱D஺ூvw௃y⚪ὃᐗ?ᕜJ⊤ᐗ?ᕜJ{ḄD|C}ᔜᐗ?~⚪ḄᐵA஺᪷45ᡂḄ78ᓄᔠᱥ;᪀;ᔠᔜᐗ?5ᡂḄ@ABCDXEHஹYECஹZENஹWE0஺2ஹAூ᪆௃A.lᑴ◌ᘤḄ^ᡂḄᱥᓄᓄᦑA┯[\B.☘~78BឋḄᐭᑮḄᦑBst\C.᝱Ḅ᧕ᡂn¡¢£¤¥ឋᨵ¦ᱥ§¢¨©ᡂ©ᓄKª■¬ᐸᡂn®¯ᢣᕈ²®⁐Ḅ©´ᦑCst\D.µn¶ᑣᑭᵨ¹ºᔠᱥḄ»v¼½ᑖ¿ᑣ]ÀEÁᦑDst\ᦑ⌱A»3ஹBூ᪆௃A.ÂÃḄiÄᓄấÆÇᵨᑴÈᐝÊËÌiÄᓄấ¢Íh`ÄᓄÎÏÐÑᡂấ⏚¨ÓᡠÔᐝÊËÌ¢ÍÕÑῖ⇨ª⌼ᡂÙÚᦑAst\B.ÛÜÝÞᛛᧇàEáᨵÜᨵ¦BÔâãᩈᩞæç⚶éᦑB┯[\C.êëìí⊤☢ïᜧ᧕ᔾ▬`nᡠÔBÔᵨÈóÁ`ᩞᧇᦑCst\D.ôõ8ḄᓄឋHᙠö÷ᜐù᧕ᵯᓄῖ⇨ᦑDst஺-ᫀ⌱B஺4ஹCூ᪆௃᪷4ÄᓄúO^ᜫᵯ1üឤஹᐗ?üឤþÿᑖ᪆஺ூ௃A.ᐰᑮ2.54gᓄஹᓄ╅ᦑOH-Ḅ!2.54g-1.52g=1.02g,»OH
=-^^-=0.06mol,᪷#ᵯ₹&ឤ()*+ḄᵯᱥḄ-.OH-ḄᱥḄ/ஹ╅ᔠ'717g/mol

13CuஹMgḄᱥḄᑖ2xmolஹymol,ᑣ:2x+2y=0.06ஹ64x+24y=1.52,!x=0.02ஹy=0.01,ᑣ5ᔠn(Cu):n(Mg)=2:bᦑA678B.᪗:;1.12L<=ḄᱥḄ0.05mol,/>ᔠ<=?ᓄ@ḄᱥḄamol,ᑣAᓄ?@ḄᱥḄ(0.05-a)mol,᪷#ᵯBC&ឤ()!ax]+(0.05-a)x2xi=0.06,a=0.()4,ᑣ>ᔠ<=Dᨵ?ᓄ@O.()4molஹAᓄ?@O.OlmoLNO2FN2O4Ḅ>ᔠ<=NChḄ=Gᑖᦪ!——0-041-)1——xl00%=80%,ᦑB6780.04mol+0.01molC.50mL5J⏚DᨵJ⏚ḄᱥḄ14mol/LxO.05L=O.7moLLMNḄOJ⏚P᪷#NᐗR&ឤJ⏚PḄᱥḄ!n(NaN03)=n(HN0)-n(N0)-2n(N204)=0.7mol-0.04mol-0.01x2=0.64mol,ᦑ◤⌕ᓄPOUḄ=32G864ᔳ=o64L=640mL,ᦑC┯W81mol/LD.CuஹMgḄᱥḄᑖ20.02molஹO.Olmol,ᑣXᡂCu(N()3)2ஹMg(NCh)2ᔜ0.02mlஹO.Olmol,NO2FN2O4ḄᱥḄᑖ20.04molஹ0.01mol,ᑣ᪷#NᐗR&ឤ()[ὑJ⏚ḄᱥḄ0.02x2+0.01X2+0.04+0.01x2=0.12mol,ᦑD678]ᫀ⌱C஺ூ`a௃]5⚪Ḅᐵdefᑮgẚi!╅ஹjJ⏚LMᜫᵯᱥḄjlmᔠ᪷ḄᱥḄn-ᐵopCu~2eஹCu2+~2OH-,Mg~2e~Mg2+~2OH,qrᓄ╅jᓄḄsj╅ᔠḄt(u᪷ḄᱥḄvw7xLMBCḄᵯᦪ஺5ஹCூ
᪆௃Aஹyz{|}~᠒ḄXᡂ᳛⌱⚗A┯W8—Bஹ{;pH=4Ḅ⏚OUNOUḄ|yzᵫc(OH-)=w)()᪷Ḅ|ᜧ⌱⚗B┯W8CஹLM4Fe(OH)2(s)+2H2O(I)+O2(g)=4Fe(OH)3(s),AS<0,{;AH-DASCO,()AHV0,⌱⚗C678Dஹஹ(5LMḄ⊝ᦪḄ᎔ᦪ,{|⊝ᦪᑣ5⌱⚗D┯W஺c(SO)c(O)22]ᫀ⌱C஺6ஹAூ
᪆௃A.╅¡ᨬ᜜¤¥ᨵ2¦ᵯ᧕ᜫ¨4.8gMgᙠªCO2«¬BCḄᵯᦪ0.4NA,ᦑA678

14B.ℍ⃔¯Ḅm᪀±pCH20H(CHOH)4cHO,²¦ℍ⃔¯ᑖDᨵ5¦³´ᡠuO.lmolℍ⃔¯(C6Hl2஺6)D³´(-OH)ᦪ¶0.5NA,ᦑB┯W8C.{·;4.48LCO2FNth>ᔠ<=e0.2moLᡠD¡sᦪe0.6NA,ᦑC┯W8D.Pj¹º(uLMXᡂ<ᦑD┯W஺ᦑ⌱A஺7ஹBூ
᪆௃A.»¼ᑖe☢ᑖ5ᓄᔠᱥDᨵ⛳FḄ¿¿ÀdjÁ¦⛳F¿¡ÃÄḄC¡ᙠ»¼ᑖḄ☢ᑁÆ.»´ᩭuÈᵬ´C¡ẆËÆÌᐸᕜÏḄC¡᪀ᡂḄeA☢=m᪀ᨬЦ⚔`j5¡ᙠÒ²☢Óᡠu5ᑖḄ5¦¿¡(ᐳ☢AÕᔠ⚪Ö8CH3B.j5ᨵ×ᱥDnÒØÙḄÒᑖÚ᪀=ᨵCH2=CH-CH2cH2cH3ஹCH3cH=CH-CH2cH3ஹIஹCH2=CH-CHCH3?H3,BÕᔠ⚪Ö8CH3-CH2=C-CH3c.5ᱥᑖDᨵ¿¿ÀdjH2XÛᡂLMÜXÝ`8jᓴᓄFᓴRᓫXÛᡂLM(ᑴᓴá«CÕᔠ⚪Ö8D.âÝឋäxl⏚ឋå═⏚çOUᓄw5ᱥᑖDᨵ⛳F¿¿Àd(ul⏚ឋå╎⏚çOUᓄwéᐸê⁐(uᵨ⏚ឋå═⏚çOU␺2?ὅDÕᔠ⚪Ö8ᦑᔠᳮ⌱⚗eB஺8ஹAூ
᪆௃ð╅ñḄò⌕ᡂᑖeMgC(h,óDôḄAI2O3ஹFeCCh-ÛᐭrX⏚O᪷#ö÷¶ḄX⏚eø⏚8qᐭù⏚ᦑA┯ABBஹᐭCDᓄEFD7GHIpH◀ᐗLᦑBMNBCஹ᪷7Pᑖ᪆QRMgOI⁚pHᑮᓄஹᓄᡠ7TᔠᱥEFe(OH)3WA1(OH)3,ᦑCMNBDஹ╅=XYZ[ᡠ7ᙠ%&P\ᑭᵨᵯ"ᰚ_ᓄ╅Ḅ`aᑴ5Z[╅ᦑDMNBᦑ⌱Ao

159ஹCூ
᪆௃A.dᨵeᱥḄfᡂᐗLhᨵᐗLWiᐗL[HjklHᦑA┯ABB.dᑖm.ᨵ⛳WiomlQpᡠᨵomᐳ☢ᦑB┯ABC..ᨵiistQ7uvᓄwxWᡂwxᦑCMNBD.ᵫz᪀|}ឋQR.4H,ᱥᨵ4ᦑD┯ABᦑ#ᫀECo10ஹDூ
᪆௃᪷QRwxE(1)ᜫᵯmEmFe(ID)ᵯmEFe(II);(2)Fe(II)ᵯmEFe(HI),NO2-Fe(II)/oEN2஺᝞H2◀⏚ឋḄᱥNth-ḄḄwxE3H2+2N(h-+2H+=N2f+4H2O஺ூ
௃᪷P☢ᑖ᪆QRA.PdPuvḄᵯ᩽wxEH-2e--2H+,ᦑl⌱A2B.ᵫQRFe(II)Fe(DD=dwxḄᓄᑺᐸᓄᑮ¡¢⌴ᵯmḄ¤ᵨᦑl⌱BC.wxNO2-Fe(H)/oEN2,ᦑl⌱CD.wxE3H2+2NO2-+2H+=N2T+4H2O஺ᵨdaᜐᳮᵫHὑ¨ḄmpHᓣªᦑ⌱D#ᫀD11ஹAூ
᪆௃᪷ᑖ᪆A|om2«E28Ḅ¬ᡈFᐗLfᡂᓄᔠᱥ®᧕°ᑮᓄiW±²³Bᑖmᨵ18´ᵯmḄᓄᔠᱥ®᧕°ᑮᓄஹµᓄஹ¶ᓄஹấ¸ஹ±¸ஹᵬ⏣»¼⌕᪷⌕uvwx®᧕°ᑮAE±²BEᓄCE±¸DEEEᵬ⏣½³XஹY,ZஹWᑖ¾EHஹCஹOஹCLூ
௃A⌱⚗C,HfᡂᓄᔠᱥEÀÁ=Â᝱ᓻḄÅ᎛ÇÈQpÉHஹOfᡂᓄᔠᱥḄÇȪᦑA┯ABB⌱⚗CḄᨬªDᓄᱥḄᓄᱥ=i⏚ËEÌ⏚ᦑBMNBC⌱⚗YஹZfᡂḄᑖmCᓄiEÍ᩽ឋᑖmᦑCMNBD⌱⚗ÎᕜнÑᑮÒÓÔ⌲Ö×ØÙC1=ÚFᕜÐomÓÔᨬØḄᐗLᦑDMN஺ÛPᡠÜ#ᫀEA஺12ஹC

16ூ"᪆௃A.ßᵨᓄᑺpàáwxḄXᓄpßwxâ᳛äᵫQRᓄᑺdÉᓄᑺcßXᓄpàḄåæᡠ7ᓄᑺXឋc-⊝⌕ᜧCN
aᐸᵯ᩽AL-+2e-=3A⚗┯B.ᵯSZ[ᐸ120ᔣA“Zn-ᵯ᩽a,ᵯ᩽b-"B⚗┯C.1Imolᵯ
ᨵOSmolZi?+v1ᔣlC⚗┯D.<ᵯḄᐙᵯ¡¢£¤ᵯᑁF¦ᣚ¨Ḅ©ª«4¬ᡠu“®¯⍝”Ḅ²ᵨ3u´ᵯ©µḄ4¬¶·ᵯ¸¹D⚗@wᫀ⌱D஺

1715ஹDூa᪆௃A.»ᓄᑺa⊤☢3gJ¿ᡂÁ»ᓄᑺa⊤☢ÂÃ᩽ឋᐳÅÆḄTÇJ᩽ឋÆḄÈᡂᦑAᔠᳮB.»ᓄᑺËÌÍᓄᦋ%᳛8SᦋÎᦑBᔠᳮC.»ᓄᑺb⊤☢3Á»ᓄÏᓄᡂNOḄḄ3Ïᓄ>ÐÑᵯ1ᦑCᔠᳮD.»ᓄᑺaஹbᦋ%᳛Sᦋᓄ-⊝SÒÓḄ-⊝ᓄ᳛ᦑDSᔠᳮᦑ⌱D஺16ஹBூa᪆௃A.ấ⏚Õ3᧕Z5ᵯaq×ᑏᡂFA⚗┯B.ÙÚSO2ÛNaCK
Ïᓄ>ᡂḄH+ÛCKTᡂB⏚HC1O,B⚗@C.Ó═⏚ÝZ[ÏᓄÞÏß
ÞÏßKḄÏ>àᵯ1áÓ═⏚ÝKḄâ>ᑏᡂ2MnO4+5H2O2+6H+=2Mn2++5Of+8H2O,C⚗┯2D.ãᡭå⏚gÕ×ᡂNa+JHCOj,D⚗┯஺{⚪⌱B஺ூyz௃+4Åæᐹᨵè5Ḅ>ឋ+1Åéᐹᨵè5ḄÏᓄឋêë᧕Ïᓄ>஺17ஹAூa᪆௃A.Ci?+ìíîFïðñqឋᦑCuSO4ᵨ*ÍᵨßWòA┯B.ᓴßôõῖ3Mg2+ஹCa?+Iïðñq÷øù¡B@C.úûZ[üûឋuýþ⚶ᐹ
ḄCD.ᑵᙠ⊤◞ᵨᩭ■┤⇨Dᫀ⌱A஺18ஹBூ$᪆௃A.'(
ᨵ3*+,-
ᨵ2*+ᐸ/01ᱥᨵ5*ᦑAB.4ᵬ6789:;<Ḅ9:ᡈ6>?ᡂA☢CD᪀ᑖ:7ᡠᨵ89:HIJKᙠL/M☢ᦑB┯OC.Pᨵ'(IQRSTᡂUVWX1UVIQYZ,-IQ[⏚ឋ^_⏚`abcᓄᦑCD.'(JW+RSTᡂUV1moleᱥfᨬhJi3moljRSUVᦑD஺ᦑ⌱kB.ூlm௃/01ᱥḄ*nᓽᑨqᑖ:ᑁḄsᦔ+ᦪv/wL/xᵬ6
Ḅ+sᦔஹL/x8
;

18D᪀Ḅ+sᦔ஺19ஹCூ
᪆௃A.ᵫ}I~al⊤SO2Cᐭ112mLᓽ0.005molpH=7,abᕈ7ឋSthCWH2sabាᐰUVI~⛳iH2sab7afᱥfḄO.OlmoLc(H2S)=0.1mol/L,alH2salSO2,abᙳᕈ⏚ឋ⏚ᢓᑴḄᵯᦑalḄᵯᨬᜧḄᵯᐜᜧᦑA┯OB.ᵫ}7lI~O.lmol/LH2sabᵯḄc(H+)=l()4imol/L,ᵯ¡¢H2SUH++HSஹHS^H++S2Q£in-41xIO-41/¤¥᪷§M⊝©ᦪ⊤ª¢«e¬112sḄᡡ¯[IH0-72,ᦪ°10-8,ᦑB┯O0.1-10-41C.±SO2Cᐭ336mL²±³ab7Ḅc(H2so3)=0.1mol/L,´H2sO3⏚ឋµ³H2S,ᦑ¶ab7yVḄpHV³4.1,ᦑ·¸y1⊤¹ºᐭSO2CabpHḄ»ᓄᦑCD.᪷§M⊝©ᦪ⊤ª¢I~ᚪ,==½7,al¾S(hCḄᐭc(H+)ᜧ±c(H2so3)c(H2so3)C(H)c(H)ᐭḄSO2Cª⛳ic(H+)ÄH»ÅKalÆÇ/xÈÉÊËḄÉÌᢝH»ᦑD┯Oc(H2so3)ᫀ⌱c஺20ஹAூ
᪆௃ᐗÏXḄ/*^ÐᓫfÇÒÓᓽXÇC,Y?+ᵯ:D᪀WIJLᑣYMg,ZḄf:ᦪᏔᦪZIJÇSi,ÆIJÇS,׬MḄᓫfØÙ⁐ÛCᑣMS,ᓽZSi,AஹCWSJÜ<ᓄᔠᡂCSz,ᦑÞ┯OBஹ╅ᔠfàÐᜧὊ^¬IᵨâããᜩåæᘤᩞᧇᦑÞCஹ+-ëMg-h/xᵯ:´¶S஺-Ḅìíᜧ³Mg2+,ᦑÞDஹ+ᓄᱥᑖîÇCH,ஹSiH,ïឋðµ+ᓄᱥðñÈïឋC>Si,4ᓽCH,ëSiKñÈᦑÞ஺21ஹBூ
᪆௃ὃóᑭᵨWḄ/*LõÏöÈ/÷ᦻᱥḄù1ᑣWCXÇᙢû7PᨬhḄᐗÏᑣXOYஹZḄf:ᦪᑖîÇWஹXḄf:ᦪḄ2üᑣYḄf:ᦪ6x2=12,YMg,ZḄf:ᦪ8x2=16,ZS,RḄ9:ýᦪᨬᜧRCLQ¶ᩭ$஺ூ
௃ᵫ
þᑖ᪆I~WCஹXOஹYMgஹZSஹRCIA.MgWCChlYRSÿᣚ
ᡂMgOஹC,ᦑAB.ᓄஹᓄᙳᮞᑣḄᮞ␺ᦑB┯!

19C.#ᕜ%&'ᔣ)*+,-./ᑣ*+,-0Y>Z>Rᵯ+2345+,-3ᜧ7ᐹᨵ:#ᵯ+᣸<Ḅ5+=*+>ᦪᜧḄ5+,-/ᑣ@ᓫ5+,-0Z>X>Y,ᦑCD.MgBCDEFGHIJᵨᵯLᰚNOᓄ╅QRMg,ᦑDᦑSᫀBB஺22ஹBூ
᪆௃VWXEFᩞᧇ[◀EFᩞᧇஹ]ᑖ+ᩞᧇ_᜜ḄᡠᨵᩞᧇḄbc஺d[ᵫấ⏚hஹi⏚hஹj⏚hஹk⏚hஹ┯⏚hl*ᧇmnᡈpᓄᱥஹrᓄᱥஹᓄᱥஹjᓄᱥஹᓄᱥஹấᓄᱥஹᓴᓄᱥl*ᧇtuvḄGwᑴᜓzᡂḄᩞᧇ,ᵫ|ᑨ~஺ூ
௃A.…VᔠEFEFᩞᧇ=ḄᔠEᦑA┯!B.ᵬὊSiC2FVWXEFᩞᧇᦑBC.…WᢱᯚiᔠEFEFᩞᧇ=ḄᔠEᦑC┯!D.ᨵWấᓽᨵWấᓄᔠᱥ[ᢣᨵSi-Cஹ7ᨵuᨵW[ấ*+:ḄᓄᔠᱥI¡¢£¤¥¦ஹஹrlᨵWấ*+:Ḅᓄᔠᱥ§¨ᨵWấᓄᔠᱥFVWXEFᩞᧇFᨵWᩞᧇᦑD┯!Sᫀ⌱B஺ூ௃Lª⚪Ḅᐵ[⍝¯°[VWXEFᩞᧇVWXEFᩞᧇ[◀EFᩞᧇஹ]ᑖ+ᩞᧇ_᜜ḄᡠᨵᩞᧇḄbc஺ஹX⌱±⚪nᐳ84ᑖp23ஹ³´µᵬ¶nᡈ4-´µᵬ¶p·ஹ⏚Ci3Hl403cL¸ᡂ
COOHBr+HBr12BrCHLᔆCH-HC-0-CH-COOH32CH,CH3ூ
᪆௃A(HOpHCHOᙠ»ឋᩩ¾¿À¸ᡂ
ᡂBnHOCHOH
BᓄᡂC2HO-CᡂDDQiÁÂÀÃÄ
ᡂE>

20`HBraEbᓄcᡂF(j⏚ឋᩩijk:cᡂlCl),mnᑖ᪆஺ூp:௃(1)C#HO-—CHO,qr#stuvᵬx(ᡈ4-tuvᵬx);{ᫀ}stuvᵬx(ᡈ4-tuvᵬx)F~#uஹ⏚;{ᫀ}uஹ⏚(3)H#ᵫ᪀"HḄᑖ>"#Ci3Hl4O3CI2;{ᫀ}C13H14O3CI2(4)!জ#ᡂ!,!ট#!ᱥᨵHBr,ᓄ"#{ᫀ}ᡂ!-+HBrBr(5)M#ḄIᑖ᪀ᩩiḄMḄ᪀"#HC—CH—CH—CH,ஹCOOHCOOHBrHG-CH—CH—CH^2COOHCOOHCOOHCOOHBrBrBrCOOHBrCOOHH,C—CH—€H—CH^H3C—CH—CH}—CH}ஹH,O-C—CH2COOHஹH2C—CH—CH2ஹBr—CH,-C—CH^COOHCOOHCH3CH3CH.,BrCOOHIHC—CH—CHCOOHᐳ12;ᐸiHNMRᨵ3J☢¢£¤#6:2:1Ḅ᪀"#BrCH[%C—CHஹ3IICHCHS3

21BrIHc—C—€HCOOH;32ICH3COOHBrIISᫀ012ÅBrCH-G—CH,,HC—O-CH,—COOHaIICHCH,a(6)᪷Ç⚪ÈÉÊজঝঞÎÏÐᔠᡂÑÒᵫÓÔÕB*ᧇᑴᜓOuḄᔠᡂÑÒB{ᫀ஺¥K/¦5§¨©ூ×Ø௃Úঠ/⚪ÜÝ#ᑖÞ᪀àB᧕┯×Î_ᑖâv0জ᪷Ç#ᑖÞ᪀à⌕äÎåᙠæçè-COOHஹ-BrঝvéÅêঞëæçè-COOHஹ-BrJᵨvuìuív#ᑖÞ᪀àÅê஺24ஹ2-O-1,3-ïð¸ᡂ
ñஹ·O*+HJC=CHCvCN/DMF-ó"-BA*NSCூL᪆௃᪷Ç᪾ömᔜᱥøḄù᪀@úû
ᩩ¾üýþ~஺ூÿ௃(1)BḄ᪀III,=_vrl-VHᡠB2--1,3-ᵫaªCHrCHCOOCH஺CI~^2}-COTX?H,,ᡠজḄᡂ஺ᫀ!2-T,3-;CH,-CCH-CH,জᡂ஺(2)ᵫCḄ᪀a-Q^OOCH,,ᑣᓄᔠᱥC'ᨵḄ)*+Ḅ,--./ஹ12ஹ34஺ᫀ!--./ஹ1234஺(3)a.5ᵬ7⏚Ḅ᪀!HNCHY^00”ᑣ5ᵬ7⏚Ḅᑖ4C8H15NO2,ᦑa┯<b.5ᵬ7⏚Ḅ

22᪀!UNCHLQ-T00"52>ᙠa-34@ᡠ>ABCᜩᯠ52⏚ᦑb┯<C.5ᵬ7⏚ᑖ4Ḅ7@ᨵFCḄGᡠBHᱥᨵ4CᦑcIJd.ᵫEKᡂ5ᵬ7⏚Ḅ᪾MNOUNCHr-Q-COOHNaBH.NNCO'COOHPQGᡠRS,T3ᦑd;ᫀ!cd஺;ট4
ᵫ5ᵬ7⏚Ḅ᪀!HNCH<-COOH,'ᨵV2W52ᡠNXKYZKᡂ[ᑖ4ᓄᔠᱥ,ᦑ5ᵬ7⏚ᙠB\ᩩ^_Kᡂ[ᑖ4ᓄᔠᱥḄᓄ`ab”HNCH<^-COOH-^c||e1fᫀ!"H:NnXZXCOO~j^*஺5
ᵫDḄ᪀ḄNwcO»COOCH,,tᔠ_ᑡᩩ^!জPQv✏xᓄᔠᱥyz'ᨵ{7ঝᐹᨵ~2yz'ᨵ)*+-N02ঞ᪶ᐳGᨵ3yz'ᨵ3CḄG34,tᔠᩩ^Ḅᑖ᪀:ᫀ:25ஹa■KḄSO2⍎ᡈ◞■ᓄᔠᳮᫀ
2FeS2+15Na2h=Fe2SO43+NaS4+14Na20Pbshᜧ⏚ᴻ¡100mL¢£ூ᪆௃1
¦ᵨ¨W◌ªᵨ«ᙠ[¬_Nᓄᡈ-⏚®ᵨ¯>°ᡠ±²জ〉´ᩞ¶Ḅ·«Aa஺2
±²জ¸@☢ºB»Na2cO3Ḅ¼⌕¾ḄA!■KḄSth⍎஺ᯏÀÁFeSzWNa2O2KᡂÂ⏚ÃWᓄḄᓄ`ab2FeS2+15Na2Ch=Fe2SO43+NaSO+14NaO஺42

23(3)PbSCU>ÄQÅW⏚ᡠ±²ঞ¸ÆᑮḄÈPbSOs(4)±²টÉ>◀ËḄSnCL,ÌSi?+ḄT3ឋÎQFe2+,Ï☢ᵨK2O2O7ÄÐÑ\KᡂḄFe?+Á°ÓὑÕḄKzCmChÄÐÖᯠ°⌼ᡂ®Ḅ'ØÙᜧ஺(5)±²ঠÑ\ÁK2O2O7ÄÐᨵÎᓄឋᦑÛᐸÝÞᙠ⏚Ñ\߸àáâãᑴ1()()mLO.O5moi/LQCHOÄÐ◤⌕ḄᴻæᘤᨵÀèஹéᜮÑßஹᴻ¡W100mL¢£஺26ஹABCD5~6minë5ÄÐḄᵨ>ᡈpH>NHìíḄî⁐ðñᙠNaOHòᙠ_ó3ôõNHyHzOḄᑖ⍎N%,ôöAg(NH3)2++2H2஺=Ag++2NHyH2஺ø⊝Iᔣûüc(Ag+)ýᜧAg\OHKḄAgOHþᓽᓄAgO:Ag++2OH=AgOi+HOᱥAgClḄAg2sCh2223Ag+4HNCh()=3AgNO3+NOf+2H2Oூ᪆௃(1)ᮞ⁐ᨵAgOHAgzO,ᨬ!ᱥ"ᙳ$%&'(2)জᵫ)*1)*4+ᙠ5~6min-.'ঝ᪷1⊤3ᦪ15ᵨ7ᑴ9:;ᑖ᪆'(3)᪷1ᱥ"Ḅᡂᑖ>ឋ"@ᔠB⊝DEFᳮᑖ᪆HḄIJAgOḄFK'2(4)FeCbFe2(SO4)3Ḅ□MNOPKQR▢MNḄTὃ⇋஺XᓄYḄZ⏚YRB⊝ᑖ᪆஺ூ\௃পᔣ%&_`ab⏚Y✌ᐜeHfᑖghiAgNO3+NHyH2O=AgOH+NH4NOAgOHjkl%&3,meHghAgOH+2NHH2O=Ag(NH3)2OH+2H2OghHḄAgOHnop,meHᑖghi2AgOH=AgO+H2O,32ᑖHḄAgzOrml%&sᑮuvᓄw%ᔠYghxyziAg2O+4NH3H2O=Ag(NH)2OH+3HO,ᦑᔠ32ᳮ⌱⚗~ABCDফজY%Ḅ:1mL,Ḅ:3`&60࠷,ghᔠpH11ᵫ)*1)*4+YḄ.~ᙠ5~6min-.'ঝ᪷1)*1ஹ2+ghnPY.nP'᪷1)*1ஹ3+iḄᵨ:nPY.nP'ᙠᐸᩩOPḄpHnPY.rmnPᦑghᱥḄᵨ:ᡈpHY᠒Ḅ'বজᙠY%_ᨵAg(NH3)OH,ᱥ"ᙠ_ᙠB⊝iAg(NH3)2++2H2O=Ag++2NHyH2O,2NH3+H2ONH3H2ONHZ+OH,a¡aᐭ£ᵯMB⊝⌮ᔣDE¦&ᔠ%ᑖH%IᦑIJᓄ§zNH3,᪷1%IḄ&¨£ឋᵨ©ªḄ«⁐¬®*¯°±9²⁐³H´%I'ঝHᡂAgzOḄFK~iᙠNaOHᙠµa¶·NHyHzOḄᑖ⍎N%¶¹Ag(NH3)2++2H2O=^Ag++2NHyH2OB⊝ºᔣDEc(Ag+)»ᜧAg\ONghHḄAgOH½ᓽᓄAgzO:Ag++2OH=AgO+H2O2(4)FeCbFe2(SO5Ḅ□MN¿~Fe3+,▢MNnPÀᙠÁ°ÂÃḄYeᵨFeCbÁḄᦔÅÆ

24Fe2(SC>4)3~ᵫC1ÈAg+@ᔠÉᡂḄAgCl~ÊឋḄᱥ"ÀS(V-ÈAg+@ᔠÉᡂḄAg2sOÌÍ&ᱥ"ḄiAg2SO4>AgCl,ᱥ"ḄÎÎÏ᧕Éᡂᱥ"¹Yᓫ"ÒÏ᧕ÀÁÓKQ¹ᵨFeCk(ÔFe2(SOSÁᦔÅÒÕ஺ூÖ×௃Ø⚪ὃÚ´ᱥ"ឋ")*ḄÛÜᱥ"Ḅឋ")*Fᳮ~Ø⚪ÝḄᐵßàá⌕5ᵨÔx;᪷17ᑴ9:;ã⊤ᦪ1nPÖ·äᑖ᪆+⍝Y%ᑴᜓx;çèὃÚ§H)*jéஹᑖ᪆ê⚪ஹë@ìíjé஺27ஹecdabf11:7îïð`ᑮNaClO_ᡈñ`a,¿m¹ñ:ḄNaClOvᓄ&ᔠòóô᳛■÷Ớᓣú2IOT+3N2H0H2O=3N2t+21-+90N2H"IhOlvᓄḄᱥN2H2O,nûᐭᩖ"ý94.5%ூ᪆௃(1)জᑴþÿ⏚ᓄᔠᐜᑭᵨCᑴB◀ḄᓄAᑮᔠᨬ!ᑭᵨD"#$ᜐᳮᦑ()*+,ecdabfCh-ᡂCK1/ClCh,12ᓄḄ3ᓄᔠ4ᑖ6ᵫ34ᓣ9,+14+54CIO-/C1O3-Ḅᱥ<Ḅ=>?@A,61,ᑣCDCKT,6mol,CIO3,ImoL2ᓄḄClᐳ,7mol,ᜫᵯHḄIᱥ<Ḅ=,6moix(1-3)+lmolx(5-3)=llmol,ᓄJKᓄᑺJKᑺ@MᜫᵯHᦪOPQCL-ᡂKCI12JKḄ3ᓄᔠ4ᵫ34RS,-14ᑣᑮᵯHḄᱥ<Ḅ=T,7mol,ᑣ2JKḄClḄᱥ<Ḅ=,Umol,ᡠV2JKḄᐗX2ᓄḄᐗXḄᱥ<Ḅ=@A,llmol7mol=ll7ঝ〉=AḄᔠ⌲\]ᐭᑮ_=Ḅ`XaᑴᜓcᔠῙef\]*+ghi᎔k\]l?ghmn`X\ᑮNaClOaᡈm\]pqr=ḄNaClOaᓄcᔠῃRSt᳛v(2)জ“ᔠᡂ”3,■zỚᓣ|}?g~73࠷ঝᙠ“JK”3⌕ὑ3-ᡂḄtᱥIO,N2H40/103-ᡂᑣ2JK,ỚH,33ḄH3,2KV+3N2H4H2O=3N2T+2I-+9H2O;TCVᵨᓄᡈJKỚ⏚ᑴᜓỚᓄcᔠJKᑴḄt?9ᐸK1N2H402ᓄ!Ḅtᱥ,N2H2O,gᐭᩖ

25HH28ஹFM9sp\sp2H-B-N-HPC1\PC16¶ὅ¸KHᙳºsp3ᩖᓄPCbᑖHPKH4HHᨵ¼½ᵯH¼½ᵯH¼ᡂ¾ᵯH¼¿ÀᜧPC1JPÂᨵ½ᵯH¼ÃÄ☢Æ□H¾ÈᜧÉPCbḄ0;——0——Oஹ/¾È0H9412ூ
᪆௃পÌÍCVÎaஹbஹcஹdp1ÏÐᕜÒᐗXḄᓄᱥḄÓÔᵫÉNH3ஹH2OஹHFᑖHMphÆᡂ¾rÕÖḄÓÔᓣ9×ᨵCH»ᑖHMghÆᡂ¾ᡠVÓÔᨬSÌØd,CH4ḄÓÔe,SiWḄÓÔ஺ᙠÆᡂᓄᱥḄᑖHHFÆᡂ¾Ḅh=ᨬᜧÓÔᨬ9஺ফ(CH3)3C+HCH3-4ᵯH¼ᦪ,4,/3Ù-CH3P(ḄC,4ᵯH¼ᦪ,3,ᵫÚCÛ_ÜKHᩖᓄ஺(3)ÝÞß1àßḄQᵯHᑣÝÞßḄá᪀ã,H2NBH2,ᵫÚCäᐸá᪀஺(4)PCkᨔÃÄ☢Æ□H,ABa+æÃç☢Æ▢H,ABs-æᵫÚC¶éHḄᓄêvÃÄ☢Æ□H¾ÈᜧÉPCbḄ¾ÈᐸKC̽ᵯH¼Ḅ᣸¿ᵨ"#ᑖ᪆஺মÌîᓄÞᨔKHḄᑖᦪᙶ᪗CVÎBKHᙠñḄ⚔Ô☢óôAsKHᙠᨔõḄçÙöñḄó஺জ÷ᓄÞᨔõḄøùÍBKHúÉÃÆḄóஹ⚔Ôûó4ÙAsKHúɼÈük⚔ÔÄᑖ@ᜐ஺ঝ/ồKHþÿḄ
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௃(1)ᵫ!ᑖ᪆$%d&CH'Ḅ(e&)*Ḅ(஺ᙠ+ᡂ-ᓄᱥḄᑖ0HF+ᡂ-1Ḅ23ᨬᜧ(ᨬ6஺789*aஹbஹcஹdஹe;<ᐗ>ᵯ@ឋᨬᜧḄBF,ᙠSiḄC᝱0᪶᜜ᵯᓰHḄᨬ62IJK&M,L2IᐹᨵḄO⍝(ᒹR3sஹ3pஹ3dᡠᐹᨵḄO⍝)ᦪᐳ&9஺Vᫀ&XFM9ফ(CH3XC+Y0CH3-Zᵯ;ᦪ&4,3-CH3[ḄC,Zᵯ;ᦪ&3,ᵫ$\]^ᩖᓄ`ᑖa&Sp3ஹSp2oVᫀ&XSp\Sp2;HH(3)c
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dḄh᪀j`&H2NBH2,ᵫ$k*ᐸh᪀`&H-1-mHoVᫀ&XHHHHIITHH-IrHH(4)PCkᨔ0op☢+□Y<&AB,+sot☢+▢Y<&AB6-sᵫ$9*wxYḄᓄy`ᑖa&PCI4+ஹPC16op☢+□Y01zᜧPC13Ḅ1zᐸ{BXwὅ}ᙳsp3ᩖᓄPC13ᑖ0Pᨵ;ᵯ;ᵯ;ᡂ1ᵯ;ᜧPC1J0Pᨵᵯ;op☢+□Y01zᜧPCb

26Ḅ«஺{ᫀ#}PC14\PC16-¬ὅ®=>ᙳ¯Sp3ᩖᓄPC13ᑖ>P=>ᨵ%s±ᵯ>s±ᵯ>`sᡂᵯ>s²³´ᜧPC14+Pµᨵ±ᵯ>s¶·☢¸□º>«ᜧOPC13Ḅ«a(5)»¼ᓄ½ᨔ=>Ḅᑖᦪᙶ᪗ÁÂÃB=>ᙠÄḄ⚔Æ`☢Ç}As=>ᙠᨔÈḄÉ./ÄḄÇ஺জồᓄ½ᨔÈḄËÌÍB=>ÎO¶¸ḄÇஹ⚔Æ`ÏÇ4.As=>ÎOs«ÐJº⚔Æ·ᑖ£%ᜐ஺ঝÒồ=>ÓÔḄ½=>ÎO/ÄḄÇÕ=>ÎO/ÄḄ⚔ÆᑣÒ¼=>ÓÔḄ½=>ᨵ4.aÒ0.½=>(Ön½=>ᙠÄḄ⚔Æ)ÓÔḄ½=>ᙠ×ØOn⚔ÆḄÙ.☢Ç,ᑣÒ0.½=>ÓÔḄ½=>ᨵ12.஺{ᫀ#}412oூÆÚ௃ᙠÛÜÒ½=>ݺᨬÞJ×NḄ½=>ᡃàÖáâOãäᐸᕜå½=>ᡠᙠÎḄ%.½=>ᓽᙠᨔÈè«Ḅ½=>éêO8.ᨔÈ஺ᙠ0.ᨔÈÒéݺᨬÞJ×NḄ½=>ᑖëÎO×ØḄÙ.☢Ḅ☢Ç0.3☢êO¬.ᨔÈᑣÒ0.½=>ÓÔḄ½=>ᨵ%x8=12.஺229>>22.5x103,ᡈ0.0625136.62NO2+8e'4O2+N216ூ᪆௃(1)ᓣíîïKᙠðᜧñò¶ᔣóôᓣîᔣᔾö!ᔣóôᓽ¶ᔣ#ᔾö!ᑣH>0஺(2)÷!ø᳛ú"#Vi=Kixcm(NO)-c-(O2),2.5x10-3=KiEx0.01mx0.01n,5x103=Kix0.01mx0.02n,4.5x102=Kx0.()3mx0.02"᪷m1ஹ2¬.N"×◀ýÃn=1,᪷m2ஹ3¬.N"×◀ýÃm=2,þ᪷mÿ1
iE,KJE=2.5X103L2•mol'2,s'1.641বজḄ⊝ᦪK=K=-=—,Ppঝ4s(ᶍ)ᘤ!"#$!Ḅ1/2,6s%&'ᑮ⊝)K=Pg஺+)=—.P46.75216(4)᪷01234NO2ᙠbᵯ᩽"#89)ᐸᵯ᩽#2NO2+8e-=4O2-+N2«ூ௃(1)ᓣ<=>)Kᙠ"ᜧ)@ABᔣDE)ᓣ=ᔣᔾGHᔣDEᓽBᔣ#ᔾG)ᑣK!!>(),ᦑPᫀ#R>«ফUVW᳛Y#Vi=Kixcm(NO)•cn(O),2.5x10-3=Kx0.01,nx0.01n,5x103=Kix0.01mx0.02n,4.5xl022iE=KiEx0.03mx0.02n,᪷01ஹ2\
]◀n=1,᪷02ஹ3\
]◀m=2,_᪷0`1
KE=2.5X103L2-mol'2-s1,ᦑPᫀ#R22.5x1*

27বজḄ⊝ᦪKp=Kp=3=ᦑPᫀ#Rঝ4saᶍbᘤ!"#$!Ḅ1/2,6s%&'ᑮ⊝)K=,ᑣc46.75216PNO
=136.6kPao244
᪷01234NO2ᙠbᵯ᩽"#89)ᐸᵯ᩽#2NCh+8e—=402-+ᵨ+ᦑPᫀ#R2NO+8e-=4O2"2+N20